To improve the calibration accuracy of an electric field (E-field) probe loaded with a diode detector for digital wireless communication signals with complex waveforms, the effect of the nonlinear characteristics of the E-field probe on the detection response of a long-term evolution (LTE) signal is investigated. In this article, we focused on single-carrier frequency division multiple access (SC-FDMA) and orthogonal frequency-division multiplexing access (OFDMA) signals used for LTE uplink and downlink, respectively. First, we investigated the effect of the nonlinear characteristics of the E-field probe on the detection response of continuous SC-FDMA and OFDMA signals simulating frequency division duplexing LTE. Then, intermittent SC-FDMA and OFDMA signals simulating time-division LTE were also investigated. Furthermore, we proposed a method of estimating the detection response of SC-FDMA and OFDMA signals using the probability density function of the envelope amplitude. When the envelope variation of the LTE signal is fully covered within the response time of the E-field probe, the estimated detection response agrees well with the measured result. In addition, the detection response of an intermittent LTE signal with a typical repetition period can be calculated with the proposed approximation formula by separately considering the probability density functions of the envelope amplitude for the burst and nonburst periods.