Significant Differences In Bond Strength Research Articles

In vitro Examination of the Bond Strength of PEEK and PEKK Materials Used as Substructure Materials with the Superstructure Composite before and after Artificial Aging and Examination of Scanning Electron Microscope Images

Abstract Objective This study aims to evaluate the bond strength of polyetheretherketone (PEEK) and polyetherketoneketone (PEKK) materials when used as substructures with composite superstructures, before and after artificial aging. Surface treatments, including sanding and sandblasting, were examined to determine their impact on bond strength and surface topography. Materials and Methods Sixty samples, divided equally between PEEK and PEKK, were prepared. Each group was further divided into three subgroups (n = 10): control, 10,000 thermal cycles, and 30,000 thermal cycles. The samples were subjected to surface treatments using 600-, 800-, and 1,200-grit silicon carbide wet sandpaper, followed by air abrasion with 110 µm alumina particles. Bond strength tests were conducted using an INSTRON-3345 universal testing machine, and failure types were analyzed under a stereomicroscope. Results Sandblasting with 110 µm aluminum oxide (Al2O3) significantly increased the bond strength of both PEEK and PEKK materials compared with sanding. PEEK samples treated with sandblasting showed the highest bond strength (mean = 1.296 MPa), while PEKK samples treated with sanding had the lowest (mean = 0.056 MPa). Thermal cycling reduced bond strength in both materials, with a more pronounced decrease observed in the 30,000 cycle groups. analysis of variance results indicated significant differences in bond strength based on the material, surface treatment, and the interaction between these factors. Conclusion Sandblasting with 110 µm Al2O3 is an effective method for enhancing the bond strength of PEEK and PEKK substructures with composite materials. These findings support the continued use of PEEK and PEKK polymers in dental applications, suggesting that appropriate surface treatments can significantly improve clinical outcomes.

Comparison of various methods of restoring adhesion to recently bleached enamel

AimThis study compared the effectiveness of several techniques in restoring compromised bonding to recently bleached enamel.MethodsSeventy-five healthy bovine incisors were divided into five groups (n = 15). Fifteen teeth (Group 1) remained intact, whereas 60 (Groups 2 to 5) underwent at-home bleaching with 16% carbamide peroxide. The bonding procedures were as follows: Group 1: Bonding of resin composite to unbleached enamel; Group 2: Bonding immediately after bleaching; Group 3: Application of a 10% sodium ascorbate solution for 10 min before bonding; Group 4: Enamel removal to the depth of 0.5 mm; and Group 5: Increased curing time of the bonding agent to 80 instead of 20 s. After 24 h, the specimens were subjected to micro-shear testing, and the failure mode was determined.ResultsANOVA revealed a significant difference in bond strength among the groups (P < 0.001). The mean bond strength was significantly lower in group 2 than in other groups (P < 0.05), which showed comparable bond strength to each other (P > 0.05). Adhesive failure was the most predominant failure type in all groups. The mixed failure occurred with a frequency of 26.7% in groups 3 and 5. The Fisher’s exact test revealed a significant difference in failure modes among the groups (P = 0.047).ConclusionsThe three experimental procedures used in this study, including the application of 10% sodium ascorbate before bonding, enamel removal to the depth of 0.5 mm, and increasing the curing time of the bonding agent to 80 s, were effective in restoring the compromised bonding to recently bleached enamel.

The Aspects of Dimensionality in the Analysis of Raman Spectra of 2D Materials

Two-dimensional crystals are a class of materials in which an individual layer is indefinitely extended in two dimensions. Each layer is the molecular unit in the crystalline lattice. The nature of interlayer/intermolecular interaction is poorly understood. However, it defines physical properties such as carrier mobility, thermal conductivity, photoluminescence, etc. The vibrational properties of 2D materials are described based on triperiodic space groups. However, the triperiodic space groups do not apply to the description of these structures. The 17 two-dimensional groups in triperiodic space groups do not allow the existence of a third dimension. Therefore, if structures are not planar, the approach is inappropriate. The way to describe such structures is using the diperiodic groups in three dimensions. The well-known 2D materials are graphite, graphene, chalcogenide of Ga, Mo, W, and other elements. The crystalline As2S3 belongs to a class of 2D materials. The unit cell contains two layers with ten atoms in each layer, and it is similar to a structure of metal chalcogenide (MoS(Se)2, WS(Se)2). A bond length of 2.24 A is within the layer, and 3.56 A is between the layers. This interlayer/intralayer bond length ratio (= 1.59) corresponds to a significant difference in bond strengths. Center-zone optical phonons in crystalline As2S3 have been investigated by Raman scattering in a wide temperature range for two polarizations in the layer plane (ac). The crystal's and individual layers' symmetry are different, defining different selection rules for optical phonons. According to the crystallographic data, crystal symmetry is monoclinic with 20 atoms in a unit cell and is P21/n (C2h 5). The axis b, perpendicular to the layers, is the only unique axis of the crystal. Therefore, all phonons in the ac plane should be indistinguishable. The layer symmetry is orthorhombic in the diperiodic space group in three dimensions, in which a, b, and c axes are axes of symmetry with a space group of Pnm21 (C2v 7). The intensity of Raman bands in the layer plane shows strong polarization dependence, indicating layer symmetry's dominance. Interlayer interaction is weak, and as a result, low-frequency Raman bands appear in the spectra. The position of these bands defines the strength of interlayer interaction. The data presented provides an understanding of the structural motives of 2D As2S3 and may predict the optical/electronic properties of similar 2D materials based on Raman spectra.

Shear Bond Strength of Clear Aligner Attachment Using 4-META/MMA-TBB Resin Cement on Glazed Monolithic Zirconia.

Increasing demand for adult orthodontic treatment using clear aligners has highlighted challenges in bonding clear aligner attachments to various restorations. Specifically, the bond strength of clear aligner attachments to glazed monolithic zirconia has not been extensively studied. This study aims to compare the shear bond strength (SBS) and mode of failure (MOF) of conventional bonding methods versus Superbond C&B (4-META/MMA-TBB resin cement) for clear aligner attachments on glazed monolithic zirconia. Fifty sintered and glazed zirconia samples were divided into five groups and attached with clear aligner attachments: Si (silane), B (bonding agent), SiB (bonding agent and silane), SU (Superbond C&B), and SiSU (silane and Superbond C&B). SBS and MOF of these samples were analyzed. Results indicated a significant difference in bond strength among the groups. SiSU exhibited the highest bond strength, followed by SU, while B had the lowest bond strength. SEM analysis revealed that SiSU and SU predominantly exhibited mixed failure, indicating high bond strength without affecting the glazed layers of the zirconia. In contrast, B exhibited only adhesive failure at the interface, resulting in insufficient bond strength for effective orthodontic treatment. In conclusion, using 4-META/MMA-TBB resin cement provides high bond strength for clear aligner attachments on glazed zirconia with minimal material damage during debonding.

Evaluation of the Effectiveness of Semolina in Improving the Bond Strength of Metal Alloys and Acrylic Resins for the Fabrication of Hybrid Prostheses for Implant Restoration: An In Vitro Study.

Introduction Fixed prosthodontic solutions for restorations of multiple implants are often done using acrylic-metal hybrid prosthesis. These restorations have a high failure rate due to poor bond strength between metal and acrylic, despite using digital attachments and primers. This study has been done to demonstrate an economical yet effective method of increasing shear bond strength between acrylic and metal. Materials and methods Disc specimens of 10 mm diameter and 2 mm thickness were designed using the Meshmixer version 3.5 software (Autodesk Inc., San Rafael, USA). The standard tessellation (STL) file was imported and sent for direct metal laser sintering (DMLS) in cobalt-chromium (CoCr),titanium (Ti), and wax milling. The groups were defined. Ten samples were included in each group. Group 1: Conventional Casting in CoCr; Group 2: Conventional Casting with Opaquer (CoCr); Group 3: DMLS CoCr; Group 4: DMLS CoCr with Opaquer; Group 5: DMLS Ti; Group 6: DMLS Tiwith Opaquer; Group 7: Casting with Semolina (CoCr); and Group 8: Casting with Semolina and Opaquer (CoCr). Wax-up was performed using double wax sheet thickness of modeling wax. Flasking and acrylization were done using the injection moulding technique. A universal testing machine was used for shear bond strength. Results were tabulated and statistical analysis was done usingIBM SPSSStatistics for Windows (IBM Corp., Armonk, USA). The Shapiro-Wilk test was done to confirm the normality of the data, followed by the one-way analysis of variance (ANOVA) test to compare the shear bond strength between metal alloys and heat cure acrylic resin. Results The one-way ANOVA results reveal significant differences in bond strengths among the various groups. Conventional Casting with Opaquer showed no significant difference (p=0.335), but there were notable improvements in bond strength when compared to DMLS CoCr, DMLS CoCr with Opaquer, DMLS Ti, DMLS Ti with Opaquer, Semolina, and Semolina with Opaquer, with DMLS Ti having the largest mean difference (3.368). Conventional Casting with Opaquer significantly outperformed all groups, especially Semolina, which showed the highest mean difference (7.558). Similar trends were seen with DMLS CoCr and DMLS Ti, where Semolina consistently demonstrated superior bond strength. Overall, Semolina produced the highest bond strengths across all conditions. These results underscore the importance of material selection and treatment in enhancing bond strength. Conclusion Semolina can be used as an economicaland reliable method to increase the shear bond strength between acrylic and metal bonding. Its ability to burn out during dewaxing without any remains or remnants in mould deems it a useful material for increasing mechanical bonding.

The Effect of Carbamide Peroxide Bleaching Gel with and without Remineralizing Agents on Microtensile Bond Strength of Resin Composites to Enamel

Introduction: Carbamide peroxide bleaching gel, along with remineralizing agents, can induce changes in the structure and mineral content of enamel, potentially leading to a decrease in the bond strength of resin composite to the enamel. Therefore, this laboratory study aimed to determine the effect of carbamide peroxide bleaching gel with and without remineralizing agents on the microtensile bond strength (µTBS) of resin composites with microhybrid and nanofill structures to enamel. Materials and Methods: Thirty extracted third molar teeth were randomly divided into five groups, each group subdivided into two equal subgroups: Group 1: Control group, Group 2: Bleaching gel without fluoride, Group 3: Bleaching gel containing fluoride, Group 4: Bleaching gel containing CPP-ACP, and Group 5: Bleaching gel containing fluoride and CPP-ACP. In the first subgroups, nanofilled resin composite Filtek Z350, while in the second subgroups, microhybrid resin composite Filtek Z250 were bonded to enamel surface. After specimen preparation, µTBS was measured using a universal testing machine. Data were analyzed using parametric tests (P value&lt;0.05). Results: The highest µTBS of resin composite to enamel was observed in the control group, while the lowest bond strength was seen in the fluoride-containing bleaching group. Comparisons of µTBS between the study groups pairwise, except for the comparison between the control group and the bleaching group, the bleaching group with (CPP-ACP+Fluoride), and the (CPP-ACP) group with the fluoride group, showed significant differences in bond strength. Although, the mean µTBS of the Filtek Z250 composite was higher than the Filtek Z350 composite in all groups, but this difference was not statistically significant. Conclusion: The use of carbamide peroxide bleaching gel with remineralizing agents leads to a decrease in µTBS of the resin composite to the enamel.

Efficacy of root-end filling techniques using premixed putty type bioceramic cements: an ex vivo study.

Currently, premixed putty-type bioceramic cements (PPBCs) have become popular materials for root-end fillings. This study investigated three root-end filling techniques using PPBCs and calcium silicate-based sealers including EDTA pretreatment. Ninety root segments were prepared and standardized with an artificial fin and lateral canal, and assigned to three groups (n = 30). Root-end fillings were placed using BC-RRM Putty alone (Group PA), injection of BC sealer followed by BC-RRM Putty (Lid Technique: Group LT) or BC-RRM Putty with BC sealer coating (Deep putty packing technique: Group DP). Half of each group was pretreated with 17% EDTA. The radiographic images of the specimens were assessed by five graders and push-out bond strength tests were conducted. The data were analyzed with a general linear model including two-way ANOVA and chi-square test at a significance level of 5%. DP approach demonstrated significantly higher bond strength than LT (P < 0.05). However, there was no statistically significant difference in bond strength between PA and either DP or LT. EDTA pretreatment had no significant effect on push-out bond strength. Radiographically, for the main canal, PA and DP scored significantly higher than LT. In the fin, PA scored significantly higher than others (P < 0.05). Our study highlights variations in root-end filling techniques. Injecting a bulk of bioceramic sealer before the placement of PPBCs may reduce bond strength and radiopacity. The application of PPBCs alone or in the deep putty technique demonstrates potential for favorable outcomes. EDTA pretreatment did not enhance bond-strength. Careful selection and application of bioceramic materials and techniques in root-end fillings may influence the outcome of endodontic root-end surgery. When PPBCs and calcium silicate-based sealers are used together for root-end fillings, sealer followed by deep putty application may offer improved bond strength and radiographic fill compared to the lid technique.

Effect of Salvadora persica on resin-dentin bond stability

BackgroundThe stability of resin–dentin interfaces is still highly questionable. The aim of this study was to evaluate the effect of Salvadora persica on resin–dentin bond durability.Materials and methodsExtracted human third molars were used to provide mid-coronal dentin, which was treated with 20% Salvadora persica extract for 1 min after acid-etching. Microtensile bond strength and interfacial nanoleakage were evaluated after 24 h and 6 months. A three-point flexure test was used to measure the stiffness of completely demineralized dentin sticks before and after treatment with Salvadora persica extract. The hydroxyproline release test was also used to measure collagen degradation by endogenous dentin proteases. Statistical analysis was performed using two-way ANOVA followed by post hoc Bonferroni test and unpaired t-test. P-values < 0.05 were considered statistically significant.ResultsThe use of Salvadora persica as an additional primer with etch-and-rinse adhesive did not affect the immediate bond strengths and nanoleakage (p > 0.05). After 6 months, the bond strength of the control group decreased (p = 0.007), and nanoleakage increased (p = 0.006), while Salvadora persica group showed no significant difference in bond strength and nanoleakage compared to their 24 h groups (p > 0.05). Salvadora persica increased dentin stiffness and decreased collagen degradation (p < 0.001) compared to their controls.ConclusionSalvadora persica extract pretreatment of acid-etched dentin preserved resin–dentin bonded interface for 6 months.Clinical significanceDurability of resin-dentin bonded interfaces is still highly questionable. Endogenous dentinal matrix metalloproteinases play an important role in degradation of dentinal collagen within such interfaces. Salvadora persica may preserve resin-dentin interfaces for longer periods of time contributing to greater clinical success and longevity of resin composite restorations.

Effect of Different Primers on Shear Bond Strength of Base Metal Alloys and Zirconia Frameworks.

Ensuring a secure bond between a framework structure and layering composite resin veneer is essential for a long-lasting dental restoration. A variety of primer systems are available to facilitate the adhesive bonding. Nevertheless, the growing preference for efficiency and simplicity in dentistry has made the one-bottle universal primers a desirable option. This study aims to compare the effectiveness of universal primers on the shear bond strength (SBS) of base metal alloy (BMA) and zirconia to layering composite resin. Each 160 BMA and zirconia 20 × 10 × 5 mm test specimen was fabricated. Eight different primers (SunCera Metal Primer, Metal Primer Z, Reliance Metal Primer, Alloy Primer, MKZ Primer, Monobond Plus, ArtPrime Plus, and Clearfil Ceramic Primer Plus) were applied to 20 specimens in each group. Subsequently, a 5 × 2 mm composite resin build-up was applied. SBS tests were performed after 24 h of water storage and after thermocycling (25,000 cycles, 5-55 °C). On BMA, after water storage for 24 h, the bond strength values ranged from 26.53 ± 3.28 MPa (Metal Primer Z) to 29.72 ± 2.00 MPa (MKZ Primer), while after thermocycling, bond strength values ranged from 25.19 ± 1.73 MPa (MKZ Primer) to 27.69 ± 2.37 MPa (Clearfil Ceramic Primer Plus). On a zirconia base, after 24 h, the bond strengths values ranged from 22.63 ± 2.28 MPa (Reliance Primer) to 29.96 ± 2.37 MPa (MKZ Primer) and from 23.77 ± 3.86 MPa (Metal Primer Z) to 28.88 ± 3.09 MPa (Monobond Plus) after thermocycling. While no significant difference in bond strength was found between the primers on the BMA base, five primer combinations differed significantly from each other on zirconia (p = 0.002-0.043). All primers achieved a bond strength greater than 23 MPa on both framework materials after thermocycling. Thus, all primers tested can be applied to both framework materials with comparable results.

Filling Material Bond Strength to Dentin Is Positively Influenced by the Agitation of Endodontic Final Irrigating Solutions.

The final step of irrigation has been considered to of increase the bonding strength of filling material to dentin. This study investigated the impact of three final-step irrigation methods on the endodontic sealer bond strength to dentin by using a micro push-out test. Palatal roots of human maxillary molars were cleaned and shaped and randomly divided in six groups (n=15) according to the final-step irrigation method and the type of root canal sealer used. The solutions used for the final-step irrigation were 17% ethylenediaminetetraacetic acid and 2.5% sodium hypochlorite, which underwent three methods: 1) syringe-needle irrigation/conventional, 2) passive ultrasonic irrigation, and 3) XP-endo Finisher agitation. The root canal sealers used were: EndoSequence BC Sealer, and AH-Plus sealer. Roots were obturated with the single cone technique and then, cross-sectioned in 2-mm-thick slices (3 slices from each root). Push-out test was performed on the sliced specimens (cervical, middle, and apical thirds) with a universal testing machine. Bond strength values were recorded in megapascal (MPa). Subsequently, each specimen was longitudinally split to verify the type of failure. Data analysis was performed using Johnson transformation, three-way analysis of variance, Tukey's post-hoc tests, and the partial Eta squared test. There were significant differences in bond strength between the sealers [AH: 4.46±2.24 and BC: 3.47±2.19 MPa (P<0.001)]; between final-step irrigation methods [passive ultrasonic irrigation: 4.52±2.25, XP-endo Finisher: 3.93±3.93 and syringe-needle irrigation/conventional: 3.37±2.51 MPa (P<0.001)], and between the root canal thirds represented by the sliced specimens [cervical: 5.45±2.39, middle: 4.14±1.99 and apical: 2.30±1.30 MPa (P<0.001)]. The interaction between the variables had no significance (P>0.05). Agitation of the final irrigating solution may improve the bonding of the sealer to canal walls. AH-Plus sealer had the highest bond strength. The bond strength reduced significantly towards the apical third.

Evaluation of Sealer Remnants Using a Bioceramic Sealer Single-cone Technique after Post Space Preparation and its Influence on the Adhesion of Fibre Posts in vitro.

To compare calcium silicate-based endodontic sealer and epoxy resin-based sealer remnants on root canal walls after post space preparation and their influence on the bond strength of fibre posts fixed with a dual-cured resin cement. Thirty-six extracted single-root mandibular premolars were instrumented and divided randomly into two equal groups with different endodontic sealers. iRoot SP (Innovative BioCeramix, Vancouver, Canada) was employed in the experimental group and AH Plus (Dentsply Sirona, Charlotte, NC, USA) was used in the control group. Sealer remnants were observed under an endodontic microscope after root canal therapy and post space preparation. Fibre posts were fixed with dual-cured resin cement. Specimens were taken at each third of the post space. The push-out bond strength was measured using a universal testing machine and fracture modes were assessed. Statistical analysis was performed using an independent samples t test and one-way analysis of variance. There was no statistically significant difference in bond strength of fibre posts between the control and experimental group (P > 0.05); however, sealer remnants were observed in 38.9% of the samples treated with iRoot SP and none of the samples treated with AH Plus. The major fracture mode in samples treated with iRoot SP was adhesive failure between the resin cement and the post, and no adhesive failure between the resin cement and dentine occurred at the site of the sealer remnant. The presence of iRoot SP remnants on the root canal walls after post space preparation did not interfere with bonding. iRoot SP is a viable option for root canal obturation before fibre post cementation.

Bond Strength of a Novel Universal Resin Cement to Dentin with or without an Adhesive Bonding Agent: An In Vitro Study.

The purpose of this study was to evaluate the bond strength and fracture mode of universal resin cement to dentin compared to self-adhesive and adhesive resin cement with and without an adhesive bonding agent. Seventy-two molar teeth were sectioned to expose coronal dentin, divided into three groups, and assigned to RelyX Universal (universal), RelyX Ultimate (adhesive), or RelyX Unicem 2 (self-adhesive) cements from 3M. The 3 groups were further subdivided into 2 subgroups of 12 specimens each, with or without the use of an adhesive bonding agent. Lithium-disilicate discs were bonded to the dentin surface using the cements, stored for 24 hours in distilled water, and subjected to 2,000 thermocycles before shear bond strength testing and fracture mode analysis. Significant differences in bond strength and fracture mode were found between groups based on cement or the use of a bonding agent. Both the universal and adhesive cements had significantly greater bond strengths to dentin with the use of a bonding agent versus no bonding agent. With the self-adhesive cement, there was no significant increase in bond strength to dentin with the use of a bonding agent. The novel universal resin cement had similar bond strengths to dentin as the adhesive cement with the use of a bonding agent, and similar bond strengths as the self-adhesive cement without the use of a bonding agent. The adhesively bonded universal cement had the greatest percentage of mixed and cohesive fractures. When greater adhesion is needed clinically, the novel universal resin cement may be used with an adhesive bonding agent. However, when less adhesion is needed, it could be used without a bonding agent in self-adhesive mode.

In vitro performance of an autocured universal adhesive system in bonding to dentin

BackgroundThe successful integration of resin-based dental adhesives significantly impacts restorative dentistry, providing efficient and aesthetically pleasing caries treatments. Among various adhesives, one-step self-etching adhesives (1-SEAs) have gained popularity due to their simplicity and short application time. However, concerns have been raised regarding their bonding performance and marginal adaptation characteristics, which differ from two-step self-etching adhesives (2-SEAs) and three-step etch-and-rinse adhesives. Additionally, light-cured bonding materials may encounter challenges in deep cavities and inaccessible areas, necessitating extended light irradiation time. Autocured bonding materials are a potential solution, but limited comparative studies have been conducted on their performance.MethodsIn this in vitro study, we evaluated a new autocured universal bonding material (Bondmer Lightless 2) and compared the results with recent light-cured bonding materials. Microshear bond strength (μSBS) tests were performed on 25 human molars using five different combinations of adhesives and composite resins: Bondmer Lightless 2 with Estelite Bulk Fill Flow (BE group), Bondmer Lightless 2 with a prototype composite resin (BO group), Prime&Bond Universal with SDR flow + (PS group), Scotchbond Universal with Filtek Bulk Fill (SF group), and G-Premio Bond with Gracefil BulkFlo (GG group). The bond strengths and failure modes were assessed using a universal testing machine and scanning electron microscope (SEM), respectively. Marginal adaptation was evaluated using swept-source optical coherence tomography (SS-OCT) and confocal laser scanning microscopy (CLSM) on 40 sound bovine maxillary incisors.ResultsThe μSBS test showed no significant differences in bond strength among the tested groups. Most failure modes were observed at the bond interface between the adhesive and the dentin. The autocured bonding material demonstrated significantly higher marginal adaptation (SI%) than PS, SF, and GG. The CLSM images corresponded with gaps observed in the SS-OCT images, indicating improved marginal sealing in the autocured group.ConclusionsThe new autocured universal bonding material exhibited comparable bond strength to a conventional light-cured material while demonstrating a superior marginal adaptation level. This finding suggested that the autocured material could be a valuable alternative, especially when extended light irradiation would pose a challenge. Further clinical studies would be warranted to evaluate the performance of the autocured bonding material in actual restorative dental practice.

Synthesis and analyses of injectable fluoridated-bioactive glass hydrogel for dental root canal sealing.

This study aimed to synthesize fluoride-doped bioactive glass (F-BG) based thermo-sensitive injectable hydrogel for endodontic applications. The structural and phase analyses were done with Fourier Transform Infrared spectroscopy and X-ray Diffraction, respectively. The setting time of prepared injectable was investigated at 21°C (in the presence and absence of an ultrasonic scalar) and at 37°C. Flowability was tested according to ISO-6876:2012 specifications, whereas injectability was checked by extrusion method using 21-, 22-, and 23-gauge needles. The in vitro bio-adhesion and push-out bond strength were studied on days 7 and 90 and compared with the commercially available TotalFill®. The ion release profile was analyzed for up to 30 days with Inductively Coupled Plasma Optical Emission Spectroscopy. The fluoride release analysis was conducted periodically for up to 21 days in deionized water and artificial saliva using an ion-selective electrode. The final setting time at 21°C, 21°C+ultrasonic scalar, and 37°C were 38.66±3.21, 29.12±1.23, and 32±3.46 min, respectively. The flowability was 25±3.94 mm, and the injectability coefficient was ≥70.3 for 22, 21, and 57% in a 23-gauge needle. Fluoride release in deionized water was found to be significantly higher than in artificial saliva and increased with time. A significant difference in bond strength was found between days 7 and 90, where the strength was increased, and a new apatite layer was formed on the tooth surface. A rapid release of calcium, phosphate, and silicon ions was seen initially, whereby the continuous release of these ions was observed for up to 30 days. The prepared F-BG injectable hydrogel has shown promising results and has the potential to be used as an endodontic sealer.

Root canal filling quality and bond strength of endodontic sealers to human and bovine dentin

Objective: This study aimed to compare the filling quality and bond strength of two endodontic sealers, AH Plus and Bio-C Sealer, in human and bovine teeth. Methods: The root canals of 60 [30 human (H) and 30 bovine (B)] single-rooted teeth were prepared and filled by lateral condensation of gutta-percha and AH Plus (groups AP-H and AP-B) or Bio-C Sealer (groups BC-H and BC-B). Six 1.5-mm-thick slices were obtained from each root. The specimens were observed under a stereomicroscope to assess filling quality, considering possible voids within the filling material. Subsequently, root slices were evaluated in terms of push-out bond strength and failure mode. Data were analyzed by Mann-Whitney tests and Spearman correlation coefficients (α=5%). Results: The filling quality provided by AP and BC was similar in both dentin substrates. However, when comparing human and bovine teeth, void scores were greater in the bovine samples, for both sealers. AP had higher bond strength to human and bovine dentin than BC. However, there was no significant difference in bond strength between dentin substrates, for both sealers tested. Also, there was a positive and moderate correlation between the bond strength values of human and bovine teeth. The mixed failure mode was the most prevalent. Conclusion: AP and BC provide similar filling quality, but the first presents higher bond strength values to human and bovine dentin. The use of bovine teeth as substitutes for human samples seems adequate in studies related to bond strength, but not in those testing root canal filling quality.&#x0D; Keywords: Dentin, Endodontics, Root canal filling materials.

Influence of surface treatments and adhesive protocols on repair bond strength of glass-matrix and resin-matrix CAD/CAM ceramics.

To specify the effects of self-etching ceramic primer, Monobond Etch and Prime (MEP), and universal adhesive (UA) on repair bond strength between CAD/CAM blocks and resin composite. Vita Mark II (VM), IPS e.max CAD (EMAX), Shofu Block HC (SHC), and Tetric CAD (TET) blocks were sliced and thermocycled. They were divided into four groups according to surface treatments (n = 24): control, sandblasting (AL), hydrofluoric acid etching (HF), and MEP application. SEM analysis assessed surface topography. Subdivided, specimens followed distinct adhesive protocols (n = 12): control (silane + adhesive [SA] or adhesive [A] only for MEP group) and UA. Microshear bond strength (μSBS) was measured following resin composite repair. Data were analyzed using two-way ANOVA and Tukey tests (p < 0.05). The μSBS of CAD/CAM blocks was significantly influenced by surface treatment type and adhesive protocol. The highest μSBS values for each block, considering surface treatment + adhesive protocol, were VM, HF + SA, or HF + UA; EMAX, MEP + A; and SHC and TET, AL + SA, or AL + UA. Except for EMAX, it was not the adhesive protocol that made the significant difference in bond strength for each CAD/CAM block, but the surface treatment. MEP + UA application on glass ceramics lowered μSBS values significantly, so it is not recommended in clinical conditions. Repair is an essential therapeutic option, particularly in esthetic restorations, to swiftly repair the impaired esthetics caused by fracture. Repair protocol is dependent on the restorative material, and to have a reliable repair bond strength, the following surface treatment and adhesive protocol combinations are recommended for each CAD/CAM block: VM, HF + SA, or HF + UA; EMAX, MEP + A; and SHC and TET, AL + SA, or AL + UA.

Effect of water aging on the shear bond strength of different self-adhesive restorative materials to dentin

This study aimed to evaluate the effect of water aging on the shear bond strength of four self-adhesive restorative materials on dentin. Sixty permanent human molars recently extracted for prophylactic purposes were used in this study. The crown of each tooth was cut under water-cooled conditions using a plaster cutting engine to expose the middle dentin surface of the teeth. The prepared teeth were randomly divided into six groups according to the restorative materials [KERR Vertise Flow (VF), GC EQUIA Forte (EQ), PENTRON Fusio Liquid Dentin (PF), IMICRYL Nova Compo SF (NC) Clearfil Majesty ES-2 (CM-control) and Clearfil Majesty ES Flow (CF-control)]. Each restorative material was applied to two different areas of each tooth (n = 120) using cylindrical silicone molds with dimensions of 2 mm × 2 mm. Macro-shear tests were conducted using a Universal Testing Machine (1 mm/min) initially (24 h) and after aging (6 months of water aging), and the failure types were analyzed. For the initial values, a significant difference in the shear bond strength of the self-adhesive and control groups was observed. After aging, the bond strength increased for flowable composite material (CF) and decreased for two different self-adhesive restorative material groups (NC and EQ). There was no significant difference in the bond strength before and aging in the paste-like control composite group (CM) and in the two self-adhesive restorative material groups (VF and PF). Differences in the shear bond strength were observed between the self-adhesive and control materials both before and after aging.

Push-out bond strength and SEM fractographical analysis of hollow fibre posts used with self-adhesive resin cement: a pilot study.

Detachment is the major cause of failure of endodontic fibre posts. Hollow posts have been recently introduced to overcome such issue. The primary aim of this pilot study was to compare the push-out bond strength of hollow posts and traditional solid posts. Eight round-shaped single-canal premolars extracted for periodontal reason were selected as sample and equally randomized into two groups: (i) traditional solid fibre posts-TECH21xop and ii) hollow fibre posts-TECHOLE. A dual-curing self-adhesive cement (new TECHCEM) was used for posts placement. Six horizontal sections-two from each portion of the root (coronal, middle and apical)-were obtained from each sample root, yielding a total of 24 sections for each group. Push-out test was performed on the sections and bond strength values were compared between groups and within each group. Scanning electron microscope (SEM) fractographical analysis was conducted on each section. Additional SEM and EDX analyses were performed on new samples of both posts, to assess fibres density and distribution, and the chemical composition of the fibres and the matrix. Hollow posts showed a significantly higher push-out bond strength (6.36±1.22 MPa) than solid posts (3.64±1.62 MPa). Among the three root portions of the same group, there was no significant difference in bond strength. In both groups, the most frequent type of fracture was a mixed adhesive failure with the cement covering 0 to 50% of the post perimeter. Hollow post fibres appear more similar in size and have a more homogeneous distribution, compared to solid posts. The two post types also have different chemical compositions.

Influence of antimicrobial photodynamic therapy on the bond strength of endodontic sealers to intraradicular dentin: A systematic review and meta-analysis.

The objective of this systematic review and meta-analysis (SRMA) was to investigate the influence of antimicrobial photodynamic therapy (aPDT) on the bond strength of endodontic sealers to intraradicular dentin. This SRMA followed the Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) and was registered in the International Prospective Registry of Systematic Reviews (PROSPERO) (CRD42022319856). A population, intervention, control, and outcome (PICO) question was formulated: "Does antimicrobial photodynamic therapy decrease the bond strength of root canal sealers?". A literature search was performed in PubMed/MEDLINE, Embase, Web of Science, Scopus, Cochrane Library, and ProQuest databases until July 2022. Joanna Briggs Institute Critical Assessment Guidelines for Quasi-Experimental Studies were used for quality assessment. The meta-analysis was based on the inverse variance (IV) method (p<0.05). Out of an initial 345 articles, 8 in vitro studies were included, published between 2013 and 2022. The studies were qualitatively analyzed; two studies showed a positive effect, two studies a negative effect, and the other studies showed no effect on bond strength of endodontic sealers to intraradicular dentin. Seven of the studies were included in the SRMA, which indicated that there was no significant difference in bond strength when using aPDT (P=0.90; MD: -0.03; 95% CI: -0.46 to -0.41). There was a high level of evidence for each meta-analysis outcome. It can be concluded that the use of aPDT as a method of root canal disinfection does not negatively influence the bond strength of endodontic sealers in the root canal.

Biomechanical performance of three fiberglass post cementation techniques: Imaging, in vitro, and in silico analysis.

The structural integrity of the resin cement layer, the bond strength, and the biomechanical behavior of different fiberglass post cementation techniques were evaluated. Thirty-three bovine incisors were divided into three groups (n = 11): conventional fiberglass post (CFP), conventional fiberglass post in flared root canals (CFL), and relined fiberglass post (RFP). Six specimens from each group were submitted for high-resolution microcomputed tomography (μCT) to evaluate the integrity and presence/volume of voids at the resin cement layer. Finite element analysis (FEA) of two three-dimensional (3D) models of each group were conducted, one considered ideal (without interface defects) and another containing the conditions identified in the μCT analysis. Push-out bond strength tests were conducted for all specimens. The CFL group had the greatest mean values of void (Thirds cervical: 73.67; middle: 95.67; apical: 47.33) and gap concentration (Thirds cervical: 14.67; middle: 15.83; apical: 8.33) compared with CFP and RFP. A significant difference in bond strength was observed between the cervical (1.33 MPa) and middle thirds (1.85 MPa) compared with the apical third (4.85 MPa) of the CFL. A significant difference was observed in the bond strength in the CFL (1.33 MPa) and RFP (3.29 MPa) in the cervical third, which were statistically similar to the bond strength of the CFP. The tensile stress distributions were similar in most structures, localized in the cervical region on the lingual surface. Structural defects in the interface layer might influence the bond strength and biomechanical behavior under the different fiberglass post cementations.