Silicate Source Research Articles

Optimization of magnesium silica aerogel production and evaluation as a food additive: a comparative study of water glass and bio-based sodium silicate source as a precursor

Optimization of magnesium silica aerogel production and evaluation as a food additive: a comparative study of water glass and bio-based sodium silicate source as a precursor

Effects of the Sedimentary Environment on Organic-Rich Shale in the Intracratonic Sag of the Sichuan Basin, China

The enrichment of organic matter in high-quality marine shale is generally controlled by factors such as the redox conditions of sedimentary environments, productivity levels, terrigenous input, and ancient productivity. However, the controlling effect of the sedimentary environment on organic matter enrichment in intracratonic sag is still unclear. This study takes samples from the Qiongzhusi formation shale in southern Sichuan Basin as the research object, focusing on trace elements as well as rare earth elements in different stratigraphic intervals. The provenance of the Qiongzhusi formation shale is mainly terrigenous, with sediment sources mainly consisting of sedimentary rocks and granites. The primary sedimentary environment transitions from a continental margin setting, influenced by rift-related tectonic activity and sediment influx from adjacent landmasses, to an open oceanic environment characterized by mid-ocean ridge processes and oceanic plate subduction zones. During sedimentation, saline water was present, with predominant sedimentary environments ranging from shallow water to deep water continental shelves. The shale in the study area is characterized by a higher content of silicates and a lower content of carbonate minerals. Its siliceous sources are mainly influenced by biogenic and terrigenous debris, indicating higher ancient primary productivity and representing a favorable target for shale gas exploration.

Aerogel-based collection of ejecta material from asteroids from libration point orbits: Dynamics and capture design

Scientific interest in asteroids and their physical characteristics is growing. These bodies provide insights into the primordial solar system and represent a valuable source of metals, silicates, and water. Several missions over the past few years have aimed to improve and better identify the main properties of these poorly known celestial bodies. However, these missions relied on touchdown(s) on the target asteroid to gather samples, which is complicated owing to the difficulty of accurately reaching and rendezvousing with the body. This study aims to assess the feasibility of an in-orbit asteroid sample collection mission. Such a strategy could prevent complex operations related to landing and touchdown maneuvers and avoid the dead times present in a mission requiring several landings. The presented collection scenario, which focuses on the asteroid Ryugu, proposes gathering samples using a spacecraft injected into a halo orbit around the second libration point, L2. For this purpose, the orbits in the neck region of the zero velocity curves are analyzed. A novel methodology to characterize bouncing behavior is introduced. An interpolation-based approach was used to recover the appropriate restitution coefficients for each collision occurring at a specific impact angle. This was applied to both the rigid body model and the point mass approximation studied for two different sites on the asteroid. Furthermore, the study enlarged the region of interest from only L2 to its neighboring zones to return a more global and realistic point of view. Considering the solar radiation pressure and asteroid aspherical potential, particles of different sizes ejected from different longitudes and with different ejection angles were classified according to their trajectories to finally build a database. Based on this analysis, an aerogel-based collection strategy inspired by that used in the Stardust-NExT (NASA) mission was investigated to assess its possible applicability to the analyzed scenario.

Unveiling the potential of desert sand-derived mesoporous silica supported nickel-based catalysts for co-production of H2 and carbon nanomaterials via methane cracking

This study investigates the replacement of a costly commercial silicate source with locally abundant desert sand in the United Arab Emirates (UAE), for synthesizing mesoporous silica. Hydrothermal synthesis methods were employed to develop various mesoporous materials having different pore geometries, namely MCM41-S, SBA15-S and MCF-S, using desert sand as a silica source. These materials were then impregnated with 15 wt% NiO (∼13 wt% Ni) by sono-wet impregnation technique. All Ni-based silica supported catalyst demonstrated enhanced stability at 550 °C during the reaction. It was observed that the synthesized MCF-S proves to be a highly efficient catalyst support, as Ni/MCF-S, for the catalytic decomposition of methane (CDM), exhibiting the highest methane conversion (60 %), which is 1.4–2.1 times higher than the Ni-based classic-structured mesoporous siliceous supported catalysts, such as SBA15-S and MCM41-S. In particular, the H2 yield (62 %) of the Ni/MCF-S catalyst was 1.40 and 2.38 times higher than that of the Ni/SBA15-S and Ni/MCM41-S catalysts, respectively. To understand the observed differences, a detailed characterization of the physicochemical properties of these materials was conducted. The results revealed that the macro/mesopores size (4–60 nm) and bimodal sinusoidal pore geometry of MCF-S, played a critical role in enhancing Ni particle dispersion, resulting in the highest active Ni metal surface area (7.66 m2/gcat) and contributing to the improved catalytic activity of Ni catalysts in methane cracking.

Effects of Cs-137 radiation on hydrophobic silica monolithic prepared by two precursors

Cesium (Cs-137) radiation energy was shined on two aerogel samples made from two different starting materials at room temperature and pressure three times a day for one hour, two hours, and twenty-four hours. G1 and G2 were used as silicic acid sources to fabricate the two different types of aerogel samples. G1 represents tetraethyl orthosilicate (TEOS), while G2 represents sodium silicate (Na2SiO3). Field emission scanning electron microscopy analysis revealed the morphological characteristics of the molecular bonds and the impact of irradiation on them. Fourier-transform infrared spectroscopy investigated the molecular bonds and their characterization before and after exposure to radiation. The samples made from TEOS at room temperature and pressure were not affected by radiation in either the FTIR or FESEM tests. However, the samples made from Na2SiO3 at room temperature and pressure showed that some of the peaks were disappearing because they were exposed to radiation. Also, the peaks of the CH3 functional group are associated with the hydrophobicity of the material. The homogeneity and uniformity for all samples are dominant, and the size of the colloidal particles is about 30-33 nanometers (nanometer structure), which is no different from the size of the particles before and after exposure to gamma rays.

Provenance of the late Jurassic to Cenomanian sedimentary succession of the Araripe Basin (NE Brazil) and implication for the geodynamic evolution of Western Gondwana

The separation of Gondwana was controlled by preexisting Proterozoic structures and by the development of rift aborted basins, of which the Araripe Basin (NE Brazil) is one of the best examples. Previous studies have focused on the presence and provenance of Aptian–Albian shallow-marine incursions in the Araripe Basin but to date, little attention has been given to its paleodrainage evolution during sedimentation stages. Understanding the paleodrainage evolution is crucial for determining sediment sources and how topographic changes relate to the geodynamic development of the northern part of South America during the fragmentation of Gondwana, and this study investigates the provenance of Mesozoic rift and post-rift sedimentary rocks in the Araripe Basin using a multi-proxy dataset comprising major and trace element concentrations, Sm–Nd isotopic composition, and detrital zircon U–Pb ages. The low Eu/Eu* ratios (0.3–0.9) and high Th/Sc ratios (>0.64) in the most of analyzed samples suggest a felsic and silicic source. The εNd(0) values (−12.3 to −23.7) and TDM ages (1.68 to 2.55 Ga) of analyzed samples suggest overall ancient crustal sources. The presence of oval and elongated zircon grains suggests a major contribution of first-cycle transport sediments. The presence of 2.3–1.8 Ga and 0.63–0.58 Ga U–Pb zircon ages further indicates the dominant contribution of the Borborema Province influenced by the Brasiliano cycle (650–520 Ma). The low contribution of Tonian (∼940 Ma) zircons to the U–Pb zircon age distribution of the rift-beginning stage sample associated with published paleocurrent direction suggests sources located in the northern and northwestern terranes of the Borborema Province. The increase of Tonian (0.9–1.0 Ga) zircon grains during the rift stage suggests a provenance change with a dominant source in the eastern terranes during the rift stage. During the post-rift I stage, the decrease of 1.2–0.72 Ga zircon ages suggests a change in the source areas, with the paleodrainage coming from northern Borborema Province, similar to that of the rift-beginning stage. The samples of the post-rift II stage exhibit dominant contributions of Paleoproterozoic and Neoproterozoic U–Pb ages related to the Albian to Cenomanian uplift of the Borborema plateau during the opening of Equatorial Atlantic Ocean. Together with previous published studies, these findings highlight the significant role played by the post-rift continental uplift to the paleodrainage of the northern part of South America.

Novel treatment method of coal bottom ash for strain-hardening alkali-activated composite

This study explored the viability of using coal bottom ash (CBA), treated as a silicate source for preparing activators, as a filler in strain-hardening alkali-activated composites. The silica content provided by CBA was approximately 30% of that provided by silica fume, and its surface morphology exhibited a rough texture after treatment. The incorporation of CBA led to an improved compressive strength, and the subsequent substitution of treated CBA up to 100% resulted in a 10% increase in the compressive strength. Furthermore, incorporating the treated CBA enhanced the bond strength and pullout energy by up to 70% and 75%, respectively, compared with those of plain composites. The treated CBA also improved the tensile performance, as the replacement rate increased. At a substitution rate of 100%, the tensile strength, strain capacity, and strain energy density increased by 168.64%, 118.3%, and 479.41%, respectively, compared with those of plain composites. Thus, utilizing CBA as an alkaline activator is a promising solution to environmental challenges in the field of construction materials.

Use of spent fluid catalytic cracking catalyst (FCC) in Limestone Calcined Clay Cement (LC3) systems: Studies in pastes and mortars

This study evaluates the substitution of calcined clay for a waste from the petrochemical industry, spent fluid catalytic cracking catalyst (FCC), as a source of reactive aluminosilicates in Limestone Calcined Clay Cements (LC3) systems. Three carbonate types were used to make cement-type LC3: a high-purity calcium carbonate, waste from the marble industry, and another from a dolomite soil source. LC3 blends were prepared by mixing 50 wt% OPC, 5 wt% calcium sulfate dihydrate, 30 wt% FCC and 15 wt% from each carbonate source. A mixture than substituting the carbonate source for a siliceous source was prepared to analyse the influence of carbonate phases in LC3 systems. The hydration process of the LC3 blends was studied by X-ray diffraction, thermogravimetric analyses, isothermal calorimetry and FESEM. Mechanical properties were studied by measuring compressive strength at 7, 28 and 90 days. The obtained results corroborated that the mortars prepared with LC3 cements using the FCC obtained higher compressive strength than the control mortar prepared with ordinary Portland cement (OPC) at 28 and 90 curing days. It has been demonstrated that FCC is a by-product that can substitute calcined clay, and the different sources of carbonates such as high purity, waste or contaminated with magnesium do not interfere with the performance of this type of cement.

Synthesis of millimetre-scale HZSM-5 single crystals by secondary hydrothermal treatment

Millimetre-scale HZSM-5 single crystals were successfully synthesized by a two-step hydrothermal method. In the first step, millimetre-sized silicalite-1 single crystals were prepared by hydrothermal synthesis using quartz tube as siliceous source. In the second step, framework Al atoms were inserted into the single crystals of silicalite-1 by another hydrothermal treatment involving NaAlO2 as aluminium source. Through the characterizations of power and single crystal X-ray diffraction, optical microscope, ICP, 27Al MAS NMR, 29Si MAS NMR, and n-propylamine temperature-programmed decomposition (NPA-TPD), it was confirmed framework Al atoms with uniform spatial distribution can be inserted into giant single crystals of silicalite-1 with no obvious effects on the crystal structure, size and morphology. Such giant HZSM-5 single crystals are a promise candidate for the probe adsorption investigations, which can be applied in the measurement of framework Al spatial distribution. The strategy of insertion of aluminium or other heteroatoms of pure siliceous zeolite through secondary hydrothermal method provides a possible route to prepare giant single crystals that is difficult to synthesize directly.

Optimization of local modified metakaolin-based geopolymer concrete by Taguchi method

Abstract Geopolymer in recent concrete (GP) has gained significant attention due to its sustainability and environmental friendliness. Local metakaolin-based geopolymer is weaker than geopolymers made from other materials due to its low Si/Al ratio. A consistent mixture design is also lacking because geopolymers are affected by many variables. This study presents a method to find the optimal geopolymer mixture based on locally modified metakaolin as a source of aluminates and silicates using the Taguchi method. Metakaolin was modified using different contents of materials rich in silica, such as silica fume (SF), or materials rich in calcium, such as calcium oxide (CaO) of 5, 10, and 15%. The inclusion of 5% SF, 10% CaO, and a combination of 5% SF and 5% CaO as substitutes for metakaolin increases the compressive strength by 16.8, 6.9, and 22.8%, respectively, compared to the reference mixture without any modifications. In other words, adding 5% SF and CaO increased the molar ratio of SiO2/Al2O3 (R) from 1.782 to 1.914, resulting in the highest compressive strength of 53.3 MPa after 7 days of sun curing. To obtain the optimal mixture that achieves the highest compressive strength, the impact of three main variables, including the concentration of sodium hydroxide (SH), alkali solution-to-binder (Al/B) ratio, and sodium silicate-to-sodium hydroxide (SS/SH) ratio, must be considered using Taguchi method. A total of nine mixtures were investigated. It was found that 13 M of SH, 0.65 Al/B, and 2.5 SS/SH give a high compressive strength of 58.6 MPa at 7 days. Also, it was found that the concentration of SH plays a more important role in increasing the compressive strength than the alkali-to-binder ratio and SS/SH ratio. The scanning electron microscopy images show that the 5% weight replacement of metakaolin by silica and CaO could source fewer and smaller pores and reduce the microcracks’ width.

Experimental Behaviour of Hybrid Fiber-Reinforced Low Calcium Ferro Geopolymer Paver Block

The environment friendly and creative material in the construction field is the Geopolymer concrete. The two main constituents of Geopolymer are the source material and the alkaline liquids. In previous studies, alternate for alumino silicate source material as wood ash in geopolymer concrete was found and optimized with fly ash. Moreover, from the previous literatures it could be noted that, GPC had a less brittleness and energy absorbent. To improve the brittleness and energy absorption capacity polypropylene fibre and rubber fibre were added by 0, 0.25, 0.5, 0.75, and 1 % of volume fraction at different ratios. Further, effects on addition of polypropylene and rubber fibres of the optimized wood ash-fly ash based low calcium geopolymer were studied. In the previous study, hybridization of fibres was found out. On other hand, concrete paver block has major disadvantages of less skid resistance, less strength, less energy absorbent, less slip resistance. Hence, the research on finding an alternative to the cement paver block is needed. Ferro-cement was a wonderful technology in the construction industry which have tendency to give more strength to the structure. In this study, the low calcium ferro-geopolymer paver block for an alternate of cement paver block was proposed. Meanwhile, the ferrogeopolymer technology was used by varying the different type of meshes and different layout patterns of meshes. The optimized ferro-geopolymer paver block is going to be produced by varying the shape and size of paver block, surface texture of the paver block. The compressive behaviour, split tensile behaviour, and flexural behaviour is going to be studied for the optimization of low calcium ferro-geopolymer paver block. Micro-structural characterization is also going to be studied for the detailed understanding of inside reaction of low calcium ferro-geopolymer paver block by SEM and EDX.

Mineral chemistry in apatite from heavy mineral concentrate samples as a prospecting tool for carbonatites in the Angico dos Dias region, BA/PI border, Brazil

Apatite is one of the most common minerals found in a wide variety of rocks. It has variations of minor and trace elements in its composition that allow the recognition of its host lithotype. In this study, apatite grains identified in rock samples and grains recovered from heavy mineral concentrates in the Angico dos Dias Carbonatite Complex region, located on the border between the State of Bahia and the south of the State of Piauí, Brazil, were analyzed using an electron probe microanalyzer. These concentrates come from alluvial sediments downstream of the carbonatitic body from drainage channels. Sampling was guided by regional geochemical analytical results for the chemical elements of apatite. Grains were detected in alluvial covers for up to 9.5 km downstream in all fraction including coarse sand (1.0 mm) in proximal samples and up to medium sand fractions (0.50 mm) in distal samples. The 96 analytical results on 48 apatite grains show that most have chemical signatures characteristic of metacarbonatitic lithotypes (SrO 0.88–1.7 wt%) and that some host lithotypes were affected by the substituition processes (Si + LREE (Ce+La+Nd) 0.15–0.59 apfu), which may be an alternative to metasomatic fenitization. Statistical analysis by principal component analysis (PCA) helped the visualization and interpretation of the data by constructing clusters of the different compositions of apatite. The apatite fields of carbonatitic and silicate source rocks were separated and associated with the results obtained for alluvial apatite grains, resulting in carbonatitic derivation. The results of using this prospecting tool were satisfactory. Thus, it was possible to classify and detect the sources of alluvial apatite grains relating them to the Angico dos Dias carbonatite body, in addition to proposing a new potential area for the occurrence of carbonatitic bodies northeast of the Angico dos Dias phosphate deposit.

Silicified unicellular green microalga as a significant oil source in the Late Paleozoic alkaline lake-playa deposit, Junggar Basin, NW China

Siliceous mudstones and chert-shale couplets are primary source rocks for many large paleo-oil reservoirs over the world. It is well established that photosynthetic organisms can be exceptionally well preserved in silica precipitates, but the fate of the trapped organic matter (OM) during burial remains poorly studied. Here, dense unicellular microbial fossils have been recently discovered in the cherts of the Late Paleozoic alkaline saline lake deposit in NW Junggar Basin, NW China. We use petrographic observations and organic geochemical analysis to study the origin of unicellular microbes and how silicified organic matter generate and expel hydrocarbons. A 300-m-long oil shale core shows overall low levels of porosity, permeability and total organic carbon contents (generally <0.5 wt%), but very high extracts (on average 0.26 wt%), suggesting that the rich extracts were mostly indigenous and the original organic matter had a high hydrocarbon conversion. Analysis of biomarkers and silicified fossils both suggest that the bio-precursor for the organic matter is a special green alga. Reconstruction of silica diagenesis of cherts indicates that both the trapped lipids and hydrocarbons in silicified microbial cells and extracellular polymeric substances had been effectively expelled out during the transformations of Opal-A to microcrystalline quartz and during OM thermal maturation. Exceptional OM preservation and effective oil expelling ways render siliceous source rocks as excellent unconventional hydrocarbon reservoirs.

Tidal variation modulates the dissolved silicate behavior and exchange flux across the semi-enclosed bay‐coastal water continuum, China

Coastal water is the key transition zone for the circulation and transport of nutrients. Their role in transporting nutrients is important to understanding global dissolved silicate (DSi) cycles and sources of nutrients supporting the biological pump and ocean carbon cycle. However, the understanding of controlling DSi exchange flux between the semi-enclosed bay and coastal water was still scarcely due to limitations in continuous observation. In this study, we conducted continuous investigations during spring tide (ST) and neap tide (NT) in 2021 in Shuidong Bay (SDB), China, to explore the impacts of different tidal cycles on DSi in SDB and the fluxes across SDB and South China Sea (SCS) coastal water. The findings demonstrated that there were significant differences in DSi concentrations and nutrients ratios between ST and NT in S1 station (P &amp;lt; 0.05). In addition, the DSi concentrations were 32.01 ± 27.21 μmol/L and 51.48 ± 48.44 μmol/L in ST and NT, respectively. Besides, the net export of DSi from SDB to SCS was 0.18 t throughout the entire early of autumn tidal cycle, suggesting SDB was the source of DSi, and its behavior across the semi-enclosed bay‐coastal water continuum was largely controlled by tidal characteristics (tidal height, flow velocity), water physicochemical parameters (salinity, pH), biological uptake and terrestrial sources input. SDB in ST has higher proportions of DSi: DIN (dissolved inorganic nitrogen) (1.49 ± 1.28) and DSi: DIP (dissolved inorganic phosphorus) (58.6 ± 43.73) compared with NT, DSi: DIN and DSi: DIP for the NT period were 1.45 ± 1.15 and 43.99 ± 28.59, indicating that phosphorus (P) is the limiting trophic factor for SDB. The tidal cycle in SDB would alter the DSi stoichiometry and mitigated the impact of eutrophication caused by terrestrial sources. This study provides new insights in the Si tidal cycling across the semi-enclosed bay‐coastal water continuum, which was implications for understanding DSi biogeochemical process and primary production dynamics in coastal water.

Mg and Sr Isotopes in Cap Dolostone: Implications for Oceanic Mixing after a Neoproterozoic Snowball Earth Event

The snowball Earth (SBE) describes a state of the Earth’s climate with global or near-global ice cover. The cap dolostone at the base of the Ediacaran successions serves as useful archives for studying environmental change during the Marinoan Snowball Earth deglaciation in Neoproterozoic. The characteristic compositions in dolomite provide critical information on continental weathering and coastal water mixing after glacial retreat. However, valid methods for pristine dolomite separation remain challenging. In this study, four selected cap dolostone samples from the base of the Ediacaran Lantian Formation were used for establishing a new 3-step leaching method, to remove the secondary calcite and other impurities before determination of δ26Mg and 87Sr/86Sr in dolomite. Non-destructive Raman, X-ray diffractometer (XRD) and scanning electron microscopy (SEM) were used to examine the distribution of dolomite and minor calcite/silicate in each sample. Micro-drill powders before each extraction procedure were examined in weight loss and mineralogical compositions, as well as the chemicals in the leaching solutions. Potential diagenetic artifacts were evaluated using Sr/Ca, Mn/Sr, 87Sr/86Sr and δ26Mg in solutions. By applying a simple two-end member mixing between the seawater and the silicate sources (R2 = 0.48, n = 23), the down-core variations of δ26Mg and 87Sr/86Sr in cap dolostone can be used to gain a better understand of the temporal weathering intensity changes, as well as the coastal oceanic mixing processes, after the Marinoan deglaciation.

Silicate solubilizing and plant growth promoting bacteria interact with biogenic silica to impart heat stress tolerance in rice by modulating physiology and gene expression.

Heat stress caused due to increasing warming climate has become a severe threat to global food production including rice. Silicon plays a major role in improving growth and productivity of rice by aiding in alleviating heat stress in rice. Soil silicon is only sparingly available to the crops can be made available by silicate solubilizing and plant-growth-promoting bacteria that possess the capacity to solubilize insoluble silicates can increase the availability of soluble silicates in the soil. In addition, plant growth promoting bacteria are known to enhance the tolerance to abiotic stresses of plants, by affecting the biochemical and physiological characteristics of plants. The present study is intended to understand the role of beneficial bacteria viz. Rhizobium sp. IIRR N1 a silicate solublizer and Gluconacetobacter diazotrophicus, a plant growth promoting bacteria and their interaction with insoluble silicate sources on morpho-physiological and molecular attributes of rice (Oryza sativa L.) seedlings after exposure to heat stress in a controlled hydroponic system. Joint inoculation of silicates and both the bacteria increased silicon content in rice tissue, root and shoot biomass, significantly increased the antioxidant enzyme activities (viz. superoxidase dismutase, catalase and ascorbate peroxidase) compared to other treatments with sole application of either silicon or bacteria. The physiological traits (viz. chlorophyll content, relative water content) were also found to be significantly enhanced in presence of silicates and both the bacteria after exposure to heat stress conditions. Expression profiling of shoot and root tissues of rice seedlings revealed that seedlings grown in the presence of silicates and both the bacteria exhibited higher expression of heat shock proteins (HSPs viz., OsHsp90, OsHsp100 and 60 kDa chaperonin), hormone-related genes (OsIAA6) and silicon transporters (OsLsi1 and OsLsi2) as compared to seedlings treated with either silicates or with the bacteria alone. The results thus reveal the interactive effect of combined application of silicates along with bacteria Rhizobium sp. IIRR N1, G. diazotrophicus inoculation not only led to augmented silicon uptake by rice seedlings but also influenced the plant biomass and elicited higher expression of HSPs, hormone-related and silicon transporter genes leading to improved tolerance of seedling to heat stress.

Directing Highly a-Axis-Oriented ZSM-5 Nanosheets with Pre-estimated Bifunctional Imidazole Cations.

An MFI-topology nanosheet zeolite with a highly a-axis-oriented structure has rarely been reported but with a great potential for industrial applications. Theoretical calculations on the interaction energies between the MFI skeleton and ionic liquid molecules indicated the possibility of preferential crystal growth along a specific direction, according to which highly a-oriented ZSM-5 nanosheets were synthesized from commercially available 1-(2-hydroxyethyl)-3-methylimidazolium and layered silicate sources. The imidazolium molecules directed the structure formation and meanwhile acted as zeolite growth modifiers to restrict the crystal growth perpendicular to the MFI bc plane, which induced unique a-axis-orientated thin sheets with ∼12 nm thickness. The a-oriented ZSM-5 exhibited more competitive propylene selectivity and longer lifetime than bulky crystals in methanol-to-propylene (MTP) reaction. This research would provide a versatile protocol for the rational design and synthesis of shape-selective zeolite catalysts with promising applications.

Assessment of Two Calcium Silicate Sources on Cucumber Under Water Restriction

Silicon (Si) is beneficial for plants that are under unfavorable conditions. In this study conducted under greenhouse conditions at Chapingo Autonomous University, Si fertilization was tested to examine whether it affected yields, biometrics, physiological parameters, and nutritional attributes of cucumber plants cultivated at different moisture levels in the substrate. Fifteen treatments were tried in a completely randomized design, including three moisture levels (50-60%, 75-85%, and 90-100% of container capacity (CC) and five Si doses (0, 50, 100 mg L-1 SiO2, 2 g L-1, and 3 g L-1 Wollastonite). Uniform irrigation was applied until the 18th day after transplantation, and controlled irrigation was applied according to the moisture levels until the end of the experiment. 3 g L-1 of wollastonite under 75-85% CC enhanced cucumber yield by 24.9% in comparison to untreated plants, while no Si dose affected fruit length, diameter, weight, and total soluble solids. At 90-100% of CC, 50 mg L-1 SiO2 increased the aerial biomass production (ABP) of the plants by 9.3%, and at 50-60% of CC, 100 mg L-1 SiO2 generated 11.8% more aerial biomass than untreated plants. As Si did not affect root production, mainly at 50-60% of CC, it improved chlorophyll a, b, and the total content of the leaves. Different parts of the plant saw significant increases in N, P, K, Ca, Mg, and Si concentrations because of Si&amp;rsquo;s interactions with moisture levels. When the substrate is low in moisture, Si is likely to improve cucumber yields, physiological, and nutritional characteristics of the plant.

Groundwater as a source of phosphorus and silicate in an estuarine zone: results from continuous monitoring of nutrients and 222Rn

The concentrations of 222Rn and dissolved inorganic nutrients in river water at a fixed station of the Nakdong River estuary which has an artificial barrage were continuously measured from October 2014 to May 2015. Monthly benthic 222Rn flux from the river bottom was estimated using a simple mass balance model, taking into account 222Rn sources and sinks. The estimated benthic 222Rn flux shows a significant correlation with groundwater level, suggesting that groundwater level can be used as a representative of the groundwater input. Based on correlation analyses, the concentration of dissolved inorganic nitrogen (DIN) was found to be dependent primarily on river water input. In contrast, the concentrations of dissolved inorganic phosphorus (DIP) and dissolved inorganic silicate (DSi) were predominantly controlled by groundwater input. Our results suggest that groundwater input may be an important source of DIP, especially under P-limited condition, which can affect marine primary production and ecological problems such as eutrophication and algal blooms in the coastal zones.

Rice husk as a potential source of silicate to oceanic phytoplankton

Global oceans are witnessing changes in the phytoplankton community composition due to various environmental stressors such as rising temperature, stratification, nutrient limitation, and ocean acidification. The Arabian Sea is undergoing changes in its phytoplankton community composition, especially during winter, with the diatoms being replaced by harmful algal blooms (HABs) of dinoflagellates. Recent studies have already highlighted dissolved silicate (DSi) limitation and change in Silicon (Si)/Nitrogen (N) ratios as the factors responsible for the observed changes in the phytoplankton community in the Arabian Sea. Our investigation also revealed Si/N < 1 in the northern Arabian Sea, indicating DSi limitation, especially during winter. Here, we demonstrate that rice husk with its phytoliths is an important source of bioavailable DSi for oceanic phytoplankton. Our experiment showed that a rice husk can release ∼12 μM of DSi in 15 days and can release DSi for ∼20 days. The DSi availability increased diatom abundance up to ∼9 times. The major benefitted diatom species from DSi enrichment were Nitzshia spp., Striatella spp., Navicula spp., Dactiliosolen spp., and Leptocylindrus spp. The increase in diatom abundance was accompanied by an increase in fucoxanthin and dimethyl sulphide (DMS), an anti-greenhouse gas. Thus, the rice husk with its buoyancy and slow DSi release has the potential to reduce HABs, and increase diatoms and fishery resources in addition to carbon dioxide (CO2) sequestration in DSi-limited oceanic regions such as the Arabian Sea. Rice husk if released at the formation site of the Subantarctic mode water in the Southern Ocean could supply DSi to the thermocline in the global oceans thereby increasing diatom blooms and consequently the biotic carbon sequestration potential of the entire ocean.