Small Radius Research Articles

Localized Water Restriction in Ternary Eutectic Electrolytes for Ultra‐Low Temperature Hydrogen Batteries

AbstractProton batteries are promising candidates for next‐generation large‐scale energy storage in extreme conditions due to the small ionic radius and efficient transport of protons. Hydrogen gas, with its low working potentials, fast kinetics, and stability, further enhances the performance of proton batteries but necessitates the development of novel electrolytes with low freezing points and reduced corrosion. This work introduces a localized water restriction strategy by incorporating a tertiary component with a high donor number, which forms strong bonds with water molecules. This approach restricts free water molecules and reduces the average hydrogen bond ratio and strength. As‐prepared ternary eutectic electrolytes lowered the freezing point to −103 °C, significantly lower than the traditional binary electrolyte (9.5 m H3PO4, −93 °C). This electrolyte is highly compatible with the Cu0.79Co0.21[Fe(CN)6]0.64 ⋅ 4H2O (CoCuHCF) cathode, reducing material dissolution and current collector corrosion. The H2||CoCuHCF battery using this electrolyte demonstrated a high‐power density of 23664.3 W kg−1, excellent performance at −80 °C, and stable cyclability over 1000 cycles (>30 days) at −50 °C. These findings provide a framework for proton electrolytes, highlighting the potential of hydrogen batteries in challenging environments.

Design and development of bridge erecting machine with small curve radius and bottom feeding beam.

As a key equipment in highway and railway construction, bridge erecting machines directly affect the feasibility, progress, and quality of project implementation. In order to solve the problem that traditional bridge building machines are only suitable for application scenarios with large turning radii and large lifting sites, and have low lifting efficiency, which cannot meet the requirements of urban elevated bridge construction, a small radius bottom feeding beam bridge building machine suitable for urban highway and railway construction is proposed. The feasibility and reliability were verified through force analysis and finite element analysis; Design a secondary turning structure and bridge construction process for the front leg, adjusting the turning angle to around 7°, significantly reducing the turning radius of the bridge building machine; Propose a technology for feeding and lifting beams at the bottom of dual-use bridge decks for highways and railways. By vertically lifting beams and slabs, the lifting space is significantly reduced and the lifting efficiency is improved. Finally, a small radius bottom feeding beam bridge erecting machine was developed and tested and applied. The results show that the small radius bottom feeding beam bridge erecting machine designed in this article reduces the turning radius of traditional bridge erecting machines from over 300m to about 80m, making it possible to carry out projects that were originally impossible, and solving the problem of elevated bridge construction in limited urban spaces.

On the two-dimensional harmonic oscillator with an electric field confined to a circular box

Abstract We revisit the quantum-mechanical two-dimensional harmonic oscillator with an electric field confined to a circular box of impenetrable walls. In order to obtain the energy spectrum we resort to the Rayleigh-Ritz method with polynomial and Gaussian basis sets. We compare present results with those derived recently by other authors. We discuss the limits of large and small box radius and also do some calculations with perturbation theory.

The quantum vortices dynamics: spatio-temporal scale hierarchy and origin of turbulence

Abstract This study investigates the evolution and interaction of quantum vortex loops with a small but non-zero radius of core a. The quantization scheme of the classical vortex system is based on the approach proposed by the author Talalov S V (2022 Eur. Journ. Mech B/Fluids 92 100-6), Talalov S V (2023 Physical Review Fluids 8 034 607-1-03460712). We consider small perturbations in the ring-shaped loops, which include both helical-type shape variations and small excitations of the flow in the vortex core. The quantization of the circulation Γ is deduced from the first principles of quantum theory. As a result of our approach, the set of quantized circulation values is wider than the standard one. The developed theory introduces a hierarchical spatio-temporal scale in the quantum evolution of vortices. We also explore the applicability of this model for describing the origins of turbulence in quantum fluid flows. To achieve this specific objective, we employ the method of random Hamiltonians to describe the interaction of quantum vortex loops.

KMT-2024-BLG-1044L: A sub-Uranus microlensing planet around a host at the star-brown dwarf mass boundary

We analysed microlensing data to uncover the nature of the anomaly that appeared near the peak of the short-timescale microlensing event KMT-2024-BLG-1044. Despite the anomaly's brief duration of less than a day, it was densely observed through high-cadence monitoring conducted by the KMTNet survey. Detailed modelling of the light curve confirmed the planetary origin of the anomaly and revealed two possible solutions, due to an inner--outer degeneracy. The two solutions provide different measured planet parameters: $(s, q)_ inner $ for the inner solutions and $(s, q)_ outer $ for the outer solutions. Using Bayesian analysis with constraints provided by the short event timescale ($t_ E 9.1$ day) and the small angular Einstein radius ($ E 0.16$ mas for the inner solution and $ 0.10$ mas for the outer solutio), we determined that the lens is a planetary system consisting of a host near the boundary between a star and a brown dwarf and a planet with a mass lower than that of Uranus. The discovery of the planetary system highlights the crucial role of the microlensing technique in detecting planets that orbit substellar brown dwarfs or very low-mass stars.

Interfacial Electric Field Enhanced Free-Standing VO2/rGO Aerogel Anode with Ultra High Mass Energy Density for Aqueous Ammonium Ion Battery.

Aqueous batteries have become a promising means of energy storage due to its environmental friendliness. Nevertheless, it often exhibits limited energy density that hinder their application. Considering that ammonium ion (NH4 +) has a low mass and a small hydration radius, aqueous ammonium ion batteries (AAIBs) are expected to solve the problem of low energy density. Herein, we obtain Vanadium dioxide/reduced graphene oxide aerogel (VOGA) by in-situ growth of VO2 on the graphene surface for interfacial electric field enhanced AAIBs to achieve high mass energy density. The VOGA free-standing electrode achieves a specific capacity of up to 655 mAg-1 at a current density of 0.5 Ag-1. And the mass energy density of the VOGA.

On the convergence of cosmographic expansions in Lemaître–Tolman–Bondi models

Abstract We study cosmographic expansions of the luminosity distance for a variety of Lemaître–Tolman–Bondi (LTB) models which we specify inspired by local large-scale structures of the Universe. We consider cosmographic expansions valid for general spacetimes and compare to the Friedmann–Lemaître–Robertson–Walker (FLRW) limit of the expansions as well as to its naive isotropic extrapolation to an inhomogeneous Universe. The FLRW expansions are often poor near the observer but become better at higher redshifts, where the light rays have reached the FLRW background. In line with this we find that the effective Hubble, deceleration and jerk parameters of the general cosmographic expansion are often very different from the global ΛCDM values, with deviations up to several orders of magnitude. By comparing with the naive isotropic extrapolation of the FLRW expansion, we assess that these large deviations are mainly due to gradients of the shear. Very close to the observer, the general cosmographic expansion is always best and becomes more precise when more expansion terms are included. However, we find that the convergence radius of the general cosmographic expansion is small for all studied models and observers and the general cosmographic expansion becomes poor for most of the studied observers already before a single LTB structure has been traversed. The small radius of convergence of the general cosmographic expansion has also been indicated by earlier work and may need careful attention before we can safely apply the general cosmographic expansion to real data.

Localized Water Restriction in Ternary Eutectic Electrolytes for Ultra-Low Temperature Hydrogen Batteries.

Proton batteries are promising candidates for next-generation large-scale energy storage in extreme conditions due to the small ionic radius and efficient transport of protons. Hydrogen gas, with its low working potentials, fast kinetics, and stability, further enhances the performance of proton batteries but necessitates the development of novel electrolytes with low freezing points and reduced corrosion. This work introduces a localized water restriction strategy by incorporating a tertiary component with a high donor number, which forms strong bonds with water molecules. This approach restricts free water molecules and reduces the average hydrogen bond ratio and strength. As-prepared ternary eutectic electrolytes lowered the freezing point to -103 °C, significantly lower than the traditional binary electrolyte (9.5 m H3PO4, -93 °C). This electrolyte is highly compatible with the Cu0.79Co0.21[Fe(CN)6]0.64·4H2O (CoCuHCF) cathode, reducing material dissolution and current collector corrosion. The H2||CoCuHCF battery using this electrolyte demonstrated a high-power density of 23664.3 W kg-1, excellent performance at -80 °C, and stable cyclability over 1000 cycles (> 30 days) at -50 °C. These findings provide a framework for proton electrolytes, highlighting the potential of hydrogen batteries in challenging environments.

Three-dimensional elastic Rayleigh–Taylor instability at the cylindrical interface

This paper presents a linear analysis of elastic Rayleigh–Taylor instability at both cylindrical column and cylindrical shell interfaces. By considering the rotational part of the disturbance flow field, an exact solution is derived, revealing that the most unstable mode is two-dimensional in the cross section. As the column radius decreases, the maximum growth rate increases, while the corresponding azimuthal wave number decreases incrementally until it reaches 1. Thinning the cylindrical shell is found to be a destabilizing effect, leading to an increase in both the cutoff wave number and the most unstable azimuthal wave number. The maximum growth rate usually increases as the shell becomes thinner, except in cases with small radii where feedthrough effects occur. For thin shells with small radii, the cutoff axial wave number is determined by the radius rather than the shell thickness. Comparisons between the growth rates derived from the potential flow theory and the exact solution show significant discrepancies in cylindrical shells, mainly due to substantial deviations in the cutoff wave number.

Nanoscale Ga/Al substituted yttrium iron garnet films by liquid phase epitaxy

Yttrium iron garnet (YIG) has minimum damping factor and low ferromagnetic resonance (FMR) linewidth, making it a preferred material for low loss microwave and spintronic devices. The saturation magnetization of YIG is 1750 Gauss, and for low-frequency devices, a lower saturation magnetization is more suitable. Ga3+ and Al3+ are with smaller radii and non-magnetic moment, so the substitution of Ga3+ and Al3+ can decrease saturation magnetization. Here, 4.8–193.7 nm ultra-thin Y3(GaAlFe)5O12 garnet (GaAl-YIG) monocrystalline films are prepared on gadolinium gallium garnet (GGG) substrates by using the liquid-phase epitaxy (LPE) method. As expected, these films exhibit a low saturation magnetization of almost less than 100 Gauss, while their FMR linewidth remains at levels close to that of YIG. The films show a (111) orientation and in a state of tension, and the diffraction intensity of the films get stronger as films thickness increases. The free energy and density of states are calculated for different Ga/Al substitution position by density functional theory simulations. The elements show a different diffusion distance in the GaAl-YIG/GGG interface, and the variation of magnetization properties with interface width are analyzed. The surface roughness of the films is only a few angstroms. The damping factor of these ultra-thin films are on an order of 10−4 except the 4.8 nm film, which suggests that the minimum thickness of the garnet film with good performance by using the LPE method is about 10 nm. According to the analysis of structure and magnetization properties, it demonstrates that the LPE method has potential to provide nanoscale garnet films for low loss microwave and spintronic devices.

Interlayer engineering of V2O5·nH2O by conductive Ni-BTA enabling high-performance aqueous ammonium ion batteries

Aqueous ammonium ion batteries (AAIBs) are of interest due to the low molar mass, small hydration radius, abundant raw materials and high safety of the carrier ammonium-ion. Nevertheless, there are numerous constraints associated with electrode materials that are suitable for ammonium-ion storage. In this study, we design and synthesize a composite comprising of one-dimensional conductive metal-organic skeleton material (1D c-MOF) embedded between layers of hydrated vanadium pentoxide (VOH) with improved ammonium-ion storage. The central ion of the 1D c-MOF is selected to be the nickel ion, while the ligand is 1,2,4,5-benzenetetramine (BTA). The incorporation of Ni-BTA between the vanadium oxide layers results in the formation of a composite (Ni-BTA/VOH) exhibiting enhanced structural stability, augmented layer spacing and elevated conductivity. Furthermore, the dual energy storage mechanisms of VOH and CN rearrangement act in concert to yield a “1+1 > 2” effect, thereby markedly enhancing the ammonium-ion storage. The specific capacity of Ni-BTA/VOH can reach 183 mAh g−1 at 0.2 A g−1, and the retention rate can reach 52.5 % after 500 cycles at 2 A g−1. This work not only proves the potential of Ni-BTA/VOH for widespread application in the field of aqueous batteries, but also provides a new method for structural engineering of VOH with boosted ammonium-ion storage properties.

High‐Performance Flexible Silicon Nanowire Field Effect Transistors on Plastic Substrates

AbstractInorganic semiconductor nanowires, known for their exceptional electronic properties and mechanical flexibility, are widely regarded as the ideal 1D channel materials for creating high‐performance flexible electronics. In this work, the integration of ordered arrays of silicon nanowire (SiNW) field effect transistors (FETs) directly onto flexible plastic substrates is showcased. The self‐aligned crystalline SiNW multi‐channels are first grown through an in‐plane solid–liquid–solid mechanism on rigid substrates, and then efficiently transferred in‐batch onto flexible polyethylene terephthalate (PET) plastics. The FETs constructed on these transferred SiNW channels exhibit outstanding performance, with a high on/off current ratio of >105, a low subthreshold swing of 175 mV dec−1, and remarkable mechanical stability that can endure an extremely small bending radius of 0.5 mm for 1000 cycles. Furthermore, inverter logics are also successfully demonstrated on plastic substrates, highlighting a prominent routine for scalable integration of high‐quality SiNW channels in the development of low‐cost, high‐performance flexible displays and wearable electronics.

Electric Field Intensity Assessment on Curved Wires for Domestic Installations

The increasing complexity of domestic electrical installations necessitates a thorough understanding of electric field intensity, particularly when dealing with curved wires. This paper presents the results on the assessment of the electric field intensity in curved wire configurations, which are commonly encountered in residential settings due to architectural constraints. This study employs both theoretical and simulation approaches with the help of the Finite Element Based Software (COMSOL Multiphysics). The theoretical and simulations were used for a case of straight wire to allow validation of the model through comparing simulation results with the theoretically computed electric field intensity using mathematical formula. Later on, the COMSOL Multiphysics were used to compute electric field intensity under various curvature radii. The results of maximum electric field intensity against curvature radii were then plotted as scatter in excel and then fitted by the equation from the trendline option. The results show that the curvature of wires significantly influences electric field distribution. The electric field intensity was observed to be much higher for a case of small curvature radius as compared to larger curvature radius. For example, for the type of the geometry presented in this paper to represent the PVC wire used in domestic buildings’ electrical installations, the maximum electric field intensity for curvature radius of 0.025 mm was observed to be about 7 times for a case when the curvature radius was 10 mm. In additional, the power equation was found to model well the relationship between the maximum electric field intensity and curvature radius of the geometry presented in this paper

Better Hardness Results for the Minimum Spanning Tree Congestion Problem

AbstractIn the spanning tree congestion problem, given a connected graph G, the objective is to compute a spanning tree T in G that minimizes its maximum edge congestion, where the congestion of an edge e of T is the number of edges in G for which the unique path in T between their endpoints traverses e. The problem is known to be $$\mathbb{N}\mathbb{P}$$ N P -hard, but its approximability is still poorly understood, and it is not even known whether the optimum solution can be efficiently approximated with ratio o(n). In the decision version of this problem, denoted $${\varvec{K}-\textsf {STC}}$$ K - STC , we need to determine if G has a spanning tree with congestion at most K. It is known that $${\varvec{K}-\textsf {STC}}$$ K - STC is $$\mathbb{N}\mathbb{P}$$ N P -complete for $$K\ge 8$$ K ≥ 8 , and this implies a lower bound of 1.125 on the approximation ratio of minimizing congestion. On the other hand, $${\varvec{3}-\textsf {STC}}$$ 3 - STC can be solved in polynomial time, with the complexity status of this problem for $$K\in { \left\{ 4,5,6,7 \right\} }$$ K ∈ 4 , 5 , 6 , 7 remaining an open problem. We substantially improve the earlier hardness results by proving that $${\varvec{K}-\textsf {STC}}$$ K - STC is $$\mathbb{N}\mathbb{P}$$ N P -complete for $$K\ge 5$$ K ≥ 5 . This leaves only the case $$K=4$$ K = 4 open, and improves the lower bound on the approximation ratio to 1.2. Motivated by evidence that minimizing congestion is hard even for graphs of small constant radius, we also consider $${\varvec{K}-\textsf {STC}}$$ K - STC restricted to graphs of radius 2, and we prove that this variant is $$\mathbb{N}\mathbb{P}$$ N P -complete for all $$K\ge 6$$ K ≥ 6 .

Copper-induced lattice distortion in Na4Fe3(PO4)2(P2O7) cathode enabling high power density Na-ion batteries with good cycling stability

Na4Fe3(PO4)2P2O7 (NFPP) has attracted attention due to its high theoretical capacity, low cost, and good structure stability for Na-ion batteries. However, its practical application is limited by the low intrinsic electronic conductivity and sluggish ion diffusion kinetics. To tackle those problems, lattice strain engineering by heteroatom doping is applied to tune the local molecular structure and optimize the electrochemical properties of electrode materials. Copper cation (+2) with a smaller ionic radius was chosen to dope at Fe-site in NFPP, and the doping amount was also optimized, illustrating the optimized sample of Na4Fe2.7Cu0.3(PO4)2P2O7 (NFPP-0.3Cu) delivered a high capacity of 119.01 mAh g-1 at 1 C (1 C = 129 mA g-1) and a high capacity retention of 82.76 % after 3000 cycles at 20 C. Notably, full cells with NFPP-0.3 Cu as cathode and hard carbon as anode delivered a high energy density of 230 Wh kg-1 and a power density of 2280 W kg-1. The exceptional electrochemical performances are attributed to the modulated electronic structure and abundant lattice defects by Cu-doping. Furthermore, in-situ X-ray diffraction technique and theoretical calculation have jointly proved that the lattice distortions originated from Cu-doping have reduced the band gap of the NFPP-0.3Cu and altered the coordination environment of Fe, shortening the Fe-O and Cu-O bond lengths, significantly enhancing the intrinsic ionic conductivity and the diffusion kinetics of Na+. This work provides new point of views on lattice strain engineering and reaction kinetics of cathode materials in promoting high energy and power density sodium-ion batteries.

One-Stone-for-Multiple-Birds Additive Strategy for Highly Efficient and Stable Carbon-Based Hole-Transport-Layer-Free CsPbI2Br Solar Cells.

During fabrication and operation of perovskite solar cells (PSCs), defects commonly arise within the crystals as well as at grain boundaries. However, conventional additive strategies typically only serve to mitigate the occurrence of a single defect and fail to significantly enhance device performance. Herein, carbon-based hole-transport-layer-free CsPbI2Br devices are focused on, one kind of important PSCs with more stable structure and an appropriate bandgap for a semitransparent solar cell or a top cell in a tandem configuration, and present a highly efficient one-stone-for-multiple-birds additive strategy based on lanthanide trifluoromethanesulfonates (Ln(OTF)3, Ln: neodymium (Nd), europium (Eu), dysprosium (Dy), thulium (Tm)). Density functional theory calculations reveal that the Ln3+ ions with a smaller radius can elevate defect formation energy for Pb and I vacancies within the crystals, while the presence of OTF- can effectively passivating uncoordinated Pb2+ at grain boundaries. In addition, Ln(OTF)3 addition increases the grain size and meanwhile reduces the surface roughness of the CsPbI2Br layers. All these positive contributions lead to a significant enhancement in power conversion efficiency (PCE) to 15.13% which is among the top PCEs reported for the corresponding solar cells, from 11.80% of the pristine device without Tm(OTF)3 addition, while notably boosting long-term stability and reducing current-voltage hysteresis.

Preparation and performance evaluation of a low‐damage fracturing fluid for unconventional reservoirs

AbstractThe characteristics of tight matrix, underdeveloped natural fractures, small pore throat radius, poor pore connectivity, and abundant clay minerals result in a high potential for damage to the tight sandstone reservoirs of the Shaximiao Formation in the Qiulin Block in the Sichuan Basin. In order to reduce the retention damage caused by fracturing fluid to the tight sandstone reservoir, a low damage fracturing fluid system applicable to the target reservoir is developed in this work, and the indoor performance meets the requirements of on‐site fracturing operation. A low‐damage, heat‐resistant, shear‐stable amphiphilic polyacrylamide (PAAD) was prepared by free radical polymerization in aqueous solution using acrylamide, acrylic acid, and methacryloyloyloxyethyl dimethyloctadecyl ammonium bromide (DM18) as the monomers. The amphoteric polyacrylamide was characterized by Fourier infrared spectroscopy, nuclear magnetic resonance spectroscopy (1H NMR), light scattering molecular weight determination, and thermogravimetric analysis. Fracturing fluids were formulated with the amphiphilic hydrophobic associative polymer PAAD as a drag‐reducing agent, the fluorine‐containing and nonionic complex surfactant FD1 as a clean‐up additive, CT10‐4B as a bactericide and CT1‐12 as an emulsion breaker. The fracturing fluid formulation was preferred, and the performance of the fracturing fluid was evaluated in terms of temperature resistance and shear resistance, drag reduction, anti‐expansion, and core damage. The fracturing fluid showed good temperature and shear resistance, with a viscosity retention of 58.4% at 120°C and 170 s−1 shear for 1 h. At a loading of 0.1%, the drag reduction rate reaches 72.3%, the anti‐expansion rate of the gel‐breaking fluid is 86.04%, and the damage rate to the tight sandstone core is 16.25%. The results show that the fracturing fluid has good heat resistance and shear stability, as well as low damage and good resistance reduction and anti‐expansion properties. This work can provide new strategies for designing polymeric fracturing fluids with low damage, good heat resistance and shear stability.

Three-Dimensional Printing Limitations of Polymers Reinforced with Continuous Stainless Steel Fibres and Curvature Stiffness

This study investigates the printability limitations of 3D-printed continuous 316L stainless steel fibre-reinforced polymer composites obtained using the Materials Extrusion (MEX) technique. The objective was to better understand the geometric printing limitations of composites fabricated using continuous steel fibres, based on a combination of bending stiffness testing and piezoresistive property studies. The 0.5 mm composite filaments used in this study were obtained by co-extruding polylactic acid (PLA), with a 316 L stainless steel fibre (SSF) bundle. The composite printability limitations were evaluated by the printing of a series of ’teardrop’ shaped geometries with angles in the range from 5° to 90° and radii between 2 and 20 mm. The morphology and dimensional measurements of the resulting PLA-SSF prints were evaluated using μCT scanning, optical microscopy, and calliper measurements. Sample sets were compared and statistically examined to evaluate the repeatability, turning ability, and geometrical print limitations, along with dimensional fluctuations between designed and as-printed structures. Comparisons of the curvature bending stiffness were made with the PLA-only polymer and with 3D-printed nylon-reinforced short and long carbon fibre composites. It was demonstrated that the stainless steel composites exhibited an increase in bending stiffness at smaller radii. The change in piezoresistance response of the PLA-SSF with load applied during the curvature bending stiffness testing demonstrated that the 3D-printed composites may have the potential for use as structural health monitoring sensors.

First-principles study on lanthanide dopants in BaTiO3

Using first-principles calculation based on density-functional theory and density-functional perturbation theory, the microscopic structure and dielectric properties of Lanthanide (Ln) doped BaTiO3 are investigated. The doped Ln atoms exhibit significant displacement from Ba sites for charge compensation, forming off-centered configurations. This displacement is more pronounced for elements with smaller ionic radii. The change in ionic dielectric constant is strongly correlated with Ln displacement and Ln ion radius. As Ln displacement (ionic radius) increases (decreases), Ln-doped BaTiO3 has a higher ionic dielectric constant. However, regardless of the Ln species, the added Ln reduces the ionic dielectric constant compared to pristine BaTiO3.

Are Modern Market-Available Multi-Rotor Drones Ready to Automatically Inspect Industrial Facilities?

Industrial inspection is a well-known application area for unmanned aerial vehicles (UAVs), but are modern market-available drones fully suitable for inspections of larger-scale industrial facilities? This review summarizes the pros and cons of aerial large-scale facility inspection, distinguishing it from other inspection scenarios implemented with drones. Moreover, based on paper analysis and additionally performed experimental studies, it reveals specific issues related to modern commercial drone software and demonstrates that market-available UAVs (including DJI and Autel Robotics) more or less suffer from the same problems. The discovered issues include a Global Navigation Satellite System (GNSS) Real Time Kinematic (RTK) shift, an identification of multiple images captured from the same point, limitations of custom mission generation with external tools and mission length, an incorrect flight time prediction, an unpredictable time of reaching a waypoint with a small radius, deviation from the pre-planned route line between two waypoints, a high pitch angle during acceleration/deceleration, an automatic landing cancellation in a strong wind, and flight monitoring issues related to ground station software. Finally, on the basis of the paper review, we propose solutions to these issues, which helped us overcome them during the first autonomous inspection of a 2400 megawatts thermal power plant.