Risk Of Soil Contamination Research Articles

Treatment of biowaste commingled with biodegradable bioplastic films using Black Soldier Fly larvae: Generation and fate of micro-plastics

The use of Black Soldier Fly (BSF) larvae is emerging as a promising alternative for biowaste (i.e. food waste) treatment, generating larval biomass and process residues, suitable for use as animal feed and fertilizer, respectively. In line with an increasing use of starch-based bioplastics in food packaging, the presence of these biopolymers and associated biodegradable microplastics (BMPs) in food waste is expected to rise. Knowledge of the generation of BMPs and their fate in the BSF treatment process is scarce, or indeed, completely lacking in the case of small-sized BMPs (<50 μm). The present study aims to investigate the generation and potential accumulation of BMPs in BSF larvae process. Food waste mixed with starch-based bioplastic films was fed to larvae and BMPs of two particle sizes (inferior to and exceeding 10 μm in diameter) were monitored over time in rearing substrate and larval biomass. BMPs concentrations in substrate were compared with larvae-free control tests. The presence of larvae favoured the generation of BMPs. Concentrations of smaller-sized BMPs (<10 μm) increased by approximately 172% in the final substrate, and accumulated in the larval biomass with a peak exceeding the initial larval concentration by over 1000% just before prepupation, which is the typical stage they are collected when used as animal feed. These results indicate a potential risk of soil contamination by BMPs when final substrate is used as fertilizer and a risk of biomagnification phenomena when larvae are used as animal feed.

Evaluation of soil contamination and health risks associated with consumption of Brassica perviridis grown on various soils collected in Northern Vietnam

Evaluation of soil contamination and health risks associated with consumption of Brassica perviridis grown on various soils collected in Northern Vietnam

Battery-Operated Power Weeding Machines: Advancements, Challenges, and Future Prospects

In recent years, significant advancements have been made in the development and adoption of battery-operated power weeding machines, offering a sustainable and efficient alternative to traditional weed management methods. Previous studies have highlighted several critical benefits of these machines, particularly in reducing labor costs and minimizing environmental impact. Battery-powered weeders have been shown to significantly cut down on manual labor requirements, thus reducing the physical strain on farmers and decreasing the reliance on hired labor. This reduction in operational costs makes them an economically viable option for small and medium-sized farms. Furthermore, the environmental advantages of these machines are notable. Unlike chemical herbicides, which pose risks of soil and water contamination and potential health hazards, battery-operated weeders offer a clean alternative, eliminating the need for harmful chemicals. This aligns with the growing demand for environmentally sustainable agricultural practices. Technological advancements have further enhanced the efficiency and usability of these machines. Modern battery-powered weeders are increasingly equipped with lithium-ion batteries that provide longer operation times, precision sensors for accurate weed targeting, and automated control systems that simplify operation. These innovations have not only improved the effectiveness of weed management but have also made these machines more accessible and user-friendly for farmers. Field trials and studies conducted in various agricultural settings have consistently demonstrated the practicality and reliability of battery-operated weeders, making them a transformative solution in modern agriculture. The integration of these machines into farming practices has been shown to improve productivity, reduce costs, and promote sustainability, solidifying their role as a critical innovation in the future of agriculture. This review article aims to build upon these findings by providing a detailed examination of the design, development, and performance of battery-operated weeding machines, and exploring their broader applications in diverse agricultural environments.

Soil pollution identification and human health risk assessment of soil heavy metals in an abandoned mine area in the Republic of Korea

ABSTRACT In this study, the Geo-accumulation index (Igeo), Human Health Risk Assessment (HRA), and Ecological Risk Index (ERI) were utilized to examine the risks associated with the soils at the DaeyangYeongseong mine. Brassica juncea and Raphanus sativus were employed in the ecological toxicity test. In all soil samples, the mean Igeo value of arsenic measured 3.15, and cadmium measured 6.63, indicating a very high level of heavy metal contamination. The carcinogenic risk of cadmium and arsenic for adults was 4.30×10−3 and 1.43×10−5, respectively. For children, these values were 3.92 × 10−2 and 1.33 ×10−4, exceeding the acceptable level (1×10−6). In all soils, cadmium showed extremely high ecological risk levels, and arsenic had extremely high risk levels in 34.8% of the total area. This was also confirmed in toxicity assessments using plants. Therefore, arsenic and cadmium were found to be the main causes of soil contamination and ecological risk.

Geostatistical modelling of soil properties towards long-term ecological sustainability of agroecosystems

A profound grasp of the quantitative spatial heterogeneity and distribution of the soil physicochemical attributes is crucial in understanding agricultural landscapes for ensuring the provisioning of soil ecosystem services. However, the analysis of data from remote sensing, like NDVI, can be of help in analysing the capacity of the landscape to provide supporting ecosystem services such as primary productivity. The research investigated and addressed the dispersion of important soil physico-chemical attributes in agricultural lands of the temperate Himalayan region of India using a geostatistical method and combining normalized difference vegetation index (NDVI) time-series data and the regression Kriging method. A 206 soil samples were gathered and assessed for soil parameters like pH, EC, OC, and available N, P, K, Ca, and Mg from Kishtwar district of Jammu. The coefficient of variation (CV) for pH and electrical conductivity (EC) ranged notably from 8.75 % to 118.98 %, highlighting diverse soil characteristics critical for local management practices. Mean elevation averaged 2743.32 m (m), with a moderate NDVI of 0.15, indicating dynamics in vegetation cover. Soil pH ranged from intensely acidic to marginally alkaline, with varying EC levels. Seemingly high organic carbon (OC), nitrogen (N), and potassium (K) levels, accompanied by medium phosphorus (P), calcium (Ca), and magnesium (Mg) levels were found in the region. The study employed ordinary kriging (OK) to map the spatial distribution of soil parameters, utilizing mean square error (MSE), root mean square error (RMSE), and the Moran’s I index. Exponential models were the best fit models for OC, while spherical models were fit for pH, EC, N, P, and Ca. Mathematical models were best fit for K and Mg. Spatial analysis using spherical and exponential models revealed distinct distribution patterns for pH, N, P, Ca, and Mg. The results of the degree of spatial dependence from the semi-variogram analyses indicated a strong (0.06 %) to moderate (0.51 %) to weak (2.81 %) dependence. The interpolated maps showed a distinct gradient in elevation (1053–4413 m), OC (0.13–2.80 %), NDVI (−0.16–0.54), pH (4.80–8.00), EC (0.03–9.80 dS m−1), N (201.15–993.19 kg ha−1), P (3.00–96.00 kg ha−1), K (124.88–1110.71 kg ha−1), Ca (7.00–46.00 meq 100 g soil−1), and Mg (2.30–21.50 meq 100 g soil−1) at the regional scale, indicating a wide range of spatial soil heterogeneity. The heterogeneity maps of soil parameters generated by this research can be effectively used by land planners and farm managers at a regional scale for crop nutrient management to reduce soil contamination risk. These maps serve as baseline materials and effective tools for suitable land management strategies such as conservation-effective tillage, integrated nutrient management, and organic farming based on the spatial distribution of soil properties and they can significantly enhance the long-term ecological sustainability of agro-ecosystems’ management.

Monitoring of Herbicide Residues in Agricultural Soils in Vojvodina Province (Northern Serbia)

Pesticides in soils raise concerns about the biodiversity, food safety, and contamination of watercourses, contributing to unsustainable land management practices. Monitoring the residue levels in agricultural soils is essential, as this offers valuable insights into the current extent of soil contamination and potential environmental risks attributed to their application. This study aimed to address the occurrence of the currently used herbicides in soil under intensive crop production, comparing the results of monitoring at two depths (0–30 and 30–60 cm) in 2013 and 2023. The research concerned the main agricultural area in Vojvodina Province (Serbia) and evaluated the presence of 41 herbicides in 128 localities. Pesticides were found in all samples, finding even more than six different herbicides per sample. The significant concentrations of s-metolachlor, etofumesate, clomazone, diflufenican, pendimethalin, and terbuthylazine found can be attributed to application practices, as they are typically applied pre-emergence, either through direct soil treatment with or without incorporation. Moreover, the correlation between different depths, herbicide residues, and soil properties was not significant. The decrease in the herbicide residues found in 2023 compared to the residues found in 2013 can be attributed to the implementation of good agricultural practices, which promote sustainable agricultural strategies through controlled pesticide application.

In vitro tungsten bioaccessibility in Chinese residential soils: Implications for human health risk assessments and soil screening level derivation

Tungsten (W) contamination presents emerging environmental challenges, necessitating the need to establish soil screening levels (SSLs), especially for residential soils. This study assessed the health exposure risk and derived national and regional residential SSLs for W in Chinese residential soils, incorporating machine-learning prediction of in-vitro soil W bioaccessibility. We analyzed 204 residential soil samples collected across 24 provinces, recording a wide range of W concentrations (0.01–3063.2 mg/kg). Synchrotron-based X-ray fluorescence spectroscopy, chemical extractions, and random forest modeling indicated that the key determinants of soil W bioaccessibility were soil pH, cation exchange capacity, organic matter, and clay contents. Monte Carlo simulations demonstrated that soil W contamination predominantly results in noncarcinogenic health risks to residents via oral exposure, especially in mining-affected regions. A national residential SSL (NRSSL) of 35.5 mg/kg and regional residential SSLs (RRSSLs) of 34.5–49.2 mg/kg were established. Incorporating predicted bioaccessibility increased the NRSSL to 73.8 mg/kg and the RRSSLs to 69.8–112.5 mg/kg. Southern China, which is rich in W ore, exhibited lower RRSSLs, underscoring a need for enhanced safety management. Our framework and findings provide a robust scientific foundation for future soil contamination risk assessment studies, and we present customized SSLs that can guide targeted W risk control strategies.

Impact of Environmental Conditions on Soil Geochemistry in Southern Kazakhstan

This study investigated the elemental composition of soils in Kyzylorda and Turkestan (southern Kazakhstan), an area rich in natural resources but facing potential environmental threats from industry and agriculture. The goal was to establish baseline geochemical values and assess soil contamination risks. Soil samples were collected from across the region and analyzed using ICP-MS and INAA techniques, providing a comprehensive profile of 72 elements. Statistical analysis revealed significant variations in elemental concentrations, with enrichments observed for specific elements when compared with reference values. Notably, both regions shared a core set of elements including rare earth elements (yttrium series: holmium, erbium, thulium), noble metals (gold, platinum, ruthenium, palladium), and tungsten. Enrichment patterns, however, provided distinct insights. Rare earth element enrichments likely reflect the region’s geology, while elevated radioactive elements necessitate further investigation to understand potential environmental and health risks. Enrichment of iron group elements might be linked to a combination of geological factors and anthropogenic activities like mining or industrial processes. A significantly higher number of elements exceeded background levels in Kyzylorda compared with Turkestan, suggesting greater element accumulation in Kyzylorda’s soil. This difference could be attributed to variations in regional geology or historical anthropogenic activities. The established geochemical baseline for 72 elements and the identified areas of potential contamination will inform land management practices, guide future environmental monitoring efforts, and ultimately contribute to the safeguarding of public health in southern Kazakhstan.

Research on pollution identification and safety thresholds based on the olfactory effect on a halogenated hydrocarbon contaminated site

To effectively address odor control issues at sites contaminated with halogenated hydrocarbons, it is essential to establish an odor risk prediction system for evaluating potential risks that may impact future planning. This research focuses on a representative halogenated hydrocarbon-contaminated site, examining the spatial and temporal distribution characteristics of key pollutants in soil gas. By analyzing odor contribution rates, the study identifies significant odorants in soil gas, which enables the derivation of both probabilistic and deterministic safety thresholds for soil and groundwater based on olfactory effects. The findings indicate that 1,1-dichloroethylene, vinyl chloride, chloroform, and 1,1-dichloroethane are prevalent throughout the contaminated site, displaying elevated concentration levels and substantially influencing the overall contamination extent. These substances are highlighted as critical pollutants requiring attention. Correlation analysis (P < 0.05) reveals a strong relationship between the concentrations of vinyl chloride, 1,1-dichloroethane, and chloroform with groundwater depth and air temperature. Additionally, the analysis of odor activity values (OAV) identified 1,1-dichloroethene, 1,4-dichlorobenzene, chlorobenzene, chloroform, and vinyl chloride as key olfactory factors at the site. The corresponding probabilistic safety thresholds are 0.68, 1.65, 0.50, 7.87, and 3.72 mg kg−1 for soil, and 9.29, 3.46, and 1.09, 69.55, and 47.01 mg L−1 for groundwater, respectively. Among them, the odor risks of chlorobenzene and 1,1-dichloroethylene warrant more attention than soil contamination risks; regarding 1,4-dichlorobenzene, it is recommended to concurrently consider odor risks during human health risk assessment; as for vinyl chloride and chloroform, their odor risks can be largely eliminated based on human health-oriented pollution management.

Pollution assessment and index properties of Okpulor soils, Rivers State, Nigeria: geochemical characterization, geotechnical and geoenvironmental implications

This study assessed soil pollution and index properties in Okpulor through geochemical, geotechnical, and geoenvironmental analyses. Twenty samples, comprising 14 surface and 6 shallow subsurface ones, underwent geochemical analysis for heavy metals (Fe, Cr, Cu, Zn, Ni, and Pb). Five geochemical indices, including the Geoaccumulation Index (Igeo), Enrichment Factor (EF), Contamination Factor (CF), Metal Pollution Index (MPI), and Potential Ecological Risk Index (PERI), were utilized. Simultaneously, six subsurface samples underwent geotechnical analysis for Natural Moisture, Grain Size, Specific Gravity, Bulk Density, and Atterberg Limits, following Unified Soil Classification System (USCS) and American Association of State Highway and Transportation Officials (AASHTO) guidelines. The Igeo highlighted significant heavy metal contamination in Okpulor soils, particularly Cd. EF values exceeding 1.5 underscored a strong anthropogenic influence, with CF indicating Cd's substantial contribution to overall contamination. PERI underscored the ecological risks associated with Cd contamination. Natural moisture content, ranging from 18.21% to 21.45%, indicated a notable presence of water in the soil during the dry season, potentially leading to increased leaching and migration of water-soluble contaminants. Bulk density values suggested moderate to lightly packed soils, impacting porosity and permeability, and influencing contaminant movement. Atterberg limits indicated low soil plasticity, impacting moisture retention and contaminant behaviour. Grain size analysis revealed poorly graded soils with a close sand-to-clay ratio, affecting water drainage. These geotechnical properties and heavy metal contamination reveal the intricate interplay between soil characteristics and contamination risks in the Okpulor area, emphasizing the need for targeted interventions to safeguard the environment.

Assessment of the risk of contamination by heavy metals and correlation analysis of the content of toxicants in animal feed and organic waste

Pollution of agroecosystems by heavy metals posesa signifcant threat to agricultural production in various countries of the world, including Ukraine. In the postwar period, the environmental situation will be even more complicated. Timely assessment of environmental risk using the results of laboratory analysis of the feed of dairy cows and their organic waste for the content of ecotoxicants such as cadmium and lead obtained in scientific experiments is important. Correlation analysis is one of the methods of statistical data processing that, when properly applied using modern computer software, allows you to quickly establish the strength of the relationship between indicators and its statistical signifcance. Such research methods are used by scientists from the countries of the European Union, the USA, China, and other countries. Previous studies have focused directly on the concentrations of contamination with heavy metals Cd, Pb, and other animal feed and organic waste, but have not investigated the relationship between them. Scientifc and economic experiments were conducted on dairy cows with different types of feeding. The animals were selected by the method of analogues for live weight and productivity. The diet included feed with an excess of cadmium and lead. The high biological activity of pollutants influenced their transition from ration fodder to products and organic waste. The aim of the research was to analyze the correlation dependence between the content of Cd and Pb in cow feed and their organic waste with an assessment of the risk of soil contamination by hazardous toxicants in the area of activity of agro-enterprises producing milk after the introduction of organic waste as organic fertilizer. With the help of the STATISTICA version 10.0 computer program, the Shapiro-Wilk's W test, the conformity of the obtained data of laboratory analyzes of feed and organic waste with the concentration of heavy metals, the law of "normal" distribution (Gaussian), and then the non-parametric Spearman rank correlation coefcient necessary in this case is selected for calculation. The analysis established a high r=0.66-0.75 (Cd) (р&lt;0.05), r=0.66-0.77 (Pb) (р&lt;0.05) and a very high r=0.83 (Cd) (р&lt;0.05), r=0.83 (Pb) (р&lt;0.05) correlation dependence between the content of toxicants in feed and organic waste, which allows specialists to act quickly and efectively in production conditions, confdently use the method of environmental monitoring, forecast the environmental situation, assessenvironmental risks, including those related to organic and biological farming and avoid disturbing the ecological balance of agroecosystems. Further research is aimed at correlational and regression analysis, but on other important indicators of environmental safety in veterinary, zootechnical and ecological practice, with an assessment of the relevant risks of running the livestock industry in the forest-steppe zone of Ukraine. Key words: feed, organic waste, organic fertilizers, heavy metals, cadmium, lead, correlation, ecological risk, dairy cows.

Nitrogen-Rich Sewage Sludge Mineralized Quickly, Improving Lettuce Nutrition and Yield, with Reduced Risk of Heavy Metal Contamination of Soil and Plant Tissues

Sewage sludge should primarily find use in agriculture, reducing the quantity directed towards alternative disposal methods like incineration or deposition in municipal landfills. This study evaluated the agronomic value and the risk of soil and plant tissue contamination with heavy metals in sewage sludge obtained from two wastewater treatment plants (WWTP). The experiment was arranged as a 2 × 5 factorial (two sewage sludges, five sanitation treatments), involving lettuce cultivation in pots over two growing cycles. The two sewage sludges were sourced from the WWTPs of Gelfa and Viana do Castelo and underwent five sanitation and stabilization treatments (40% and 20% calcium oxide, 40% and 20% calcium hydroxide, and untreated sewage sludge). The Gelfa sewage sludge, characterized by a higher initial nitrogen (N) concentration, resulted in greater dry-matter yield (DMY) (12.4 and 8.6 g plant−1 for the first and second growing cycles, respectively) compared to that from Viana do Castelo (11.0 and 8.1 g plant−1), with N release likely being a major factor influencing crop productivity. The high N concentration and the low carbon (C)/N ratio of sewage sludge led to rapid mineralization of the organic substrate, which additionally led to a higher release of other important nutrients, such as phosphorus (P) and boron (B), making them available for plant uptake. Alkalizing treatments further stimulated sewage sludge mineralization, increasing soil pH and exchangeable calcium (Ca), thereby enhancing Ca availability for plants, and indicating a preference for use in acidic soils. Cationic micronutrients were minimally affected by the sewage sludge and their treatments. The concentrations of heavy metals in the sewage sludge, soils, and lettuce tissues were all below internationally established threshold limits. This study highlighted the high fertilizing value of these sewage sludges, supplying N, P, and B to plants, while demonstrating a low risk of environmental contamination with heavy metals. Nevertheless, the safe use of sewage sludge by farmers depends on monitoring other risks, such as toxic organic compounds, which were not evaluated in this study.

Accumulation of ions in soil fertigated with dilutions of dairy effluents in the Brazilian semi-arid region

Wastewater is an alternative water source with the potential to guarantee agricultural productivity in semi-arid regions, where quantitative and qualitative scarcity is a limiting factor. This study aimed to analyze the effects of the application of dairy effluent dilutions on the alterations of sodium, calcium, magnesium, and nitrogen contents along the profile of an Ultisol cultivated with Cereus hildmannianus in the semi-arid region of Brazil. The experimental design used was a 5 x 5 factorial randomized block design with five dilutions of dairy effluent (T1 - only well water (WW); T2 - 0.1 x annual loading rate according to EPA (1981) (LW) plus WW; T3 - 0.2 x LW plus WW; T4 - 0.3 x LW plus WW; and T5 - 0.4 x LW plus WW) and five depths (0 to 0.10 m; 0.10 to 0.20 m; 0.20 to 0.30 m; 0.30 to 0.40 m and 0.40 to 0.50 m), with five replicates. Cereus hildmannianus cultivation lasted 240 days, and after this period, soil samples were taken to determine the contents of sodium, calcium, magnesium, and nitrogen. Fertigation using dairy effluent with up to 40% of the annual loading rate in Ultisol poses no risk of water and soil contamination by nitrogen leaching. Fertigation using dairy effluent in proportions of up to 20% of the annual loading rate poses no risk of soil degradation due to excessive accumulation of ions.

Quantifying the mitigating effect of organic matter on heavy metal availability in soils with different manure applications: A geochemical modelling study

Manure is one of the main sources of heavy metal (HM) pollution on farmlands. It has become the focus of global ecological research because of its potential threat to human health and the sustainability of food systems. Soil pH and organic matter are improved by manure and play pivotal roles in determining soil HM behavior. Geochemical modeling has been widely used to assess and predict the behavior of soil HMs; however, there remains a research gap in manure applications. In this study, a geochemical model (LeachXS) coupled with a pH-dependent leaching test with continuously simulations over a broad pH range was used to determine the effects and pollution risks of pig or cattle manure separate application on soil HMs distribution. Both pig and cattle manure applications led to soil pH reduction in alkaline soils and increased organic matter content. Pig manure application resulted in a potential 90.5–156.0 % increase in soil HM content. Cattle manure did not cause significant HM contamination. The leaching trend of soil HMs across treatments exhibited a V-shaped change, with the lowest concentration at pH = 7, gradually increasing toward strong acids and bases. The dissolved organic matter-bound HM content directly increased the HM availability, especially for Cu (up to 8.4 %) after pig manure application. However, more HMs (Cr, Cu, Zn, Ni) were in the particulate organic matter-bound state than in other solid phases (e.g., Fe-Al(hydr) oxides, clay minerals), which inhibited the HMs leaching by more than 19.3 % after cattle manure application. Despite these variations, high HM concentrations introduced by pig manure raised the soil contamination risk, potentially exceeding 40 times at pH ±1. When manure is returned to the field, reducing its HM content and mitigating possible pollution is necessary to realize the healthy and sustainable development of circular agriculture.

Recognizing Functional Groups of MES/APG Mixed Surfactants for Enhanced Solubilization toward Benzo[a]pyrene.

Benzo[a]pyrene is difficult to remove from soil due to its high octanol/water partition coefficient. The use of mixed surfactants can increase solubility but with the risk of secondary soil contamination, and the compounding mechanism is still unclear. This study introduced a new approach using environmentally friendly fatty acid methyl ester sulfonate (MES) and alkyl polyglucoside (APG) to solubilize benzo[a]pyrene. The best result was obtained when the ratio of MES/APG was 7:1 under 6 g/L total concentration, with an apparent solubility (Sw) of 8.58 mg/L and a molar solubilization ratio (MSR) of 1.31 for benzo[a]pyrene, which is comparable to that of Tween 80 (MSR, 0.95). The mechanism indicates that the hydroxyl groups (-OH) in APG form "O-H···OSO2-" hydrogen bonding with the sulfonic acid group (-SO3-) of MES, which reduces the electrostatic repulsion between MES molecules, thus facilitating the formation of large and stable micelles. Moreover, the strong solubilizing effect on benzo[a]pyrene should be ascribed to the low polarity of ester groups (-COOCH3) in MES. Functional groups capable of forming hydrogen bonds and having low polarity are responsible for the enhanced solubilization of benzo[a]pyrene. This understanding helps choose suitable surfactants for the remediation of PAH-contaminated soils.

Health risk assessment of soil heavy metals in a typical mining town in north China based on Monte Carlo simulation coupled with Positive matrix factorization model

The accumulation of heavy metals (HMs) in soil caused by mineral resource exploitation and its ancillary industrial processes poses a threat to ecology and public health. Effective risk control measures require a quantification of the impacts and contributions to health risks from individual sources of soil HMs. Based on high-density sampling, soil contamination risk indexes, positive matrix factorization (PMF) model, Monte Carlo simulation and human health risk analysis model were applied to investigate the risk of HMs in a typical mining town in North China. The results showed that As was the most dominant soil pollutant factor, Cd and Hg were the most dominant soil ecological risk factors, and Cr and Ni were the most dominant health risk factors in the study area. Overall, both pollution and ecological risks were at low levels, while there were still some higher hazard areas located in the central and south-central part of the region. According to the probabilistic health risk assessment (HRA), children suffered greater health risks than adults, with 21.63% of non-carcinogenic risks and 53.24% of carcinogenic risks exceeding the prescribed thresholds (HI > 1 and TCR>1E-4). The PMF model identified five potential sources: fuel combustion (FC), processing of building materials with limestone as raw materials (PBML), industry source (IS), iron ore mining combined with garbage (IOG), and agriculture source (AS). PBML is the primary source of soil HM contamination, as well as the major anthropogenic source of carcinogenic risk for all populations. Agricultural inputs associated with As are the major source of non-carcinogenic risk. This study offers a good example of probabilistic HRA using specific sources, which can provide a valuable reference for strategy establishment of pollution remediation and risk prevention and control.

Assessment of pesticide contamination in groundwater bodies in the Jucar River Basin (Spain) and its spatial distribution

Exposure to the pesticides used in agriculture is a threat to human health and the environment. Nowadays, the world experiences a number of global changes, such as anthropogenic climate change and agricultural expansion which are associated to an increased consumption of water, fertilisers, and pesticides. This has increased the risk of soil and groundwater contamination. In this study, the model Pesticide Root Zone Model 5 (PRZM 5) has been applied to model the behaviour of pesticides in groundwater bodies within the Júcar River Basin (JRB) in Spain. We consider a groundwater body to be at risk of contamination if pesticide estimated concentrations exceed the Maximum Concentration Levels (MCL) and two additional indicators. We identified that Mancha Oriental groundwater body presents a high risk of Atrazine contamination. In the case of the Bromacil risk indicators, Castellón groundwater body was the most likely to be contaminated. Regarding Terbuthylazine risk maps, the probability of exceeding the threshold is low, thus posing a minimal risk in the studied area. Conversely Terbumeton risk maps, showed a high risk of contamination, detecting new areas of contamination that had not been studied for contamination for any pesticide. The spatial distribution of pesticides corresponds to areas mostly dedicated to irrigated agriculture which are associated to regular pesticide applications. Therefore, it can be concluded that the amount of pesticide applied on the field is the most important factor influencing pesticide concentration in groundwater bodies.

Soil Contamination and Ecological Risk Assessment of Different Types of Lithuanian Shooting Ranges

ABSTRACT Contamination at shooting ranges is a growing concern due to the accumulation of potentially toxic elements in the soil. The aim of the study was to determine the level of soil contamination in different types of Lithuanian shooting ranges (clay-target, practical, small-bore) and assess the potential ecological risks. Soil samples were taken in two soil layer depths (0–10 cm and 10–30 cm) and locations (range floor and berm/target line) of different types of shooting ranges. The soils of the practical and small-bore shooting ranges were neutral, clay target – slightly alkaline. The soil of the clay-target firing range floor had a significantly lower organic matter, than small-bore and practical firing ranges. Lead contamination was significantly higher in the floor and berm surface soil and subsoil (about 1000 mg kg−1 and 360–527 mg kg−1, respectively) of the practice range compared to the others and controls. The Cd concentrations in the surface soil of the practical range and the small-bore firing ranges and in the soil of the berm were considerably higher than in the soil of the clay target. There was a significant negative correlation between soil pH and Pb and Cd concentrations. Pb content was positively correlated with organic matter content. The soils of the practical range floor and berm indicated high ecological risk. The research showed that heavy metal contamination is specific in different types of shooting ranges, therefore various management practices should be applied to prevent pollution in particular shooting range.

Ecological Studies of Heavy Metals in E-Waste Dumpsites from Two Local Government Areas of Ogun State, Southwestern Nigeria

The study analyzed soil samples from e-waste dumps in two local government areas of Ogun State, Nigeria, to determine the concentrations of nine heavy metals. Samples were analyzed using spectrophotometric techniques. The results were used to assess ecological health risks and conduct correlation analysis. The study found that the dumpsites had high residue concentrations of Cd, Zn, Pb, and Fe, exceeding WHO acceptable limits, also concentration of Zn and Fe at the control sites exceeds WHO limits. At the dumpsite in Ijebu-Ode, Cd had an extremely high enrichment factor of 126.67 and an Igeo of 6.400, while the dumpsites at Ijebu North, Pb had the highest enrichment factor values of 14.063 and an Igeo of 3.229 respectively which suggested severe enrichment. Therefore, the dumpsites have a high pollutant of lead. The risk index for both Ijebu North and Ijebu-Ode LGA dumpsites were 396.983 and 3916.273 respectively and thereby indicating significant risk of toxic pollution and soil contamination respectively. The high-risk index value at the Ijebu-Ode dumpsites was caused by the excessive Cd contamination in Ita-Osu. Common anthropogenic sources of the contaminants were indicated by the correlation analysis.

Impacts of sugarcane industrial effluent as an alternate source of irrigation on growth, chlorophyll contents and antioxidants of different canola varieties

The sugarcane industry often utilizes effluent for irrigation purposes; however, its intricate composition and elevated metal contaminants pose a potential risk of soil and crop contamination. Consequently, it is imperative to employ effective strategies to ensure the safe utilization of this resource for crop cultivation. One such strategy involves the dilution of sugarcane industry effluent. Dilution is a practical approach to mitigate its toxicity, minimizing its adverse impact on soil and crop health. That’s why the current study explored the best dilution of sugarcane industrial effluent (SW) for cultivating canola varieties. A total of 15 canola varieties were cultivated 0%, 20%, 40%, 60%, 80%, and 100% SW. Results showed that 60% SW Faisalabad Canola and Punjab Canola improved germination, shoot length, root length, shoot fresh and dry weight, root fresh and dry weight, and chlorophyll contents compared to other treatments and control. AARI Canola and CON-III showed poor growth and chlorophyll contents under 60%SW. Dunkled and Oscar cultivars showed moderate improvement in growth and chlorophyll contents under 60SW. The 60% SW can be recommended for maximum growth benefits in canola cultivars, specifically Faisalabad Canola and Punjab Canola. At 20SW, the root dry weight of Faisalabad Canola increased by 2.7%, while Punjab Canola increased by 3.4%. Canola showed the highest increase in POD activity compared to the control, with a 55.45% increase, followed by Sandal Canola, with a 43.26% increase. However, additional field-level experiments are needed to determine the best cultivars suitable for optimal growth under 80SW and 60SW irrigation conditions.