The effect of hygrothermal environment on the energy harvesting capabilities of piezolaminated shallow shell panels made of variable stiffness composite layers (VSCL) is investigated. The use of curvilinear fibers to tailor the characteristics of the energy harvester is also explored. To model the deformation of the harvester, a finite element model based on a first-order normal shear deformation theory (FNSDT) is developed. Nonlinear strain–displacement relations based on Green–Lagrange strains are considered for nonuniform stress distribution due to temperature and moisture. A nine noded isoparametric element is used to discretize the domain. The effects of temperature and moisture concentration change on Power frequency response functions (FRFs), Voltage FRFs and Motion FRFs are presented. Power FRFs, Voltage FRFs and Motion FRFs are plotted for optimum load resistance when the shell structure is excited at short and open circuit frequencies. The current study is expected to help design and optimize the vibrational energy harvester to power sensors used in different automotive, aerospace, nuclear applications, subjected to elevated temperature and moisture conditions.