Seven samples of fly ash and four of spoil area material from the Appalachia coal regions were analyzed by neutron activation (NAA) for elemental abundances. Gross concentrations of Na, Al, Fe, V, and Ti detected appear to corroborate other analytical techniques. Detection of concentrations less than 2000 ppm were obtained for Mn, Co, Sc, Th, U, Tb, Tm and La. Selective separation appears to be occurring in the generation of fly ash and stack gasses for Sc/Fe and Sc/Co ratios normally anticipated in crushed coal. The diversity of trace elements which may be involved in leaching processes and subsequent environmental hazards are not well known nor established at this time. Trans. Kans. Acad. Sci., 76 (1), 1973. Introduction Fly ash residues from coal-fired electrical generating plants have been proposed as soil modifiers to neutralize coal strip mine spoil areas in grassland reclamation projects throughout the United States. Fly ash tends to concentrate the trace elements inherent in the original coal beds from which this by-product is produced. A paucity of data exists in studies of the micro-constituents which may be present in beneficial or harmful concentrations to substantially affect the physiology of plants and animals within the food subchain created by fly ash-soil modifications. The intent of these studies was to formulate a procedure to identify the nature and concentration of some of these trace elements by neutron activation analysis. Capp and Spencer (1970) considered ten macro/semimicro constituents found in ash as they affect pedology and agronomy. Of the 17 most commonly occurring elements' in fly ash, boron was noted as the principal offender in restricting growth, followed quickly by aluminum and manganese. Duel et al., (1956) reported standard sensitivities of trace elements in mid-continent coals by the semi-quantitative spectrographic method. With the (NAA) method, it is possible to determine more precise concentrations of the microconstituents and their corresponding synergetic or antagonistic relationships when released directly to the atmosphere or by soil water leaching. Pfitzer, Schroeder and others (1971) argue that these unknown trace elements pose an unseen pollution threat in being recycled and dispersed to the environment. Transactions of the Kansas Academy of Science, Vol. 76, No. 1, 1973. Published January 22, 1974. 1 Department of Geology, Wichita State University. 2 Nuclear Engineering Department, Kansas State University [74] This content downloaded from 207.46.13.180 on Thu, 08 Sep 2016 05:05:15 UTC All use subject to http://about.jstor.org/terms