Soil Rock Research Articles

CO₂ sequestration and soil improvement in enhanced rock weathering: A review from an experimental perspective

AbstractEnhanced rock weathering (ERW) is an emerging negative emission technology (NET) with significant potential for mitigating climate change and improving soil health through the accelerated chemical weathering of silicate minerals. This study adopts a critical research approach to review existing ERW experiments, focusing on the mechanisms of soil improvement and CO₂ sequestration, as well as the economic costs and environmental risks associated with its large‐scale implementation. The results demonstrate that while ERW effectively enhances soil pH and provides essential nutrients for crops, its CO₂ sequestration capacity is highly dependent on variables such as soil type, rock type, application rate, and particle size. Furthermore, the economic feasibility of ERW is challenged by high costs related to mining, grinding, and transportation, and environmental risks posed by the release of heavy metals like Ni and Cr during the weathering process. Notably, significant discrepancies exist between laboratory experiments and field applications, highlighting the need for extensive in‐situ monitoring and adjustment of ERW practices. This study underscores the importance of optimizing ERW strategies to maximize CO₂ sequestration while minimizing environmental impacts. Future research should focus on long‐term field experiments, understanding secondary mineral formation, and refining the application techniques to enhance the overall efficiency and sustainability of ERW. © 2024 Society of Chemical Industry and John Wiley & Sons, Ltd.

Effects of Tide Dikes on the Distribution and Accumulation Risk of Trace Metals in the Coastal Wetlands of Laizhou Bay, China

Tide dikes play a key role in preventing seawater intrusion in coastal regions; however, their effects on trace metal distribution and accumulation remain unclear. This study explored the distribution and enrichment of trace metals (As, Cr, Cu, Ni, Pb, and Zn) inside and outside tide dikes in Laizhou Bay. The accumulative risk of these metals in the two habitats was analyzed by combining their sources. The results show that the average enrichment factor, geological accumulation index, and potential ecological risk index of As in the outside habitat are significantly higher than those in the inside habitat (p < 0.001), which indicates that the tide dike effectively reduces the migration of As from outside to inside habitats. For other trace metals, no statistical differences were found between the two habitats. Based on principal component analysis and redundancy analysis of trace metals and their correlations with soil physicochemical properties, we speculated that Cr and Zn may derive from soil parent material and rock weathering. Cu, Pb, and Ni may be related to atmospheric nitrogen deposition resulting from nearby agricultural activities, and As may come from industrial wastewater or transport through seagoing rivers. The findings suggest that tide dikes effectively block exogenous trace metals but not those from natural sources.

A Computer Aided System for Reservoir Rock Classification

This study is mainly aimed to know the reservoir rocks among core specimens that are obtained during the stage of drilling of exploration oil and gas wells by the processing of the image digitally using a Computer-Aided System. This computerized method has been conducted using two programming languages; Python and Matlab. The Python program is used to segment rock images and classify the extracted features, whereas the MATLAB language has been used to extract intensity features from segmented images. The database used in this project has been collected from two sources, one of them from the Sarier formation (the biggest Libyan oil field) while the second source was from the internet. The images used in this study are sedimentary rocks images, which include sandstone, limestone, and dolomite. As a result, this study has reached that the system, which was used here is capable of classifying rocks and can be used to classify oil rocks or any other type of rocks. Also, it can be used near the well due to certain conditions such as the absence of experts due to the lack of enough database, the study has only introduced the preliminary results as proof of the concept.

Experimental investigation on the temperature-dependent shear strength of frozen coarse-grained soil-rock interfaces by considering three-dimensional roughness

Climate warming has led to landslides, especially the slopes containing soil-rock interfaces. A series of shear tests were conducted on the coarse-grained soil (CGS) rock interface at low temperatures. The interface shear strength comprises the pre-peak bonding strength produced by ice and post-peak residual strength created by friction between the CGS and rock surface. As the temperature rose from −15 to −1 °C, the bonded ice strength at different rough interfaces rapidly decreased by a maximum of 82.99 %, because more than 21.29 % of the pore ice had thawed within the CGS. However, the average interface residual strength had decreased by only 18.56 %, which is consistent with the variation of the internal friction angle of the frozen CGS. The interfacial shear strength was much lower than the shear strength of the frozen CGS below −1 °C and that the shear slide typically occurred at the interface. In addition, as the freezing temperature increased, the impact of the three-dimensional roughness to the interfacial shear strength decreased, because the warm frozen CGS could easily shear rupture and adhere to the interface, reducing the influence of the roughness. Finally, it was demonstrated that the Mohr-Coulomb failure criterion could be employed to predict the interface peak shear strength for different normal stresses. This study aims to determine the mechanism responsible for shear strength reduction at a frozen CGS-rock interface during warming and to provide some references for preventing landslides caused by rising temperatures.

A coupled peridynamics–smoothed particle hydrodynamics model for fluid–structure interaction with large deformation

Fluid–structure interaction (FSI) is ubiquitous in various engineering disciplines, and effectively managing FSI often appears to be the key for successful failure analysis and safety-oriented design. Smoothed particle hydrodynamics (SPH) serves as a potent nonlocal meshfree method for fluid dynamics modeling, while peridynamics (PD) demonstrates exceptional capability in addressing structural dynamics involving large deformations and discontinuities. Thus, leveraging their respective strengths in a combined approach holds significant promise for tackling FSI challenges. In this work, we propose a new peridynamics–smoothed particle hydrodynamics (PD-SPH) coupling model for addressing FSI. A stable and efficient coupling algorithm for data transfer between PD and SPH is put forward. In this coupling strategy, a PD particle directly participates in solving the SPH governing equations when it is identified to be within the support domain of an SPH particle. This can be done since the SPH quantities including the density, velocity, and pressure of a PD particle are naturally attainable within the framework of non-ordinary state-based peridynamics theory. Concurrently, in solving PD governing equations, reaction forces from SPH particles act as external forces for PD particles, determined straightforwardly through Newton's third law. As such, the proposed PD-SPH coupling strategy is straightforward to implement and offers high computational efficiency. Validation examples demonstrate that the proposed PD-SPH coupling model is computationally robust and adept at capturing physical phenomena in diverse FSI scenarios involving breaking free surfaces of fluid and large structural deformations of solid. Moreover, the proposed PD-SPH coupling model is flexible introducing no constraint conditions for applications and can accommodate different particle resolutions for PD and SPH domains. These features enable a broad application range of the proposed PD-SPH coupling model including simulations of explosion-induced soil fragmentation, rock fracture, and concrete dam failure, which will be conducted by authors in the near future.

Estimation of Vs30 and site classification of Bhaktapur district, Nepal using microtremor array measurement

The severe damage observed in the Kathmandu Basin, Nepal, during past earthquakes necessitates a thorough study of the seismic behavior of the basin sediments. As the shear-wave velocity is directly related to the elastic shear modulus of the material, it is essential to determine it to incorporate the behavior of the soil in the design of the structure. Hence, we determined average shear-wave velocity in upper 30 m (Vs30) of soil in Bhaktapur district in the eastern part of the Kathmandu Basin at 73 observation points, employing two methods involving the use of non-invasive microtremor array measurements (MAMs). These MAMs are widely used for determining subsurface soil characteristics by analyzing the ambient vibrations of the ground. The first method involves inversion using a genetic algorithm, and the second is a method for obtaining Vs30 directly from the dispersion curve. We found that Vs30 in the southeastern part of the study area was higher than that in other parts. Conversely, Vs30 in the western region was lower. The calculated Vs30 values were used to classify the sites. The elevated eastern and southeastern areas with high Vs30 were categorized as dense soil or soft rock, whereas the areas with low Vs30 that had suffered significant damage during the 2015 Gorkha earthquake were classified as soft soil sites.Graphical

Failure analysis and deformation characteristics of shield tunnel obliquely crossing ground fissure under earthquake

In order to study the deformation law and failure characteristics of shield tunnel obliquely crossing ground fissure under earthquake action, taking the shield tunnel of Xi ’an Metro Line 8 crossing f3 ground fissure as the engineering background, the 1: 20 shaking table model test method was used to analyze the strain of shield tunnel, the contact pressure with surrounding rock soil, the dislocation of segment and the axial force of bolt in detail, and the seismic damage mechanism and failure characteristics of shield tunnel obliquely crossing ground fissure were obtained. The test results show that under the action of earthquake, the shield tunnel has complex three-dimensional deformation characteristics, among which the vertical deformation is the most obvious. The deformation is mainly concentrated in the location of the ground fissure. The tensile strain and contact pressure of the hanging wall of the tunnel segment are greater than the strain value and contact pressure of the footwall. Because the vertical deformation of the tunnel is the largest, the bolts at the vault and the arch bottom are most obviously pulled. Excavation after the test, it can be seen that the tunnel appeared the phenomenon of ring joint opening, lining cracking and other damage. Under the action of the earthquake, the shield tunnel across the ground fissure is mainly subjected to tensile failure. The failure area is within 10 m from the ground fissure in the hanging wall and footwall, and the total length is 20 m. The closer to the ground fissure, the more serious the damage. The research results provide a scientific and reasonable reference for the subsequent construction and disaster prevention and mitigation design of Xi ’an Metro.

Tracking the Role of Faults on Mudstone Caprock Seals: A Case Study from Beier Depression, Hailar Basin, NE China

To study the oil and gas enrichment characteristics of the reservoir rocks in the second Member of the Nantun Formation (N2) of the F1 fault in the Beier Depression, this research focuses on the mechanism of shortening the sealing time of the regional mudstone cap due to faults and the factors influencing the sealing duration. The period during which the regional mudstone cap seal began is determined by analyzing the relationship between the diagenetic index of the regional mudstone cap and its underlying reservoir rocks and time. This relationship between the rock-formation index and time helps establish the onset of regional mudstone cap seal, and from this, the index of shortening time due to faults is derived. A research framework to study the sealing time shortening of regional mudstone cap seal caused by a fault was developed, which was further applied to analyze the relationship between the fault-induced shortening time of the seal in the lower of the first Member of the Damoguaihe Formation section (D1x) of the Beier Depression and hydrocarbon concentrations in the N2 Formation. The results show that the F1 fault at measurement points 1–4, 6, and 9–11 reduced the blocking time of the regional mudstone cap in D1x to 100%, hindering hydrocarbon accumulation and preservation in the N2. Conversely, the F1 fault at measurement points 5, 7, 8, and 12–15 reduces the blocking time of the regional mudstone cap in the D1x by 37–99%, which is more conducive to hydrocarbon accumulation and preservation in N2, resulting in positive oil and gas shows. Based on the test results, a discussion on the feasibility, applicability, and limitations of the new method is conducted, yielding the following conclusions: (1) The relationship between oil and gas indications in the reservoir rocks of the Nan’er Member confirms the feasibility of the new method. The research findings of the new method on the F1 fault align with current oil and gas exploration realities, indicating its potential use in studying the degree to which faults shorten the sealing time of regional mudstone caprocks. (2) The new method is primarily applicable to the study of the modification effects of tensile normal faults on regional mudstone caprocks and their impact on oil and gas sealing capacities. However, its application to other types of faults may have limitations. (3) The new method is mainly suitable for caprocks dominated by mudstone. When studying other types of caprocks, such as carbonate rocks, evaporites, igneous rocks, and metamorphic rocks, different research methods and technical means are required. These findings provide valuable insights for oil and gas exploration efforts near fault zones.

Organic geochemistry and 1D-basin modeling in the Taranaki Basin, New Zealand: Implications for deltaic-source rocks of the cenozoic oil and condensate reservoirs

The Taranaki Basin in New Zealand is an area of active exploration for oil and condensate. This research focuses on integrating geochemical characteristics and 1-D basin modeling to Late Cretaceous to Miocene source rock systems, along with oil and condensate data from fifty-seven wells in the Taranaki Basin. The geochemical study reveals that the oil and condensate samples were generated from clay-rich source rocks, containing mixed organic matter, with large amounts of terrestrial organic matter input. These source rocks were deposited in fluvial to fluvio-deltaic environments under oxic conditions. The presence of oleanane in both oil and condensate samples suggests that the source rocks had a significant terrestrial component and deposited during the Late Cretaceous to Cenozoic. Using various biomarker proxies, oil-source rock correlation along with 1-D basin modeling revealed that the oil and condensate were mainly derived from the Late Cretaceous Rakopi and Paleocene Farewell formations at different maturity stages. The oils were generated within the peak-mature oil window, while the condensates primarily resulted from the secondary cracking of oil taking place in the source rock within the gas generation window. This finding is consistent with the 1-D basin modeling results. The model shows that the Paleocene Farewell source rock has achieved the primary stage of oil generation (0.55–0.95 Easy %Ro), contributing to most of the discovered oils in the Cenozoic reservoir rocks. Meanwhile, the Late Cretaceous Rakopi source rock reached the gas window with a higher vitrinite reflectance of more than 1.30 Easy %Ro, indicating greater gas generation potential.

Sound absorption properties of different green wall systems

Façade of the buildings generally consists of acoustically rigid materials. They reflect or scatter sound emitting from sound sources especially main roads thus affects sound environment in a negative way. Applying green walls can be nature-based solution to these urban scale noise. The aim of this research is to compare green wall systems in terms of sound absorption and to determine which one is more effective. Sound absorption at normal incidence of 8 different green wall systems measured via impedance tube in accordance with TS ISO EN 10534-2 standard for 50-6400 Hz. The ivy type, evergreen Hedera Helix plant was used. Potting soil or felt or rock wool was used as a growth medium. As a result, it was seen that the sound absorption of the 'plant + 20 cm potting soil + 10 cm air gap' green wall system was higher than the others. It is followed by the system with 'plant + 20 cm potting soil', 'plant + 3 cm felt + 10 cm air gap' and 'plant + 3 cm rock wool + 10 cm air gap' systems. The sound absorption value was found to be lowest when the plant was applied only as a green façade.

Circular economy strategies in sedimentary phosphate mine reclamation: Development of technosol from phosphate waste rock

Proper management of mine waste plays a crucial role in minimizing environmental impacts. One potential solution to tackle this problem involves transforming mine waste rock into soil to facilitate the process of mine restoration. The aim of this study was to assess the mineralogical, chemical, and physical characteristics of technosol derived from phosphate mine waste dumps. Following this evaluation, a novel rehabilitation strategy was proposed. For this purpose, a total of 32 samples were systematically collected across a 4 ha area of technosols, which had been established in accordance with the waste rock soil rehabilitation strategy involving geomorphic reshaping. According to the findings, phosphate mining left the soil with a sandy texture, resulting in a degraded soil structure with severely unfavorable crop growth conditions, notably poor stability, and low water retention. The chemistry of the studied soils was characterized by the dominance of CaO (29.02 wt%± 1.01) > SiO2 (27.61 wt% ± 0.61) > P2O5 (11.34 wt% ± 0.23) > MgO (5.97 wt%±0.16). Mineralogically, the samples were mainly formed by quartz, dolomite, calcite, apatite, and clay minerals. The prevalence of dolomite played a significant role in enhancing the accessibility of Mg as an essential nutrient and the occurrence of apatite in the soil resulted in the presence of P2O5. However, the abundance of Ca was linked to three major minerals: calcite, apatite, and dolomite. X-ray fluorescence analyses demonstrated that the concentrations of Fe2O3, K2O, and SO3 did not exceed 2 wt%.Organic matter, represented by SOC <0.2% and N < 0.02%, demonstrated an extraordinary deficiency in the study area. The analysis of element bioavailability confirmed that the soil was rich in Ca (10383,26 mg/kg), Mg (278,47 mg/kg), Zn (12,82 mg/kg), and Cu (3,7 mg/kg) but deficient in other essential nutrients such as P, K, S, Mn, and Fe. Our research results provide a set of recommendations aimed at enhancing existing mine rehabilitation practices applicable to both pre- and post-rehabilitation phases, leveraging automated mineralogy and circular economy principles. Notably, we propose a rehabilitation strategy to be implemented prior to the geomorphic reshaping phase, which is intended to reduce costs and efforts associated with soil reconstitution.

Rare earth elements enrichment and extraction potential of bauxite deposits in Samar, Philippines

Abstract Rare earth elements (REE) play an integral part of modern life, from smartphones to satellites. Dubbed ‘critical metals’, the demand for REE has significantly increased, driven by the growth in global production for green technologies such as e-vehicles, solar panels, wind turbines, and other energy-economic infrastructure. Therefore, there is a need to explore alternative REE sources to ensure continued development of emerging green technologies. A possible alternative REE source is bauxite, which is soil that forms from intense weathering of aluminum oxide-rich rocks exposed to tropical climate. This paper investigates the REE enrichment and extraction potential from bauxite deposits in Paranas, Samar, Philippines. The sampling survey included collection of rock and soil on surface exposures, test pits, and drill cores from accessible portions of the bauxite mineral reservation site. The soil and parent rock samples collected were then subjected to various geochemical and mineralogical analyses. The main ore minerals of aluminum are gibbsite and boehmite; with minor goethite, hematite, and magnetite. Investigation of the geochemical composition of the bauxite reveals a total REE content of up to ~300 ppm, which is one of the highest REE and critical metal content among geological deposits in the country. These results will provide inputs in the design of a green and economical process to recover REE from bauxites. If the bauxite deposits prove to be a valuable REE resource, this study will help maximize the economic potential of the mineral resource in the Philippines and contribute to an economically efficient and environment-friendly way to produce e-tech elements for the country.

Stable isotopic evidence of cadmium enrichment in soils of black shale distribution areas

Black shale-derived soils exhibit significant heavy metal enrichment, notably cadmium (Cd) enrichment. This study pioneered the reporting of δ114/110Cd isotopic values within a black shale-soil system, offering novel insights into the geochemical behaviors and enrichment mechanisms of Cd during soil formation processes influenced by weathering. Systematic rock‒soil sampling was conducted on the lower Cambrian Hetang Formation in western Zhejiang, China, which is characterized by Cd-rich black shale. Employing analytical methods, including principal component analysis and multiple linear regression, we investigated the factors influencing heavy metal content in soil, such as element dissolution during weathering, soil pH, and the presence of iron-manganese oxides, sulfides, organic matter, and clay minerals. Our findings revealed a compositional range of δ114/110Cd in black shale (1.93‰–3.31‰) contrasting with that in adjacent soils (0.31‰–1.82‰), illustrating significant Cd isotopic fractionation during weathering, where heavier Cd isotopes are preferentially leached, and lighter isotopes are enriched in the soil in association with iron-manganese oxides. This research not only deepens the understanding of Cd enrichment mechanisms within the rock‒soil system against a black shale geological background but also elucidates the formation processes of soil Cd pollution in areas with a high geochemical background.

A new combined finite-discrete element method for stability analysis of soil-rock mixture slopes

PurposeThe purpose of this paper is to propose a new combined finite-discrete element method (FDEM) to analyze the mechanical properties, failure behavior and slope stability of soil rock mixtures (SRM), in which the rocks within the SRM model have shape randomness, size randomness and spatial distribution randomness.Design/methodology/approachBased on the modeling method of heterogeneous rocks, the SRM numerical model can be built and by adjusting the boundary between soil and rock, an SRM numerical model with any rock content can be obtained. The reliability and robustness of the new modeling method can be verified by uniaxial compression simulation. In addition, this paper investigates the effects of rock topology, rock content, slope height and slope inclination on the stability of SRM slopes.FindingsInvestigations of the influences of rock content, slope height and slope inclination of SRM slopes showed that the slope height had little effect on the failure mode. The influences of rock content and slope inclination on the slope failure mode were significant. With increasing rock content and slope dip angle, SRM slopes gradually transitioned from a single shear failure mode to a multi-shear fracture failure mode, and shear fractures showed irregular and bifurcated characteristics in which the cut-off values of rock content and slope inclination were 20% and 80°, respectively.Originality/valueThis paper proposed a new modeling method for SRMs based on FDEM, with rocks having random shapes, sizes and spatial distributions.

3D Stability Analysis of Soil–Rock Tunnel Faces: Pore Water Pressure and Partial Failure Perspectives

3D Stability Analysis of Soil–Rock Tunnel Faces: Pore Water Pressure and Partial Failure Perspectives

Failure mechanism of a tunnel in a soil–rock mixture based on a new combined finite–discrete element method

The mechanical properties and failure characteristics of soil–rock mixtures (SRMs) directly affect the stability of tunnels constructed in SRMs. A new SRM modelling method based on the combined finite–discrete element method (FDEM) was proposed. Using this new SRM modelling method based on the FDEM, the mechanical characteristics and failure behaviour of SRM samples under uniaxial compression, as well as the failure mechanism of SRMs around a tunnel, were further investigated. The study results support the following findings: (1) The modelling of SRM samples can be achieved using a heterogeneous rock modelling method based on the Weibull distribution. By adjusting the relevant parameters, such as the soil–rock boundaries, element sizes and modelling control points, SRM models with different rock contents and morphologies can be obtained. (2) The simulation results of uniaxial compression tests of SRM samples with different element sizes and morphologies validate the reliability and robustness of the new modelling method. In addition, with increasing rock content, VBP (volumetric block proportion), the uniaxial compressive strength and Young’s modulus increase exponentially, but the samples all undergo single shear failure within the soil or along the soil–rock interfaces, and the shear failure angles are all close to the theoretical values. (3) Tunnels in SRMs with different rock contents all exhibit X-shaped conjugate shear failure, but the fracture network propagation depth, the maximum displacement around the tunnel, and the failure degree of the tunnel in the SRM roughly decreases via a power function as the rock content increases. In addition, as the rock content increases, such as when VBP = 40%, large rocks have a significant blocking effect on fracture propagation, resulting in an asymmetric fracture network around the tunnel. (4) The comparisons of uniaxial compression and tunnel excavation simulation results with previous theoretical results, laboratory test results, and numerical simulation results verify the correctness of the new modelling method proposed in this paper.

Mechanism of Instantaneous High-Strength Sand–Water Inrush in Steeply Inclined Mining of Soft Coal Seam under Disturbed Rock–Soil Overburden

Abstract Water and sand inrush pose significant threats to underground geotechnical engineering, including shallow buried resource extraction and tunnel construction. To understand the mechanisms behind these phenomena, a mud collapse accident in Chaider Coal Mine was comprehensively investigated through field exploration and laboratory-based testings. Using numerical simulation experiments, we analyzed the failure patterns and seepage characteristics of overlying strata in steeply inclined coal seam mining under various working conditions. We established a structural instability model for water and sand inrush and identified the critical conditions for sand collapse occurrence. Our research indicates that the backfill in the surface mining pit provided a substantial material source for the accident. The overall destabilization of the top coal, due to its insufficient thickness and strength, created a pathway for sand collapse. Furthermore, frequent rainfall during the flood season and the inadequate arrangement of pumping equipment acted as triggers for the sudden water collapse. Preventative measures, such as limiting the mining height, enhancing the shear strength of the top coal, and altering the working face layout, can effectively control the development height of the water-conducting fracture zone. Additionally, timely evacuation and lowering of the aquifer water level, weakening its seepage effect in the top coal area, reducing the moisture content of the bottom soil, and improving its shear strength can mitigate water and sand inrush accidents in the backfill areas of open-pit mines.

Pore-scale fluid distribution and remaining oil during tertiary low-salinity waterflooding in a carbonate

The utilization of low-salinity waterflooding as a promising enhanced oil recovery method has exhibited exciting results in various experiments conducted at different scales. For carbonate rock, pore-scale understanding of the fluid distribution and remaining oil after low-salinity waterflooding is essential, especially the geometry and topology analysis of oil clusters. We performed the tertiary low-salinity waterflooding and employed X-ray micro-CT to probe the pore-scale displacement mechanism, fluid configuration, oil recovery, and remaining oil distribution. We found that the core becomes less oil-wet after low-salinity waterflooding. Furthermore, we analyzed the oil-rock and oil-brine interfacial areas to further support the wettability alteration. By comparing images after high-salinity waterflooding and low-salinity waterflooding, it is proven that wettability alteration has a significant impact on the behavior of the two-phase flow. Our research demonstrates that low-salinity waterflooding is an effective tertiary enhanced oil recovery technology in carbonate, which changes the wettability of rock and results in less film and singlet oil.

Local hydrology control of radiocarbon in stalagmites from the Kyusendo Cave, Kumamoto, Japan

Stalagmite is an important archive of paleoclimate especially in the region of the East Asian Monsoon. Despite the widespread use of radiocarbon (14C) dating to explore past environmental changes, the contribution of a14C-free carbon fraction leached from soil and/or host rocks during stalagmite formation, known as the dead carbon fraction (DCF), impedes its application to stalagmite chronology. Thus, uranium series dating is preferentially used to determine stalagmite ages. However, both U/Th and 14C dating can be applied to stalagmite samples, U/Th can be used to calibrate the radiocarbon ages by assuming a relatively constant DCF contribution over time. Studies exploring DCF changes from glacial to interglacial periods remain scarce, suggesting that temporal and speleothem-specific DCF studies are needed. Here, we present findings on DCF changes over the last 38 ka in speleothems obtained from southwestern Japan. Our analysis includes measurements of both 14C in drip water and speleothem calcite alongside U/Th dating of three stalagmites collected from Kyusendo Cave, located in southern Japan. The DCFs reconstructed from these stalagmites exhibited variations of 37.8%–73.9% between 4.2 and 38.3 ka, which exceeded the typical DCF values reported previously. Intra-test variations of the DCF values in Kyusendo Cave also revealed differences of up to 30%–40% among the three stalagmites. A higher drip water DCF and dripping rate showed a strong negative correlation, indicating that variations in DCF may reflect changes in local hydrology. The study findings suggest that speleothem-specific and temporally varied DCF should be considered in paleoclimate reconstructions using speleothems.

Phosphorus Adsorption as Affected by Concretionary Nodules of Oxic Rhodustalf in Southern Guinea Savannah Agroecological Zone of Nigeria

Hard, rounded masses of mineral matter, known as concretionary nodules, can be found in soil or sedimentary rock. These nodules are typically made up of minerals like iron oxides, hydroxides, and carbonates that have been deposited in groundwater. Their sizes can range from small pebbles to large boulders, and they often differ in composition or hardness compared to the surrounding rock or soil. Nodules act as a highly effective storage space for extra P, leading to a significant increase in overall P requirements. Phosphorus, although an essential element for all living organisms, including plants and animals, is scarce. Despite its importance, only a small fraction of the total phosphorus available can be readily absorbed by plants. Given the worldwide demand for phosphorus in food production, it is crucial to devise techniques for extracting it from different sources. However, there has been limited research on the understanding of phosphorus availability and adsorption mechanisms in these areas. Therefore, the study focused on exploring the impact of concretionary nodules on phosphorus sorption and the characteristics of low-activity clay soil in the Guinea savannah of Nigeria. Soil samples collected from the study area were used to investigate the soil’s ability to absorb phosphorus at depths ranging from 0 to 30-60-90-120-150 cm in different soil and concretion locations. Various soil and concretion types demonstrated distinct capacities for phosphorus adsorption, as indicated by the adsorption isotherm. The maximum monolayer adsorption capacities (Qmax values) were 161.0, 154.5, 149.6, 141.7, 139.8, and 139.3 mg/g for OBC, OBS, OC, OIS, OS, and OIC, respectively. At equilibrium with a 50-ppm solution, the pseudo-second-order rate constants for P sorption were 1.180 x 10&lt;sup&gt;–4&lt;/sup&gt;, 9.740 x 10&lt;sup&gt;–5&lt;/sup&gt;, 1.120 x 10&lt;sup&gt;–4&lt;/sup&gt;, 1.140 x 10&lt;sup&gt;–4&lt;/sup&gt;, 1.000 x 10&lt;sup&gt;–4&lt;/sup&gt;, and 8.010 x 10&lt;sup&gt;–5&lt;/sup&gt; g mg&lt;sup&gt;–1&lt;/sup&gt; min&lt;sup&gt;–1&lt;/sup&gt; for OIS, OIC, OBS, OBC, OS, and OC, in that order. In the 300-ppm equilibrium solution, the OIS, OIC, OBS, OBC, OS, and OC pseudo-second-order rate constants were 1.250 x 10&lt;sup&gt;–4&lt;/sup&gt;, 1.130 x 10&lt;sup&gt;–4&lt;/sup&gt;, 9.550 x 10&lt;sup&gt;–5&lt;/sup&gt;, 1.040 x 10&lt;sup&gt;–4&lt;/sup&gt;, 2.750 x 10&lt;sup&gt;–4&lt;/sup&gt;, and 1.420 x 10&lt;sup&gt;–4&lt;/sup&gt; g mg&lt;sup&gt;–1&lt;/sup&gt; min&lt;sup&gt;–1&lt;/sup&gt;, respectively. At the 500-ppm equilibrium, the pseudo-second-order rate constants for OIS, OIC, OBS, OBC, OS, and OC were 1.240 x 10&lt;sup&gt;–4&lt;/sup&gt;, 1.090 x 10&lt;sup&gt;–4&lt;/sup&gt;, 1.020 x 10&lt;sup&gt;–5&lt;/sup&gt;, 1.100 x 10&lt;sup&gt;–4&lt;/sup&gt;, 2.730 x 10&lt;sup&gt;–4&lt;/sup&gt;, and 1.180 x 10&lt;sup&gt;–4&lt;/sup&gt; g mg&lt;sup&gt;–1&lt;/sup&gt; min&lt;sup&gt;–1&lt;/sup&gt;, respectively. Consequently, the soil adsorption capacity increased with higher pseudo-second-order rate constants.