Sink Effect Research Articles

A Simulation-Based Prediction of Land Use Change Impacts on Carbon Storage from a Regional Imbalance Perspective: A Case Study of Hunan Province, China

Land use imbalances are a critical driving factor contributing to regional disparities in carbon storage (CS). As a significant component of China’s Yangtze River Economic Belt, Hunan Province has undergone substantial shifts in land use types, resulting in an uneven distribution of ecosystem CS and sequestration capacity. Therefore, within the framework of the “dual carbon” strategy, examining the effects of land use changes driven by regional resource imbalances on CS holds practical importance for advancing regional sustainable development. This study focuses on Hunan Province, utilizing the PLUS-InVEST model to assess the spatiotemporal evolution of CS under land use changes from 1990 to 2020. Additionally, multiple scenario-based development modes were employed to predict county-level CS. The results indicate the following: (1) From 1990 to 2020, Hunan Province experienced continuous urban expansion, with forest land and cultivated land, which are core ecological land types, being converted into construction land. (2) Over these 30 years, the province’s total CS increased by 2.47 × 108 t, with significant spatial differentiation. High-value zones were concentrated in bands along the province’s borders, while lower values were observed in the central and northern regions. The highest CS values were recorded in forested areas at the province’s periphery, whereas the lowest values were observed in the northern water bodies. (3) The scenario-based predictions revealed notable differences, with the ecological protection scenario demonstrating a substantial carbon sink effect. By prioritizing forest and cultivated land, CS could be maximized. This research provides valuable insights for enhancing CS and optimizing land use structures in regions facing resource imbalances.

Linkage engineered poly(heptazine imide) optimizes charge transfer for efficient photocatalytic H2O2 production: Regulating oxygen reduction pathway

Photocatalytic H2O2 production via oxygen reduction reaction (ORR) is of great interest. However, the inferior charge transfer efficiency and the low 2e− ORR selectivity grossly constrain this process. Herein, we incorporated pyrimidine (PM) groups as linkers between heptazine units into the poly(heptazine imide) (PHI-PM). There was an augmented in-plane built-in electric field leading to elevated charge separation and transfer capabilities. Additionally, the incremental electron sink effect by PM groups prolonged the charge lifetime and fostered an efficient transfer of electrons from PM groups (electron trapping center) to −C≡N groups (oxygen adsorption center), significantly improving the activity and selectivity of 2e− ORR. Results indicated that the optimization of charge transfer greatly increased the proportion of two-step single-electron ORR, accelerating the reaction kinetics. Meanwhile, side-reaction 4e− ORR was inhibited attributed to the selective generation of •O2−. This work paved new avenues for regulating the pathway of photocatalytic ORR for H2O2 production.

The Upshots of Dufour and Soret in Stretching Porous Flow of Convective Maxwell Nanofluid with Nonlinear Thermal Emission

In this paper, the combined upshot of Soret and Dufoue of a convective Maxwell nanofluid on a porous perpendicular surface with nonlinear thermal emission was investigated. In the present work, the impact of permeable stretching sheet, nonlinear thermal emission, heat sour sink, Dufour and Soret effect, chemical reaction, Brownian motion and thermophoresis in a convective Maxwell nanofluid flow is widely discussed. The governing equations derived for the problem are highly nonlinear coupled partial differential equations. The governing equations were transformed into ordinary differential equations using Lie symmetry group alterations. The BVP4C MATLAB solver was employed to solve the ordinary differential equations numerically after validating the convergence of the method with existing results in the literature. The numerical results were established and discussed using tables and graphs. It was found that variations in porosity parameter (K), Dufour (Du) and Soret (Sr) improves velocity, temperature and concentration profiles respectively and the present of nonlinear thermal radiation and heat source emit more heat for the flow. Also, it is exciting to report that both porosity (K) and Dufour (Du) parameters has a strong impact on the flow of skin frictions, Nusselt number and Sherwood number. However, the current results may present applications in the areas of petroleum reservoir, heat exchangers, steel industries, cooling applications, nuclear waste disposal and so on.

How does the value of ecological restoration techniques affect ecosystem carbon density: A resource endowment-based perspective

In the context of carbon neutrality and carbon peaks, innovations in ecological restoration technology play a key role in carbon adsorption and maintaining ecological balance. Regional governments, tasked with formulating differentiated and rational ecologically sustainable development plans and carbon-neutral strategies tailored to various resource endowment conditions, require timely identification of the mechanisms by which ecological restoration technologies affect the carbon density of ecosystems. Based on data from 31 provinces in China from 2006 to 2021, this study employed the Spatial Durbin Model with both time and space fixed effects to examine the impact of the value of ecological restoration technologies on ecosystem carbon density under varying resource endowments. The empirical results indicate that (1) the value of ecological restoration technology has a significantly positive effect on ecosystem carbon density, particularly in neighbouring areas; (2) energy resource endowment exhibits a significantly inverted U-shaped boundary effect, whereby regions with moderate energy endowment can optimise the positive impact of ecological restoration technology; (3) the heterogeneity analysis, based on levels of regional environmental governance and forest cover, shows that in regions with less investment in environmental infrastructure and lower forest cover, ecosystem carbon density is more sensitive to the value of ecological restoration techniques, making their carbon sink effect more pronounced. This study elucidates the key role of ecological restoration techniques in enhancing carbon storage, promoting the goal of carbon neutrality, and identifying optimal pathways for increasing ecosystem carbon stocks across various regions with differing resource endowments. Moreover, it provides a reference for accelerating the achievement of carbon neutrality targets.

Estimation and Spatial Distribution of Individual Tree Aboveground Biomass in a Chinese Fir Plantation in the Dabieshan Mountains of Western Anhui, China

Understanding aboveground biomass (AGB) and its spatial distribution is key to evaluating the productivity and carbon sink effect of forest ecosystems. In this study, a 123-year-old Chinese fir forest in the Dabieshan Mountains of western Anhui Province was used as the research subject. Using AGB data calculated from field measurements of individual Chinese fir trees (diameter at breast height [DBH] and height) and spectral vegetation indices derived from unmanned aerial vehicle (UAV) remote sensing images, a random forest regression model was developed to predict individual tree AGB. This model was then used to estimate the AGB of individual Chinese fir trees. Combined with digital elevation model (DEM) data, the effects of topographic factors on the spatial distribution of AGB were analyzed. We found that remote sensing spectral vegetation indices obtained by UAVs can be used to predict the AGB of individual Chinese fir trees, with the normalized difference vegetation index (NDVI) and the optimized soil-adjusted vegetation index (OSAVI) being two important predictors. The estimated AGB of individual Chinese fir trees was 339.34 Mg·ha−1 with a coefficient of variation of 23.21%. At the local scale, under the influence of elevation, slope, and aspect, the AGB of individual Chinese fir trees showed a distribution pattern of decreasing from the middle to the northwest and southeast along the northeast-southwest trend. The effect of elevation on AGB was influenced by slope and aspect; AGB on steep slopes was higher than on gentle slopes, and the impact of slope on AGB was influenced by aspect. Additionally, AGB on north-facing slopes was higher than on south-facing slopes. Our results suggest that local environmental factors such as elevation, slope, and aspect should be considered in future Chinese fir plantation management and carbon sink assessments in the Dabieshan Mountains of western Anhui, China.

Analysis of the influence of nonlinear energy sink parameters applicable to helicopter main reduction systems

Abstract In response to the vibration problem of helicopter fuselage caused by continuous rotor periodic excitation force, a nonlinear energy sink is considered to be installed on the main reduction transmission channel to reduce the vibration level of the fuselage. This article conducts an analysis of the influence of nonlinear energy sink structure parameters under harmonic excitation force, establishes a coupled dynamic model of helicopter main reduction/absorber/fuselage, and uses harmonic balance method and stability analysis theory to analyze the periodic solution and stability of the system. Using the vibration amplitude of the system as the evaluation criterion, the influence of damping, stiffness, and mass ratio on the vibration suppression effect of the nonlinear energy sink was explored. The results showed that as the damping of the nonlinear energy sink increased, the resonance frequency of the coupled system shifted to the left, and the vibration amplitude of the main reduction system increased; As the stiffness of the nonlinear energy sink increases, the vibration amplitude of the coupled system will first decrease and then increase, gradually approaching the vibration amplitude of the system without coupled dampers; The influence of mass ratio on system amplitude follows the same trend as the influence of stiffness. By optimizing, the structural parameters of the nonlinear absorber with good vibration suppression effect are ultimately obtained.

Prospects for the potential carbon sink effects of afforestation to enhance weathering in China

Prospects for the potential carbon sink effects of afforestation to enhance weathering in China

Temperature Simulation of an Ablation Needle for the Prediction of Tissue Necrosis during Liver Ablation

Background/Objectives: Microwave ablation (MWA) is the leading therapy method for treating patients with liver cancer. MWA simulation is used to further improve the therapy and to help develop new devices. Methods: A water-cooled ablation needle was reconstructed. MWA simulations of a polyacrylamide phantom were carried out and compared with a representative clinical example (tumor diameter: 8.75 mm). The Arrhenius damage model and a critical temperature approach of 60 °C were applied to assess the necrosis zones. Finally, the simulation results were compared to the corresponding MR measurements. Results: Most of the heating in the simulation took place at a distance of 5 mm along the transverse axis and 20 mm along the longitudinal axis above the needle tip. The calculated Dice scores for the Arrhenius model were 0.77/0.53 for the phantom/clinical case. For the critical temperature approach, Dice scores of 0.60/0.66 for the phantom/clinical case were achieved. Conclusions: The comparison between simulated and measured temperature increases showed an excellent agreement. However, differences in the predicted necrosis volume might be caused by omitting consideration of the heat sink effect, especially in the clinical case. Nevertheless, this workflow enables short MWA simulation times (approximately 3 min) and demonstrates a step towards possible integration into daily clinical use.

Assessment of Land Subsidence Pattern in Pokhara Valley Using Sentinel-1 InSAR Processing

This research examines the use of Sentinel-1's enhanced remote method and Interferometric Synthetic Aperture Radar (InSAR) processing to monitor ground subsidence in Pokhara Valley City, Nepal. It aims to comprehend the reciprocal effects of land sinking on environmental sustainability, infrastructure stability, and urban growth. The methodology encompasses the acquisition and processing of Sentinel-1 SAR data, along with rigorous interferometric analysis to detect and quantify ground deformation. Spanning from 2019 to 2022 AD and, -analyzing annual displacement trends, initially, a subsiding trend was observed in 2019-20 AD with an average rate of 0.037 m/year followed by 0.072 m/year in 2020-21 AD, and then escalating to 0.165 m/year in 2021-22 AD. These fluctuations in rates illustrate the intricate interplay of urbanization and geological dynamics affecting land stability in the region. The implications of this study extend to urban planning and infrastructure management, emphasizing the necessity of integrating land subsidence monitoring into the developmental policies and strategies of Pokhara Valley. Additionally, the potential of Sentinel-1 InSAR as a valuable tool for geotechnical investigations offers a non-invasive, cost-effective means to assess and monitor ground deformation risks. By leveraging the capabilities of Sentinel-1 InSAR, the study contributes to the body of knowledge in geotechnical and civil engineering fields, particularly within the context of sustainable urban planning and disaster risk reduction.

Gust response alleviation of the aircraft wing aeroelastic systems in supersonic flows using nonlinear energy sink

In order to reduce the gust response level of the aircraft wing aeroelastic systems in supersonic flows, the nonlinear energy sink (NES) is introduced into the aeroelastic system, and the effect of the nonlinear energy sink on the aeroelastic gust response is studied. The gust response dynamic model without and with NES is established by Lagrange equation, considering the cubic nonlinear characteristics of both plunge and pitch stiffness. The piston theory model as well as the '1-cos' model are employed to describe the unsteady aerodynamic load and the gust velocity, respectively. Besides, the comparison study of the gust response amplitude and energy characteristics of the wing aeroelastic systems with and without NES are analyzed. For systems with NES, the amplitude of gust dynamic response decreases rapidly, while vibration can be transmitted to the NES mechanism and causing its vibration. From an energy perspective, about 72.15 % of the original vibration energy has been transferred into NES, and further consumed through its damping. The influence of NES parameters, such as frequency ratio, mass ratio, damping ratio, and installation position on gust response, is discussed. Numerical simulations demonstrate that: as the frequency ratio, damping ratio and mass ratio increase, the dynamic response amplitude of the aeroelastic system decays faster, and the energy transferred from the wing system also increases. In addition, an optimal relative distance for the installation of NES can be found with best gust alleviation effect. The influence of nonlinear energy sink on the targeted transfer of vibration energy in aeroelastic systems are analyzed under different working conditions. The NES shows great gust alleviation effect and good robustness under different flight speeds, gust intensities, and gust lengths.

Sulfur-doped Bi2O2CO3 nanosheet for enhanced visible-light-driven photocatalytic CO2 reduction to CO with ultra-high selectivity.

The photocatalytic reduction of carbon dioxide (CO2) has emerged as a compelling strategy for the conversion of renewable energy. However, the expeditious recombination of photogenerated charge carriers and the inadequate light absorption capabilities are currently predominant challenges. Herein, we developed a facile hydrothermal approach to synthesize a sulfur doped Bi2O2CO3 nanosheet with a tunable energy band structure designed to enhance visible light absorption. Our findings indicate that the incorporation of sulfur into the catalytic sites induces an electron sink effect, significantly improving the separation efficiency of photogenerated charge carriers. Consequently, this sulfur-doped Bi2O2CO3 catalyst exhibits a remarkable carbon monoxide (CO) yield of 16.64 μmol gcat-1 h-1 with nearly 100 % selectivity under illumination ranging from 420 to 780 nm. Through in-situ characterization techniques and theoretical calculations, it was revealed that sulfur-coordinated bismuth sites greatly enhance CO2 adsorption and decrease the energy barrier for critical intermediates formation (*COOH), thus selectively driving the reaction towards CO production. This work not only advances our understanding of mechanisms underlying photocatalytic reduction of CO2 on sulfur-doped bismuth-based catalysts but also sets a precedent for developing sophisticated photocatalytic systems for enhanced photoreduction reactions.

Carbon sink of forest ecosystems: Concept, time effect and improvement approaches.

The widespread utilization of fossil fuels has emitted large amounts of CO2 into the atmosphere since the Industrial Revolution, leading to climate warming and frequent occurrence of extreme climate events. To effectively alleviate climate change, the international community has made various efforts to reduce carbon emissions and eliminate CO2 from the atmosphere. In 2020, the Chinese government announced that carbon emission peaking and carbon neutrality will be achieved by 2030 and 2060, respectively. According to the current forecast, by the time carbon neutrality is achieved in 2060, even under the minimum conditions of fossil energy use, production, and living emissions, China will still have to emit about 1/4 of the current total emissions. These carbon must primarily be absorbed by ecosystems. Furthermore, approximately 140 ppm increase in CO2 in the atmosphere since the Industrial Revolution still needs to be removed by ecosystems. Forests are the main component of terrestrial ecosystems, contributing more than 80% of the carbon sequestration capacity of all terrestrial ecosystems. However, due to the long periodicity, complexity and dynamic variability of forests, the basic concepts of ecosystem carbon sink and its time effect are still unclear, leading to problems, such as lacking technologies for improving carbon sink capacity and disorganized rules in the carbon sink trading market. In this review, we introduced carbon sink concept according to the processes of absorbing and fixing CO2 by plant photosynthesis in forest ecosystems. Then, we analyzed the processes of time-scale-dependent carbon sinks of forest ecosystems, discussed the time effects of forest carbon sinks, and suggested using "t-year" as the unit of carbon sink (taking 3-6 months as the minimum measurement time, i.e., the beginning of carbon sequestration). Third, we proposed the approaches to improve the carbon sink capacity of forest ecosystems. One way is to improve the carbon sink capacity (expanding forest area, improving forest quality, and increasing forest soil carbon storage) of forest ecosystems. Another approach is to maintain the carbon sink of forest ecosystems as long as possible, i.e., to reduce temporary carbon sink (definition: carbon in the forest ecosystems emit into the atmosphere for a certain period) and to increase persistent carbon sink (definition: carbon in the forest ecosystems no longer emit into the atmosphere for a certain period; according to the relevant provisions of the Paris Agreement, the upper time limit for carbon sink measurement can be considered to be the year 2100. In order to maintain the persistent carbon sink, strateges such as efficient use of wood products (replace steel, cement, plastic with wood), control of forest fires or other disturbances-induced emissions, and turning forest biomass into biochar should be taken. Finally, we proposed to develop climate-smart forestry driven by artificial intelligence (AI), which would provide new theoretical and technical support for improving the carbon sink of forest ecosystems and facilitating sustainable forest management.

Influence of Biomass Amendments on Soil CO2 Concentration and Carbon Emission Flux in a Subtropical Karst Ecosystem

Soil in karst areas is rare and precious, and karst carbon sinks play an important role in the global carbon cycle. Therefore, the purpose of karst soil improvement is to improve soil productivity and a carbon sink effect. Biomass amendment experiments in this study included three schemes: filter mud (FM), filter mud + straw + biogas slurry (FSB), and filter mud + straw + cow manure (FSC). The characteristics of soil CO2 production, transport, and the effect on soil respiration carbon emissions in two years were compared and analyzed. The results were as follows: 1. The rate, amount, and depth of CO2 concentration were affected by the combinations with biogas slurry (easy to leach) or cow manure (difficult to decompose). 2. The diurnal variation curves of soil respiration in the FSB- and FSC-improved soils lagged behind those in the control soil for three hours. While the curves of FM-improved soil and the control soil were nearly the same. 3. Soil–air carbon emissions increased by 35.2 tCO2/(km2·a−1) under the FM scheme, decreased by 212.9 tCO2/(km2·a−1) under the FSB scheme, and increased by 279.5 tCO2/(km2·a−1) under the FSC scheme. The results were related to weather CO2 accumulation in the deep or surface layers under different schemes.

First-Strike Rapid Predictive Dosimetry and Dose Response for 177Lu-PSMA Therapy in Metastatic Castration-Resistant Prostate Cancer.

We devised and clinically validated a schema of rapid personalized predictive dosimetry for 177Lu-PSMA-I&T in metastatic castration-resistant prostate cancer. It supersedes traditional empiric prescription by providing clinically meaningful predicted absorbed doses for first-strike optimization. Methods: Prostate-specific membrane antigen PET was conceptualized as a simulation study that captures the complex dosimetric interplay between tumor, marrow, and kidneys at a single time point. Radiation principles of fractionation, heterogeneity, normal-organ constraints (marrow, kidney), absorbed dose, and dose rate were introduced. We created a predictive calculator in the form of a free, open-source, and user-friendly spreadsheet that can be completed within minutes. Our schema achieves speed and accuracy by sampling tissue radioconcentrations (kBq/cm3) to be analyzed in conjunction with clinical input from the user that reflect dosimetric preconditions. The marrow-absorbed dose constraint was 0.217 Gy (dose rate, ≤0.0147 Gy/h) per fraction with an interfraction interval of at least 6 wk. Results: Our first 10 patients were analyzed. The first-strike mean tumor-absorbed dose threshold for any prostate-specific antigen (PSA) response was more than 10 Gy (dose rate, >0.1 Gy/h). The metastasis with the lowest first-strike tumor-absorbed dose correlated the best with the percentage decrease of PSA; its threshold to achieve hypothetical zero PSA was 20 Gy or more. Each patient's PSA doubling time can be used to personalize their unique absorbed dose-response threshold. The predicted mean first-strike prescription constrained by marrow-absorbed dose rate per fraction was 11.0 ± 4.0 GBq. Highly favorable conditions (tumor sink effect) were dosimetrically expressed as the combination of tumor-to-normal-organ ratios of more than 150 for marrow and more than 4 for kidney. Our schema obviates the traditional role of the SUV as a predictive parameter. Conclusion: Our rapid schema is feasible to implement in any busy real-world theranostics unit and exceeds today's best practice standards. Our dosimetric thresholds and predictive parameters can radiobiologically rationalize each patient's first-strike prescription down to a single becquerel. Favorable tumor-to-normal-organ ratios can be prospectively exploited by predictive dosimetry to optimize the first-strike prescription. The scientific framework of our schema may be applied to other systemic radionuclide therapies.

DeNOxing the air in urban spaces by building and construction photocatalytic coverings

A variety of air depolluting TiO2-based marketed products were applied on bituminous mixtures, sidewalk pavements and facades, giving NOx oxidation ratios under ISO 22197–1:2007 in the 35–9%, 56–2% and 28–2% ranges, respectively. Correspondingly, DeNOx toxicity indexes varied from −0.8 to 5.6, 0 to 14 and −4 to 1.The three most efficient photocatalytic products were selected: two TiO2-water emulsions, for road and sidewalk, and a TiO2-paint, for facade. NOx purifying ability of these materials were evaluated when key physical parameters were modified. The observed NOx conversion is positively correlated with UV-A irradiance up to 10 W/m−2(−|-), reaching a plateau, and negatively correlated with relative humidity, with a more pronounced decrease above 35 %. Inversely, no dependence with inlet NOx concentration is observed in the range of 0.14–1 ppmv.Further, two first-order kinetic approximations were followed to calculate NO surface deposition rates, giving 2 to 8 10−3 m/s on the selected photocatalytic urban surfaces. Subsequently, the potential NOx sink effect induced in a photocatalytic urban canyon and a NOx-purifier was modelled taking NOx surface deposition rates from 10−3 to 10−1 m/s. Purifying devices could be utilised as a preferred option to help alleviate local atmospheric NOx in high-polluted areas.

Cluster dynamics modeling of hydrogen retention and desorption in tungsten with saturation and multi-trapping effect of sinks

Hydrogen (H) retention and desorption in tungsten (W)-based plasma-facing materials are still not well understood, largely due to the limitations of ex-situ observations in experimental detection methods like thermal desorption spectroscopy (TDS). In order to reveal the fundamental mechanisms behind H retention and desorption, we developed a cluster dynamics model, IRadMat-TDS, for theoretical modeling of depth distribution and TDS of deuterium (D) in polycrystalline W. The model newly includes the saturated absorption and emission of D in inherent sinks like grain boundaries (GBs), as well as the multi-trapping effect of D in various types of GBs with different trapping energies. The simulated TDS spectra are in agreement with experimental ones. For polycrystalline W under D ion irradiation within keV-energy range, two typical thermal desorption peaks in TDS at around 490 and 550 K are explicitly attributed to D emission from GBs and vacancies, respectively. And GBs play a major role in D retention. Moreover, the broad peaks in TDS come from the convolution of multi-trapping of D in sinks with different types of trapping sites rather than a single-site approximation.

A potential CO2 carrier to improve the utilization of HCO3– by plant-soil ecosystem for carbon sink enhancement

IntroductionImproving the rhizospheric HCO3– utilization of plant-soil ecosystem could increase the carbon sink effect of terrestrial ecosystem. However, to avoid its physiological stress on the crop growth, the dosage of HCO3– allowed to add into the rhizosphere soil was always low (i.e., <5–20 mol/m3). ObjectivesTo facilitate the utilization of relatively high concentrations of HCO3– by plants in the pursuit of achieving terrestrial carbon sink enhancement. MethodsIn this study, the feasibility of directly supplementing a high concentration HCO3– carried by the biogas slurry to the plant rhizosphere was investigated using the tomato as a model plant. ResultsThe CO2-rich biogas slurry was verified as a potential CO2 carrier to increase the rhizospheric HCO3– concentration to 36 mol/m3 without causing a physiological stress. About 88.3 % of HCO3– carried by biogas slurry was successfully fixed by tomato-soil ecosystem, in which 43.8 % of HCO3– was assimilated by tomato roots for the metabolism, 0.5 ‰ of HCO3– was used by microorganisms for substances synthesis of cell structure through dark fixation, and 44.4 % of HCO3– was retained in the soil. The rest of HCO3– (∼11.7 %) might escape into the atmosphere through the reaction with H+. Correspondingly, the carbon fixation of tomato-soil ecosystem increased by 150.1 g-CO2/m2-soil during a tomato growth cycle. As for the global countries that would adopt the strategy proposed in this study to cultivate the tomato, an extra carbon sink of soil with about 1031.1 kt-C per year (i.e., an additional 0.21 tons of carbon per hectare soil) could be obtained. ConclusionThis would be consistent with the goal of soil carbon sink enhancement launched at COP21. Furthermore, the regions with low GDP per capita may easily achieve a high reduction potential of CO2 emissions from the agricultural land after adopting the irrigation of CO2-rich biogas slurry.

Effect of high blood flow on heat distribution and ablation zone during microwave ablation-numerical approach.

Microwave ablation has become a viable alternative for cancer treatment for patients who cannot undergo surgery. During this procedure, a single-slot coaxial antenna is employed to effectively deliver microwave energy to the targeted tissue. The success of the treatment was measured by the amount of ablation zone created during the ablation procedure. The significantly large blood vessel placed near the antenna causes heat dissipation by convection around the blood vessel. The heat sink effect could result in insufficient ablation, raising the risk of local tumor recurrence. In this study, we investigated the heat loss due to large blood vessels and the relationship between blood velocity and temperature distribution. The hepatic artery, with a diameter of 4 mm and a height of 50 mm and two branches, is considered in the computational domain. The temperature profile, localized tissue contraction, and ablation zones were simulated for initial blood velocities 0.05, 0.1, and 0.16 m/s using the 3D Pennes bio-heat equation, temperature-time dependent model, and cell death model, respectively. Temperature-dependent blood velocity is modeled using the Navier-Stokes equation, and the fluid-solid interaction boundary is treated as a convective boundary. For discretization, we utilized elements for the wave propagation model, elements for the Pennes bio-heat model, and elements for the Navier-Stokes equation, where represents the computational domain. The simulated results show that blood vessels and blood velocity have a significant impact on temperature distribution, tissue contraction, and the volume of the ablation zone.

Evolution of the regional innovation system in terms of the Covid-19 pandemic, financial and economic crisis: The long term perspective from Central European region

Research background: The evolution of the innovation system is not easy to explore due to the small number or selective nature of the international research about it. The natural trajectory is well known in a long time period but differs between regions and countries — more or less developed. If the impact of the external shocks on regional innovation system (RIS) is added here, the situation is even more complicated. The answer for the crises depends on the development level of a country and region, the maturity of the relationships between actors of the Triple Helix (entrepreneurship, science, government) — their strength and stability over time, some endogenous conditions specific to it. The knowledge about the evolution of the innovation system is crucial to understand how the system works, where it was, is and will be at the evolution trajectory. Purpose of the article: Therefore, the purpose of this paper is to identify the evolution of the RIS in the one of Central Europe’s regions (Lower Silesian in Poland) including the impact of the global financial crisis and the Covid-19 pandemic on the innovation technology there. Methods: Using microdata collected by the authors and the stepwise logit modelling, industrial enterprises were analysed in three time periods: 2004–2006, 2010–2012 and 2019–2021. Total 1649 questionnaires forms were collected. The research was made in the one of Poland's well advanced regional innovation systems — the Lower Silesian. The matrix of success and fail was used as long as the AUC curve and some statistical indicators to prove the usefulness of models. The dependent variables were the new technology pushed by R&amp;D and the investment in new machinery and equipment. Findings &amp; value added: The nature of RIS evolution in the one of the regions in Central Europe in a catching-up country in the context of financial crises and Covid-19 was examined. The analyses identified two alternative groups of conditions — high or low resilience to various market shocks. To the first group belongs: R&amp;D and equipment interactions (the growing competence effect) and a cooperation along the supply chain in the industry. The low resilience is observed in the other categories, as follows: the cooperation with science institutes and business support organizations (the isolation effect), the lack of external sources of funding (the sinking effect), the short time reaction of entrepreneurs (the adaptation effect). As was pointed above in the catching-up country, some elements of the Triple Helix are more sensitive to external shocks, while others are not. The crisis situation can radically slow down an evolutionary development or change its direction. Knowing them will allow the local authority to react on time or with a low delay to reduce negative consequences of it to the regional economy. Authors have shown a new approach to the evolution process of regional innovation system. It could be useful to learn how, where and when the system is going to.

Highly efficient Bi/BiOCl with oxygen vacancies photocatalyst with synergetic effects of oxygen vacancy, surface plasmon resonance, and electron sink effects of metallic Bi

Bi/BiOCl with oxygen vacancies composite was synthesized through a facile and rapid in situ surface reduction of BiOCl, utilizing NaBH4 as the reductant. The reduction process yielded metallic Bi nanoparticles on the surface of BiOCl and meanwhile created the oxygen vacancies within the BiOCl lattice. As a consequence, the as‐synthesized Bi/BiOCl composites exhibited a substantially enhanced visible‐light absorption capacity, whereas pure BiOCl was only responsive to ultraviolet light. Additionally, the Bi/BiOCl composite demonstrated a markedly accelerated photodegradation rate of Rhodamine, exceeding that of pure BiOCl and P25 by a factor of 6.10 and 19.74, respectively. The density functional theory (DFT) calculation was carried out to estimate the band structural and electronic properties of samples. Based on systematic analysis, the underlying mechanism was attributed to the extended responsive light range due to the surface plasma resonance of metallic Bi and the formation of oxygen vacancy energy level. Moreover, the electron sink effect of Bi nanoparticles was found to suppress the recombination of photoinduced charges, further contributing to the enhanced photocatalytic performance of Bi/BiOCl.