Solid Source Research Articles

Mechanistic insights into the pH-driven radical transformation of the Fe(II)/nCP in groundwater remediation.

Calcium peroxide nanoparticles (nCP) as a versatile and safe solid H2O2 source, have attractedsignificant research interst for their application potential in groundwater remediation. Compared to the traditional Fenton system, the nCP-based Fenton-like system has a wider pH-working window for contaminants degradation. This results from the dominant radical transformation under different pH. Unlike the traditional Fenton system which is only effective in acid conditions with hydroxyl radical (•OH) as the main active species, the release of H2O2 and O2 from nCP provides multiple contaminants degradation pathways. In acidic environments, •OH and Fe(IV) predominate as the active species, facilitated by substantial H2O2 production which activates the Fenton reaction. In neutral or alkaline conditions, the production of H2O2 was dramatically decreased. While the O2 released from nCP can be catalyzed by Fe(II) to form superoxide radical (•O2-), which subsequently generate singlet oxygen (1O2). The formation pathway of •O2- was tracked by O18 isotope labeling experiment. The impact of the water matrix on radical generation in the Fe(II)/nCP Fenton-like system was also studied. This research deepens the understanding of the radical formation mechanisms in nCP-based Fenton-like system, offering insights to support their application in remediating contaminated groundwater.

A Review on Photovoltaic Model Cleaning Robot

The PV Sun oriented Board made a difference us tackle the control of the sun and change over it into electrical vitality with adequate productivity and comfort. Sun powered vitality is one of the most solid and maintainable sources of renewable vitality. But the productivity is unfavorably influenced by the collection of tidy, fog, winged creature droppings, and snow and in this manner it is the require of the hour to have normal cleaning of sun oriented boards. Along with the planned cleaning, it is moreover basic to have fitting and viable sun based board cleaning. Customarily, Sun powered boards are cleaned physically. The impediments of manual cleaning are non-uniform cleaning, detachment, harm to boards, hazard of human casualties (particularly in roof- top boards) and development troubles. The labour-hire is too a lumbering errand for PV board cleaning. The errand of PV board cleaning gets to be troublesome an exorbitant if work is contracted. The drawback can be overcome with the offer assistance of an robotized mechanical cleaning arrangement. This extend, we propose an programmed sun powered following framework with an programmed cleaning solar-based instrument to keep up the effectiveness of sun powered boards. The plan, execution, and appraisal of a sun oriented following framework with an programmed board cleaning component are secured in this venture. By expanding sun powered vitality retention and protecting the cleanliness of sun oriented boards, the framework looks for to increment the viability of control era.

Nutri-Score : what can we tell patients about this current scientific topic?

Issues such as the Nutri-score is regularly in the media spotlight like those of PFAS and 5G which are discussed in a second article. The model of the physician possessing all medical knowledge is evolving. Patients now come to consultations with information from a variety of sources, some of which are exhaustive, some of which are not. How can we keep our knowledge up to date on recent scientific topics that are regularly in the spotlight and evolving? Where can we, as a healthcare professionals, find reliable, up-to-date information to discuss the subject during the consultation? This article summarizes information from a variety of solid sources, which we hope will serve as a knowledge base for your discussions.

PFAS and 5G: what can we tell patients about these two current scientific topics?

Issues such as PFAS and 5G are regularly in the media spotlight like this of Nutri-Score which is discussed in a second article. The model of the physician possessing all medical knowledge is evolving. Patients now come to consultations with information from a variety of sources, some of which are exhaustive, some of which are not. How can we keep our knowledge up to date on recent scientific topics that are regularly in the spotlight and evolving? Where can we, as a healthcare professionals, find reliable, up-to-date information to discuss the subject during the consultation? This article summarizes information from a variety of solid sources, which we hope will serve as a knowledge base for your discussions.

Analytical Model for Heat Transfer Around Energy Piles in Layered Soil With Interfacial Thermal Resistance by Integral Transform Method

ABSTRACTEnergy piles are commonly deployed in vertically layered geological conditions due to the geological structure and pile foundation backfill. The imperfect contact between adjacent soil layers results in resistance to heat transfer at the interface, known as the interfacial thermal resistance effect. In this paper, the energy pile was simplified as a finite‐length solid cylindrical heat source, and an analytical model was established for layered heat transfer of energy piles considering the interfacial thermal resistance effect. The Laplace‐domain solutions to the temperatures in the layered ground were derived by using the finite Hankel and Laplace transforms. The Crump method was subsequently employed to numerically invert Laplace‐domain solutions to the time‐domain solutions. The proposed model was validated by comparing with an analytical solution of a homogeneous model and COMSOL numerical solution. These solutions were used to analyze the temperature response around energy piles considering interfacial thermal resistance. Finally, a parametric study was performed to explore the effects of interfacial thermal resistance and other thermal properties of the soil layer on the layered heat transfer of energy piles.

Contribution of ingestive/dietary uptake to bioaccumulation of organics in worms

Ingestive uptake is critical for understanding the accumulation and trophic transfer of chemicals and synthesized particles in general. This study explored the contribution of ingestion in the bioaccumulation of chemicals focusing on worms. Novel theory and equations were developed to derive fractional ingestive contribution, fs, from a broad range of dietary uptake and accumulation studies, and to build a small dataset of fs (n = 43) from relevant toxicokinetic and bioaccumulation measurements. Worm fs could be fitted to log KOW-based sigmoidal models with small errors (RSE < 0.15, RMSE<0.15). The basis and limitations of the applied fs equations were elaborated. These included the assumption that aqueous-based and dietary-based elimination rate constants (kTw and kTS) may be statistically equivalent, as demonstrated using fish and worm data. Bioaccumulation and toxicokinetic parameters obtained at under-exposed conditions can also result in non-sensical, negative fs. The developed fs theory suggested a novel way to model bioaccumulation in the presence of aqueous and solid sources, and the potential to consolidate bioaccumulation data in their variant forms and definitions for assessment, modeling, and benchmarking purposes. While the presented fs-log KOW dependence remained to be explored in other species, the importance of ingestive uptake for high-log KOW chemicals questioned the validity of characterizing and regulating bioaccumulation potential of hydrophobic organics – for which dietary uptake matters – using aqueous-only bioconcentration factor (BCF). This question, along with other less important ones, is yet to be explored in future works.

Low-frequency contact-electro-catalysis driven by friction between the PTFE-coated fabric and dye solution

The process of contact electrification occurs when two materials with dissimilar work functions are in contact and charged. Contact-electro-catalysis may occur when electron exchange at the liquid-solid interface initiates a redox reaction. This type of catalysis falls under the mechanically-driven tribocatalysis and has been demonstrated to be able to degrade dye under high-frequency ultrasonic excitation. In this work, a high RhB dye decomposition ratio of 91.5% is achieved by harnessing the ordinary low-frequency solid-liquid friction energy through the design and use of the recyclable fabric with PTFE coating as a solid friction source to agitate the dye solution. In the absence of PTFE coating, the RhB dye decomposition ratio is about 14.8% under the same friction conditions. The enhanced contact-electro-catalysis may be attributed to the high electronegativity of PTFE coating. According to the quenching experiments with active species, it is found that hydroxyl radical (·OH) and superoxide radical (·O2-) are the main active species induced by low-frequency solid-liquid friction. The fabric with PTFE coating after being dried and reused for 5 cycles still possesses 87.9% RhB dye decomposition ratio. With these advantages of high decomposition ratio of organic pollution, low cost, good recyclability, and environmental friendliness, the developed low-frequency contact-electro-catalysis in this work, is potential for organic wastewater treatment application through utilizing waste solid materials to harvest the mechanical friction energy between solid waste fabrics and ordinary waterflow in future.

Synchronous bioremediation of vanadium(V) and chromium(VI) using straw in a continuous-flow reactor

Vanadium (V) and chromium (Cr) are key resources widely used in industrial production. However, mining causes V(V) and Cr(VI) contamination in groundwater, posing health and environmental risks. Straw is an important byproduct and considered waste, however, it could be a solid carbon source. Therefore, the feasibility of V(V) and Cr(VI) bioremediation in groundwater was determined using straw as the carbon source in this study. A continuous-flow reactor able to resist fluctuations in pollutant concentrations in groundwater was constructed. V(V) and Cr(VI) were completely removed (100%, 10-34 d) in the reactor, and the maximum Cr(VI) removal rate from effluent was 1.19 mg/(L·h) (34-64 d). After long-term reactor operation (114 d), the V(V) and Cr(VI) removal rates reached almost 100%. Moreover, the formation of humus and tryptophan contributed to V(V) and Cr(VI) bioremediation. The extracellular polymeric substance content increased from 108.28 to 113.98 mg/g VSS, and combined with V(V) and Cr(VI) to reduce their concentrations. Moreover, functional microbes associated with heavy metal removal (Bacillus and Pseudobacteroides) and straw decomposition (Paludibacter) were found. The findings of this study offer empirical evidence that support the utilization of straw for mitigating composite heavy metal pollution, thereby laying a foundation for its practical engineering applications.

Realizing single-layer graphene by simultaneous crystallization and top-down etching of amorphous graphene-like carbon obtained via CVD

Continuous large-area graphene can be obtained on copper by utilizing solid polymer carbon sources (SPCS). However, the detailed conversion process and related mechanisms have been rarely reported. Here, a low-temperature chemical vapor deposition (CVD) combined with high-temperature hydrogen annealing (HTHA) method is designed to investigate the intricate evolution process from SPCS to amorphous graphene-like carbon (AGLC), and subsequently to single-layer graphene (SLG). During low-temperature CVD process, under catalysis of copper and auxiliary catalysis of hydrogen, the pyrolysis products of SPCS undergo nucleation and growth on copper, resulting in the formation of AGLC at 500 °C. During subsequent HTHA process above 1000 °C, the conversion of AGLC to continuous SLG can be achieved through simultaneous catalytic crystallization of copper and top-down etching of hydrogen, which sequentially undergoes coexistence stage of AGLC/few-layer graphene (FLG), followed by FLG formation stage. Under different stage and conditions, there exists a synergistic-competitive relationship between catalytic effect of copper and etching effect of hydrogen. The proposed conversion mechanism can provide fundamental insights into SLG synthesis via SPCS, which could facilitate further advancements in large-scale industrial applications of graphene.

Synthesis of 3-Benzazepines via Cobalt-Catalyzed C-H Bond Functionalization with CaC2 as the Acetylene Source.

Herein, we report a simple method for the synthesis of 3-benzazepine derivatives via a cobalt-catalyzed, picolinamide-directed α-amidoacrylate C(sp2)-H bond functionalization approach. The reactions utilize calcium carbide as an inexpensive, easy-to-handle, and solid acetylene source, and simple CoCl2 as the reaction catalyst. Excellent functional group tolerance is observed, yielding diverse substituted 3-benzazepine derivatives in good to excellent yields.

Fingerprinting to trace sources of suspended solids in the transport of heavy metals in urban stormwater runoff

Suspended solids are an important pollutant in urban stormwater runoff. Past studies have mainly focused on a single transport stage of pollutants, constraining source identification of suspended solids at the catchment scale. Therefore, identifying the sources of suspended solids in stormwater runoff for the formulation of effective pollution mitigation measures is an effective way to manage suspended solids pollution in receiving waters. Sediment source fingerprinting is a widely used technique to trace the sources of river sediments, which can accurately identify the source of sediment through widely used tracers. This study used six heavy metals including Cd, Cr, Ni, Cu, Zn and Pb as tracers to quantify the sources of suspended solids in stormwater runoff from urban catchments. The spatial and temporal distribution characteristics of suspended solids during stormwater transport were investigated. The study results showed that the concentration of suspended solids was the highest in road runoff and sewer flow, especially particles <44 μm. In addition, relatively large rainfall depth, high rainfall intensity and long antecedent dry periods can lead to higher concentrations of suspended solids in roof and road runoff whereas longer rainfall duration can result in more suspended solids in sewer runoff. Sediment source fingerprinting and principal component analysis confirmed that coarse (>105 μm) particles primarily originate from road deposited sediments (63.80%), while fine (<105 μm) particles primarily originate from stormwater grate sediments and soil. The outcomes derived can help to comprehensively understand the sources of suspended solids and provide guidance for the management of urban stormwater particulate pollution, as well as being a technical reference for pollutant source traceability in urban stormwater runoff.

Three-component carbonylative Michael addition of aryl bromides using abundant metal-carbonyl under light

Carbonyl compounds are widely found in various chemical reactions and natural products. Herein, a light-driven carbonylative cross-coupling reaction of bromobenzene was reported. Co2(CO)8 was used as an abundant solid carbonyl source to synthesize various Michael addition products with high yields. This reaction has broad substrates scope with good functional group tolerance. The mechanism study indicated that the reaction is achieved by the formation of benzoyl radical from homolytic C–Co cleavage under irradiation.

An ion soft-landing apparatus for ion transport study with surface potential measurement.

An apparatus for explorations of ion transport in a medium and across an interface has been constructed. The ion soft-landing technique is used to deposit low-energy ions onto a pre-adsorbed medium layer on a metal substrate. The designed low-energy ion source can produce a mass-filtered ion beam with tens of nanoampere from solid sources such as bulk metals and salts. The kinetic energy of the ion beam can be lower than 1.0eV, enabling the ions to be soft-landed onto the medium at the surface. A Kelvin probe with a resolution of less than 32 mV is incorporated to measure the surface potential (SP) variation of the ion-landed sample to monitor the ion transport process in the medium. Temperature-programmed SP measurements on an Ag+-adsorbed ice film prepared on Pt(111) reveal that the temperature threshold for the Ag+-induced SP change of the ice film is about 110K. The apparatus performance demonstrates its potential in studies of ion transport and related phenomena at both macroscopic and microscopic levels.

Enhancing nitrogen removal by simultaneous nitritation and denitritation in a multi-cycle SBR with supplementation of solid carbon sources

Simultaneous nitritation and denitritation have the potential to significantly improve nitrogen removal in sewage treatment processes. However, their application in low-strength sewage treatment systems presents challenges. This study explored the impact of four solid carbon sources (SCSs) on N-removal via nitrite in a multi-cycle SBR with biocarriers. Results showed that both N-removal efficiencies and nitrite accumulation rates increased with higher COD/N ratios, indicating that high COD/N ratios can improve the competition between denitrifiers and nitrite-oxidizing bacteria for nitrite, leading to stable simultaneous nitritation and denitritation. The supplementation of SCSs further enhanced this high-efficiency N-removal process, with polybutylene succinate (PBS) and polycaprolactone (PCL) showing greater increases in N-removal via nitrite than poly-hydroxybutyrate (PHB) and poly-hydroxyalkanoate (PHA). Moreover, PBS showed the most significant increase in denitrification efficiency in anoxic conditions, while PHA was the most effective external SCS at a moderate level of dissolved oxygen. These findings suggest that the incorporation of external SCSs can facilitate the simultaneous nitritation and denitrification process in multi-cycle SBRs, underscoring the importance of selecting an appropriate SCS for optimizing nitrogen removal in sewage treatment projects.

Insight into using multi-omics analysis to elucidate nitrogen removal mechanisms in a novel improved constructed rapid infiltration system: Functional gene and metabolite signatures

In this study, a laboratory-scale improved constructed rapid infiltration (imCRI) system with non-saturated and saturated layers was constructed, and corn cobs as solid carbon source were added to the saturated layer to enhance the removal of nitrogen. Combined analyses of metagenomics and metabolomics were conducted to elucidate the nitrogen removal mechanism in the imCRI system. The results showed that the hydraulic load significantly influenced the treatment performance of the imCRI system, and a hydraulic load of 1.25 m3/(m2⋅d) was recommended. Under optimal conditions, the imCRI system using simulated wastewater achieved average removal efficiencies of 97.8 % for chemical oxygen demand, 85.7 % for total nitrogen (TN), and 97.6 % for ammonia nitrogen. Metagenomic and metabolomic analyses revealed that besides nitrification and denitrification, dissimilatory nitrate reduction to ammonium (DNRA), anammox, etc., are also involved in nitrogen metabolism in the imCRI system. Although nitrification was the predominant pathway in the non-saturated layer, aerobic denitrification also occurred, accounting for 22.59 % of the TN removal. In the saturated layer, nitrogen removal was attributed to synergistic effects of denitrification, DNRA and anammox. Moreover, correlation analysis among nitrogen removal, functional genes and metabolites suggested that metabolites related to the tricarboxylic acid cycle generated from the glycolysis of corn cobs provided sufficient energy for denitrification. Our results can offer a promising technology for decentralized wastewater treatment with stringent nitrogen removal requirements, and provide a foundation for understanding the underlying nitrogen transformation and removal mechanism.

Enhanced nutrients removal from low C/N ratio rural sewage by embedding heterotrophic nitrifying bacteria and activated alumina in a tidal flow constructed wetland

Rural sewage treatment facilitates nitrogen and phosphorus removal yet can be costly. To address this challenge, a cost-effective embedding material mainly consisting of heterotrophic nitrifying bacteria, activated alumina (AA), and a solid carbon source (HPMC) was applied to a tidal flow constructed wetlands (TFCWs); aimed at stable nitrogen and phosphorus removal under low carbon-to-nitrogen (C/N) ratios. The TFCWs could be shortened to 16 d of startup duration time compared with the control group; and improved the ammonia nitrogen (NH4+-N), total nitrogen (TN), and total phosphorus (TP) removal efficiencies to 98 %, 93 %, and 68 %, respectively. Also, effluent NH4+-N, TN, and TP in the enhanced TFCWs could be stable at 0.52 ± 0.18, 1.23 ± 0.45, and 0.75 ± 0.25 mg/L, respectively. Microbial community analysis revealed that AA and HPMC were enriched Pseudomonas sp., which potentially accelerated the NH4+-N assimilation pathway and phosphate biological removal. Embedding materials-TFCWs can provide new solutions for integrated rural sewage technology.

Continuous oxidation of organic contaminates in soil by polylactic acid-coated KMnO4

Potassium permanganate (KMnO4), as a versatile and safe solid source of MnO4-, received substantial attention from researchers as a potential soil oxidant reagent. In this study, we prepared polylactic acid (PLA)-coated KMnO4 (KMnO4@PLA) to control MnO4- release. The experimental results indicated that the optimal preparation scheme for KMnO4@PLA was a particle size of 1–2 mm, a solid-liquid ratio of 1:3, and a core-shell ratio of 1:3. And the release lifetimes of MnO4- from KMnO4@PLA in aqueous and quartz sand media were 200 hours and 310 hours, respectively, which were 2400 and 33 times longer than the release lifetimes of raw KMnO4. The controlled release of MnO4- from KMnO4@PLA was achieved through the hydrolysis of PLA. And the release process adhered to first-order reaction kinetics and displayed Fickian diffusion characteristics. Moreover, the removal of phenol by KMnO4@PLA in aqueous, quartz sand, and soil media were investigated through batch and flow column experiments. Compared with the raw KMnO4, the KMnO4@PLA exhibited a stronger ability to degrade phenol, due to the mildly acidic nature of the PLA shell. These findings demonstrated that KMnO4@PLA has significant advantages for the remediation of organically contaminated soils.

Mechanism and kinetics of scorodite formation in arsenic-bearing solutions using Fe(OH)3 as a solid iron source

Recently, solid iron sources have been used for scorodite synthesis in arsenic-bearing wastewater from nonferrous metallurgy. Immobilising arsenic-solution as scorodite via iron hydroxide (Fe(OH)3) solid iron source is an important method for controlling arsenic pollution. The evolution behavior of scorodite during its formation in high arsenic solution have been rarely investigated. In this paper, the mechanism and kinetics of scorodite formation using Fe(OH)3 in arsenic-bearing solution were investigated. This work was divided into three parts. Firstly, the influencing parameters were investigated, revealing that the dissolution of Fe(OH)3 and scorodite generation accelerated at lower initial pH and higher reaction temperature. Increasing Fe/As ratio delayed scorodite crystallisation, which was in turn enhanced by elevating arsenic concentration. Secondly, the mechanism of scorodite formation was investigated, revealing that Fe(OH)3 underwent acidic dissolution to form a precursor. Subsequent scorodite formation had a ΔrGmθ ranging from −69.39 kJ·mol−1 to −15.64 kJ·mol−1. Residual As was absorbed and converted into Fe(OH)3@scorodite. Thirdly, the chemical kinetics were investigated, showing that activation energy (Ea) for Fe(OH)3 dissolution was 72.54 and 105.37 kJ·mol−1 at Stages I and II, respectively, whereas it was 105.97 kJ·mol−1 for residual As absorption-conversion at Stage III outweighing the Ea of As-Fe coprecipitation. The restrictive steps were Fe(OH)3 dissolution and residual arsenic absorption-conversion. This proposed method can be applied for environment-friendly treatment of 10－40 g/L of arsenic-bearing industrial effluent for scorodite formation. Overall, this research confirmed the formation of scorodite via Fe(OH)3 and can potentially provide feasible schemes for eliminating arsenic-bearing acidic waste, dust, and anode slime from nonferrous metallurgical processes.

A review of flash flood hazards influenced by various solid material sources in mountain environment

Solid material sources, such as sediment, large wood, and vehicles, intensify flash flood hazards. This paper provides a detailed review of processes involving the recruitment, entrainment, transport, and blockage dynamics of various solid material sources. Results indicate that sediment supplied by processes like landslides and debris flows can obstruct river channels, leading to a sudden increase in flash flood levels. The failure of a barrier dam results in an expansion of downstream inundation areas. Large wood and floating vehicles transported by flash floods and debris flows may directly impact and destroy built structures or form blockages at built structures. Blockages lead to a backwater rise, and the sudden amplification of flow during the failure of these blockages causes more severe disasters. Based on these analyses, the paper proposes future research directions primarily focusing on the changes in sediment burial processes caused by the sheltering effects of building groups. Furthermore, the study aims to investigate the flow amplification effects of large wood and vehicle blockage.

Effect of Si3N4 on the in-situ synthetized non-oxide reinforcements in Al-Al2O3 composites under N2 atmosphere

Al-Al2O3 composite is widely used in high-temperature industry due to its excellent properties obtained through in-situ synthesis of non-oxide reinforcing phases. The effect of nitrogen source on the non-oxide reinforcing phases synthesized in-situ in the Al-Al2O3 composites at 1500 °C was investigated. The results show that when N2-gas is the sole nitrogen source, Al4O4C is the major reinforcing phase formed in the composite due to insufficient nitrogen amount provided. Through the construction of an Al@AlN core-shell structure and spontaneous nitrogen introduction by solid Si3N4 and N2-gas, higher amount of AlN mesophase is generated, and the complete transformation of Al to (Al2OC)1-x(AlN)x solid solution is successfully achieved. However, when Si3N4 content is excessive (i.e. Si/C mole ratio ≥ 1, where Si comes from solid nitrogen source Si3N4, C comes from phenolic resin binder), the stability of (Al2OC)1-x(AlN)x solid solution decreases, and more stable AlN-SiC solid solutions and SiAl4O2N4 are generated as reinforcing phases in the composite. This work provides meaningful information for the phase control of Al-Al2O3 composite at high temperature application.