Concentrations Of Small Crystals Research Articles

On the importance of small ice crystals in tropical anvil cirrus

Abstract. In situ measurements of ice crystal concentrations and sizes made with aircraft instrumentation over the past two decades have often indicated the presence of numerous relatively small (< 50 μm diameter) crystals in cirrus clouds. Further, these measurements frequently indicate that small crystals account for a large fraction of the extinction in cirrus clouds. The fact that the instruments used to make these measurements, such as the Forward Scattering Spectrometer Probe (FSSP) and the Cloud Aerosol Spectrometer (CAS), ingest ice crystals into the sample volume through inlets has led to suspicion that the indications of numerous small-crystals could be artifacts of large-crystal shattering on the instrument inlets. We present new aircraft measurements in anvil cirrus sampled during the Tropical Composition, Cloud, and Climate Coupling (TC4) campaign with the 2-Dimensional Stereo (2D-S) probe, which detects particles as small as 10 μm. The 2D-S has detector "arms" instead of an inlet tube. Since the 2D-S probe surfaces are much further from the sample volume than is the case for the instruments with inlets, it is expected that 2D-S will be less susceptible to shattering artifacts. In addition, particle inter-arrival times are used to identify and remove shattering artifacts that occur even with the 2D-S probe. The number of shattering artifacts identified by the 2D-S interarrival time analysis ranges from a negligible contribution to an order of magnitude or more enhancement in apparent ice concentration over the natural ice concentration, depending on the abundance of large crystals and the natural small-crystal concentration. The 2D-S measurements in tropical anvil cirrus suggest that natural small-crystal concentrations are typically one to two orders of magnitude lower than those inferred from CAS. The strong correlation between the CAS/2D-S ratio of small-crystal concentrations and large-crystal concentration suggests that the discrepancy is likely caused by shattering of large crystals on the CAS inlet. We argue that past measurements with CAS in cirrus with large crystals present may contain errors due to crystal shattering, and past conclusions derived from these measurements may need to be revisited. Further, we present correlations between CAS spurious concentration and 2D-S large-crystal mass from spatially uniform anvil cirrus sampling periods as an approximate guide for estimating quantitative impact of large-crystal shattering on CAS concentrations in previous datasets. We use radiative transfer calculations to demonstrate that in the maritime anvil cirrus sampled during TC4, small crystals indicated by 2D-S contribute relatively little cloud extinction, radiative forcing, or radiative heating in the anvils, regardless of anvil age or vertical location in the clouds. While 2D-S ice concentrations in fresh anvil cirrus may often exceed 1 cm−3, and are observed to exceed 10 cm−3 in turrets, they are typically ~0.1 cm−3 and rarely exceed 1 cm−3 (<1.4% of the time) in aged anvil cirrus. We hypothesize that isolated occurrences of higher ice concentrations in aged anvil cirrus may be caused by ice nucleation driven by either small-scale convection or gravity waves. It appears that the numerous small crystals detrained from convective updrafts do not persist in the anvil cirrus sampled during TC-4.

Testing the influence of small crystals on ice size spectra using Doppler lidar observations

Analysis of the vertical velocity of ice crystals observed with a 1.5μm Doppler lidar from a continuous sample of stratiform ice clouds over 17 months show that the distribution of Doppler velocity varies strongly with temperature, with mean velocities of 0.2ms−1 at −40°C, increasing to 0.6ms−1 at −10°C due to particle growth and broadening of the size spectrum. We examine the likely influence of crystals smaller than 60μm by forward modelling their effect on the area‐weighted fall speed, and comparing the results to the lidar observations. The comparison strongly suggests that the concentration of small crystals in most clouds is much lower than measured in‐situ by some cloud droplet probes. We argue that the discrepancy is likely due to shattering of large crystals on the probe inlet, and that numerous small particles should not be included in numerical weather and climate model parameterizations.

Dynamics of differentiation in magma reservoirs

In large magma chambers, gradients of temperature and composition develop due to cooling and to fractional crystallization. Unstable density differences lead to differential motions between melt and crystals, and a major goal is to explain how this might result in chemical differentiation of magma. Arriving at a full description of the physics of crystallizing magma chambers is a challenge because of the large number of processes potentially involved, the many coupled variables, and the different geometrical shapes. Furthermore, perturbations are caused by the reinjection of melt from a deep source, eruption to the Earth's surface, and the assimilation of country rock. Physical models of increasing complexity have been developed with emphasis on three fundamental approaches. One is, given that large gradients in temperature and composition may occur, to specify how to apply thermodynamic constraints so that coexisting liquid and solid compositions may be calculated. The second is to leave the differentiation trend as the solution to be found, i.e., to specify how cooling occurs and to predict the evolution of the composition of the residual liquid and of the solid forming. The third is to simplify the physics so that the effects of coupled heat and mass transfer may be studied with a reduced set of variables. The complex shapes of magma chambers imply that boundary layers develop with density gradients at various angles to gravity, leading to various convective flows and profiles qf liquid stratification. Early studies were mainly concerned with describing fluid flow in the liquid interior of large reservoirs, due to gradients developed at the margins. More recent work has focused on the internal structure and flow field of boundary layers and in particular on the gradients of solid fraction and interstitial melt composition which develop within them. Crystal settling may occur in a surprisingly diverse range of regimes and may lead to intermittent deposition events even with small crystal concentrations. Incorporating thermodynamic constraints in the study of the dynamics of settling has only just begun. Many dynamical phenomena have been found using theoretical arguments, laboratory experiments on analog systems, and numerical calculations on simplified chemical systems. However, they have seldom been applied to natural silicate melts whose phase diagrams and important physical properties such as thermal conductivity and chemical diffusion coefficients remain poorly known. There is a gap between model predictions and observations, as many models are designed to explain large‐scale features and many observations deal with the local texture and mineral assemblages of the rocks. This review stresses the relevance to the geological problem of the work carried out in parallel in other disciplines, such as physics, fluid dynamics, and metallurgy.