A-horizon Soil Research Articles

Unexpected consequences of afforestation in degraded drylands: Divergent impacts on soil and vegetation

Forestry has long been considered an effective means of restoring degraded drylands worldwide. Often, afforestation in such lands relies on the establishment of runoff harvesting systems that are formed as contour bench terraces on hillslopes, increasing water availability for the planted trees and shrubs. The construction of terraces requires intensive earthworks by heavy machinery. This study assessed the long-term (>10 yrs) effects of forestry-related land-use change on soil properties and herbaceous vegetation in 16-year-old and 12-year-old afforestation sites (established in 2005 and 2009), and in nearby control (“natural”) areas in the semi-arid northern Negev, Israel. Mean herbaceous vegetation height in the 2005 afforestation sites (12.1 cm) was significantly (P = 0.0009) and 23% greater than in the control areas (9.8 cm), whereas in the 2009 afforestation sites (6.2 cm) it was 37% lesser than in the control areas. Mean herbaceous vegetation aboveground biomass was similar in the 2005 afforestation (0.39 Mg ha−1) and control areas (0.38 Mg ha−1), and almost significantly (P = 0.0510) and twofold greater than in the 2009 afforestation sites (0.19 Mg ha−1). The effect of hillslope aspect on these variables was substantial; their mean values were higher in the northern (mesic) hillslopes than in the southern (xeric) hillslopes. Soil samples were obtained from depths of 0–5 and 5–10 cm and physio-chemo-biological properties were assessed in the laboratory. The overall soil quality – as calculated by two soil quality indices (SQIs), including the generalized SQI (SQIgen) and the minimum dataset SQI (SQIMDS) – was significantly (P < 0.0001 for both indices) and 13–22% greater in the control areas (0.52 and 0.61, respectively) than that in the afforestation treatments (0.44–0.46 and 0.50–0.51, respectively). These results are generally attributed to the removal of soil's A-horizon during earthworks, and the exposure of the underlying B-horizon. The similar SQI values of both hillslope aspects, as well as of both soil depths, indicate the generally degraded state of the entire region. In conclusion, while contour bench terracing may facilitate the recovery of herbacaeous vegetation to some extent, the effectiveness of this practice for soil restoration is questionable. Overall, insights of this study demonstrate a caveat that converting natural drylands to forestry systems may not yield sufficient ecological benefits, and therefore should be implemented with caution.

Mineralogical and Elemental Trends in Regolith on Historically Managed Sites in the southeastern United States Piedmont

AbstractThe deep regolith of the southeastern United States has undergone rapid erosion in the last two centuries due to intensive agricultural practices, which has altered the landscape and its inherent fertility. Parent material, landscape position, and land use are important factors in controlling the mineral and elemental composition of soil profiles. Independent quantitative X-ray diffraction (QXRD) and whole-rock chemical analysis of eight weathering profiles agreed well and allow mineral reaction pathways to be constrained as particles are conveyed in the subsurface. QXRD analysis of saprolite, argillic, and soil A-horizons in the profiles highlights the imprint of bedrock on the regolith, which includes Neoproterozoic meta-tonalitic to meta-granodioritic and Paleozoic meta-granitic to biotite- and amphibolite-gneissic lithologies. Also, aeolian input slightly influenced A-horizon composition. The clay mineral assemblage is dominated by kaolinite, but profiles differ in the amount of interstratified clay minerals, halloysite, hematite, goethite, and gibbsite. Rare-earth element totals vary between 30 and 1048 ppm and are generally correlated positively with clay and clay mineral content. Eu and Ce anomalies reflect parent rocks and subsequent hydrolysis and redox history, with trends depending upon landscape position and clay content in the weathering profile. Weathering profiles on a high-order interfluve and those that were actively cultivated have thick argillic horizons (as defined by clay mineral abundance) and are depleted in alkali and alkaline-earth elements. Profiles proximally developed on old-field pine and never-cultivated hardwood forest land do not show large differences in mineral composition trends, whereas profiles on old-field sites with ongoing cultivation exhibit assemblages enriched in clay minerals and (oxyhydr)oxides. Old-field pine sites that were historically eroded by previous cultivation tend to have shallower and thinner argillic horizons, which may well impact critical-zone processes involving gas and water fluxes. This study highlights that mineral compositions of deep regolith, saprolite, and shallow soil horizons are dependent on local geomorphology (i.e. watershed- and hillshed-orders). Quantifying soil and regolith compositional trends across the landscape is a prerequisite for determining rates of chemical and physical erosion on human and geologic time scales.

Exploration geochemistry of surficial media over the high-grade McArthur River uranium deposit, Saskatchewan, Canada

ABSTRACT An orientation survey using surficial media was performed over the high-grade McArthur River unconformity-related U deposit (Saskatchewan, Canada) to test whether or not secondary dispersion of elements related to the ore body or alteration zone can be detected at the surface more than 500 m above the deposit. Organic-rich Ah-horizon soils, Fe-rich B-horizon soils, C-horizon soils, tree cores of Jack pine (Pinus banksiana), and glacially dispersed boulders of Manitou Falls Formation sandstone that host the U deposit were collected in four sampling grids near the mine site. Two of the grids overlaid the trace of the P2 fault that hosts the deposit and extends nearly to the surface, one grid overlaid both the P2 fault and one of the high-grade ore bodies (Zone 4), and one grid was located 2.5 km away from the ore body surface trace in the barren hanging wall of the P2 fault. The grid overlying the Zone 4 ore body had the highest proportion of samples with elevated U and low 207Pb/206Pb ratios, the latter indicative of radiogenic Pb from a high-U source, measured in two size fractions of Ah-horizon soils using Na pyrophosphate leach, pine tree cores using total digestion, and sandstone boulders using 2% HNO3 leach. A handful of pathfinder elements, such as As, Co, Ni, and Pb, are variably associated with the U and radiogenic Pb. Sandstone boulders with an assemblage of dravite + kaolinite ± illite, determined using shortwave infrared (SWIR) spectroscopy and matching the alteration mineralogy in the Manitou Falls Formation above the U deposit, were prevalent in the grid above the Zone 4 ore body and in the adjacent grid in the direction of glacial dispersion. A coarse fraction of the B-horizon soils, leached with 5% HNO3, highlighted the grid above the Zone 4 ore body to a lesser extent, whereas HNO3 leaches and aqua regia digests of C-horizon soil separates did not highlight the P2 fault or ore body trace due to influence by parent till mineralogy. Results of environmental monitoring at the mine site, which was active at the time of sampling, suggest that dust containing U, Pb, and radionuclides from waste rock piles and a ventilation shaft could influence A-horizon soil geochemistry near the mine site, and that U and radiogenic Pb anomalies in B- and C-horizon soils near the water table are close to a treated mine effluent discharge point. However, older trees that record elevated U and radiogenic Pb in annual rings that pre-date mining activity, and alteration mineralogy and geochemistry of boulders that are less susceptible to the influences of mining activity, add confidence that the geochemical anomaly in diverse surficial media above the Zone 4 ore body represents secondary dispersion from the underlying U deposit.

Soil property mapping by combining spatial distance information into the Soil Land Inference Model (SoLIM)

The Soil Land Inference Model (SoLIM) was primarily proposed by Zhu et al. (Zhu A X, Band L, Vertessy R, Dutton B. 1997. Derivation of soil properties using a soil land inference model (SoLIM). Soil Sci Soc Am J.61: 523–533.) and was based on the Third Law of Geography. Based on the assumption that the soil property value at a location of interest will be more similar to that of a given soil sample when the environmental condition at the location of interest is more similar to that at the location from which the sample was taken, SoLIM estimates the soil property value of the location of interest using the soil property values of known samples weighted by the similarity between those samples and the location of interest in terms of an attribute domain of environmental conditions. However, the current SoLIM method ignores information about the spatial distances between the location of interest and those of the sample. In this study, we proposed a new method of soil property mapping, SoLIM-IDW, which incorporates spatial distance information into the SoLIM method by means of inverse distance weighting (IDW). The proposed method is based on the assumption that the soil property value at a location of interest will be more similar to that of a known sample both when the environmental conditions are more similar and when the distance between the location of interest and the sample location is shorter. Our evaluation experiments on A-horizon soil organic matter mapping in two study areas with independent evaluation samples showed that the proposed SoLIM-IDW method can obtain lower prediction errors than the original SoLIM method, multiple linear regression, geographically weighted regression, and regression-kriging with the same modeling points. Future work mainly includes the determination of optimal power parameter values and the appropriate setting of the parameter under different application contexts.

Agricultural soil loss

Soil Conservation The current era of major loss of agriculturally productive soils has gained relatively little public attention. It seems intuitively unnecessary to spell out what will happen to food production, hydrology, carbon sequestration, and ecological services if we allow soil erosion to proceed at current rates. However, it is difficult to quantify soil loss and to translate that into agricultural loss. Thaler et al. focused on the US Corn Belt and used remote sensing to map areas in fields that have no carbon-rich (i.e., A-horizon) soils remaining. Previous attempts to quantify soil loss suggested that little damage had occurred. By contrast, the new estimate indicates that ∼35% of an area of ∼400,000 square kilometers (a third of the Corn Belt area) has lost its A-horizon soil (∼1.4 petagrams), especially on hillslopes. The authors suggest that mechanically working the land (tillage) has been responsible for most soil loss in this region. This degree of erosion translates into a 6% reduction in overall crop yield and ∼$3 billion in economic loss. Proc. Natl. Acad. Sci. U.S.A. 118 , e1922375118 (2021).

The extent of soil loss across the US Corn Belt

Soil erosion in agricultural landscapes reduces crop yields, leads to loss of ecosystem services, and influences the global carbon cycle. Despite decades of soil erosion research, the magnitude of historical soil loss remains poorly quantified across large agricultural regions because preagricultural soil data are rare, and it is challenging to extrapolate local-scale erosion observations across time and space. Here we focus on the Corn Belt of the midwestern United States and use a remote-sensing method to map areas in agricultural fields that have no remaining organic carbon-rich A-horizon. We use satellite and LiDAR data to develop a relationship between A-horizon loss and topographic curvature and then use topographic data to scale-up soil loss predictions across 3.9 × 105 km2 of the Corn Belt. Our results indicate that 35 ± 11% of the cultivated area has lost A-horizon soil and that prior estimates of soil degradation from soil survey-based methods have significantly underestimated A-horizon soil loss. Convex hilltops throughout the region are often completely denuded of A-horizon soil. The association between soil loss and convex topography indicates that tillage-induced erosion is an important driver of soil loss, yet tillage erosion is not simulated in models used to assess nationwide soil loss trends in the United States. We estimate that A-horizon loss decreases crop yields by 6 ± 2%, causing $2.8 ± $0.9 billion in annual economic losses. Regionally, we estimate 1.4 ± 0.5 Pg of carbon have been removed from hillslopes by erosion of the A-horizon, much of which likely remains buried in depositional areas within the fields.

Pb and Cd chemisorption by acid mineral soils with variable Mn and organic matter contents

Adsorption of Pb2+ and Cd2+ on acidic A and B horizon mineral soils of New York (MP) and Vermont (BH) were determined in 0.2 M Na acetate buffered at pH 5.5 to determine strength and capacity of the soils for chemisorption of these trace metal ions. Adsorption isotherms over a very wide concentration range were better modeled using the linearized Freundlich compared to the linearized Langmuir equation. Adsorption of Pb was much stronger than that of Cd for all soils, and A horizon soils adsorbed Pb and Cd more strongly than their B horizon counterparts. The logarithms of the Freundlich binding coefficients (log KF) were greater by about 1.0 unit for Pb than for Cd for all but the B-horizon of the MP soil, which was the least strongly adsorptive of all soils tested. Pb binding constants were significantly correlated to hydroxylamine- and NH4 oxalate-extractable Fe and Mn in addition to soil CEC, but the Cd binding constants were correlated significantly to extractable Fe only. Partition coefficients (KP) were calculated for Pb and Cd from the adsorption experiments, and for the lowest additions of Pb to the A-horizon soils, ranged from more than 4000 L kg−1 in the BH soils to about 300 in the more acidic MP soils. Cd partition coefficients were much lower than those of Pb in all soils, and the MP soils retained Cd particularly weakly, with a KP in the range of 3–20 for the A-horizon and even lower for the B-horizon. Pb and Cd were adsorbed more strongly on A-horizon than B-horizon soils, indicating the importance of organic matter in both Pb and Cd retention by chemisorption at low pH. For both Pb and Cd, partition coefficients diminished markedly with increasing metal addition levels.Adsorption of Pb and Cd ions caused release of alkaline earth metals and Mn into solution during the adsorption process on the high-Mn BH soils, whereas the more strongly acidic MP soils released Al. Decreasing solubility of P and S corresponding to increasing Pb adsorption on the soils suggested that, in addition to chemisorption, precipitation of Pb phosphate and Pb sulfate may have been involved in Pb removal from solution.

Small-scale spatial resolution of the soil phytolith record in a rainforest and a dry forest in Costa Rica: applications to the deep-time fossil phytolith record

Phytolith analysis, a well-established tool in archaeology and Quaternary paleoecology, has become a source of data for deep-time paleoecological studies only in the last 15 years. Recent years have also witnessed the publication of numerous soil phytolith inventories from extant vegetation types, representing modern analogues. However, this work suffers from several methodological shortcomings limiting inter-study comparisons, and the development of a single, and repeatable protocol for soil sample collection. In this paper, we focus on two fundamental methodological questions that must be answered before modern analogue studies can be meaningfully applied to deep-time paleoecology. (1) Do phytoliths from the lower portion of the A-horizon (more commonly preserved in paleosols) reflect standing vegetation equally well as the upper A-horizon (which is more commonly used in modern analogue studies but often truncated by erosion in paleosols)? (2) Does a point soil sample (usually collected from paleosols) capture standing vegetation as accurately as a composite soil sample (commonly used in modern analogue studies), which is made from subsamples taken from a small area? To address these questions, we collected soil from 10 × 10 m quadrats in a rainforest (La Selva) and a dry forest (Palo Verde) in Costa Rica and compared phytolith assemblages from upper vs. lower soil A-horizons, and composites vs. single phytolith assemblages. At both sites, phytolith assemblages from the lower vs. upper A-horizon, and from single vs. composite samples provide similar vegetation structure signal despite some compositional differences. These results suggest that the typical approach in deep-time paleoecology of taking point samples from the lower A-horizon of paleosols is likely justifiable (at least for paleosols reflecting rainforest and dry forest soils). We discuss possible mechanisms driving differences between sites, and future approaches to further expand and test our results.

Above-ground growth and temporal plant–soil relations in midterm hybrid aspen (Populus tremula L. × P. tremuloides Michx.) plantations on former arable lands in hemiboreal Estonia

ABSTRACTShort-rotation forestry with hybrid aspen is a novel silvicultural system in northern Europe on former arable lands. However, knowledge about hybrid aspen growth potential in different soil types and the impact of soil physico-chemical properties on tree productivity in the long term is still scanty. We used repeated monitoring of soil properties and tree growth in young (5-year) and midterm (15-year) hybrid aspen plantations in various soil types (corresponding to four forest site types) to determine the temporal changes in tree growth–soil relationships. Growth of midterm hybrid aspen plantations exceeded same-aged native European aspen stands about two-fold. Growth had improved on Aegopodium, remained moderate on moist Dryopteris and was increasingly suppressed on dry Hepatica soils. The pHKCl, available Ca, content of clay and layer thickness of the soil A-horizon had a significant effect on tree growth in young plantations, but these effects disappeared in the midterm age. The soil water-holding capacity and available P in the A-horizon had a significant growth-controlling effect on tree growth in both ages. We concluded that former arable soils provide a sufficient supply of major nutrients in midterm hybrid aspen plantations whereas minor changes have occurred in growth–soil relationships between young and midterm age.

Conservative tracer bromide inhibits pesticide mineralisation in soil

Bromide is a conservative tracer that is often applied with non-conservative solutes such as pesticides to estimate their retardation in the soil. It has been applied in concentrations of up to 250 g Br L−1, levels at which the growth of single-celled organisms can be inhibited. Bromide applications may therefore affect the biodegradation of non-conservative solutes in soil.The present study investigated the effect of potassium bromide (KBr) on the mineralisation of three pesticides – glyphosate, MCPA and metribuzin – in four agricultural A-horizon soils. KBr was added to soil microcosms at concentrations of 0, 0.5, 2.5 and 5 g Br− L−1 in the soil solution. The study concluded that KBr had a negative effect on pesticide mineralisation. The inhibitory effect varied depending on the KBr concentration, the type of pesticide and the type of soil. Furthermore, 16 S amplicon sequencing revealed that the KBr treatment generally reduced the abundance of bacteroidetes and proteobacteria on both an RNA and DNA level.Therefore, in order to reduce the effect of KBr on the soil bacterial community and consequently also on xenobiotic degradation, it is recommended that KBr be applied in a concentration that does not exceed 0.5 g Br− L−1 in the soil water.

Soil urease activity and bacterial ureC gene copy numbers: Effect of pH

Urea-N is ubiquitous in soils, having both natural and anthropogenic sources. The enzyme urease catalyzes its hydrolysis to NH3 and is produced by plants and many soil microorganisms, but there are growing concerns related to possible urea-induced eutrophication of surface waters proximate to agricultural fields. Agronomic research has focused on the relationship between urea hydrolysis and soil physical or chemical properties, rather than on direct measurements of the microbial community and its population diversity, especially using quantification of genes that code for urease. We quantified bacterial and archaeal 16S rRNA, fungal ITS, and bacterial ureC gene copies as a function of physical and chemical soil properties. Soils were sampled from A and B horizons along a toposequence that comprised an agricultural field, a grassed field border, and a forested riparian zone in the Chesapeake Bay watershed of Maryland. The riparian zone soils contained the highest total number of genes among both A- and B-horizon soils. The soils were then experimentally altered in the laboratory to achieve a range of pH values between 3.1 and 7.1. Soil pH was chosen as a variable because it varies both naturally and due to agronomic practices, and it influences microbial community structure and function. Archaeal 16S rRNA extracted from the pH-adjusted soils did not show a consistent pattern of increase or decrease with changes in pH, while ITS was greatest at low pH and bacterial 16S and bacterial ureC were greatest at high pH. We measured higher urea hydrolysis rates and gene copy numbers in A-horizon soils than in B-horizon soils, and found that urea hydrolysis rate was significantly correlated with gene copies of bacterial 16S, ureC, and increased pH. This suggests that liming acid soils increases urea hydrolysis rates in part by encouraging the growth of microorganisms capable of producing urease.

Early Prehistoric Maize in Northern Highland Ecuador

The discovery of the fully developed Formative sites of Cotocallao (ca. 3750-2350 cal. B.P.) in the Quito Basin and La Chimba (ca. 2650-1700 cal. B.P.) in the northern highlands of Ecuador has raised questions about their cultural antecedents, which have not been resolved despite decades of archaeological work in the region. Paleoenvironmental coring investigations were conducted at Lake San Pablo in northern highland Ecuador to determine the date for the onset of prehistoric maize farming in the temperate highland valleys of this region. The investigations included analysis of lake sediments for pollen, phytoliths, diatoms, and tephra. Maize pollen was identified as early as 4900 cal. B.P., while maize phytoliths dated even earlier, to 6200 or 6600 cal. B.P. These results demonstrate a long history of maize farming in valleys around Lake San Pablo, but in the context of a punctuated record of major and minor volcanic eruptions. It is concluded that early horticultural sites predating Cotocallao and La Chimba must exist, but to find such sites, archaeologists will have to locate and study deeply buried A-horizon soils.

The impact of short-rotation hybrid aspen (Populus tremula L. × P. tremuloides Michx.) plantations on nutritional status of former arable soils

The area of short-rotation forest (SRF) plantations with hybrid aspen (Populus tremula L.×P. tremuloides Michx.) for pulp and energy wood production in approximately 25-year rotation period has increased considerably during the last few decades in Northern Europe on previous agricultural lands. However, little is known about how this new land use will alter the chemical properties of soils in the long-term and how long nutrients from the land’s previous use will sustain high productivity of trees. Little is also known about the dynamics of soil micronutrients and the plantations’ influence on subsoil layers. Repeated soil monitoring was carried out in hybrid aspen plantations at the ages of 5 (young) and 15years (midterm) to detect changes in soil chemical characteristics, including soil reaction (pHKCl), and concentrations of nutrients and organic carbon (Corg) in A- and B-horizon on 51 permanent experimental plots. The main soil- and stand-related factors responsible for changes in soil chemical properties, were analyzed. Significant changes were observed both in soil A-horizon and B-horizon. In A-horizon, pHKCl (−0.2 units), Ca (−19.4%) and B (−25.8%) had decreased while total N (+5.8%), Cu (+20.3%) and Mn (+21.3%) had increased. In B-horizon, Ca (−23.4%), Mg (−12.8%) and B (−45.0%) had decreased, while Corg (+17.2%) and Cu (+53.8%) had increased. The concentrations of available P, K and Corg in A-horizon had remained unchanged. Reduction of soil chemical characteristics mainly occurred in plantations where their initial level had been high (this relationship was observed in A-horizon for total N and B and in B-horizon for Corg, Mg and B). Several soil chemical characteristics decreased more (or increased less) in plantations where tree growth was more vigorous (in A-horizon: pHKCl, total N and B; in B-horizon: Mg and B). Soil cation exchange capacity, base saturation and moisture conditions also explained some of the observed variation in changes. Relatively high loss of B in faster growing plantations indicates possible future limitations of this essential micronutrient. To summarize, first generation hybrid aspen plantations planted on former agricultural fields had significantly altered soil reaction (pHKCl) but did not show significant depletion of primary macronutrients (N, P, K) and soil organic carbon.

Lead distribution and possible sources along vertical zone spectrum of typical ecosystems in the Gongga Mountain, eastern Tibetan Plateau

A total of 383 samples from soil, plant, litterfall and precipitation in four typical ecosystems of Gongga Mountain were collected. Pb concentrations of samples were measured and analyzed. The results showed mean Pb concentrations in different soil layers were in the order of O > A > C, and mean Pb concentrations of the aboveground parts of plant was 3.60 ± 2.54 mg kg−1, with the minimum value of 0.77 mg kg−1 and the maximum value of 10.90 mg kg−1. Pb concentrations in soil's O-horizon and A-horizon showed a downward trend with increasing elevation (the determination coefficient R2 was 0.9478, 0.7918 and 0.9759 respectively). In contrast to other soil layers, the level of Pb concentrations in O-horizon (incomplete decomposition) was significantly high. Litterfall decomposition, atmospheric deposition and the unique climate could be main factors leading high Pb accumulation in soil's O-horizon. What's more, significant correlation (R2 = 0.8126, P < 0.05) was found between Pb concentrations in fine roots and soil's A-horizon confirms that fine roots could adsorb and accumulate Pb materials in soil. In general, the fact that Pb inputted into the typical ecosystems in the Gongga Mountain via long-range transportation and deposition of the atmosphere from external Pb sources could be confirmed by the HYSPLIT model and the ratio of CPb/CAl in plants (leaves) and CPb/CAl in litterfall. The mining activities and increasing anthropogenic activities (tourism development) could be main sources of Pb in this area. In order to better understand Pb sources and eco-risks of these typical ecosystems, litterfall decomposition characteristics, biomass of productivity of forest ecosystem, Pb isotopic tracing among air mass, twigs, leaves, litterfall and O-horizon soil in this vertical belt should also be taken into consideration.

Polychlorinated naphthalenes (PCNs) in Chinese forest soil: Will combustion become a major source?

We collected O- and A-horizon soil samples in 26 Chinese mountainous forests to investigate the content, spatial pattern, and potential sources of polychlorinated naphthalenes (PCNs). Spatial patterns were influenced mainly by the approximation to sources and soil organic contents. High concentrations often occurred close to populated or industrialized areas. Combustion-related activities contributed to PCN pollution. Relatively high proportions of CN-73 in northern China may be attributed to coke consumption, while CN-51 could be an indicator of biomass burning in Southwest China. There are evidences that PCNs may largely derived from unintentional production. If uncontrolled, UP-PCN (unintentionally produced PCNs) emissions could increase with industrial development. The abnormally high concentrations at Gongga and Changbai Mountains appear to be associated with the high efficient of forest filter of atmospheric contaminants at these densely forested sites. We question whether this is caused by ecotones between forests, and raise additional questions for future analyses.

The distribution of selected elements and minerals in soil of the conterminous United States

In 2007, the U.S. Geological Survey initiated a low-density (1 site per 1600km2, 4857 sites) geochemical and mineralogical survey of soil of the conterminous United States as part of the North American Soil Geochemical Landscapes Project. Three soil samples were collected, if possible, from each site; (1) a sample from a depth of 0 to 5cm, (2) a composite of the soil A-horizon, and (3) a deeper sample from the soil C-horizon or, if the top of the C-horizon was at a depth greater than 100cm, from a depth of approximately 80–100cm. The <2mm fraction of each sample was analysed for a suite of 45 major and trace elements following near-total multi-acid digestion. The major mineralogical components in samples from the soil A- and C-horizons were determined by a quantitative X-ray diffraction method using Rietveld refinement. Sampling ended in 2010 and chemical and mineralogical analyses were completed in May 2013. Maps of the conterminous United States showing predicted element and mineral concentrations were interpolated from actual soil data for each soil sample type by an inverse distance weighted (IDW) technique using ArcGIS software. Regional- and national-scale map patterns for selected elements and minerals apparent in interpolated maps are described here in the context of soil-forming factors and possible human inputs. These patterns can be related to (1) soil parent materials, for example, in the distribution of quartz, (2) climate impacts, for example, in the distribution of feldspar and kaolinite, (3) soil age, for example, in the distribution of carbonate in young glacial deposits, and (4) possible anthropogenic loading of phosphorus (P) and lead (Pb) to surface soil. This new geochemical and mineralogical data set for the conterminous United States represents a major step forward from prior national-scale soil geochemistry data and provides a robust soil data framework for the United States now and into the future.

Paleoenvironmental and geoarchaeological reconstruction from late Holocene slope records (Lower Huerva Valley, Ebro Basin, NE Spain)

Slope deposits in semiarid regions are known to be very sensitive environments, especially those that occurred during the minor fluctuations of the late Holocene. In this paper we analyse Holocene colluvium genesis, composition, and paleoenvironmental meaning through the study of slope deposits in NE Spain. Two cumulative slope stages are described during this period. In the study area, both slope accumulations are superimposed and this has enabled an excellent preservation of the aggregative sequence and the paleosols corresponding to stabilisation stages. 14C and TL dating, as well as archaeological remains, provide considerable chronological precision for this sequence. The origin of the accumulation of the lower unit is placed around 4295–4083calyr BP/2346–2134calyr BC (late Chalcolithic) and it developed until the Iron Age in a cooler and wetter climate (Cold Iron Age). Under favourable conditions, a soil A-horizon was formed on top of this unit. A new slope accumulation was formed during the Little Ice Age. Within the slope two morphogenetic periods ending with A-horizons are distinguished and related with two main cold–wet climatic events. The study of these slopes provides a great amount of data for the paleoenvironmental and geoarchaeological reconstruction of the late Holocene in NE Spain.

Statistical variability of the geochemistry and mineralogy of soils in the Maritime Provinces of Canada and part of the Northeast United States

A soil geochemical survey in the Maritime Provinces of Canada and part of the Northeast United States was completed for the North American Soil Geochemistry Landscapes Project. Soil samples, derived largely from unsorted glacial till, were collected over 349 sites, from 0 to 5 cm depth (regardless of horizon), A-, and C-horizons. The 0 to 5 cm depth interval represents the soil of interest in health risk assessments and is termed the Public Health (PH-) layer. The &lt;2 mm fraction of each sample was analysed for a broad suite of major and trace elements using a near-total four-acid digestion, and major mineralogical components were determined by quantitative X-ray diffraction. Multivariate statistical analyses of the logcentred soil geochemistry from the PH-layer and the two soil horizons, and of the soil mineralogy from the A- and C-horizons, reveal distinctive inter-element relationships from deeper soil (represented by the C-horizon) upwards into topsoil (represented by the A-horizon and PH-layer). Statistical dispersion of several elements increases upwards in the soil profile. Maximum data dispersion occurs in the PH-layer and A-horizon soils. Elements including S, P, Pb, Hg, Cd, Se, Mo, Sb, Bi and Sn are relatively enriched in the PH-layer and A-horizon, and are positively correlated with increasing organic carbon contents. The relative enrichment of groups of elements in the C-horizon, in contrast to those elements in the A-horizon and PH-layer, suggests a composition that reflects the geochemistry of the glacial till that is derived from the local bedrock. Elements such as Ni, Mg, Cr, V, Co, Fe and Sc, represent a mafic component of the parent material, and relative enrichments of K, Rb, Zr, rare-earth elements, Li and Al indicate a more felsic component. The patterns revealed by the application of multivariate methods to the soil chemistry and mineralogy are attributed to underlying geology, soil-forming processes, and anthropogenic activity, or combinations of all three factors. Both the soil geochemistry and mineralogy were tested in their ability to predict soil horizon and underlying bedrock lithology or time-stratigraphic assemblages. The geochemistry and mineralogy of the soils are both good for predicting soil horizon; however, the soil geochemistry is better for predicting the underlying lithologies/assemblages than the soil mineralogy.

Influence of Soil Geochemical and Physical Properties on Chromium(VI) Sorption and Bioaccessibility

The Department of Defense (DoD) is faced with the daunting task of possible remediation of numerous soil-Cr(VI) contaminated sites throughout the continental U.S. The primary risk driver at these sites is hand-to-mouth ingestion of contaminated soil by children. In the following study we investigate the impact of soil geochemical and physical properties on the sorption and bioaccessibility of Cr(VI) in a vast array of soils relevant to neighboring DoD sites. For the 35 soils used in this study, A-horizon soils typically sorbed significantly more Cr(VI) relative to B-horizon soils. Multiple linear regression analysis suggested that Cr(VI) sorption increased with increasing soil total organic C (TOC) and decreasing soil pH. The bioaccessibility of total Cr (CrT) and Cr(VI) on the soils decreased with increasing soil TOC content. As the soil TOC content approached 0.4%, the bioaccessibility of soil bound Cr systematically decreased from approximately 65 to 10%. As the soil TOC content increased from 0.4 to 4%, the bioaccessibility of Cr(VI) and CrT remained relatively constant at approximately 4% and 10%, respectively. X-ray absorption near edge structure (XANES) spectroscopy suggested that Cr(VI) reduction to Cr(III) was prevalent and that the redox transformation of Cr(VI) increased with increasing soil TOC. XANES confirmed that nearly all bioaccessible soil Cr was the Cr(VI) moiety. Multiple linear regression analysis suggested that the bioaccessibility of Cr(VI) and its reduced counterpart Cr(III), decreased with increasing soil TOC and increasing soil pH. This is consistent with the observation that the reduction reaction and formation of Cr(III) increased with increasing soil TOC and that Cr(III) was significantly less bioaccessible relative to Cr(VI). The model was found to adequately describe CrT bioaccessibility in soils from DoD facilities where Cr(VI) contaminated sites were present. The results of this study illustrate the importance of soil properties on Cr(VI) sorption and bioassessability and help define what soil types have the greatest risk associated with Cr(VI) exposure.

Substrate modification for enhanced native forest restoration, Reefton

SummaryRestoration of postmining substrates to native forest is a standard requirement of resource consents for mine sites located within areas of native forest in New Zealand. Unweathered waste rock presents significant challenges for plant growth, and past research highlights the importance of replacing soil as part of restoration. However, replacing soil with its horizon structure intact or even obtaining sufficient soil for restoration can be a challenge in some situations. In this paper, we describe the results of two trials undertaken at the OceanaGold Ltd. open‐cast gold mine in Reefton to explore the influence of substrate conditions on the growth of native forest seedlings. We show that beech (Nothofagus) seedlings grown on A‐horizon soil grew significantly better than those grown on soil mixed with waste rock, and both grew significantly better than plants grown just on waste rock. In the second trial, we show that bark chips are not a good substitute for soil. These results confirm the importance of having the correct substrate for successful native forest restoration.