The dry soil layer (DSL) typically forms on the surface of sandy soils during the evaporation process, with water in the DSL moving solely as vapor. Understanding the DSL thickness and its water vapor distribution is crucial for accurately estimating soil water flux, improving evaporation mechanisms, and enhancing ecological conservation efforts. This study employed distributed fibre-optic sensing (DFOS) technology to achieve high spatial resolution measurements (up to 1 mm) of the water vapor distribution within the DSL. We measured soil water vapor profiles in a sand column subjected to evaporation over 24 days using a 60 cm long relative humidity sensing probe and an optical frequency domain reflection (OFDR) interrogator. We effectively captured the downward migration of the evaporating surface from the sand surface and quantified the inhibitory effect of DSL thickness on evaporation using a logarithmic function. Additionally, we identified a linear distribution of water vapor with depth in the DSL. Our findings offer novel insights into the role of DSL in the hydrological behaviour of unsaturated soils and demonstrate the potential of our approach for investigating dynamic changes in in-situ DSLs, particularly in arid and semi-arid regions.