Sodium Chloride Concentration Research Articles

Effect of Temperature and Salinity on Survival of Protoscoleces of Hydatid Cyst in Liver In Vitro.

Hydatid cyst is the metacestode stage of Echinococcus granulosus that occurs in herbivores and humans as intermediate hosts by consuming parasite eggs through forage and vegetables. Carnivores, as definitive hosts, become infected by consuming infected vesicles of herbivores. The most effective treatment for a hydatid cyst is surgical operation. Inactivating E. granulosus protoscoleces through heating, cooling, or chemicals such as sodium chloride can be considered an effective method for controlling hydatidosis in both humans and animals. The main objective of this study was to evaluate the effect of different temperatures and salinity conditions on the survival of Echinococcus granulosus protoscoleces. For this purpose, 50 g of infected liver (in triplicate) was separately treated with different temperatures (+10°C, +50°C, +60°C, +72°C, and -20°C) and concentrations of sodium chloride (5%, 10%, 15%, and 20%) for 3, 6, 12, 24, 48, and 72 h. Additionally, 50 g of infected liver was stored separately in the refrigerator (+4°C) as a control group. The survival rate of the protoscoleces was evaluated by staining with 1% eosin under a light microscope. The results showed that the protoscoleces were significantly affected, with 100% mortality at -20°C after 0.5 h, and complete death at +72°C, +60°C, +50°C, and +10°C after 1, 1.5, 3, and 24 h, respectively (p < 0.005). Similarly, the protoscoleces in the liver mass survived at 5% NaCl after 3 h but died at 10% after 24 h, at 15% after 12 h, and at 20% after 6 h. It is concluded that exposing the liver infected with protoscoleces hydatid cyst to a temperature of -20°C and a sodium chloride concentration of 10% for 24 h is suitable for inactivating the protoscoleces.

The use of amines as steel corrosion inhibitors in butanol-gasoline blends

Butanol is an interesting component used for blending gasoline fuels. However, the polar nature of butanol allows the solubility of water and ionic compounds in butanol-gasoline blends (BGBs) making them aggressive to mild steel. Amines, such as ethylenediamine, diethylenetriamine, triethylenetetramine, tetraethylenepentaamine, morpholine, piperazine, and hexamethylenediamine, were tested as corrosion inhibitors for mild steel in BGBs. Additionally, the influence of the acetic acid and sodium chloride concentrations on the inhibition efficiency was examined. Electrochemical impedance spectroscopy andpotentiodynamic polarization were employed for the measurements, complemented by static immersion testing and an XPS surface analysis. The highest inhibition efficiency was demonstrated for diethylenetriamine, triethylenetetramine, andhexamethylenediamine, achieving a value of 95 % or more at aconcentration of 100 mg/L. The formation of ionic pairs involving protonated amines andchlorides was also confirmed. The XPS analysis revealed a very thin passive layer of iron oxides, which may form in the presence of amines, protecting mild steel in BGBs.

REMOVAL OF LINEAR ALKYLBENZENE SULFONATE BY ELECTROCOAGULATION/FLOTATION USING A CYLINDRICAL VERTICAL REACTOR

This study proposes a vertical electrocoagulation/flotation reactor model and evaluates its efficiency through hydraulic tests and the removal of linear alkylbenzene sulfonate (LAS), a common wastewater surfactant. Residence time distribution assays and computational fluid dynamics verified the fluid flow pattern. Response surface methodology (RSM) was used to assess the impact of pH, electric current, and sodium chloride concentration on LAS removal. Ecotoxicity tests using Artemia salina detected no toxic byproducts from electrocoagulation/flotation (ECF). Adsorption kinetics and isotherms were used to evaluate the removal behavior of LAS, which showed the highest efficiencies with an electric current of 1.5A, a pH of 5.73, and a NaCl concentration of 4652.4mgL-1. The electric current and pH were the most influential variables. The ecotoxicity assay indicated no toxic byproduct generation, even at high chloride concentrations, and increased LAS biodegradability posttreatment. Adsorption kinetics followed a pseudo-first-order model at 20mg/L and a pseudo-second-order model at 240mg/L. The Freundlich isotherm indicated a high affinity between the LAS and aluminum hydroxide flakes, achieving nearly 90% removal in 30min at an energy cost of 5.25Wh.

Salt-responsive polyamide thin-film nanocomposite membrane based on zwitterionic polymeric nanoparticles for high-efficient dye desalination

To simultaneously improve the water permeability, selectivity, and antifouling properties of polyamide nanofiltration (NF) membranes in textile wastewater treatment, we fabricated a salt-responsive thin-film nanocomposite (TFN) membrane with the incorporation of zwitterionic polymeric nanoparticles (ZNPs) into polyamide selective layer. Herein, the ZNPs were synthesized via an inverse miniemulsion polymerization with zwitterionic monomer, amino monomer, and cross-linker reagent. The salt-responsive property of ZNPs rendered their resultant membranes TFN-ZNPs with adjustable microstructure and separation performance via varying the sodium chloride (NaCl) concentration in water. The water permeance of TFN-ZNPs was enhanced to be 1.7 times that of its pure water permeance with the 10 g L-1 NaCl solution, and the salt-responsive behavior was reversible. Moreover, this salt-responsive property endowed the membrane with outstanding separation performance for the salt/dye or dye/dye mixtures. The selectivity of TFN-ZNPs to NaCl/congo red and methyl orange/ neutral blue was enhanced to ∼104 and ∼127, respectively. The TFN-ZNPs with salt-responsive property also exhibited an improved antifouling performance, i.e., the flux recovery ratio was enhanced from 85.6% to 96.5% by washing with NaCl solution instead of deionized water. Thus, this work provided a paradigm shift in the fabrication of salt-responsive TFN membranes for the highly efficient separation of organic molecules and inorganic salts and wastewater treatment.

Isolation, molecular identification, and genomic analysis of Mangrovibacter phragmitis strain ASIOC01 from activated sludge harboring the bioremediation prowess of glycerol and organic pollutants in high-salinity.

The physiological and genotypic characteristics of Mangrovibacter (MGB) remain largely unexplored, including their distribution and abundance within ecosystems. M. phragmitis (MPH) ASIOC01 was successfully isolated from activated sludge (AS), which was pre-enriched by adding 1,3-dichloro-2-propanol and 3-chloro-1,2-propanediol as carbon sources. The new isolate, MPH ASIOC01, exhibited resilience in a medium containing sodium chloride concentration up to 11% (with optimal growth observed at 3%) and effectively utilizing glycerol as their sole carbon source. However, species delimitation of MGBs remains challenging due to high 16S rRNA sequence similarity (greater than 99% ANI) among different MGBs. In contrast, among the housekeeping gene discrepancies, the tryptophan synthase beta chain gene can serve as a robust marker for fast species delimitation among MGBs. Furthermore, the complete genome of MPH ASIOC01 was fully sequenced and circlized as a single contig using the PacBio HiFi sequencing method. Comparative genomics revealed genes potentially associated with various phenotypic features of MGBs, such as nitrogen-fixing, phosphate-solubilizing, cellulose-digesting, Cr-reducing, and salt tolerance. Computational analysis suggested that MPH ASIOC01 may have undergone horizontal gene transfer events, possibly contributing unique traits such as antibiotic resistance. Finally, our findings also disclosed that the introduction of MPH ASIOC01 into AS can assist in the remediation of wastewater chemical oxygen demand, which was evaluated using gas chromatograph-mass spectrometry. To the best of our knowledge, this study offers the most comprehensive understanding of the phenotypic and genotypic features of MGBs to date.

Characterization of the Solution Properties of Sodium Dodecylsulphate Containing Alkaline–Surfactant–Polymer Flooding Media

Alkaline–surfactant–polymer (ASP) flooding by means of which alkali additives, surfactant and polymer are inserted as the same slug is one of the most favourable worldwide focuses of Chemical Enhanced Oil Recovery (cEOR) research and field trials, due to the individual synergy of the three chemical components. To develop efficient oil recovery chemicals, it is essential to fully understand the mechanism behind ASP flooding. Nonetheless, there are hardly any studies reporting a systematic characterization of the ASP process. Thus, the present paper focuses on modelling this process in a laboratory by the use of an anionic surfactant—sodium dodecyl sulphate (SDS) in alkaline–polymer media—which is composed of a commercial water-soluble polymer (Flopaam AN125SH®, SNF Floerger, Andrézieux-Bouthéon, France) and alkali compounds (NaOH and Na2CO3). The samples were characterized using rheometry, dynamic light scattering (DLS), infrared spectroscopy (IR) and measurement of inferfacial tension (IFT) between the samples and rapeseed oil. In accordance with the experimental results, surprisingly lower IFT values were recorded between the alkaline–polymer solutions and rapeseed oil than the samples which contained SDS. Increasing polymer and sodium chloride concentration caused a decrease (from 0.591 mN/m to 0.0486 mN/m) in IFT between the surfactant containing samples and rapeseed oil. The IR measurements confirmed that the surfactant was not detected in the oil phase in the absence of NaOH and Na2CO3. The effects of SDS on the viscosity of the mixtures were also investigated, as viscosity is a considerably important parameter in processes using polymers.

Revealing the effects of amino acid, organic acid, and phytohormones on the germination of tomato seeds under salinity stress.

Salinity accumulation poses a threat to the production and productivity of economically important crops such as tomatoes (Solanum lycopersicum L.). Currently, salt tolerance breeding programs have been limited by insufficient genetic and physiological knowledge of tolerance-related traits and a lack of an efficient selection domain. For that purpose, we aimed to determine the ability of tomato cultivars to tolerate salt based on seed traits by multiple biochemical pathways. First, we tested three tomato cultivars according to their response to different sodium chloride (NaCl) concentrations (0, 6.3, 9.8, 13.0, and 15.8 dS m-1) and then we analysed their amino acids, organic acids, and phytohormones. Considering the results of germination traits, it is possible to conclude that cultivar H-2274 was more tolerant to salt stress than others. As a result, multivariate discriminant analysis including principal component analysis and two-way hierarchical clustering analyses were constructed and demonstrated that tomato cultivars were separated from each other by the amino acid, organic acid, and phytohormone contents. Considering germination traits of tomato seeds, cv. 'H-2274' was more tolerant to salinity than others depending on high proline (29 pmol µl-1) and citric acid (568 ng µl-1) assays. Biochemical variability offers a valuable tool for investigating salt tolerance mechanisms in tomatoes, and it will be appreciated to find high-tolerant tomato cultivar(s) to saline conditions. Also, the findings of this study have significant potential for practical applications in agriculture, particularly in developing salt-tolerant tomato cultivars to enhance productivity in saline environments and address socio-economic challenges.

Electrocoagulation employing recycled aluminum electrodes for methylene blue remediation

This work focuses on the recycling of aluminum-based metal joinery waste in the context of the treatment of wastewater containing organic materials, such as dyes, by electrocoagulation (EC); aluminum scraps were used as electrodes to process synthetic solutions of the methylene blue (MB) dye. The study investigated the effect of different parameters, including pH (3, 4, 5, 7, 9, 11) current density (100, 150, 200, 250 A/m2), electrolysis time (30, 60,120 min), sodium chloride concentration (0.5, 1, 2 g/L) and the initial dye concentration (10, 20, 45, 60 mg/L) on the removal efficiency of MB. The results showed that the optimum conditions for MB removal were achieved at the original pH of the solution which is 7 using a current density of 200 A/m2 and an inter-electrode distance of 1 cm with 10 mg/L as a dye concentration and 2 g/L of electrolyte. The removal efficiency under these conditions can reach 97.81 %. An estimation was made of the electrical energy needed to attain the ideal removal, which was found to be approximately 0.97kWh/g removal dyestuff the electrode consumption was 0.13 (kgAl /g of dyestuff), with an operation cost of 0.106 ($/g of dyestuff). The study suggests that EC using only two aluminum electrodes is efficient technique for the removal of MB from synthetic wastewater. The removal of the dye was monitored by UV–visible spectroscopy and scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR) is used for the identification of the functional groups of MB in the obtained sludge by the EC process; and the aluminum electrodes surfaces, before and after treatment, were characterized by scanning electron microscopy (SEM) and Dispersive Energy Spectroscopy (EDS).

Electrochemical Polishing Method for Titanium Alloys with a Microgroove Structure

TI–6AL–4V alloys are widely used in various fields owing to their excellent corrosion resistance, high-temperature resistance, and low-temperature toughness. Herein, a microgroove fixture was used to simulate the microgrooves in a titanium alloy with different aspect ratios to study the influence of the electrolyte flow rate on the polishing effect. The optimization of the electrochemical polishing parameters was conducted using experiments and simulations. The effects of process parameters, such as the concentration of sodium chloride (NaCl) and zinc chloride (ZnCl2), polishing time, and processing voltage, on the quality of the post-polished surface were studied. Experiments were conducted on microgrooves with different aspect ratios under the optimized polishing process parameters. Changes in the surface elements of the microgrooves after polishing were detected. The experimental results indicated that the optimal electrochemical polishing solution flow rate, NaCl concentration, ZnCl2 concentration, polishing time, and processing voltage were 0.2 m/s, 4.0 wt.%, 0.4 wt.%, 8 min, and 90 V, respectively. After 8 min of electrochemical polishing, a TiO2 passivation film was formed on the surface of the microgroove. The surface roughness of the notch and bottom of the microgroove decreased from 250 nm to below 40 nm, with a minimum of 24.5 nm.

Effects of the Salt Stress Duration and Intensity on Developmental and Physiological Features of the Moss Polytrichum formosum.

The two accessions of the polytrichaceous moss species Polytrichum formosum, namely German and Serbian genotypes, were subjected to salt stress, aiming to study the species' developmental and physiological features. Various concentrations of sodium chloride were applied to an axenic in vitro culture of the two moss genotypes, and the growth parameters as well as physiological feature changes were followed. As inferred by the morpho-developmental parameters and survival index, the Serbian genotype showed higher resistance to salt stress as compared to the German one. However, both moss genotypes survived the highest applied concentration (500 mM). As expected, short exposures to salt were rather easily overcome. No clear patterns in sugar content and changes were observed during the stress, but they are surely included in salt stress response and tolerance in P. formosum. Longer stress increased total chlorophyll content in both genotypes. In short-term applied salt stress, the Serbian genotype had a higher total chlorophyll concentration to control unstressed plants, while the German genotype decreased the total amount of chlorophyll. Similarly, carotenoids were shown to be significantly higher in the Serbian genotype, both in unstressed and treated plants, compared to the German one. The contents of tocopherols were higher in the Serbian genotype in controlled unstressed and subsequently short- and long-stressed plantlets compared to the German accession. In general, we can assume that P. formosum is unexpectedly tolerant to salt stress and that there are differences within various accessions of overall European populations, as referred by two randomly selected genotypes, which is most probably a consequence of different genetic structure.

Development of standard operating procedure "Quality control of sodium chloride solution 0.9% (350 ml) for infusion (intra-pharmacy preparation) in pharmacy organizations manufacturing pharmaceuticals"

To develop a standard operating procedure (SOP) for quality control of 0.9% sodium chloride solution (350 ml) for infusion (intra-pharmacy preparation) in accordance with the requirements of the current regulatory documentation. Materials and Methods. Sodium chloride 0.9% sodium chloride solution (350 ml) for infusion (intra-pharmacy preparation) served as the object of the study. The SOP was developed taking into account the requirements of updated regulatory documents used in the field of quality control of medicines: Federal Law No. 61 dated 12.04.2010 "On Circulation of Medicines", Order of the Ministry of Health of the Russian Federation dated 22.05.2023 No. 249n, Order of the Ministry of Health of the Russian Federation dated 22.05.2023 No. 647n dated 31.08.2016, State Pharmacopoeia XV ed. and GOST R 52249-2009. Results. The main stages of the SOP in accordance with the current regulatory documentation are given, reagents, instruments and equipment required for testing are listed, mandatory and sample types of control are indicated. For this dosage form the mandatory controls will be organoleptic, written, control at release, physical and full chemical control. The methods of pH and authenticity tests are described, and the chemistry of qualitative reactions is given. For quantitative determination by the method of argentometry according to Mohr, the method of analysis is given, chemical reactions occurring during titration, the necessary calculations are made: the titer of silver nitrate solution of sodium chloride, the preliminary volume of titrant, the content of sodium chloride in the dosage form in grams. Permissible content limits are given in accordance with OFS.1.8.0001 "Medicinal preparations of pharmacy manufacture". Based on the results of the SOP development, a working instruction for quality control of sodium chloride solution 0.9% (350 ml) for infusion was drawn up. Conclusion. The presented SOP for quality control of sodium chloride solution 0.9% (350 ml) for infusion (intra-pharmacy preparation) describes the requirements for the organization and conditions of testing in assessing the quality of this dosage form and can be implemented in the work of manufacturing pharmacies as a detailed instruction for intra-pharmacy control.

Ecological Studies on the Soil and Vegetation of Krusadi Group of Islands in the Gulf of Manaar

The account presents the plant ecology with a description of soils and other related features of the Krusadi group of islands situated in the Gulf of Manaar approximately between 9°14'-9°15'N and 79°10.5'-79°14.5' E. Data on pH, organic matter contents, total soluble salts, sodium chloride contents and calcium carbonate contents in the soils of different habitats are presented in tabular form and an attempt made to correlate vegetation with the soil features. A classification of vegetation situations rather than strictly vegetation type has been brought out and comparison made with the main neighbouring island of Rameswaram with similar climate. The paper includes a vegetation map of the area prepared during the field work.

Effect of Gibberellic Acid and Mechanical Scarification on the Germination and Seedling Stages of Chenopodium quinoa Willd. under Salt Stress.

Quinoa (Chenopodium quinoa Willd.) is a facultative halophyte renowned for its importance in enhancing food security, and it supports forage production across diverse climatic regions. The objective of this study is to examine the impacts of multiple pre-treatment methods on C. quinoa seed (Titicaca cultivar) germination parameters, identify the optimum pre-treatment to diminish the consequence of salinity, and promote the productivity of this crop, especially in marginal environments. For this purpose, a spectrum of sodium chloride (NaCl) concentrations spanning from 0 to 500 mM and gibberellic acid (GA3) concentrations ranging from 0 to 300 ppm were tested, and mechanical scarification (MS) was carried out. The effect of a combination of these pretreatment NaCl/GA3 and NaCl/MS on the germination parameters of C. quinoa seed was also investigated. The results showed that the total germination, vigor index, and germination index decreased progressively with an increase in salinity. Hence, salinity exhibited a notable influence on most germination parameters. Moreover, seeds scarified with 500 mM of NaCl negatively affected all measured parameters. In contrast, gibberellic acid applied at 200 ppm was effective on most of the parameters measured, particularly under 100 mM of NaCl. These findings indicate that immersing seeds in gibberellic acid could mitigate the adverse impacts of salinity.

Wood Distillate Promotes the Tolerance of Lettuce in Extreme Salt Stress Conditions.

Soil salinization is an adverse phenomenon in agriculture that severely affects crop growth and yield. The use of natural products, such as wood distillate (WD, derived from the pyrolysis of woody biomass), could be a sustainable approach to enhance the tolerance of plants cultivated in the saline soils. Hence, this study aimed to evaluate the potential of WD, a foliar sprayed at 0.2% (v/v), in lettuce plants subjected to grow under both moderate and high soil sodium chloride (NaCl) concentrations (ranging from 0 to 300 mM). The changes in the physiological and biochemical responses of these plants to the varying salt stress conditions allowed the identification of a maximum tolerance threshold (100 mM NaCl), specific to lettuce. Beyond this threshold, levels related to plant defense antioxidant power (antiradical activity) were lowered, while those indicative of oxidative stress (malondialdehyde content and electrolyte leakage) were raised, causing significant losses in leaf fresh biomass. On the other hand, WD significantly improved plant growth, enabling plants to survive high salt conditions >200 mM NaCl. Collectively, these observations highlight that treatments with WD could be of paramount importance in coping with current environmental challenges to have better yields under soil conditions of high salt concentrations.

Clinical and Ultrasound Efficacy of Topical Hypertonic Cream (Jovita Osmocell®) in the Treatment of Cellulite: A Prospective, Monocentric, Double-Blind, Placebo-Controlled Study.

Background and Objectives: Cellulite, or edemato-fibro-sclerotic panniculopathy (EFP), is characterized by dermal and hypodermal changes leading to adipose tissue accumulation and compromised venous circulation. This study investigates the efficacy of a hypertonic cream containing concentrated sodium chloride (Jovita Osmocell®) in addressing water retention and structural alterations in adipose tissue, aiming to interrupt the cellulite formation process. Materials and Methods: A 12-week, prospective, monocentric, double-blind, placebo-controlled study enrolled 30 female subjects with grade II or III cellulite. Patients were randomized to receive hypertonic cream or a placebo. Thigh circumference, ultrasound evaluations, and standardized photographs were collected at baseline, intermediate, and endpoint visits. Adverse events were monitored. Results: After 84 days, the hypertonic cream group exhibited a significant reduction in thigh circumference compared to the placebo group (p = 0.0037). B-mode ultrasound examinations revealed significant changes in the parameters studied, such as the thickness of the subcutaneous tissue. No statistically significant changes were noticed in the placebo group. Volunteers reported the investigational product's pleasantness and good anti-cellulite activity, with no reported adverse events. Conclusions: The hypertonic cream demonstrated efficacy in reducing thigh circumference, addressing water retention and structural alterations in adipose tissue. The proposed mechanism involves osmosis, releasing accumulated fluids between fat cells, supporting drainage, and reducing inflammation. This study supports the efficacy and safety of hypertonic sodium chloride emulsions in cellulite treatment and confirms safety and user satisfaction.

Preparation, taste characterization, and evaluation of oyster composite products with increased umami and salty

Excessive consumption of sodium chloride is known to contribute to a range of health issues. Umami components, when combined with salt, can effectively lower sodium consumption due to their synergistic flavor enhancement. In this research, through sensory evaluation, electronic tongue, and electronic nose, we have determined the optimal formulation of oyster extracts for a Composite Umami-Enhancing Seasoning (CUES). The ideal CUES formulation comprises 50% monosodium glutamate (MSG), 16% salt, 6% sugar, 5% maltodextrin, 10 % of oyster powder (OY–W), 10% plant hydrolyzed protein, and 3% I + G. The OY-W fraction contains a low-threshold umami peptide that enhances the overall taste profile. Sensory evaluation indicates that the CUES formulation diminishes perceived sourness, sweetness, and bitterness, while simultaneously elevating the umami and saltiness compared to OY-W alone. Among the CUES formulations with an equivalent sodium chloride content, M-PO achieves the highest umami value. CUES were distinguished by Principal Component Analysis (PCA) analysis from the electronic nose, and odor profiles of M-PO and a commercially available clam-based umami enhancer (BWG) were similar. The W5S component was identified as the most significant contributor. The physical properties of the CUES formulations were systematically evaluated, taking into account factors such as water loss, moisture retention, hygroscopicity, bulk density, solubility, and flowability. The utilization of maltodextrin has led to a significant enhancement in water loss and moisture retention. This study paves the way for the development of low-sodium seasoning alternatives that can satisfy consumer taste preferences without compromising health and safety.

MOF-derived porous carbon microspheres Ni@C-acid as solid-phase microextraction coating for extraction of polycyclic aromatic hydrocarbons from tea infusions

The improvement of the stability and adsorption properties of materials on targets in sample pre-treatment has long been an objective. Extensive efforts have been made to achieve this goal. In this work, metal-organic framework Ni-MOF precursors were first synthesized by solvothermal method using polyvinylpyrrolidone (PVP) as an ideal templating agent, stabiliser and nanoparticle dispersant. After carbonization and acid washing, the nanoporous carbon microspheres material (Ni@C-acid) was obtained. Compared with the material without acid treatment (Ni@C), the specific surface area, pore volume, adsorption performance of Ni@C-acid were increased. Thanks to its excellent characteristics (high stability, abundant benzene rings), Ni@C-acid was used as fiber coatings in headspace solid-phase microextraction (HS-SPME) technology for extraction and preconcentration of polycyclic aromatic hydrocarbons (PAHs) prior to gas chromatography-flame ionization detector (GC-FID) analysis. The experimental parameters of extraction temperature, extraction time, agitation speed, desorption temperature, desorption time and sodium chloride (NaCl) concentration were studied. Under optimal experimental conditions, the wide linear range (0.01-30 ng mL−1), the good correlation coefficient (0.9916-0.9984), the low detection limit (0.003-0.011 ng mL−1), and the high enrichment factor (5273-13793) were obtained. The established method was successfully used for the detection of trace PAHs in actual tea infusions samples and satisfied recoveries ranging from 80.94-118.62 % were achieved. The present work provides a simple method for the preparation of highly stable and adsorbable porous carbon microsphere materials with potential applications in the extraction of environmental pollutants.

Potential-Modulated Surface-Enhanced Raman Spectroscopy of Tolmetin at Gold Nanoparticle Film Functionalized Polarizable Liquid-Liquid Interfaces.

An aqueous colloidal suspension of gold nanoparticles (AuNPs) may be condensed into a thin fractal film at the polarizable liquid-liquid interface formed between two immiscible electrolyte solutions upon injection of millimolar concentrations of sodium chloride to the aqueous phase. By adjusting the interfacial polarization conditions (negative, intermediate, and positive open-circuit potentials), the morphology of the film is modified, resulting in unique surface plasmon properties of the film, which enable in situ surface-enhanced Raman spectroscopy (SERS). Intense SERS signals are observed at the polarizable liquid-liquid interface when micromolar concentrations of tolmetin, a nonsteroidal anti-inflammatory drug, are entrapped in the AuNP fractal film. The change in the signal intensity, averaged over multiple spectra, with respect to the concentration of tolmetin, depends on the polarization conditions and suggests the presence of chemical-induced damping effects on the surface plasmons of the gold film.

Multiple factors influencing high-purity indium electrolytic refining

The effects of various contaminants in the electrolytic refinement of indium were investigated using a glow discharge mass spectrometer (GDMS). The effects of several factors such as the indium ion (In3+) concentration, the sodium chloride (NaCl) concentration, the current density, the gelatin concentration, the pH, and the electrode distance, were examined. Significant variations in impurity levels concerning gelatin concentration were observed. Both the gelatin and In3+ concentration were moderately positively correlated with the Pb content. The Sb concentration was associated positively with the NaCl concentration, while the Ti concentration had an adverse correlation with the NaCl concentration. The Bi element content was positively linked to the electrode distance. As the current density increased, Cu, Pb, and Bi impurities initially rose and then eventually declined. Notably, a critical current density of 45 A·m−2 was identified in this behavior.

Investigation of the Physicochemical Properties and its Correlation during Koji-Moromi Fermentation Stage of Production Soy Sauce Naturally Brewed in Central Java, Indonesia

Soy sauce, a widely consumed condiment, undergoes intricate physicochemical transformations during its natural fermentation process. This research delved into the analysis of physical and chemical properties in naturally brewed soy sauce, aiming to elucidate the impact of fermentation stages (Koii, earlier moromi, final moromi, soy sauce product) and sample variations on these properties. Parameters such as pH, total acid, total soluble solids, and water activity (aw) were assessed. Additionally, chemical attributes were analyzed, including total nitrogen, crude protein, formol nitrogen, and sodium chloride (NaCl) content. The correlation between physical and chemical properties during the fermentation stages was determined using the principal component analysis (PCA) method. The fermentation process significantly affected soy sauce's physical and chemical properties. Key factors include total dissolved solids, water activity, total acids, salt, total nitrogen, crude protein, and formol nitrogen, which display distinct patterns. These fluctuations were primarily driven by microbial activity and enzymatic hydrolysis, and total nitrogen, crude protein, and formol nitrogen play pivotal roles in characterizing soy sauce quality. Remarkably, total acid content and pH values exhibited significant variations that deviate from expected correlations due to weak acids. Samples C and D were deemed the most suitable out of the five tested, aligning better with quality standards for soy sauce. This study sheds light on the complex physicochemical changes during soy sauce fermentation, emphasizing the impact of raw materials and microbial processes on its properties.