With the continuous development of mobile communication and satellite navigation technologies, the positioning requirements of 5G smart communication base stations are becoming higher and higher. With the opening of GNSS raw observation data, research on the positioning of a 5G smart communication base station has become a research hotspot in the surveying and mapping disciplines. In this paper, based on the GNSS observation data of the 5G smart communication base station, the quality of the original GNSS observation data of the 5G smart communication base station is studied and analyzed. A method based on Doppler smoothing pseudorange solves the problem that the original pseudorange observation values of the 5G smart communication base station are noisy and prone to multipath errors due to the limitations of the base station chips and processes, which makes the traditional data processing methods unable to meet the demand for higher accuracy positioning. This method uses Doppler observations to smooth the pseudorange and determines the Doppler smoothing strategy and closure values to improve the data quality. The experimental data show that Doppler smoothing pseudorange can improve data quality and positioning accuracy by 67.9% in the E direction, 64.8% in the N direction, and 65.5% in the U direction. The future world will develop in the direction of intelligence, and the wireless network 5G technology used to support the construction of this intelligent system will become the core driver for the development of a leading intelligent society. 5G network signals have higher reliability and lower latency and can meet the specific needs of smart manufacturing, autonomous driving, and other industrial applications. This new base station product can meet the construction needs of future 5G base stations, adapt to the future intensive, miniaturized, intelligent station construction mode, and realize safe and fast station construction, providing the necessary hardware support for 5G network coverage.