Siliciclastic Samples Research Articles

Unlocking clues on the provenance of the Zigzag Formation in Mountain Province, Northern Luzon, Philippines using sedimentary geochemistry

Abstract Provenance analysis using whole-rock geochemical data was carried out on the Late Oligocene to Early Miocene Zigzag Formation in southwestern Mountain Province, North Luzon, Philippines. Major and trace element geochemistry of the siliciclastic samples from the Zigzag Formation revealed a first-cycle mafic source of the detrital materials. This is consistent with other discrimination diagrams such as those using La, Sc, and Th to determine the provenance. Tectonic discrimination diagrams suggest an oceanic island arc signature for the source rocks of the Zigzag Formation. The Cretaceous to Eocene Lepanto Metavolcanics is proposed to be the source of the detrital materials comprising this clastic sequence. The results present additional information on the current understanding of the evolution of the Central Cordillera.

Reconstructing the thermal history of the Morondava Basin, Madagascar, after Gondwanan breakup as resolved through detrital zircon (U–Th)/He and U–Pb geochronology

Formation of the Phanerozoic basins of Madagascar coincided with the initial stages of Permian break-up of Gondwana. The largest of these, the Morondava Basin, records the tectonic history of rifting, drifting, and uplift of the Malagasy terrane over the last 300 Myr. Herein, we have applied detrital zircon U–Pb geochronology and (U–Th)/He low-temperature thermochronology to resolve the thermal history of the basin as Madagascar separated from Africa and subsequently India. Coarse-grained siliciclastic samples were taken along two transects parallel to the Morondava River in the central basin, including from the Permo-Triassic failed rift basin and from post-Jurassic passive margin sequences. Detrital zircon U–Pb age distributions are defined by common Neoarchean and Neoproterozoic populations which suggests input from the basement terranes of the Malagasy Central Highlands (Antananarivo domain). Samples also contain Paleo-to Mesoarchean and Cambrian populations likely associated with metamorphic terranes amalgamated during the Pan-African orogeny. Single crystal zircon (U–Th)/He dates are 503 ± 17 Ma to 40 ± 1 Ma with effective uranium (eU) values ranging from 35 to 1760 ppm, which exhibit a strong negative date-eU relationship that indicates partial resetting of the He systematics in zircon throughout the basin. Inverse and forward thermal history models from the data reveal separate thermal histories for strata on either side of basin-dividing Illovo Fault. Under an elevated geothermal gradient, temperatures did not exceed 180 °C either during post-Gondwanan burial of Jurassic rift strata or during Late Cretaceous burial of Early Cretaceous passive margin strata. Intrusion of Turonian-age dikes and sills related to the Marion hot spot likely promoted subtle yet widespread heating. The time of latest cooling during the Paleogene recorded in the basin is poorly constrained by the detrital zircon thermochronology.

Characterization and Geological Implications of Precambrian Calcite‐Hosted Phosphate

AbstractConstraints on marine phosphate availability and cycling directly inform our understanding of long‐term biological evolution. However, early Earth phosphate records are sparse, biased toward siliciclastic samples, and susceptible to post‐depositional modification. Well‐preserved shallow marine inorganic carbonate precipitates provide a complementary yet understudied record of phosphate cycling. We combined micro‐X‐ray fluorescence mapping, X‐ray absorption, and Nuclear Magnetic Resonance spectroscopy on samples of Precambrian syndepositional herringbone calcite (HBC) and microspar to characterize phosphorus speciation and distribution in these carbonate fabrics. Phosphorus spectroscopy from synthetic calcite, HBC, and microspar, is qualitatively consistent with a disordered distribution of phosphate. These characteristics are diagnostic of calcite‐hosted phosphate, which is pervasive at low concentrations in HBC and microspar. This study provides evidence that ancient, well‐preserved carbonate fabrics retain phosphate sourced from seawater and highlights the potential for an unaltered archive of marine phosphate concentration over geologic time.

Acritarch clusters from the Cambrian (Miaolingian) of the Příbram-Jince Basin, Czech Republic

Monogeneric clusters of five acritarch genera (Adara, Cymatiosphaera, Eliasum, Synsphaeridium and Timofeevia) were discovered in palynological residues obtained from fine-grained siliciclastic samples from the middle Cambrian (Miaolingian) Jince Formation of the Příbram–Jince Basin (Czech Republic). The clusters consist of two to more than 100 individual specimens and lack a common pattern of organisation. Acritarchs within clusters fall within a similar size range, regardless of generic affinity. Proposed mechanisms for the formation of these acritarch clusters are discussed: for the Jince Formation clusters, aggregation within algal blooms or primary colonial behaviour are the most plausible explanations. In addition, a summary of reports of acritarch clusters from lower Palaeozoic strata is included: clusters of a variety of acritarch genera have been documented from rocks of early Cambrian to Late Devonian age.

Position of South China and Indochina along northern Gondwana margin during the Ediacaran–Silurian period

The South China Block (SCB) has often been taken as an integral member of Gondwana at its northern margin, but it remains contentious regarding when and how it joined Gondwana, its precise position in Gondwana, and what other continent(s) might have been adjacent to it at the time. This study reports new detrital zircon U-Pb and Hf isotopic data of twelve Ediacaran-Silurian siliciclastic samples from three field regions along the western margin of the SCB. They show two prevailing age populations of 810–790 Ma and 550–520 Ma, and minor ca. 2500 Ma, ca. 1850 Ma, ca. 1200 Ma and ca. 980 Ma peaks in various units. In combination with the regional lithofacies evolution, provenance analysis demonstrates that the uplifted western SCB provided a persistent supply of 810–790 Ma zircons from local Tonian granites to the Ediacaran-Silurian sediments, whereas the 550–520 Ma zircons were probably derived exotically from a magmatic arc. Provenance analysis also reveals that the SCB and Indochina have a close provenance linkage. We interpret that the exotic magmatic arc was along the northern Indian margin with the subducting lower plate carrying SCB-Indochina to eventually collide with Indian Gondwana during Cambro-Ordovician time. The uplift of the western SCB during the time likely reflects the far-field tectonic compression of the collision.

A review of U-Pb detrital zircon systematics from Cambrian- Lower Devonian rocks of the Moroccan Meseta

U-Pb geochronological analysis of detrital zircon grains is a powerful tool to decipher the pre-Mesozoic paleogeography. In this work, we present a sediment provenance study based on a compilation of 41 Cambrian-Early Devonian siliciclastic samples from the Moroccan Meseta. All of them are characterized by late Tonian-Ediacaran (c. 600 Ma, c. 50% of the data), Rhyacian-Orosirian (c. 2100 Ma, c. 20% of the data), and Neoarchean (c. 2500 Ma, c. 4% of the data)detrital zircon age populations indicating a strong West African Craton affinity. Minor populations are: (i) Cambrian-Ordovician (c. 500 Ma), particularly relevant in Lower Ordovician samples, which were probably sourced by local volcanic centers formed during an aborted rift; (ii) Stenian-early Tonian (c. 1000 Ma); and (iii) Orosirian-Statherian (c. 1800 Ma). These two latter populations were probably fed by paleocurrents from NE-African regions (e.g., Sahara Metacraton and Arabian-Nubian Shield) that reached only intermittently the studied area. Finally, the spatial and chronological distribution of the detrital zircon age populations suggests that the tectonic boundaries normally used to separate internal subdomains in northern Morocco did not imply far-travelled terranes during early-middle Paleozoic times.

U-Pb provenance fingerprints of metavolcanic-sedimentary successions of the Mineiro belt: Proxies for the continuity of plate tectonics through the Paleoproterozoic

We document new U-Pb detrital zircon LA-MC-ICP-MS data for seven metavolcanic-sedimentary successions and metasedimentary sequences and reassess additional dates of five siliciclastic samples toward their tectonic significance in the context of the Mineiro belt, Southern São Francisco Craton. This belt represents a crustal segment of the 2.47–2.00 Ga Minas Orogen, classically known by its Siderian and Rhyacian juvenile rocks with important implications in the Earth's geodynamics. The new and compiled detrital provenance constraints unravel the long-lived magmatic and sedimentary history of the studied basins, lasting ca. 230–220 Myr. The maximum depositional dates around 2.1 Ga reflect the renewed sediment budget with the subsequent metamorphic episode ca. 2.0 Ga. Most of the unmixed relative probability diagrams are consistent with sourcing from the Siderian and Rhyacian arcs of the Mineiro belt, determining a detrital provenance change in time and space for the precursor basins. Alternative potential sources could be the youngest rocks of the Mantiqueira and Juiz de Fora terranes that constitute the other segments of the Minas Orogen, given the age match. The overall detrital fingerprints determine the study basins resumed mainly in Rhyacian fore-arc and/or back-arc settings, i.e., akin to a subduction-related system that evolved to a collisional (foreland) environment. Few samples show fingerprints of primary extensional settings, determined by major Archean detrital populations sourced from areas outside the Mineiro belt beside the Paleoproterozoic detritus. The working model considers the collage between the Mineiro belt and the ancient foreland around 2.10 Ga and eventual interaction with other crustal segments of the Minas Orogen, generating the ca. 2.0 Ga metamorphism over the metasedimentary samples. The more complete isotopic repository in detrital and igneous zircon grains for the studied supracrustal successions and the associated rocks allows new insights into the Rhyacian–Orosirian dynamics of the Minas orogeny. In a broader perspective, the juvenile nature of the Mineiro belt reinforces the paradigm of uninterrupted continental growth during the Paleoproterozoic Earth.

Early Devonian tectonic conversion from contraction to extension in the Chinese Western Tianshan: A response to slab rollback

Abstract Extensive angular unconformities that occur across the Tianshan Orogen provide insight into the Paleozoic tectonic evolution of the southwestern Central Asian Orogenic Belt. This study presents new geochronological and geochemical data to unravel the age and origin of a pronounced angular unconformity in the Baluntai domain of the Chinese Western Tianshan. The angular unconformity separates a ductilely deformed metamorphic complex from overlying unmetamorphosed sequences. Detrital zircon age spectra suggest that the sedimentary samples received detritus from both the Precambrian basement and contemporaneous igneous rocks in the Central Tianshan and Yili blocks. The youngest detrital and metamorphic zircons in metasediments from the metamorphic complex reveal that their protoliths were deposited at ca. 419 Ma, and subsequently overprinted by metamorphism and ductile deformation at ca. 409 Ma. Along with ca. 532–407 Ma metavolcanics and foliated intrusions, the metamorphic complex constitutes a diachronous stratigraphic unit deposited during early Cambrian to late Silurian times, rather than a Precambrian basement as previously thought. The youngest detrital zircon age data from siliciclastic samples immediately above the angular unconformity constrain their deposition to ca. 407–397 Ma. In conjunction with a ca. 406 Ma rhyolitic tuff in the lower terrestrial siliciclastic unit and an early Carboniferous paleontological age of carbonates in the upper shallow-marine unit, it is suggested that the overlying unmetamorphosed sequences were accumulated during the early Devonian to the early Carboniferous. Thus, the angular unconformity in the Baluntai domain was formed between ca. 409 and 407 Ma. New and already published geochemical data reveal that the early Paleozoic (ca. 530–410 Ma) and late Paleozoic (ca. 410–320 Ma) igneous rocks are mainly medium- to high-K calc-alkaline I-type granitoids, which exhibit typical subduction-related geochemical signatures despite contrasting structural features. These geochronological and geochemical results are in accordance with those of similar early Devonian angular unconformities and Paleozoic igneous rocks in the southern Yili Block. The early Paleozoic igneous rocks display highly scattered zircon εHf(t) values, while the late Paleozoic rocks show a progressively increasing trend toward more positive values, attributed to slab rollback of the northward subducting South Tianshan Ocean under the Yili and Central Tianshan blocks. Thus, we propose that the formation of the angular unconformity was caused by tectonic conversion from contraction to extension due to slab rollback during the early Devonian. This study highlights the significance of geological and geochronological investigations of angular unconformities in the context of associated episodic magmatism and slab behavior in order to unravel distinct tectonic processes in the long-lived accretionary evolution of the Chinese Western Tianshan.

Constraining the links between the Himalayan belt and the Central Myanmar Basins during the Cenozoic: An integrated multi-proxy detrital geochronology and trace-element geochemistry study

Geological and tectonic analysis of the Eastern Himalayan basins has given rise to a decade-long debate on the geodynamic evolution of the Burmese terrane and on the extent of reorganization of the main SE Asia drainage systems. However, the influence of the Himalayan belt on the Central Myanmar Basin (CMB) system remains poorly documented, although it is key to providing more accurate models for the evolution of the Himalayan-Burmese orogen. In this contribution, we present geochronological, isotopic and geochemical analysis from 2500 zircon, 1700 titanite, 700 rutile and 850 apatite detrital grains from fifteen Cenozoic siliciclastic samples and one Cretaceous igneous rock. The samples were collected within the fore- and back-arc basins of the Central Myanmar Basin domain (CMB) to constrain the provenance, maximum depositional ages, and depositional environments of the west Burma terrane. Nine key lithological units, the Sadwingyi, Ketpanda, Wabo Chaung, Gwegon, Minwun, Padaung, Okmintaung and Irrawaddy formations have detrital age spectra spanning from the Miocene to Paleoarchean. The entire data set has common age peaks at ca. 20, 40, 60, 90, 100 ​Ma, with about 80% of the U–Pb ages younger than ca. 140 Ma and only ca. 1% of the grains predating ca. 3.0 ​Ga.Our results shed light on the current ambiguities on the transport pathways of Himalayan detritus in the CMB. They show that the fore-arc basin was open to the trench and fed by the unroofing of both the Wuntho Popa volcanic arc to the east and possibly from the Burmese basement and/or from Himalayan-derived Bengal Fan detritus to the west during the Eocene, from at least ca. 44 Ma to before ca. 39 Ma. We show that the west Burma Terrane was partitioned into pull-apart basins such as the Minwun Basin, which during the Oligocene recorded the first evidence of a new source contribution into the CMB at ca. 27 Ma. This new source is characterized by detritus highly compatible with the SE Asia basement rocks, which we suggest corresponds to the initiation of the palaeo–Irrawaddy River. This geodynamic evolution does not require any Yarlung Tsangpo-Irrawaddy-Brahmaputra paleodrainage reorganization, since from the Oligocene to the Early Miocene, the Irrawaddy River fed an internally drained basin, and from the Late Miocene onwards, the Yarlung drained into the Brahmaputra in the Bengal Basin.

Grain assemblages and diagenesis in organic-rich mudrocks, Upper Pennsylvanian Cline shale (Wolfcamp D), Midland Basin, Texas

Grain assemblages in the organic-rich Cline shale in the Midland Basin are dominated by components of extrabasinal derivation (11.4 to 98.5 vol. %; average volume: 82.6%). Major extrabasinal components include K-rich clay minerals, detrital quartz, albite, K-feldspar, micas, and lithic fragments. Intrabasinal components include mainly biosiliceous allochems (sponge spicules and radiolarians), agglutinated foraminifera, Ca-phosphate peloids, clay-rich peloids, organomineralic aggregates, intraclasts, and other biocalcareous allochems. Authigenic minerals are most evident as grain replacements, euhedral ankerite, Ca-phosphate cement, and precipitates in large pores. A strongly localized spatial distribution of diagenetic products at micron to centimeter scales is observed in most siliciclastic samples, except in biosiliceous allochem-rich ones in which abundant intergranular pore-filling clay-size microquartz cement is observed. Compaction is evident in the Cline shale because of low porosity and generally low cement volumes. Neither textural variation nor bulk mineral composition alone is sufficient to confidently decipher the rock bulk property (e.g., total organic carbon) and reservoir quality variation (e.g., porosity and permeability). However, a good negative relationship between the ratio of extrabasinal to intrabasinal grains and favorable reservoir properties is observed in the Cline shale. Specifically, higher porosity, permeability, and total organic carbon are observed in samples representing the extreme end members of intrabasinal-derived biosilica-rich layers. Nickel, a recognized proxy for paleoproductivity, exhibits a positive relationship with intrabasinal grain content and reservoir properties. X-ray fluorescence–based analysis of nickel can be a rapid and cost-effective way to delineate favorable unconventional reservoir quality in the Cline shale.

Geochemistry of the Paleoproterozoic Espanola Formation, Bruce Mines—Elliot Lake area, Ontario, Canada: implications for provenance, paleo-weathering, and tectonic setting

The Espanola Formation of the Paleoproterozoic Huronian Supergroup is a mixed carbonate-siliciclastic succession that is well exposed in the Bruce Mines-Elliot Lake Area, Ontario, Canada. The siliciclastic portion of the formation is mainly dominated by shale with subordinate content of wake and arkose. Elemental geochemical analysis of the rocks was conducted in order to decipher their provenance, paleo-weathering conditions, and plate tectonic setting. The analyzed Espanola Formation samples display steep REE distribution patterns with high LaN/YbN ratios ranging from 3.68 to 20.83 (average LaN/YbN = 16.4), and are characterized by consistently negative Eu anomalies (average Eu/Eu* = 0.69). Furthermore, on the La-Th-Sc ternary model, the samples cluster around the average granodiorite and tonalite-trondhjemite-granodiorite (TTG) compositions with a clear linear trend toward felsic sources. A similar distribution and trend are also displayed on the Co/Th and La/Sc ratio plot. Such geochemical characteristics indicate derivation from an exposed upper continental crust of granodioritic and TTG compositions, namely the Archean Superior Province to the north, with minor contributions from mafic volcanic and/or sedimentary rocks, as further demonstrated by provenance discriminant models (La-Th-Sc and Co/Th-La/Sc). The source rocks were subjected to relatively low to moderate chemical weathering as reflected by their generally low chemical index of alteration values (average CIA = 62.90). Tectonic discriminant models (K2O/ Na2O-SiO2 and SiO2/Al2O3-K2O/Na2O) indicate significant contributions of siliciclastic sediments from sources within a stable passive continental margin, with minor contributions from an active continental margin and continental island arcs. The Zr/Sc-Th/Sc model further confirms that the composition of the analyzed Espanola Formation siliciclastic samples was mainly controlled by tectonic setting and provenance with minimal influence of sediment recycling.

The Ribeirão da Folha ophiolite-bearing accretionary wedge (Araçuaí orogen, SE Brazil): New data for Cryogenian plagiogranite and metasedimentary rocks

The Araçuaí orogen and West Congo belt make up a singular confined orogenic system, embraced by the San Francisco – Congo craton: the AWCO. It includes a southern sector with ophiolite bodies and magmatic arc, and a northern sector free of them, suggesting the precursor basin was an embayment partially floored by oceanic crust. The northernmost ophiolitic rock-assemblage found in the Araçuaí orogen comprises metamafic and meta-ultramafic rocks with signatures of ocean-floor magmas, and associated pelagic to oceanic metasedimentary rocks of the Ribeirão da Folha Formation. Although tectonically dismembered and metamorphosed, those rocks resemble the classical ophiolite pseudostratigraphy. The Ribeirão da Folha Formation comprises rocks expected to be found in the upper units of an ophiolite edifice, like Al-rich micaschist (pelagic pelite), graphite-rich schist (black shale), sulfide-bearing metachert, diopsidite with massive sulfide, and banded iron formations (chemical-exhalative sediments), and sulfide-bearing fine-grained ortho-amphibolite with thin metachert intercalations (mafic volcanic unit). That formation hosts tectonic slices of banded ortho-amphibolite (dolerite) with plagiogranite veins, and coarse-grained massive ortho-amphibolite (gabbro), representing dismembered slivers from deeper mafic units, and slices of meta-ultramafic rocks from the deepest ophiolite units. Zircon crystals from a plagiogranite vein yielded the U-Pb SHRIMP age of 645 ± 10 Ma, providing a new time constraint for ocean-floor emplacement. Micaschist samples show chemical attributes typical of distal passive margin pelites. Among three progressive deformation phases, the main ductile phase (Dn) shows kinematic indicators related to top to SW mass transport, associated with intermediate P-T (St, Ky, Sil) metamorphic zoning. Although the few youngest grains of detrital zircon from three siliciclastic samples have distinct ages (around 599 Ma, 741 Ma, and 816 Ma), their wide-range age spectra and Hf signatures suggest similar sediment sources. The wide lithological variety and stratigraphic complexity along with the intricate tectonic framework of the Ribeirão da Folha region, comprising thrust slices of ophiolitic rocks tectonically interleaved with older rift-related rocks, characterize an accretionary wedge that was scrapped off the subducted slab and involved in collisional tectonics, marking the AWCO suture zone for some 250 km between the Guanhães basement block (lower plate) and Rio Doce magmatic arc (upper plate).

Effect of CO2–brine–rock interaction on fracture mechanical properties of CO2 reservoirs and seals

The effect of CO2–water–rock interactions on fracture mechanical properties of reservoir and seal rocks due to injection of CO2 in the subsurface may impact long-term (102–104 yr) storage security. At the Crystal Geyser and Salt Wash field sites near Green River, Utah, sandstone of the Salt Wash Member of the Morrison Formation and Mancos Shale have undergone chemical alteration associated with flow of CO2-bearing water under natural conditions over geologic time scales of 103–105 yrs. To quantify the effects of these diagenetic changes on rock fracture mechanical properties we conducted opening-mode fracture mechanics tests using the double torsion method on a suite of CO2-altered and unaltered siliciclastic samples. We show that dissolution of hematite and carbonate cement in Entrada Sandstone by CO2-rich brine lowers fracture toughness by nearly 40% relative to adjacent, unaltered samples from the same unit. In contrast, precipitation of calcite pore cement in a sandstone of the Salt Wash Member of the Morrison Formation, attributed to CO2 degassing during upward fluid flow along the Little Grand Wash Fault, results in a 100–700% increase in fracture toughness. Similarly, precipitation of carbonate mineral cements and replacement of matrix measurably strengthens Mancos Shale, considered a regional top seal. Subcritical fracture growth index (SCI) which quantifies reaction-assisted subcritical fracture propagation is also affected by CO2-related alteration. Based on previous numerical simulations of fracture network growth with varying fracture mechanical parameters, we find that the measured variations in fracture mechanical properties qualitatively match observed differences in opening-mode fracture distributions along the fault, with short, non-connected fractures in CO2-bleached rock, long, throughgoing fractures in calcite-cemented shale, and short, closely spaced, interconnected fracture networks in highly altered rock directly adjacent to fault conduits. Our fracture mechanics tests demonstrate that fracture mechanical properties of reservoir and seal rock can change as a result of chemical CO2–brine–rock interaction. These chemical interactions may favor or inhibit subcritical fracture growth processes and thus reservoir and seal flow properties. In regions of CO2-related mineral dissolution, subcritical fracture growth may reduce seal integrity over time scales beyond those of active injection and reservoir monitoring, thus negatively affecting seal integrity over the expected design lifetime of a CO2 reservoir.

Detrital provenance evolution of the Ediacaran–Silurian Nanhua foreland basin, South China

We report here in-situ U–Pb and Hf isotopic results of detrital zircons from sixteen Cambrian–Silurian siliciclastic samples across the Nanhua foreland basin, South China. Together with published data from Ediacaran–Silurian sandstones in the region, we establish the temporal and spatial provenance evolution across the basin. Except for samples from northeast Yangtze, all other Ediacaran–Silurian samples exhibit a prominent population of 1100–900Ma, moderate populations of 850–700Ma and 650–490Ma, and minor populations of 2500Ma and 2000–1300Ma, grossly matching that of crystalline and sedimentary rocks in northern India. Zircon Hf isotopes further reveal four episodes of juvenile crustal growth at 2.5Ga, 1.8Ga, 1.4Ga and 1.0Ga in the source regions. Utilizing the basin history and late Neoproterozoic to early Paleozoic paleogeography of South China, we conclude that the Ediacaran–Cambrian sediments in the Nanhua foreland basin were mainly sourced from northern India and adjacent orogens, and the Ordovician–Silurian sediments were derived from both locally recycled Ediacaran–Cambrian rocks and eroded Cathaysian basement. The Wuyi–Yunkai late-orogenic magmatic rocks also contributed to the Silurian sediments in the basin. The upper-Ordovician to Silurian samples in northeast Yangtze received higher proportions of local Cryogenian (850–700Ma) magmatic rocks which were uplifted during late-Ordovician to Silurian time. We speculate that there was an Ediacaran–Cambrian collisional orogen between South China and northern India, shedding sediments to the early Nanhua foreland basin. Far-field stress during the late stage of this collisional orogeny triggered the Ordovician–Silurian intraplate Wuyi–Yunkai orogeny in South China, and erosion of the local Wuyi–Yunkai orogen further provided detritus to the late Nanhua foreland basin.

U–Pb detrital zircon analysis of the lower allochthon of NW Iberia: age constraints, provenance and links with the Variscan mobile belt and Gondwanan cratons

Detrital U–Pb laser ablation inductively coupled plasma mass spectrometry zircon ages from six siliciclastic samples from the lower allochthon of NW Iberia are analysed to constrain their maximum sedimentation age and provenance, and to evaluate the connections to the adjacent tectonostratigraphic domains. Deposited in the external sections of the Gondwana platform, their maximum depositional age is latest Neoproterozoic ( c . 560 Ma). Comparison of the age populations of the lower allochthon with those of the rest of the allochthonous and autochthonous units of NW Iberia suggests that the terranes located in the footwall of the Variscan suture should not be considered as exotic elements, but as contiguous pieces of the same continental margin transported onto the adjacent Gondwana mainland in Variscan times. The data are in agreement with the regional trend defined by the drop in Early Neoproterozoic and Mesoproterozoic zircon content upward in the tectonic pile, which had been previously proposed as a marker of proximity to the eastern part of the West African Craton. Based on the age spectra, the palaeoposition for the time of sedimentation is placed in northern Africa, between the West African and Saharan cratons. Particular attention is paid to the occurrence of an Early Neoproterozoic input, probably derived from the Pan-African Hoggar suture. Supplementary materials: Isotope ratios and ages for the selected analyses are available at www.geolsoc.org.uk/SUP18548 .

U–Pb ages of detrital zircons from the Basal allochthonous units of NW Iberia: Provenance and paleoposition on the northern margin of Gondwana during the Neoproterozoic and Paleozoic

LA-ICP-MS U–Pb ages of detrital zircons from eight siliciclastic samples from the Basal units of the Variscan allochthonous complexes of NW Iberia are used to establish the maximum depositional age and provenance of two tectonically-stacked metasedimentary sequences deposited on the outermost margin of Gondwana, and subsequently involved in the Rheic Ocean suture. The maximum depositional ages for the two sequences is latest Neoproterozoic and latest Cambrian, respectively. The age spectra are also used to discuss the paleoposition of the NW Iberian basement on the continental margin of Gondwana prior to the opening of the Rheic Ocean, which is tentatively placed in northern Africa, between the West African and Saharan cratons. Based on similarities and differences with age data from the NW Iberian autochthon and other allochthonous terranes involved in the Rheic suture, the relative proportions of Mesoproterozoic zircons in both assemblages are proposed as markers of proximity to the eastern part of the West African craton during late Neoproterozoic and late Cambrian. The geodynamic processes that took place along this part of Gondwana during the late Neoproterozoic, late Cambrian and Early Ordovician are discussed in the light of the LA-ICP-MS results, as well as the sedimentological record, magmatic evolution and plate tectonic setting of NW Iberia. These processes are linked to late Neoproterozoic and Cambro-Ordovician subduction events beneath the northern Gondwanan margin.

The palynology of the Cerrejón formation (Upper Paleocene) of northern Colombia

A palynological study of the Cerrejon Formation was conducted in order to date the formation and understand the floristic composition and diversity of a Paleocene tropical site. The Cerrejon Formation outcrops in the Cerrejon Coal Mine, the largest open cast coal mine in the world. Two cores (725 m) were provided by Carbones del Cerrejon LLC for study. Two hundred samples were prepared for palynology, and at least 150 palynomorphs were counted per sample where possible. Several statistical techniques including rarefaction, species accumulation curves, detrended correspondence analysis, and Anosim were used to analyze the floristic composition and diversity of the palynofloras. Palynomorph assemblages indicate that the age of the Cerrejon Formation and the overlying Tabaco Formation is Middle to Late Paleocene (ca. 60–58 Ma). Major structural repetitions were not found in the Cerrejon Formation in the Cerrejon coal mine, and there is little floral variation throughout. The floral composition, diversity, and lithofacies do not change significantly. Lithofacies associations and floral composition indicate deposition fluctuating from an estuarine‐influenced coastal plain at the base to a fluvial‐influenced coastal plain at the top. There are, however, significant differences in the composition and diversity of coal and siliciclastic samples. Coal palynofloras have fewer morphospecies, and a distinct and more homogeneous floral assemblage compared to assemblages from the intervening sisliciclastic strata, suggesting that tropical swampy environments supported fewer plant species and had a distinct vegetation adapted to permanently wet environments.

Provenance of the Earaheedy Basin: implications for assembly of the Western Australian Craton

Abstract The Palaeoproterozoic Earaheedy Basin in Western Australia lies at the southern end of the Capricorn Orogen. The Earaheedy Group, the sole lithostratigraphic unit comprising the basin fill, is a 5 km thick succession of shallow-marine siliciclastic and carbonate sedimentary rocks. It consists from oldest to youngest of the Yelma, Frere, Windidda, Chiall, Wongawol, Kulele and Mulgarra formations. U–Pb age data for 312 detrital zircon grains from seven siliciclastic samples from the Yelma Formation, the Wandiwarra and Princess Ranges members of the Chiall Formation and the Mulgarra Sandstone reveal the presence of both Archaean (3.4–2.5 Ga) and Palaeoproterozoic (2.4–1.8 Ga) detritus. Zircon grains of Archaean age are dominantly in the range 2.7–2.6 Ga, similar to those of the Yilgarn Craton, which unconformably underlies the southern margin of the Earaheedy Basin. Age peaks in the range 2.3–2.2, 2.0 and 1.8 Ga, characterise the Palaeoproterozoic detritus. The two younger ages overlap with those of the adjoining Gascoyne Complex of the Capricorn Orogen to the west of the basin. Source components with ages in the range 2.3–2.2 Ga are extremely rare in Western Australia. Undeformed granite in the Mullingarra Complex within the Pinjarra Orogen to the west of the Darling Fault yielded an age of around 2.2 Ga. In addition, rare rims on detrital zircon grains from gneisses within basement of the Glenburgh Terrane of the Gascoyne Complex as well as a few detrital grains in metamorphosed quartz arenites of the terrane have yielded ages of around 2.4–2.2 Ga, suggesting early Palaeoproterozoic activity in this region. Detrital grains as young as 1800 Ma, combined with deposition of the unconformably underlying strata in the Yerrida Basin at c. 1840 Ma and deformation of the Earaheedy Group at around 1750 Ma, provide a relatively tight constraint on the depositional age of the Earaheedy Group.

Organic-walled microfossils from the Proterozoic Thule Supergroup, Northwest Greenland

The Proterozoic rocks of the intracratonic Thule Basin on the northern margin of the Canadian–Greenlandic shield have recently been referred to as the Thule Supergroup. The succession comprises unmetamorphosed, unfolded sedimentary and magmatic rocks, which are, with few exceptions, not deformed. Five groups have been defined and fine-grained siliciclastic samples from the uppermost three (Baffin Bay, Dundas and Narssârssuk groups), yielded moderately well-preserved acanthomorphic and non-acanthomorphic acritarchs, prasinophytes and filamentous microfossils. The age of the supergroup is quite poorly constrained, at the base by a 1268 Ma basaltic sill, and at the top by a basic dyke swarm with a K/Ar age range between 630 and 725 Ma, that cuts the entire succession. Biostratigraphical studies further constrain the age of the Thule Supergroup and suggest that the succession is of a late Mesoproterozoic/earliest Neoproterozoic age. This age assignment is corroborated by independent stable isotope data and correlation with the Bylot Supergroup to the south. This leads us to propose that the Thule Supergroup was deposited between c. 1300 and c. 1200 Ma. Microfossil taxa previously interpreted as exclusively occurring in pre-Varangerian, Neoproterozoic rocks (i.e. Simia annulare Jankauskas, Tasmanites rifejicus Jankauskas and possibly Vandalosphaeridium varangeri Vidal) are consequently re-evaluated. Process-bearing acritarchs, herein attributed under open nomenclature to ? Comasphaeridium sp., ` Trachyhystrichosphaera truncata' and ? Vandalosphaeridium sp., are of special palaeobiological importance since acanthomorphic acritarchs have rarely been reported from pre-Neoproterozoic successions.

Neoproterozoic microfossils from the Officer Basin, Western Australia

Microfossil assemblages are described from the early Neoproterozoic Madley and Browne Formations, western Officer Basin. One chert and eleven siliciclastic samples yielded microfossils. Myxococcoides cantabrigiensis occurs as pustular mats in the chert sample and Eomicrocystis malgica, Pterospermopsimorpha granulata, Skiagia sp. cf. S. pusilla, and undetermined species of Obruchevella, Heliconema, and Trachystrichosphaera are present in acid macerated samples. Leiosphaeridia spp. and Siphonophycus spp. are also found in fine-grained siliciclastic samples, with clusters of Synsphaeridium sp. in some samples. These findings enable a more substantial reconstruction of the palaeoenvironment of Supersequence 1 in the western Centralian Superbasin. The acanthomorph acritarchs are considered to be planktonic eucaryotes washed into environments which ranged from coastal sabkha through to tidal flats, which may be the source of the prokaryotic, benthic, matforming cyanobacteria.