The Rodderberg Volcanic Complex (RVC) is well-known for the long climate record archived in its crater basin, which lasts for several glacial-interglacial cycles. However, a detailed chronological framework is still lacking. Here, we perform high-resolution luminescence dating on a 72.8 m-long sediment core with the optically stimulated luminescence (OSL) signal from fine-grained (4–11 μm) quartz and three kinds of post-infrared infrared (pIRIR) stimulated luminescence signals from fine-grained polymineral fractions. Together with magnetic susceptibility, grain size and quartz OSL sensitivity measurements, a numerical age framework is built for the upper half of the sediment core. Quartz OSL ages align well with pIRIR ages for the last 45 ka, but they underestimate in relation to pIRIR ages for ages beyond 45 ka. The three pIRIR signals, including the pIRIR signal at 225 °C (pIRIR225), the pulsed pIRIR signal at 150 °C (pulsed pIRIR150) and the multi-elevated-temperature pIRIR at 250 °C (MET-pIRIR250), yield consistent ages up to ca. 250 ka at a sediment depth of 37.5 m. Below that depth, dating limits of the protocols are reached. Nevertheless, our results indicate that sediments below 37.5 m predate Marine Isotope Stage (MIS) 7. Altogether, obtained ages reveal continuous dust accumulation during MIS 7 and MIS 6. One erosional event happened at the end of the Eemian (MIS 5e), which eroded the Eemian soil. The sedimentation rate during the Weichselian glacial period is tenfold lower compared to the sedimentation rate observed during MIS 7–6. This low sedimentation rate likely arises from the cessation of slope wash effects and the occurrence of various wind erosional events alternating with dust deposition as the basin is filled by dust. A notably high sedimentation rate is observed at the transition from MIS 6 to the Eemian, marked by the deposition of a 7 m-thick loess layer between 135 and 129 (±5) ka. This high sedimentation rate could be attributed to intensified slope wash and solifluction processes resulting from the thawing of permafrost at the time of deglaciation. Alternatively, it might be a signature of Heinrich event 11, during which strong winds brought large amounts of dust into the basin within a short time.