AbstractA marked Prym curve is a triple $$(C,\alpha ,T_d)$$ ( C , α , T d ) where C is a smooth algebraic curve, $$\alpha $$ α is a $$2-$$ 2 - torsion line bundle on C, and $$T_d$$ T d is a divisor of degree d. We give obstructions—in terms of Gaussian maps—for a marked Prym curve $$(C,\alpha ,T_d)$$ ( C , α , T d ) to admit a singular model lying on an Enriques surface with only one ordinary singular point of multiplicity d, such that $$T_d$$ T d is the pull-back of the singular point by the normalization map. More precisely, let (S, H) be a polarized Enriques surface and let (C, f) be a smooth curve together with a morphism $$f:C \rightarrow S$$ f : C → S birational onto its image and such that $$f(C) \in |H|$$ f ( C ) ∈ | H | , f(C) has exactly one ordinary singular point of multiplicity d. Let $$\alpha =f^*\omega _S$$ α = f ∗ ω S and $$T_d$$ T d be the divisor over the singular point of f(C). We show that if H is sufficiently positive then certain natural Gaussian maps on C, associated with $$\omega _C$$ ω C , $$\alpha $$ α , and $$T_d$$ T d are not surjective. On the contrary, we show that for the general triple in the moduli space of marked Prym curves $$(C,\alpha ,T_d)$$ ( C , α , T d ) , the same Gaussian maps are surjective.