The present work focuses on investigation of the electrochemical properties of amino terephthalonitrile based single benzene fluorophores (Am-TN-SBFs) and correlating them with their highly emissive characteristics. We already know that the emissive properties of the Am-TN-SBFs could be modulated by altering the position and geometries of the donor and acceptor groups. In order to understand whether the electrochemical properties of these Am-TN-SBFs could also be tuned in the similar manner, redox properties were studied which remained largely unexplored till date. We were able to successfully identify the key structural characteristics responsible for inducing fluorescence in these molecules, while also facilitating the generation of appealingly low electrochemical potentials. We synthesized few benzomorpholino-based SBFs, which proved to be highly emissive and demonstrated remarkably low quasi-reversible oxidation potential. These molecules hold potential for constructing devices tailored for future electroluminescence-based applications.