Soil Aquifer Treatment Research Articles

Oxidation processes and clogging in intermittent unsaturated infiltration

Intermittent infiltration of wastewater through a non saturated sand bed is an extensive treatment process aimed at eliminating organic pollution, oxidizing ammonia and removing pathogens. A 1D numerical model, IPOX, has been worked out to simulate the transfer and oxidation of dissolved organic matter and nitrogen in unsaturated sand beds. IPOX was calibrated after real scale tests performed in Spain and Burkina Faso. Simulations allowed us to point out the influence of (i) kinetics on oxidation performances and (ii) biomass development on the process sustainability. These results brought a new light on the sizing and operation of infiltration percolation and soil aquifer treatment (SAT) plants.

Utility of Column Lysimeter for Design of Soil Aquifer Treatment System for Wastewater Renovation Using Artificial Neural Networks

An artificial neural network (ANN) model is developed to study the correlation of data with reference to various wastewater pollution parameters (biochemical oxygen demand, chemical oxygen demand, suspended solids, NH4, PO4) using two scales of experiments viz. column lysimeter and a pilot soil aquifer treatment (SAT) system for wastewater renovation in India. A unique feature of the study is that the primary treated wastewater was directly applied to SAT system for renovation in contrast to the secondary treated effluent used in most of the other studies that have been reported. The analysis of data using ANN as a tool indicates that the column lysimeter data are useful for design of SAT systems and it is possible to predict the effluent quality for SAT system based on the inputs from lysimeter experiments. The study highlights the utility of column lysimeter studies for evolving design parameters for a full-scale SAT system thereby obviating the need for pilot SAT studies which are site specific, time consuming, and expensive. Thus, the study suggests that the experimental data from lysimeter studies at a particular site can be used to predict performance of field-scale SAT systems without going in for actual experimentation. Further, the field data from one site could be utilized for design of SAT systems at other locations provided the climatic and hydrogeological conditions viz. soil matrix characteristics and wastewater characteristics, etc., are similar.

Heavy metal retention and partitioning in a large-scale soil-aquifer treatment (SAT) system used for wastewater reclamation

Soil aquifer treatment (SAT) of wastewater relies on extensive biogeochemical processes in the soil and aquifer to achieve large-scale and economic reclamation of municipal effluents. Removal of trace metals from the wastewater is a prime objective in the operation, but the long-term sustainability of the adsorptive filtration capacity of the soils is an open question. Solid/solution partitioning (measured by the distribution coefficient, K d) and solid/solid partitioning (measured by selective sequential dissolution, SSD) of heavy metals were measured in soils sampled from active recharge basins in a wastewater reclamation plant and were compared to the adjacent pristine dune. K d values for the adsorption of Cu, Ni and Zn, measured in short-term adsorption experiments positively and significantly correlated with solution pH. Quantitative estimation of Cu, Ni and Zn adsorption on multi-sorbents indicated that surface adsorption and precipitation on Fe oxides and/or carbonate may be the major mechanisms of metal retention in these soils. SSD analyses of metal partitioning in soils exposed to ∼20 yr of effluent recharge showed that all solid-phase components, including the most stable ‘residual’ component, competed for and retained added Cu and Zn. Copper preferentially partitioned into the oxide component (32.0% of the soil-accumulated metal) while Zn preferentially partitioned into the carbonate component (51.6% of the soil-accumulated metal).

Optimal Operation of Artificial Groundwater Recharge Systems Considering Water Quality Transformations

In water limited areas as water demand increases alternative sustainable water sources must be identified. One supply augmentation practice, that is already being applied in the arid southwest U.S., is artificial groundwater recharge usingwastewater effluent. The objective of a recharge facility is to supplement the available groundwater resources by storing water for the future. The resulting reclaimed water is used primarily for non-potable purposes but under increasing stressesshifting to potable use is likely to happen. Water quality thenbecomes a more pressing concern. Water quality improvements during infiltration and groundwater transport are significant and are collectively described as soil-aquifer treatment (SAT). To meet user needs, the recharge operation must be efficiently managed considering monetary, water quality and environmental concerns. In this paper, a SAT management model is developed that considers all of these concerns. Within the SAT management model, the shuffled complex evolution algorithm (SCE) is used as the optimization tool. SCEis a relatively new meta-heuristic search technique for continuousproblems that has been used extensively for hydrologic model calibration. In this application, SCE is integrated with the simulation models (MODFLOW, MT3D, and MODPATH) to represent movement and quality transformations. Two steady state case studies on a general hypothetical aquifer (modeled after a field site) were examined using the management model.

Evaluation of wastewater effluents for soil aquifer treatment in South Korea

Soil batch and column experiments were performed to characterize the wastewater effluents from seven different wastewater treatment plants in the Jonnam province, South Korea, with the purpose of evaluating the effluents for possible application of a soil aquifer treatment (SAT) in Korea. Batch experiments were conducted to measure the biodegradable dissolved organic carbon (BDOC) while 1 m soil columns, for simulating SAT, were employed to further analyze dissolved organic carbon (DOC) removal. The soils were collected from a river bottom in Jonnam. The BDOC fractions and the residual DOC concentrations for the effluents ranged from 19.3 to 59.9% and from 1.0 to 7.5 mg/L, respectively, depending on the reaction time. Applying the tentative criteria based on the data obtained for the BDOC and residual DOC, three effluents, from Gwangju, Hwasoon, and Jangsung, were found to be the most suitable for SAT applications. It was also concluded that the site characteristics should be also considered with regard to the retention time when evaluating the feasibility of SAT application in a certain region.

Sorption behaviors of heavy metals in SAT (soil aquifer treatment) system

Degradation or detoxification of pollutants by SAT system was generally focused on organic contaminants although the regulation of water reuse has provisions of heavy metals. This study is to evaluate the feasibility of SAT for metals such as Cd, Cr and Pb with the pilot scaled column experiment. The desorption possibility of sorbed metals was also examined in the condition of continuous water and even acidic water (pH 4.3) injection. Fractional factorial analysis is a tool frequently used to identify factors or variables that have an effect on a certain response. A two-level fractional factorial analysis was planned to study the effect of four factors on Pb sorption from the experiments; soil particle size, TOC in solution, Pb concentration in solution and flow rate. The main effects among the factors were obtained by ANOVA based MINITAB software. The effects of four factors were also converted into coefficients; those values may build an empirical model to predict the metal sorption of soils.

Removal mechanisms of endocrine disrupting compounds (steroids) during soil aquifer treatment

The objective of this study was to determine the primary removal mechanisms of endocrine disruptors such as steroidal hormones present in reclaimed water, specifically 17beta-estradiol, estriol, and testosterone, during groundwater recharge via soil aquifer treatment (SAT). Steroidal hormones were quantified using enzyme-linked immunosorbent assays. Bench-scale studies and laboratory-scale soil column experiments were employed to determine what mechanisms (i.e., adsorption, biodegradation, photolytic degradation) dominate the removal of the three compounds of interest during SAT. Findings of these studies revealed that the dominating removal mechanism for the compounds of interest during SAT is adsorption to the porous media matrix and additional attenuation to below the detection limit occurred in the presence of bioactivity. This additional removal occurred regardless of dominating redox conditions (aerobic vs. anoxic) or the type of organic carbon matrix present (hydrophobic acids, hydrophilic carbon vs. colloidal carbon).

Modeling the fate and transport of organic and nitrogen species in soil aquifer treatment process

Soil aquifer treatment (SAT) is a promising technique for wastewater reclamation and reuse. This treatment strategy takes advantage of physicochemical and biological processes in the subsurface. The model employed in this study is based on MODFLOW-SURFACT (HydroGeoLogic, Inc.), a three-dimensional model for variably saturated flow and reactive mass transport. The model accounts for reactions including the nitrification of ammonium, the denitrification of nitrate, and the oxidation of organic carbon. Concentration of dissolved oxygen and biomasses involved in aerobic and anaerobic biological reactions forms the basis for estimates of nonlinear reaction rates formulated using a multiple-Monod expression. Illustrative simulations were conducted in a two-dimensional cross-sectional domain, with unsaturated and saturated zones. They examine the effects that site and operational conditions have on the performance of a SAT system. The parameters and conditions of concern included length of the wet/dry cycle, ground surface condition, and infiltration rate. From the simulations, we found that organic carbon was effectively removed in all cases. The availability of oxygen was a key factor in predicting the production and removal of nitrate. Overall, the model successfully described the fate and transport of the key constituents during the wet/dry operational periods in both unsaturated and saturated subsurface.

Assessing the removal potential of soil-aquifer treatment systems for bulk organic matter

The fate of effluent organic matter (EfOM) during groundwater recharge was investigated by studying the removal behavior of four bulk organic carbon fractions isolated from a secondary effluent: Hydrophilic organic matter (HPI), hydrophobic acids (HPO-A), colloidal organic matter (OM), and soluble microbial products (SMPs). Short-term removal of the bulk organic fractions during soil infiltration was simulated in biologically active soil columns. Results revealed that the four organic fractions showed a significantly different behavior with respect to biological removal. HPI and colloidal OM were prone to biological removal during initial soil infiltration (0-30 cm) and supported soil microbial biomass growth in the infiltrative surface. Additionally, colloidal OM was partly removed by physical adsorption or filtration. HPO-A and SMPs reacted recalcitrant towards biological degradation as indicated by low soil biomass activity responses. Adsorbability assessment of the biologically refractory portions of the fractions onto powered activated carbon (PAC) indicated that physical removal is not likely to play a significantly role in further diminishing recalcitrant HPO-A, HPI and SMPs during longer travel times in the subsurface.

Fate of Steroidal Hormones During Soil‐Aquifer Treatment

AbstractThere is increasing concern that endocrine disrupting compounds such as steroidal hormones present in treated waste water effluents can affect ground water quality where waste water is used to recharge local ground water. Little is known how efficiently steroidal hormones are removed or transformed during percolation through the subsurface. The scope of this study was to examine the fate of hormones during soil‐aquifer treatment (SAT) leading to ground water recharge in controlled laboratory soil‐column studies and at two water reuse field sites where treated waste water is fed to ground water recharge basins. The selected steroidal hormones represented estrogens (17β‐estradiol and estriol) and androgens (testosterone). Composite samples of treated waste water and from ground water monitoring wells were collected and analyzed for steroidal hormones using enzyme‐linked immunosorbent assays. The study revealed that the mobility of the selected hormones in subsurface systems was low, and estriol and testosterone were both not detected (< 0.6 ng/L) in ground water monitoring wells or shallow lysimeters representing water samples after 1.5 m of travel through porous media. 17β‐estradiol, however, was consistently detected at concentrations < 2 ng/L in monitoring wells after travel of 1.5 m through porous media. Results from field sites that have been operational for more than 13 years indicated no breakthrough of the target compounds in ground water samples collected downstream of the surface spreading operation. These findings were confirmed by controlled laboratory studies simulating SAT in soil‐column experiments. It appeared that the majority of attenuation was due to adsorption of the three target compounds to the porous media matrix, and additional attenuation to below the detection limit occurred due to the presence of bioactivity regardless of dominating redox conditions (aerobic vs. anoxic) or the type of organic carbon matrix present (hydrophobic acids, hydrophilic carbon vs. colloidal carbon).

Do Pharmaceuticals, Pathogens, and Other Organic Waste Water Compounds Persist When Waste Water Is Used for Recharge?

AbstractA proof‐of‐concept experiment was devised to determine if pharmaceuticals and other organic waste water compounds (OWCs), as well as pathogens, found in treated effluent could be transported through a 2.4 m soil column and, thus, potentially reach ground water under recharge conditions similar to those in arid or semiarid climates. Treated effluent was applied at the top of the 2.4 m long, 32.5 cm diameter soil column over 23 days. Samples of the column inflow were collected from the effluent storage tank at the beginning (Tbegin) and end (Tend) of the experiment, and a sample of the soil column drainage at the base of the column (Bend) was collected at the end of the experiment. Samples were analyzed for 131 OWCs including veterinary and human antibiotics, other prescription and nonprescription drugs, widely used household and industrial chemicals, and steroids and reproductive hormones, as well as the pathogens Salmonella and Legionella. Analytical results for the two effluent samples taken at the beginning (Tbegin) and end (Tend) of the experiment indicate that the number of OWCs detected in the column inflow decreased by 25% (eight compounds) and the total concentration of OWCs decreased by 46% while the effluent was in the storage tank during the 23‐day experiment. After percolating through the soil column, an additional 18 compounds detected in Tend (67% of OWCs) were no longer detected in the effluent (Bend) and the total concentration of OWCs decreased by more than 70%. These compounds may have been subject to transformation (biotic and abiotic), adsorption, and (or) volatilization in the storage tank and during travel through the soil column. Eight compounds—carbamazapine; sulfamethoxazole; benzophenone; 5‐methyl‐1H‐benzotriazole; N, N‐diethyltoluamide; tributylphosphate; tri(2‐chloroethyl) phosphate; and cholesterol—were detected in all three samples indicating they have the potential to reach ground water under recharge conditions similar to those in arid and semiarid climates. Results from real‐time polymerase chain reactions demonstrated the presence of Legionella in all three samples. Salmonella was detected only in Tbegin, suggesting that the bacteria died off in the effluent storage tank over the period of the experiment. This proof‐of‐concept experiment demonstrates that, under recharge conditions similar to those in arid or semiarid climates, some pharmaceuticals, pathogens, and other OWCs can persist in treated effluent after soil‐aquifer treatment.

Can chemical oxidation improve the permeability of infiltration basins?

The Rapid Infiltration and Extraction (RIX) facility, a soil aquifer treatment system, began taking secondary effluent from the City of San Bernardino, California, in 1996. The gradual decrease in the hydraulic conductivity of the infiltration basins at RIX has been attributed to the accumulation of organic matter in the surface sand. Periodic tillage of the surface sand to restore the permeability has mixed this organic matter to a depth of nearly 50 cm. We hypothesized that in situ chemical oxidation of the surface sand might improve the infiltration rate and increase the time between filling and drying cycles. The effect of organic matter oxidation on sand permeability was tested in laboratory sand columns treated with sodium hypochlorite, calcium hypochorite, and ozone gas. All oxidants significantly decreased the hydraulic conductivity of the surface sand. The loss in permeability was attributed to an increase in dispersed clay plus silt-sized particles that were released as a result of oxidation. This study suggests that ex situ sand-washing operations, currently being used to clean the sand, could be improved by the addition of oxidants to the wash water.

Characteristics of biotic and abiotic removals of dissolved organic carbon in wastewater effluents using soil batch reactors.

Biodegradable dissolved organic carbon (BDOC) analyses and abiotic adsorption of dissolved organic carbon (DOC) from different wastewater effluent were conducted to evaluate biotic and abiotic removal mechanisms as a function of the initial DOC concentration and source of DOC using soil batch reactors. To obtain high DOC concentrations, a laboratory-scale reverse osmosis unit was used. It was found that BDOC fraction was independent of the initial DOC concentration and was dependent on the source of wastewater and/or the types of wastewater treatment. The BDOC fractions varied from 9 to 73%. Trickling filter effluent (Tucson, Arizona) showed the highest BDOC, ranging from 65 to 73% biodegradable, while wastewater treated by the soil aquifer treatment (SAT) (NW-4) was found to be most refractory, with DOC removals of 9 to 14%. For nitrified/denitrified tertiary effluent (Mesa, Arizona) and secondary effluent (Scottsdale, Arizona), 36 to 42% removal of DOC was observed during the BDOC test. The amount of BDOC in the wastewater depended not on the concentration of DOC, but on the effectiveness of pretreatment. Abiotic adsorption capacity of wastewater effluent varied from 6 to 18%. Molecular weight distribution analyses showed that more than 50% of DOC in the Scottsdale concentrate had a molecular weight of less than 1000 Da, and no significant change in distribution profiles occurred after approximately 12% abiotic adsorption with both soils with acclimated microorganisms (SAT soil) and soils without acclimated microorganisms (non-SAT soils). Hence, preferential adsorption was not observed and the presence of acclimated microbes did not influence adsorption.

The long-term performance of Soil Aquifer Treatment (SAT) for effluent reuse

An innovative scheme of groundwater recharge for wastewater effluent reuse has been practiced on a large scale in the Dan Region Project in Israel since 1977. The system, referred to as SAT (for Soil Aquifer Treatment), provides advanced treatment prior to effluent reuse for unrestricted irrigation. A major study recently carried out consisted of a comprehensive analysis of the water quality data available in the recharged effluent (before SAT), as well as in observation wells and recovery wells (after SAT). The results obtained with respect to suspended solids, organics and nutrients (nitrogen compounds and phosphorus) are presented and discussed. The main processes occurring in the soil-aquifer system, which are responsible for the removal of the above contaminants are filtration through the upper soil layer, organic matter biodegradation and adsorption, ammonia adsorption and biological nitirification-denitrification, and chemical precipitation and adsorption of phosphorus. The findings of the study have provided valuable information on the above processes and their interaction, and have demonstrated that the SAT system should be considered an attractive method for effluent reuse in areas where hydrogeological conditions are suitable for groundwater recharge via spreading basins.

Water reuse in Israel - the Dan Region Project: evaluation of water quality and reliability of plant's operation

Israel is a semi-arid country with insufficient natural water resources. Wastewater effluent reuse and desalination have become the main source of water to compensate for the future water shortage. Today, between 65 and 70% of wastewater of urban and industrial origin is reused in agriculture after treatment in biological treatment plants around the country. The Dan Region Reclamation Project (Shafdan) is the largest wastewater treatment and reclamation project in Israel. 130 Mm3/yr of reclaimed water is used for unrestricted irrigation after soil aquifer treatment (SAT). Extensive water quality monitoring is performed to keep an efficient and safe wastewater reuse system. After 25 years of operation, the Shafdan deals with the following operational issues on an ongoing basis: Biofouling of the effluent pipelines from the wastewater treatment plant to the SAT, and a lack of capacity in the SAT system. Biofilm growth in the pipelines is controlled by intermittently applying chlorine based compounds at a 10 mg/L dosage for a few hours.

Behavior of alkylphenol polyethoxylate metabolites during soil aquifer treatment

The attenuation of alkylphenol polyethoxylates (APEOs) metabolites was studied at a soil aquifer treatment (SAT) site located in Arizona, USA. Two parcels of water were monitored during infiltration; one parcel was predominantly oxic while the other was predominantly anoxic. In this study, only alkylphenol ethoxycarboxylates (APECs) and carboxyalkylphenol ethoxycarboxylates (CAPECs) were detected, no short-chained APEOs were observed—even under anoxic conditions. APEO metabolites were rapidly (<7 days) removed under both aerobic and anoxic conditions. In general, the length of the ethoxycarboxylate chain decreases with depth—at depths greater than 3 m, only alkylphenoxy acetic acids (AP1ECs), carboxyalkylphenoxy acetic acids (CAP1ECs), and alkylphenols (APs) remain. Under aerobic conditions, octylphenol and nonylphenol concentrations decreased by ∼80% (w/w) within 3 m of the ground surface. Under anoxic conditions however, alkylphenol concentrations increased by ∼200% during the first 1.5 m and then decreased during the next 1.5 m; overall, under anoxic conditions, alkylphenol concentrations increased by ∼38% within 3 m. During infiltration, APEC and CAPEC concentrations decrease by more than 95% within 3 m of SAT. Alternate flooding and drying cycles appear to enhance overall APEO metabolite removal efficiencies.

Potable reuse of wastewater effluent through an integrated soil aquifer treatment (SAT) - membrane system

Soil aquifer treatment (SAT) has been shown to provide significant reductions of wastewater effluent organic matter (EfOM). While SAT can renovate wastewater effluent to levels commensurate with potable reuse, SAT represents only a single treatment barrier. Membrane filtration has been demonstrated to be an alternative treatment process for wastewater reclamation. However, the performance of membrane filtration is significantly constrained by membrane fouling, reducing membrane productivity in terms of flux decline. Soil aquifer treatment (SAT) is used as a primary barrier in the reclamation system to remove a complex suite of chemical and biological contaminants in wastewater. This study of membrane filtration of SAT-source waters is intended to determine the benefits of the SAT system in terms of membrane fouling reduction with membrane filtration providing a secondary barrier. Membrane treatment of SAT-recovered water provides a multiple barrier exhibiting additional organic matter removal. Moreover, the SAT system also provides for storage of reclaimed water. The synergy between SAT and membrane treatment has led to the concept of an integrated SAT-membrane system for potable reuse.

Fate of organics during soil-aquifer treatment: sustainability of removals in the field

A 5-year program of study was conducted at the Sweetwater Recharge Facilities (SRF) to assess the performance of surface spreading operations for organics attenuation during field-scale soil-aquifer treatment (SAT) of municipal wastewater. Studies were conducted utilizing both mature (∼10 yr old) and new infiltration basins. Removals of dissolved organic carbon (DOC) were robust, averaging >90 percent during percolation through the local 37-m vadose zone. The hydrophilic (most polar) fraction of DOC was preferentially removed during SAT; removals were attributed primarily to biodegradation. Reductions in trihalomethane formation potential (THMFP) averaged 91 percent across the vadose zone profile. The reactivity (specific THMFP) of post-SAT organic residuals with chlorine decreased slightly from pre-SAT levels (60 vs. 72 μg THM per mg DOC, respectively). Variations in the duration of wetting/drying periods did not significantly impact organic removal efficiencies.

Comparing microfiltration-reverse osmosis and soil-aquifer treatment for indirect potable reuse of water

Microfiltration (MF) followed by reverse osmosis (RO) and soil-aquifer treatment (SAT) are the two principal technologies considered for indirect potable reuse of wastewater. This study, conducted at the Northwest Water Reclamation Plant, Mesa (Arizona), evaluated MF/RO and SAT (>6 months residence time) treated tertiary effluent with respect to organics removal. Effluent organic matter was characterized as total organic carbon (TOC), by UV absorbance (UVA), solid-state carbon-13 nuclear magnetic resonance spectroscopy, and size exclusion chromatography. Several trace organic micropollutants, including EDTA, NTA, and alkylphenolethoxylate residues, were analyzed by GC/MS. The study revealed that final TOC concentrations of MF/RO and SAT are 0.3 and 1.0 mg l −1, respectively. Based on the characterization techniques used, the character of bulk organics present in final SAT water resembles the character of natural organic matter present in drinking water. Depending on the molecular weight cut-off, RO membranes can efficiently reject high molecular weight organic matter (characterized as humic and fulvic acids). However, approximately 40–50 percent of the remaining TOC in permeates consists of low molecular weight acids and neutrals representing a molecular weight range of ∼500 Da and less. In the SAT treated effluent, EDTA and APECs were removed to approximately 4.3 and 0.54 μg/l, respectively, but were below the detection limit in the MF/RO treated effluent.

Fate of effluent organic matter during soil aquifer treatment: biodegradability, chlorine reactivity and genotoxicity

Hydrophobic acid (HPO-A) and transphilic acid (TPI-A) fractions of dissolved organic matter (DOM) were isolated from a domestic secondary wastewater effluent that was polished via soil aquifer treatment (SAT). Fractions were isolated using XAD resin adsorption chromatography from samples obtained along the vadose zone flowpath at a full-scale basin recharge facility in Tucson, Arizona. Changes in isolate character during SAT were established via biodegradability (batch test), specific ultraviolet light absorbance (SUVA), trihalomethane formation potential (THMFP), and Ames mutagenicity assays. The dissolved organic carbon (DOC) concentration decreased by >90% during SAT. A significant fraction (up to 20%) of isolated post-SAT HPO-A was biodegradable. The (apparent) refractory nature of DOM that survives SAT may be a consequence of low DOC concentration in groundwater as well as the nature of the compounds themselves. Specific THMFP (microg THM per mg DOC) of HPO-A and TPI-A varied little as a consequence of SAT, averaging 52 and 49 microg THM per mg DOC, respectively. The nonbiodegradable fractions of HPO-A and TPI-A exhibited higher reactivities: 89 and 95 microg THM per mg DOC, respectively. Genotoxicity of HPO-A (on a per mass basis) increased after SAT, suggesting that responsible compounds are removed less efficiently than bulk organics during vadose zone transport.