Significant Water Quality Issue Research Articles

Application of Principal Component Analysis in Establishing the Dominant Pollutants in the New Calabar River.

The New Calabar River, an essential water source in Nigeria’s Niger Delta region, is facing significant water quality issues due to human activities. This research adopts a comprehensive strategy, integrating field data gathering, statistical analyses, and modeling methods to evaluate and simulate the impact of these activities on water quality. Analysis of Variance (ANOVA) outcomes revealed notable seasonal fluctuations in certain water quality parameters like Water Temperature (F=116.009, p<0.001) and pH levels (F=12.782, p<0.001), indicating clear distinctions between the specified months. Conversely, Total Dissolved Solids (TDS) and Electrical Conductivity (EC) showed insignificant variations (F=0.050, p=0.95 and F=0.036, p=0.96, respectively). Principal Component Analysis (PCA) identified crucial factors influencing water quality variations. The rotated component matrix displayed substantial loadings for parameters such as Turbidity (0.932), Dissolved Oxygen (0.919), and Biological Oxygen Demand (0.912), suggesting their significant impact on water quality dynamics. Employing GIS techniques for spatial mapping of WQI values uncovered pollution hotspots near Points 5 and 6, aligning with the PCA findings. These regions exhibited “Very Bad” water quality status, indicating severe pollution levels. Conversely, Point 3 demonstrated a “Medium” water quality status, implying better water quality conditions. Overall, the study highlights the intricate connection between human activities and water quality in the New Calabar River. The insights gained offer valuable guidance for informed decision-making in water resource management, pollution mitigation strategies, and policy development. Future research endeavors should prioritize continuous monitoring, adaptive management approaches, and community involvement to foster sustainable water quality management practices in the area.

Marine water quality of a densely populated Pacific atoll (Tarawa, Kiribati): Cumulative pressures and resulting impacts on ecosystem and human health

The resilience of coastal ecosystems and communities to poor environmental and health outcomes is threatened by cumulative anthropogenic pressures. In Kiribati, a developing Pacific Island country where human activities are closely connected with the ocean, both people and environment are particularly vulnerable to coastal pollution. We present a survey of environmental and human health water quality parameters around urban South Tarawa, and an overview of their impacts on the semi-enclosed atoll. Tarawa has significant water quality issues and decisions to guide improvements are hindered by a persistent lack of appropriate and sufficient observations. Our snapshot assessment identifies highest risk locations related to chronic focused and diffuse pollution inputs, and where mixing and dilution with ocean water is restricted. We demonstrate the importance of monitoring in the context of rapidly changing pressures. Our recommendations are relevant to other atoll ecosystems where land-based activities and ocean health are tightly interlinked.

Physio-biochemical, metabolic nitrogen excretion and ion-regulatory assessment in largemouth bass (Micropterus salmoides) following exposure to high environmental iron

Iron overload is a significant water quality issue in many parts of the world. Therefore, we evaluated the potential toxic effects of waterborne elevated iron on largemouth bass (Micropterus salmoides), a highly valued sport and aquaculture fish species. First, a 96 h-LC50 toxicity assay was performed to understand the tolerance limit of this species to iron; and was determined to be 22.07 mg/L (as Fe3+). Thereafter, to get a better insight on the fish survival during long-term exposure to high environmental iron (HEI) (5.52 mg/L, 25% of the determined 96 h-LC50 value), a suite of physio-biochemical, nitrogenous metabolic and ion-regulatory compensatory responses were examined at 7, 14, 21 and 28 days. Results showed that oxygen consumption dropped significantly at 21 and 28 days of HEI exposure. Ammonia excretion rate (Jamm) was significantly inhibited from day 14 and remained suppressed until the last exposure period. The transcript concentration of Rhesus glycoproteins Rhcg2 declined; likely diminishing ammonia efflux out of gills. These changes were also reflected by a parallel increment in plasma ammonia levels. Under HEI exposure, ion-balance was negatively affected, manifested by reduced plasma [Na+] and parallel inhibition in branchial Na+/K+-ATPase activity. Muscle water content was elevated in HEI-exposed fish, signifying an osmo-regulatory compromise. HEI exposure also increased iron burden in plasma and gills. The iron accumulation pattern in gills was significantly correlated with a suppression of Jamm, branchial Rhcg2 expression and Na+/K+-ATPase activity. There was also a decline in the glycogen, protein and lipid reserves in the hepatic tissue from 14 days, 28 days and 21 days, respectively. Overall, we conclude that sub-lethal chronic iron exposure can impair normal physio-biochemical and ion-regulatory functions in largemouth bass. Moreover, this data set can be applied in assessing the environmental risk posed by a waterborne iron overload on aquatic life.

Nitrogen Cycle Dynamics Revealed Through δ18O-NO3− Analysis in California Groundwater

Nitrate is a significant water-quality issue in California, the United States as a whole, and the world. Critical to addressing nitrate contamination is understanding the presence and extent of denitrification, and further refining the techniques used to identify nitrate sources. The use and understanding of nitrate isotopic signatures to identify nitrate sources have advanced tremendously; however, knowledge gaps remain concerning specific fractionation pathways and the role of denitrification in altering source values. Using a large unique database of California groundwater nitrate isotopic compositions, we explored the utility of nitrate–oxygen isotope ratios in determining specific nitrate origins. Lawrence Livermore National Lab (LLNL) samples were supplemented by United States Geological Society (USGS) data to create a dataset of over 1200 dual-isotope results. Methods used at LLNL allowed for the determination of δ15N-NO3−, δ18O-NO3−, δ18O-H2O, δ2H-H2O, excess air, major dissolved gases, and excess N2. Results were examined for the degree to which δ18O-NO3− conforms to the model of nitrification in which two atoms of oxygen are sourced from ambient water and one from the atmosphere. Almost 80% of the results fall within one standard deviation of predicted values. However, 19% of samples had significantly higher values, suggesting the preservation of a synthetic nitrate source signature, mixing of sources, or widespread denitrification. Results were examined with respect to general land-use classifications and, while nitrate concentrations followed the expected pattern of being higher in agricultural settings, δ18O-NO3−patterns are complicated by application of N-fertilizer in various forms, and subsequent N cycling in the soil zone. We found that the current understanding of oxygen isotope-fractionation mechanisms cannot yet explain the prevalence of oxygen-isotope compositions with higher than predicted δ18O values, but when paired with related data such as land use and indicators of denitrification, oxygen-isotope compositions of nitrate can help to assess nitrogen cycle dynamics.

The severity of sediment desiccation affects the adsorption characteristics and speciation of phosphorus.

Phosphorus is an important nutrient for plants and algae, and can be the limiting nutrient in aquatic ecosystems. However, oversupply can lead to significant water quality issues. The largest source and sink of P in most aquatic systems is the sediment. As a consequence of drought, in many places sediments that normally would have remained inundated are now being desiccated. Based on previous studies, it is often difficult to predict what impact drying will have on the cycling of P. This is because most of these studies have looked at drying across a chronosequence in the field, where there may be differences in sediment composition or microbial community structure. In this paper we present the results of a study where sediment was exposed to progressively more severe drying in the laboratory - starting with wet sediment, followed by air drying and then sequential oven drying at 30, 50 and 85 °C. Drying resulted in a shift in P speciation, notably with an increase in NaHCO3-extractable reactive P and a decline in NaHCO3-extractable unreactive P, likely indicating an increase in bioavailable, easily exchangeable P. Drying also resulted in a decline in the microbial-P fraction. Drying significantly affected the P adsorption characteristics of the sediment. The total amount of P adsorbed by the sediment and the linear adsorption co-efficient both declined, while the amount of native P adsorbed to the sediment and the equilibrium P concentration both increased. Drying also affected iron speciation with a shift from more reactive oxalate-extractable Fe to more recalcitrant citrate-dithionate-bicarbonate-extractable Fe, suggesting an increase in iron crystallinity and hence decrease in P adsorption capacity. The increase in crystallinity is consistent with Fe EXAFS results, which showed that drying resulted in an increase in edge-sharing neighbours. We hypothesise that the shifts in P speciation, the decline in P adsorption capacity, the increase in the equilibrium P concentration, as well as the death of micro-organisms (as evidenced by a decline in microbial P) on drying all contribute to the Birch effect - the initial pulse of P and/or N upon inundation of dried soils or sediments.

Designing and evaluating a groundwater quality Internet GIS

Contaminated unregulated drinking water in rural communities is a continuing health issue, leading many resource users to unknowingly consume water with elevated levels of harmful chemicals. Though geographic information systems (GIS) and Internet technology have been particularly useful for water resource management, to date, there exist few studies that specifically address the development of Internet-based GIS applications to increase user access to unregulated drinking water source information. Informed by an existing user centered development framework for Internet mapping, we created an Internet GIS that visualized groundwater contamination on the Navajo Nation in the southwest United States. We employed a usability focus group, expert review of content and pilot test of a prototype GIS application to gather empirical evidence on effectiveness for informing users of a significant water quality issue. Results suggested that the designed and deployed GIS application was appropriate for the target audience of environmental nongovernmental organization (ENGO) and institution of higher education (IHE) professionals. Usability testing and expert review confirmed the importance of these evaluation measures to ensure a high quality GIS prior to deployment. Use of existing Internet mapping guidelines was found to be insufficient for creating a refined GIS interface appropriate for the target audience. Additionally, we demonstrated that an existing user centered design and evaluation framework could be applied successfully to visualize water quality for unregulated groundwater wells in the rural southwest United States. Suggestions for continued research in the use of Internet GIS to inform rural residents about drinking water quality are provided.

Biogeochemical value of managed realignment, Humber estuary, UK

We outline a plausible, albeit extreme, managed realignment scenario ('Extended Deep Green' scenario) for a large UK estuary to demonstrate the maximum possible biogeochemical effects and economic outcomes of estuarine management decisions. Our interdisciplinary approach aims to better inform the policy process, by combining biogeochemical and socioeconomic components of managed realignment schemes. Adding 7494 ha of new intertidal area to the UK Humber estuary through managed realignment leads to the annual accumulation of a 1.2 x 10(5) t of 'new' sediment and increases the current annual sink of organic C and N, and particle reactive P in the estuary by 150%, 83% and 50%, respectively. The increase in intertidal area should also increase denitrification. However, this positive outcome is offset by the negative effect of enhanced greenhouse gas emissions in new marshes in the low salinity region of the estuary. Short-term microbial reactions decrease the potential benefits of CO(2) sequestration through gross organic carbon burial by at least 50%. Net carbon storage is thus most effective where oxidation and denitrification reactions are reduced. In the Humber this translates to wet, saline marshes at the seaward end of estuaries. Cost-benefit analysis (CBA) was used to determine the economic efficiency of the Extended Deep Green managed realignment. When compared to a 'Hold-the-Line' future scenario, i.e. the present state/extent of sea defences in the estuary, the CBA shows that managed realignment is cost effective when viewed on >25 year timescales. This is because capital costs are incurred in the first years, whereas the benefits from habitat creation, carbon sequestration and reduced maintenance costs build up over time. Over 50- and 100-year timescales, the Extended Deep Green managed realignment scenario is superior in efficiency terms. The increased sediment accumulation is also likely to enhance storage of contaminant metals. In the case of Cu, a metal that currently causes significant water quality issues, Cu removal due to burial of suspended sediment in realigned areas translates to a value of approximately pounds sterling 1000 a(-1) (avoided clean up costs). Although this is not formally included in the CBA it illustrates another likely positive economic outcome of managed realignment. Although we focus on the Humber, the history of reclamation and its biogeochemistry is common to many estuaries in northern Europe.