The article presents the results of a research frost resistance of silicate bricks one of the Russian factories produced in different periods. The change in appearance, weight and strength of silicate bricks during alternate freezing-thawing was evaluated. It has been established that silicate bricks, can meet high frost resistance grades F150-200, in terms of appearance, while the reduction in compressive strength does not exceed 9%. Some increase in brick strength at the initial stage of testing was noted, which is probably explained by the processes of carbonization of free calcium hydroxide and high-basic calcium hydrosilicates, accompanied by their recrystallization into low-basic ones, which is confirmed by the results of differential-thermal and X-ray phase analysis. It is concluded that the frost resistance of silicate bricks is decisively influenced by the mineralogical composition of the cementitious bond. High strength and frost resistance of silicate concrete is provided by the simultaneous presence of low-basic calcium hydrosilicates and α-C2S hydrate in the composition of the new formations. The condition for the formation of such composition of neoplasms is excessive content of lime in the composition of the raw material mixture.