Effectively measuring the risk level of financial institutions is the key to preventing and defusing systemic risks. This paper uses the unconditional coverage test method to backtest the systemic risk of 35 listed financial institutions in China, and uses the quantile coherence method to construct a quantile frequency domain correlation network to explore the frequency domain mechanism of systemic risk correlation of financial institutions. The study found that: (1) During the financial market crisis, the Delta CoVaR commonly used systemic risk measurement indicators such as MES, CoVaR, and failed to effectively measure the systemic risk of China's financial institutions. (2) Compared with the short-term correlation layer and the medium-term correlation layer, China's financial institutions have obvious extreme risk linkage effects in the long-term correlation layer.(3) In the short-term, medium-term and long-term correlation layers, small and medium-sized financial institutions such as Ningbo Bank, Industrial Securities and Dongfang Energy all have high correlation importance. Relevant departments should pay attention to preventing the risk of "too correlated to fail" of small and medium-sized financial institutions in my country.