Sludge Materials Research Articles

Synthesis of a novel one-part alkali-activated material from solid wastes salt sludge and soda residue

In this paper, salt sludge (SS), a solid waste from sodium hydroxide production, was activated at high temperature for the first time. It was combined with soda residue (SR), a solid waste from sodium carbonate production, as a solid activator to activate the solid aluminosilicate precursor, blast furnace slag (BFS). This process developed a novel one-part alkali-activated material, termed salt sludge and soda residue co-activated blast furnace slag cementitious material (SRB), which effectively utilizes solid wastes. The effects of ratios of calcined SS (CSS) to SR, fine aggregate types, and curing methods on the physical and mechanical properties of SRB were investigated. The composition of the hydration products was characterized using X-ray diffraction (XRD), thermogravimetric analysis (TGA), and fourier transform infrared spectroscopy (FTIR), while the hydration process during the setting stage was examined with 1H low-field nuclear magnetic resonance (1H LF NMR). The influence of mix ratio, fine aggregate type, and curing method on the microstructure of SRB was analyzed using scanning electron microscopy (SEM). The results showed that the synergistic activation of BFS by CSS and SR was significantly more effective than individual activation. At the optimal mix ratio (CSS:SR:BFS = 15:15:70), the 3/28 days compressive strength of SRB was 14.3/53.7 MPa. The primary hydration products were C-(A)-S-H gels, along with Friedel's salt, ettringite, and hydrotalcite crystals. Using manufactured sand (MS) as a fine aggregate reduced mortar fluidity compared to river sand (RS) but enhanced the interfacial transition zone (ITZ) with the hardened paste, resulting in a denser microstructure. Heat curing promoted hydration product generation, increasing early (3 days) strength by a factor of 2.5. However, the rapid accumulation and insufficient diffusion of hydration products adversely affected the later strength.

Evaluation of extraction and storage conditions for quantification and characterization of silver nanoparticles in complex samples by single particle-ICP-MS

The extraction of nanoparticles (NPs) from complex matrices and subsequent storage can potentially alter the NPs physicochemical properties and hinder cross-study comparisons. Most NP extraction methods are designed and tested at high nanoparticle concentrations, although (eco)toxicological and regulatory monitoring programs require methods capable of analyzing NPs at environmentally relevant concentrations (lower ppb range). In this study, we investigated how extraction methods affect the characteristics of PVP coated and citrate-stabilized silver NPs (AgNPs) spiked into soil, sewage sludge, and biological samples at environmentally relevant concentrations using Single Particle Inductively Coupled Plasma Mass Spectrometry spICP-MS). Further we investigated the impact of storage temperature (-80°C to 21°C) and storage duration (1-28 days) on the particle characteristics such as particle size.We found that aqueous AgNPs samples with low ionic strength media retained their original characteristics (like particle size, particle concentration and particle-based Ag mass) when preserved at 4°C for up to 28 days. AgNPs dispersed in high ionic strength media were however better preserved at -80°C. Among the extraction agents, tetrasodium pyrophosphate was more efficient in extracting AgNPs from soil and sewage sludge matrices, while Proteinase K was more suitable for biological samples from organisms (earthworms or fish).Although our study focused only on AgNPs, it provides crucial information to aid interlaboratory comparisons and data interpretation for (eco)toxicological studies.

Analyzing the Impact of Annealed Steel Sludge Doses on the Physicochemical Properties of Biochar Obtained from Waste Date Palm Frond

Large quantities of date palm frond waste generated from the pruning process are accumulated or burned in burn barrels, harming the environment and having very little economic value. However, because of the lack of data revealing the characteristic magnetic properties of biochar derived from date palm fronds, further research on low-cost and sustainable strategies could offer a new composite material and serve to extend the way for novel applications. In this study, we prepared biochar derived from palm fronds via pyrolysis under a limited-oxygen atmosphere at a lower temperature of 300 °C for 2 h. We introduced a facile strategy for the production of magnetic biochar with various doses of annealed steel sludge material via ball milling. Various amounts of annealed steel sludge material (5%, 15%, and 25% w) were added to date palm frond biochar, and the obtained product was fabricated by ball milling. The physicochemical characteristics of the magnetic biochar composite were subsequently analyzed using scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR) spectroscopy, and UV-vis spectroscopy. Our findings showed that the ball milling method is a successful step for producing date palm fronds with magnetic biochar material possessing rough and packed pores, as shown by SEM. XRD patterns assumed the existence of magnetic phases of iron oxide (magnetite (Fe3O4), hematite (α-Fe2O3), and maghemite (γ-Fe2O3) at different generated peaks. FTIR outputs exhibited the abundant presence of various oxygen-containing functional groups (- COOH and -OH) on the surface of magnetic biochar material, which help to create chemically reactive sites to adsorb potential surrounding species. The UV spectra showed a noticeable enhancement of the optical properties of the magnetic biochar with an increase in the sludge dose for light absorption in the visible region from wavelengths of 400 – 700 nm . This result signifies the synthetic optimization and potential application of magnetic biochar materials for composites that could be employed in targeted uses including soil amendment, water remediation and energy applications.

Microbial response to the chronic toxicity effect of graphene and graphene oxide nanomaterials within aerobic granular sludge systems

Nanomaterials present in wastewater can pose a significant threat to aerobic granular sludge (AGS) systems. Herein, we found that compared to graphene nanomaterials (G-NMs), the long-term presence (95 days) of graphene oxide nanomaterials (GO-NMs) resulted in an increased proliferation of filamentous bacteria, poorer sedimentation performance (SVI30 of 74.1 mL/g) and smaller average particle size (1224.4 µm) of the AGS. In particular, the GO-NMs posed a more significant inhibitory effect to the total nitrogen removal efficiency of AGS (decreased by 14.3 %), especially for the denitrification process. The substantial accumulation of GO-NMs within the sludge matrix resulted in a higher level of reactive oxygen species in AGS compared to G-NMs, thereby inducing lactate dehydrogenase release, and enhancing superoxide oxidase and catalase activities. Such excessive oxidative stress could potentially result in a significant reduction in the activity of nitrogen metabolism enzymes (e.g., nitrate reductase and nitrite reductase) and the expression of key functional genes (e.g., nirS and nirK). Altogether, compared to G-NMs, prolonged exposure to GO-NMs had a more significant chronic toxicity effect on AGS systems. These findings implied that the presence of G-NMs and GO-NMs is a hidden danger to biological nitrogen removal and should receive more attention.

Carbide slag and sodium metasilicate synergistic activation of sludge ash-based alkali-activated materials: Towards a cleaner activation approach

Traditional activators such as sodium hydroxide and sodium silicate are commonly used in the preparation of alkali-activated materials; however, their significant environmental impact, high cost, and operational risks limit their sustainable use in treating solid waste. This study explores the innovative use of carbide slag (CS) and sodium metasilicate (NS) as alternative activators in the production of sewage sludge ash-based alkali-activated materials (SSAM) with the aim of reducing the carbon footprint of the preparation process. The results demonstrate that CS effectively activates the sewage sludge ash, enhancing the compressive strength of the SSAM to 40 MPa after curing for 28 d. When used in conjunction with NS, it synergistically improves the mechanical properties. Furthermore, the microstructure and phase composition of the SSAM are characterized. Increasing the quantities of CS and NS accelerates the dissolution of the precursor materials, promoting the formation of a higher quantity of hydration products. This significantly reduces the number of voids and defects within the samples, further enhancing the densification of the microstructure. Environmental assessments reveal that CS and NS offer substantial sustainability benefits, confirming the feasibility of activating SSAM using these materials. This approach provides a less energy-intensive and more environmentally friendly alternative to conventional activation methods and presents an effective strategy for managing large volumes of sewage sludge ash and CS.

Earthworm gut digestion drives the transfer behavior of antibiotic resistance genes in layers of extracellular polymeric substances during vermicomposting of dewatered sludge

Gut digestion by earthworms (GDE) is a crucial step in vermicomposting, affecting the fate of antibiotic resistance genes (ARGs) in vermicompost sludge. The extracellular polymeric substance (EPS) matrix of sludge is an important space for ARG transfer. However, the effect of GDE on EPS-associated ARGs remains unclear. Therefore, this study explored the role of GDE in driving the transfer of ARGs within different EPS layers in sludge. For this, the changes in intracellular ARGs and EPS-associated ARGs in sludge were analyzed after 5 days of the GDE process. The results showed that after the GDE process, both nitrate and dissolved organic carbon significantly increased in all EPS layers of sludge, while the proteins and polysaccharides only enhanced in soluble and loosely bound EPS of sludge. In addition, a 7.0% decrease in bacterial diversity was recorded after the GDE process, with a functional bacterial community structure emerging. Moreover, the absolute abundance of total ARGs and mobile genetic elements decreased by 90.71% and 61.83%, respectively, after the GDE process. Intracellular ARGs decreased by 92.1%, while EPS-associated ARGs increased by 4.9%, indicative of intracellular ARG translocation into the EPS during the GDE process. Notably, the ARGs exhibited significant enrichment in both the soluble and loosely bound EPS, whereas they were reduced in the tightly bound EPS. The structural equation modeling revealed that the GDE process effectively mitigated the ARG dissemination risk by modulating both the EPS structure and microenvironment, with the organic structure representing a primary factor influencing ARGs in the EPS.

Biogas enhancement in the anaerobic digestion of thermo-chemically pretreated sludge by stimulating direct interspecies electron transfer by biochar and graphene

It is necessary to pretreat waste-activated sludge (WAS) to disintegrate the sludge matrix and amend its anaerobic digestion (AD) with carbon-based materials (CMs) to accelerate direct interspecies electron transfer (DIET) in order to realize the maximum biogas potential of abundant and habitat-threatening organic WAS. The AD of WAS pretreated thermo-chemically at 0.5% NaOH (g/g dry sludge) and 125 °C microwave irradiation was amended by biochar doses of 0–40 g/L and graphene doses of 50–1,000 mg/L in the batch operation mode. Hybrid pretreatment of WAS deteriorated dewaterability but solubilized 38% of total chemical oxygen demand (COD). AD amended with 20 g/L biochar and 100 mg/L graphene had the optimum accumulative methane yield of 183.6 and 153.8 mL/gVS, respectively, which correspond to 42.8% and 24.8% increases compared to an unamended control assay with maximum methane content of 70.3% and 71.9%, respectively. The digestate of biochar- and graphene-amended assays resulted in higher TS% and alkalinity, reduced sCOD, VFA, and turbidity, and increased particle size distribution compared to control. Biochar-amended digestate had improved dewaterability, while digestate of graphene-amended assays resulted in worse dewaterability than control. The t-test showed a significant difference between the biochar and graphene amended batch assays, while principal component analysis (PCA) indicated that biogas yield was closely correlated with pH. CM-amended batch assays demonstrated superb fitting with modified Gompertz, logistic, and first-order models with a coefficient of determination above 0.97. Microbial community abundance and diversity were affected by CMs amendment, resulting in increased acetoclastic methanogen growth and transformed methanogenic metabolic pathways. An extended pilot-scale study and techno-economic and life cycle assessments are required to investigate environmental impacts and feasibility.

Vermicomposting preferably alters fungal communities in wasted activated sludge and promotes the production of plant growth-promoting biostimulants in the vermicompost

Waste activated sludge (WAS) is the main by-product of wastewater treatment plants. Vermicomposting integrated earthworms and reconstructive microbes to achieve WAS stabilization, with the mature composts enriched with plant hormones and humic substances (HS) forming supramolecular forces to protect hormone activity. However, how vermicomposting changes sludge microbial community, transforms sludge-derived organics into various plant biostimulants and promotes hormones-HS interaction remain elusive. Here we used multi-omics approaches to demonstrate how reconstructed microbes transformed sludge-derived organics into plant biostimulants, and molecular dynamics (MD) simulation to explore the force details of hormone-HS aggregations. Additionally, plant growth phenotype treated by the vermicompost was accessed. Our results showed that earthworm (Eisenia fetida) selectively altered fungal communities in sludge matrices, promoting the growth of phyla Mucoromycota, Ascomycota, and Cryptomycota. Reconstructed fungal communities then dominated the transformation of nitrogenous organics, accelerating the degradation rate of proteins and the production rate of plant biostimulants, including humic substances (HS, especially fulvic acid), indoleacetic acid (IAA), jasmonic acid (JA), and salicylic acid (SA). In detail, indole acted as the exclusive precursor for IAA biosynthesis (2.77 mg/kg-TS) via tryptophan metabolism. Unsaturated fatty acids generated from the citrate cycle were responsible for JA production (2.19 mg/kg-TS) via β-oxidation, while phenylalanine contributed to SA production (4.52 μg/kg-TS) via deaminase coenzyme and phenylalanine-4-hydroxylase. The results of MD simulation exhibited a stronger supramolecular force in the IAA-HS assemblage (−46.7 KJ/mol) than the SA-HS pair and JA-HS pair, thus protecting the structure and bioavailability of IAA and promoting the auxin-like activity in the vermicompost. Plant growth experiments further confirmed that vermicompost promoted plant root elongation. This work is believed to deepen the understanding of vermicomposting for sustainable management of sludge.

Experimental Investigation and Classification of Wastewater Treatment Sludge as Pozzolan for Cement

This paper presents an investigation conducted to evaluate wastewater treatment sludge for potential use as a cement extender or pozzolan. Two varieties comprising the digested wastewater sludge (DWWS) and activated wastewater sludge (AWWS) materials, were finely ground then calcined at 750 °C for 30 min. Subsequently, the calcined sludge waste materials were blended with ordinary Portland cement CEM I 52.5 N at 0, 10, 20, 30% DWWS or AWWS, and used to prepare mortar mixtures at proportions of 1:3:0.61 cement to sand to water. Various tests were conducted including workability, compressive strength, pozzolanic activity with lime, drying shrinkage and alkali-silica reaction. It was found that both varieties of the sludge waste materials, once blended with CEM I at 20% DWWS or 20% AWWS, satisfied the ASTM C618 criteria for Class C pozzolan, and may be classified as CEM II /A-P 32.5 N,R cement type of EN 197-1/SANS 50197-1. The overall performance of DWWS was relatively better than that of AWWS.

Multi-phase modelling of loose, unsaturated soil’s continuous motion using a three-phase Eulerian approach

This paper develops a numerical model for loose, unsaturated soil to represent its mixing and motion using Computational Fluid Dynamics. It was found that existing models are not suitable for loose, unsaturated soil. The Herschel–Bulkley model is more appropriate for sludge and mud-like materials, and the Kinetic Theory of Granular Flow is inapt because it lacks yield stress. To mitigate these shortcomings, a novel three-phase Eulerian model is proposed, which combines these two models with an air phase. Each phase includes a physical characteristic of loose, unsaturated soil: the Herschel–Bulkley phase includes yield stress, a solid phase includes granular behaviour, and the air fraction adds porosity. To identify the model’s parameters, density is measured, and a slump test is performed. The radial run-out of the slump test is used to determine the required yield stress in the model. Test simulations showed clear improvements over the existing models by combining yield stress and granular, lumpy behaviour successfully. Application of the new model to a 3D screw conveyor simulation showcases its ability to simulate continuous soil motion phenomena, such as avalanching caused by a recirculatory flow, soil spilling over the flight and soil flowing back to the previous pitch.

Effectiveness of biological drying for citric acid dewatered sludge: Evaluating the impact of energy-efficient ventilation strategies

The effectiveness of dehydration and utilization processes for citric acid dewatered sludge is hampered by its high concentrations of polysaccharides, proteins, and water-binding properties of microbial extracellular polymers (EPS). This research explores the efficacy and mechanisms involved in extracting water from this type of sludge using biological drying technology, with varying rates of ventilation. Especially pertinent was the use of low ventilation rates as control variables. Our results suggest that a scheduled intermittent ventilation at lower rates allows for the most efficient removal of water, achieving a rate of 41.71 % within eight days, according to the zero-order kinetic model. Remarkably, the peak temperature registered was 60 °C, reaching this threshold in just 0.1 days and maintaining high temperatures for approximately 5.9 days. Component analysis of organic matter illustrated a preferential degradation process for lipids under these ventilation conditions which is pivotal for releasing and transforming bound water for efficient extraction, as well as facilitating the breakdown of easily hydrolysable materials. Further, polysaccharide/protein (EPS) decomposition contributed to water removal, though less significantly. The periodic ventilation strategy allowed for the maximum cumulative temperature to be sustained, demonstrating superior efficiency in harnessing bio-generated heat (82.77 % for water evaporation), resulting in dry sludge suitable for self-sustained combustion at relatively low cost ($26.61/t). Highlighted by this study is the considerable potential of energy-efficient ventilation methods in the biological drying treatment of citric acid fermented sludge and similar industrial waste materials.

Energy efficient biohydrogen production from waste activated sludge through a novel phase separated pretreatment

Disintegration of sludge by microwave irradiation is considered an energy-intensive pretreatment as it demands more significant energy input to achieve the desirable solubilization. Extracellular polymeric substance (EPS) present in the floc matrix of sludge limits the extent of sludge solubilization. Hence, this study attempted to disrupt the EPS with potassium peroxymonosulphate (PPMS) before microwave (MW) pretreatment to attain maximal solubilization in an energy-efficient way. A maximal EPS disruption was achieved at 0.009 g/g TS of PPMS dosage and treatment time of 36 min. The outcome of the phase-separated pretreatment shows that PPMS induced MW pretreatment (PPMS-MW) obtained a maximum chemical oxygen demand (COD) solubilization of 35.67 % at a specific energy input of 8795 kJ/kg TS. In contrast, the MW pretreatment achieved only 22.41 % at a specific energy input of 21973 kJ/kg TS. When comparing both PPMS-MW and MW pretreatments, an ample amount of energy was saved by PPMS-MW than MW. The biohydrogen production potential assay showed that PPMS-MW obtained an increased biohydrogen production of 79.76 mL/g VS compared to MW (50.10 mL/g VS). Thus, this phase-separated PPMS-MW pretreatment was considered efficient compared to MW pretreatment.

Study of Compost Based on Sewage Sludge and Different Structural Materials

The characterization of compost compositions on the basis of sewage sludge and structural materials (straw, sawdust, bark) composting is described. A comparison of the methods most often used for composting and characterization of structural materials is also presented. Sewage sludge and structural materials were mixed in different ratios and composted in piles (laboratory scale) for 3 months. During this time, the composting process was controlled using standard methods. The bioavailability of some xenobiotics in an agriculture experiment (using beans) was also investigated.

Dewatering Process for Reuse of Seabed Dredging Material and Time and Cost Optimization of the Process by Value Engineering Method

The decrease in resources in the world has led people to produce new solutions for the more efficient use of resources and to use various management techniques. One of the techniques used is Value Engineering. Value Engineering strives to increase the value of structures by optimally organizing each component that makes up the structure. Increasing the value of a structure is possible by eliminating all the unnecessary costs in line with specific criteria and by providing the optimal solution between the owner, the user, and the contractor's objectives, that is, the duration, cost, and quality. This study includes the changes the Value Engineering team made to increase the value of the materials extracted from the submarine in a Container Port Terminal project without harming the environment and making them reusable. While expanding the project value, it also aimed to reduce the project duration and cost by considering the sustainability criteria. The original project was to create a clay pool while dewatering, separating the material, filling the loose sand into the reclamation area, and removing the sludge material by sea. With the recommendation of the value engineering team, the dewatering process was transformed into a method of directly pressing the dredged loose sand into the breeding area, filtering the material with geotextile tubes, and removing the material by loading it on the pontoons. With this change in the project, 42% savings were obtained from the cost and 21% from the project duration.

Improving the carbonation performance of sulfate-activated material cured waste sediments by calcined Mg-Al hydrotalcite: Influence of CLDH dosages, carbonation concentrations and cycles

A method was proposed to strengthen the carbonation resistance of the waste sludge matrix by replacing part of cement with industrial by-products such as ground-granulated blast-furnace slag (GGBFS) and fly ash (FA) via the structural recrystallization and anion exchangeability of calcined Mg-Al hydrotalcite in a humid carbon dioxide environment. The mechanical and workability results showed that although the addition of CLDH weakened the flow extension of the mixture samples, they accelerated the solidification and hardening of the samples and increased the development of compressive strength in a slightly carbonized environment (e.g., C5T3L0.3 and C5T3L0.6). Furthermore, XRD, TG, BSE, and MIP techniques were used to analyze the composition of the hydration products and the distribution of the pore structure of the CLDHs-containing samples at different carbonation times and carbonation concentrations. The results indicated that CLDHs had good carbon sequestration capability. The addition of CLDH helped to refine the pores, and a slightly carbonized product like calcium carbonate could enhance the strength development by filling the pores, but too much had side effects. The outcomes of the study also provided an alternative way of thinking about the anti-carbonation behavior of cement pastes.

Migration and morphological transformation patterns of heavy metals on sludge cells and extracellular polymeric substances (EPS) under the influence of different treatments.

The impediment of sludge resource utilization stems from the presence of heavy metals within the sludge matrix. To optimize heavy metal removal techniques from undried sludge, it is essential to study the distribution of heavy metals in the sludge flocs structure and the changes in morphology in the sludge cells after different treatments. In this study, the sludge was subjected to chemical treatments using citric acid (CA), EDTA, and saponin, as well as electrokinetic treatment at 2 V/cm. The distribution and migration of Cu, Ni, and Zn in sludge flocs after various treatment methods were analyzed. The heavy metals were found to migrate from intracellular to extracellular polymeric substances (EPS) without causing extensive sludge cell lysis. They gradually diffused outward with the dispersion of the EPS layer. The migration efficiency of the three heavy metals in the sludge flocs was Zn, Ni, and Cu. This was mainly related to the initial distribution and morphology of the heavy metals. Under the influence of chemicals and an electric field, the acid-soluble and reducible heavy metals in the cells partially migrated to the EPS, while the stable heavy metals transformed into an unstable state. Furthermore, the order of chemical reagents in terms of their effect on the migration efficiency of heavy metals was CA > EDTA > Saponin, owing to the varying binding strengths of heavy metals and their impact on the degree of loosening of the EPS. Especially after CA treatment a greater proportion of Cu, Ni, and Zn were transferred from the cells to the EPS. The acidification effect near the anode during electrokinetic treatment intensifies the migration of heavy metals. This study provides basic research for subsequent engineering optimization aimed at removing heavy metals from sludge.

Controllable setting time of alkali-activated materials incorporating sewage sludge ash and GGBS: The role of retarders

Utilizing sewage sludge ash (SSA) for alkali-activated materials offers an environmentally friendly approach to solid waste management. However, the rapid setting issue limits the widespread use of sludge ash-based materials (SAAM). This study aims to control the setting time of SAAM by employing retarders. The impact of sucrose and glucose on setting time, fluidity, and compressive strength was examined. XRD, FTIR, SEM, and BSE techniques were used to investigate the mechanisms of retarder action. Additionally, a sustainability assessment was conducted. The results show that both sucrose and glucose significantly extend the setting time of SAAM. Optimal control can be achieved by adjusting the retarder dosage. Microscopic tests reveal that retarders hinder the hydration process, impeding initial hardening. Furthermore, compared to adjusting activator parameters, retarder use leads to lower CO2 emissions and energy consumption, enhancing environmental sustainability.

Study on failure characteristics of baking-free bricks with wrap-shell aggregate

Using sediment at the bottom of rivers and lakes as raw materials to prepare non-fired wrap shell aggregate (WSLAs) and using wrap shell aggregates to replace natural crushed stones to prepare baking-free bricks is a means of resource utilization. In this paper, using harmless treated sludge and other cementitious material mix as the core and cement as the shell, the wrap shell aggregate baking-free bricks were prepared and its damage characteristics were studied. By means of physical test and image processing, the mechanical properties of the baking-free brick under different aggregate substitution rate and grading conditions were analyzed. At the same time, the existing image analysis method is compared to select the most suitable method to study the damage characteristics of the baking-free brick, and further explore the meso-mechanism of the baking-free brick and the development and evolution of the crack under different substitution rates. The main research contents and conclusions are as follows: (1) Based on image processing technology, Multifractal spectroscopy and Grey Level Co-occurrence Matrix are faster, lower cost, and more accurate image analysis methods. These two methods make the development and evolution of cracks more convincing through quantitative analysis when exploring the damage characteristics of the wrap shell aggregate baking-free brick. (2) The fracture width Δa, maximum peak value and Δf are linear with the substitution rate, indicating that with the increase of the substitution rate, the fracture diversity is higher, the fracture complexity is higher, and the fracture propagation is wider and richer. (3) When GLCM analysis is used, the correlation between fracture characteristic values and the substitution rate is also linear, and the results show that the energy and correlation decrease with the increase of WSLAs substitution rate. Entropy and contrast increase with the increase of WSLAs substitution rate. (4) Both multifractal spectrum and gray level co-occurrence matrix can well reflect the fracture characteristics under different CAWS substitution rates. From the perspective of fracture complexity, the entropy linear correlation degree of gray level co-occurrence matrix is better than that of multifractal spectrum, which can simply and intuitively reflect the fracture expansion degree. The grayscale level co-existence matrix divides the crack expansion form into four different levels for more detailed research. For crack propagation, the two methods can be compared and verified at the same time to provide reference value for further engineering applications.

Technical and environmental properties of recycled aggregates produced from concrete sludge and excavation materials

This study presents a Re-Con Zero dry washing technology used to produce recycled aggregates from concrete sludge (RCZ) and combined as a feedstock in wet recycling excavation materials (EM) for unbound applications. A two-component admixture i.e, high water absorbing polymer and aluminum sulphate was used in producing RCZ. RCZ0, RCZ50 and RCZ100 were produced with EM within the range 0–100%. Analysis by the Los Angeles (LA) and micro-Deval (MD) test demonstrated RCZ to be of high-quality, hence a clear trend of improved performance as the content increased was observed in the LA and MD values. X-ray diffraction analysis performed on original and pulverized residues (<1.6 mm) showed that feldspar, quartz, phyllosilicates (mica and chlorite) and minor amounts of pyroxene (diopside) were present together with paste minerals such as portlandite and residual clinker, and calcite. Acid solubility results demonstrated the relation to increased paste content as particle size reduced. This observation was more prevalent in < 1.6 mm RCZ fraction which further indicated the significant amount of remained paste after wet treatment. Low levels of the content of chemical species of potential concern were in general found and were mostly complying to Norwegian regulations. Total Cr exceeded the criteria of 100 mg/kg, but the leachable Cr(VI) was not detected which showed that remaining Cr after recycling process was present mostly on the trivalent form. This indicated low leaching of Cr upon carbonation and a decrease in pH.

Sludge drying and dewatering processes influence the abundance and characteristics of microplastics in wastewater treatment plants

Wastewater treatment plants (WWTPs) have been identified as high-load receptors of microplastics (MPs) from different sources. However, the influence of specific treatment stanges requires further research. The main objective of this research was to evaluate the abundance and chemical characteristics of MPs in the sludge of two major wastewater treatment plants in the Agadir metropolis (Central Atlantic of Morocco). The Aourir plant receives urban influents and the inputs of the M'zar facility were urban and industrial. Samples were collected from the sludge matrices after primary settling, clarifying, dewatering, and drying systems. In addition, the effect of seasonality on MP load was assessed. The results showed that a higher abundance was noticed in raw sludge than in dewatered one in Aourir WWTP, while in M'zar WWTP, a very low decrease is noticed in dried sludge compared to raw sludge. The concentration of MPs in the summer season was significantly higher compared to other seasons for Aourir WWTP, while the winter season was higher for M'zar WWTP. Moreover, the most abundant shapes were fibers and the fraction 100–500 μm was the most preponderant. Eleven polymers were identified by ATR-FTIR, being polyester, polyethylene, polypropylene, and polystyrene the most abundant ones. Scanning Electron Microscopy coupled with Energy Dispersive X-ray revealed the visible degradation and fragmentation of MPs from sewage sludge and their ability to adsorb inorganic elements. It was estimated that between 2.2 × 107 and 7.4 × 108 MPs were evacuated with the sludge per day. The obtained findings confirmed that WWTP sludge acts as a vector of MPs with a high level of hazard to various matrices, such as landfills, agricultural soils, and groundwater. Overall, consideration must be given to the regulatory system managing the fate of sewage sludge to mitigate the collateral effects and provide solutions.