Protective Shield Research Articles

Constructing an Artificial Interface as a Bifunctional Promoter for the Li Anode and the NCM Cathode in Lithium Metal Batteries.

The bottleneck of Li metal batteries toward practical applications lies at inferior cyclability as well as Li dendrite issues. As a promising solution, an interface engineering strategy is proposed herein for the Li anode through constructing a hybrid artificial interface. It is assembled onto the Li anode using photocontrolled free radical polymerization (photo-CRP) of polyethylene glycol diacrylate-hexafluorobutyl methacrylate and hexafluorobutyl methacrylate-trifluoroethyl carbonate (PEGDA-HFMBA@HFMBA-FEMC or PH@HF layer). Among such hybrid interfaces, the interior layer of PEGDA-HFMBA exists as a protective shield with flexibility and fracture resistance, while the exterior layer of HFMBA-FEMC plays a role as a LiF reservoir to promote Li mass transfer and its even electrodeposition. In the meantime, some excess HFMBA and FEMC monomers further dissolve into the electrolyte as molecular additives, followed by in situ generation of a thin and robust LiF-rich cathode electrolyte interface (CEI). With the resulting Li anode, Li/NCM811 full cells showcase multifold cyclability amplification in comparison to cells using Bare-Li, covering durable cyclability with a capacity retention of 81.8% after 400 cycles. When the cutoff voltage is elevated to 4.5 V or the working temperature is elevated to 45 °C, the cells still maintain a stable operation for extending 300 cycles.

Highly protective and functional strengthening strategies for 3D printed continuous carbon fiber reinforced polymer composites: manufacturing and properties

Carbon fiber-reinforced polymer (CFRP) composites have gradually emerged as a crucial material in the aerospace industry. However, inadequate impact resistance and thermal stability limit survival in extreme environments. Inspired by the specific functions of multiple layers of tissue, from bird feathers to the musculoskeletal system. We propose low-cost composite strengthening strategies and efficient novel three-dimensional graphene aerogel manufacturing methods. A novel graphene aerogel/carbon fiber reinforced polymer (GAC) composite prepared by in-situ laser-induced graphene (LIG) layers on the surface of 3D-printed CFRP. GAC composites enhance CFRP's impact protection, thermal insulation, and electromagnetic shielding capabilities. For protection, GAC composites reduce low-velocity impact damage by 26.2%. The graphene layer can increase the thermal buffering capacity of the material four times, and the long-term service temperature can be increased by 40% compared to traditional CFRP. For functionality, the composites enable electromagnetic interference (EMI) shielding effectiveness of up to 50.2 dB. Furthermore, it can achieve surface heating above 400 °C and rapid de-icing through electrothermal effects. The simple and efficient processing method of GAC composites and tunable functionalities holds promise for the development of highly protective and intelligent aircraft skins.

Study on the mechanical properties and gamma/neutron radiation shielding performance of SnBi/B4C composite materials

The development of multifunctional shielding materials has become a hot research topic with the increasing requirements for radiation protection materials in terms of performance, weight and non-toxicity. In this study, non-toxic SnBi/B4C composites with different B4C contents (0, 3, 6, 9, 12 and 15wt%) were successfully prepared by powder metallurgy, and their mass attenuation coefficients, half-value layers, mean free paths, effective atomic numbers, and 0.025eV thermal neutron shielding performance. The results show that B4C plays a key role in regulating the mechanical properties and thermal neutron shielding properties of SnBi/B4C composites. When the B4C content was 9wt% (S3), the integrated mechanical properties of the composites were optimal, and the yield strength, tensile strength, and microhardness were enhanced by 31%, 32%, and 129%, respectively, compared with those of the samples without B4C. The radiation shielding effect is remarkable, the gamma-ray shielding performance in the energy range of 0.03-0.08MeV is better than that of Pb. Meanwhile, the S3 sample with only 3mm thickness can shield 99.7% of thermal neutrons, while the shielding rate of the S0 sample without B4C is only 5.2%. Comprehensive analyses show that the SnBi/B4C composites are superior in terms of environmental protection, mechanical properties, gamma-ray and thermal neutron shielding, with lighter weight and safer use. This finding provides a theoretical basis for the selection of efficient, non-toxic and diverse radiation shielding materials for medical and other special environments.

Building a protective shield: The role of wound healing in reducing postharvest decay and preserving quality of citrus fruit1

Postharvest citrus fruit is susceptible to pathogenic infestation and quality reduction through wounds, leading to tremendous commercial losses. Herein, wound healing of citrus fruit was obviously at 25°C for five days to form a barrier effective against the development of infectious diseases and water dissipation. Combined with the results of transcriptional and metabolic levels, wound healing activated the expression of CsKCS4, CsKCS11, CsCYP704B1, CsFAH1, CsGPAT3 and CsGPAT9 genes in suberin biosynthesis pathway, and CsPMEI7, CsCesA-D3, CsXTH2, CsXTH6, CsXTH22, CsXTH23, CsXTH24, CsC4H and CsCAD genes in cell wall metabolism pathway, leading to the accumulation of suberin monomers and cell wall components. The results of microscopic observations proved wound healing promoted suberin deposition and cell wall strengthening. Meanwhile, wound healing required the provision of energy and precursor substances by carbohydrate metabolism and amino acid metabolism. We provide new insights into the regulatory mechanism of wound healing on improving disease resistance and maintaining the quality of citrus fruit.

Synthesis of polyaniline tannate-modified carbon nanotubes by oxidative copolymerization as highly efficient corrosion inhibitors for mild steel in HCl solution

Corrosion is a prevalent issue in industrial production, directly impacting the production process and causing severe damages. To mitigate this problem, corrosion inhibitors are highly desired. Herein, a novel type of nano corrosion inhibitor, referred to as PTCNT, was synthesized through an oxidative copolymerization method utilizing aniline, ammonium persulfate (APS), and tannic acid (TA)-modified multiwalled carbon nanotubes (MWCNTs). The results demonstrated that the PTCNT effectively inhibited the corrosion of mild steel in 1 M HCl solution, achieving the corrosion inhibition efficiency of 90.6 % at the concentration of 75 mg/L. Characterization results implied that the PTCNT adsorbed onto the surface of the mild steel, forming a protective shielding layer. Potentiodynamic polarization measurements proved that the PTCNT functioned as the hybrid corrosion inhibitor. Furthermore, the adsorption of PTCNT on the mild steel surface was investigated using adsorption isotherm and adsorption kinetic modeling. Quantum chemical calculations were used to elucidate the adsorption mechanism of PTCNT. These findings raise new avenues for the development of highly efficient corrosion inhibitors for the mild steel in HCl solutions.

Ginsenoside Rk3 Treats Corneal Injury Through the HMGB1/TLR4/NF-κB Pathway.

The cornea serves as a vital protective shield for the eye, safeguarding its intricate internal structures from external threats. Damage to the cornea compromises this protective function, triggering inflammation and potentially causing long-term harm. While ginsenoside Rk3 has demonstrated potential for repairing the corneal barrier and reducing inflammation, its effectiveness in treating corneal damage remains relatively unexplored. This comprehensive study uses both in vivo and in vitro models to investigate the therapeutic capabilities of ginsenoside Rk3. Using two models of corneal damage, a benzalkonium chloride-induced mouse model and a high osmolarity-induced human corneal epithelial cell model, we scrutinized the effects of ginsenoside Rk3 treatment. Our results showed that ginsenoside Rk3-treated mice manifested reduced corneal damage and inflammation compared with their untreated counterparts. Furthermore, mice treated with ginsenoside Rk3 exhibited an organized arrangement of corneal cells and diminished stromal layer thickness, indicating reparative properties of ginsenoside Rk3. Additionally, ginsenoside Rk3 increased the expression of tight junction proteins, suppressed inflammatory factors, and decreased HMGB1 protein expression, thereby modulating downstream signaling pathways. Collectively, our findings present compelling evidence that ginsenoside Rk3 is a promising therapeutic option for corneal injury. By repairing the corneal barrier, mitigating inflammation, and modulating specific protein levels, ginsenoside Rk3 opens new avenues for managing corneal damage.

Long-term corrosion protection of reinforcing bars via a self-responsive coating incorporating ZrP functional fillers

The conventional coating of reinforcing bars exhibits inadequate anti-corrosion efficacy stemming from a non-specific, blind protection mechanism, poses a threat to the durability of concrete. We devised a novel self-responsive functional filler, L-arginine (LA) intercalated zirconium phosphate (LCZrP), synthesized via an intercalation reaction. This innovative filler was seamlessly integrated into an epoxy (EP) resin matrix, yielding a smart anticorrosive coating that harmoniously combines active and passive corrosion protection strategies. The integration of LCZrP within the coating matrix serves a trifecta of purposes: it extends the corrosion propagation path, effectively disperses nanofiller agglomeration, and enhances interfacial adhesion with the epoxy coating. Critically, the controlled release of corrosion inhibitors from the interlayer further fortifies the coating's resistance to corrosion, imparting a multi-layered protective shield. After enduring a 60-day immersion in a simulated concrete pore solution, the LCZrP/EP coating demonstrated exceptional durability, maintaining a low-frequency impedance modulus value consistently within the range of 4.27×1010 to 5.12×1010 Ω·cm2, marking a remarkable 34-fold enhancement over the performance of the epoxy coating alone. This breakthrough underscores the LCZrP/EP coating's potential as a groundbreaking solution for reinforcing bar protection in concrete, harnessing the complementary strengths of epoxy resin's physical barrier, the impermeability of two-dimensional lamellar structures, and the proactive release of corrosion inhibitors to forge a robust, multi-faceted passivation layer.

Fabrication of polymeric shields to attenuation ionizing radiation and a flame retardant supported by nano-bismuth oxide prepared by co-deposition

The results of the preparation of protective shields from ionizing radiation, flame retardant from pure epoxy supported by nano-bismuth oxide, show that the protective shields supported by nanoparticles improve the attenuation properties, the thermal stability, the flame retardancy and mechanical properties. Also, the polymeric shield supported by Bi2O3 (Na2CO3) retardant the flame much better than supported by Bi2O3 (NaOH). Finally, the quality of the protective shields increased as the energy of the photons of the ionizing rays decreased.

Shape of fragments cloud behind heterogeneous screen by a space debris particle impact

Technogenic pollution of near-Earth space poses a threat to the functioning of spacecraft. Collisions between space debris (SD) and spacecraft (SC) structures can have catastrophic consequences or cause localized damage, leading to the loss of SC operability or the failure of certain functions. The SC body must effectively protect the internal equipment from various external impacts, be technologically feasible to manufacture, and have as little mass as possible. As a result, the task of designing spacecraft bodies and protective screens for low-orbit SC is particularly relevant due to the large concentration of SD in low Earth orbits.A comparative numerical study was conducted to evaluate the effectiveness of various thin shields in protecting against impacts from space debris particles. The study examined homogeneous shields made of A356 aluminum alloy and 316L stainless steel, as well as volumetrically reinforced composite shields produced using additive manufacturing with steel inclusions, and shields with a gradient distribution of steel throughout the thickness of an aluminum matrix, all with the same areal density. In all the heterogeneous plates considered, the volumetric concentration of steel was 36 %. The study covered an interaction velocity range of 2–9 km/s. Numerical modeling results indicated that the structure of the thin heterogeneous plate does not affect the shape of the debris cloud formed behind the protective shield. The findings of this study can serve as a basis for selecting materials for the development of more effective protection for spacecraft against high-velocity impacts.

Adding barium sulfate (BaSO4) to fly ash geopolymer increases its compressive strength as X-ray shielding for medical imaging applications

BackgroundGeopolymers, a novel cementitious material, have the potential for reducing carbon dioxide wastes resulting from the manufacture of cement. PurposeThis study presents an experimental inquiry conducted to produce a fly ash geopolymer mortar with a good of compressive strength of the batch. MethodsActivation of the mortar is accomplished through the use of sodium hydroxide and sodium silicate. The mortar is created from a mixture of fly ash and sand. In order to determine the maximum load that a material is capable of bearing before experiencing failure, the compressive strength test was utilized. ResultsAccording on the findings of the compressive strength testing device, the fly ash geopolymer with 15 % barium sulfate (BaSO4) demonstrates the highest compressive strength, which is measured at 56 MPa. When compared to the results obtained from cement mortar, this one is twice as high, which indicates that the strength improvement factor is 2. This study's findings highlighted the necessity of employing fly ash geopolymer that contains 15 % BaSO4 for the purpose of providing shielding protection. Conclusion: Therefore, in terms of its performance, fly ash geopolymer is superior to cement mortar. This is due to the fact that it is manufactured with a high compressive strength.

L-lysine enhances pork color through antioxidant activity and myoglobin conformational changes

This study aimed to investigate the effect of L-lysine (Lys) on the color of pork and reveal the possible mechanism. The results showed that the L* and a* values increased from 53.69 to 56.32, 56.39, and 56.47, and from 12.93 to 13.21, 13.24, and 13.52 with the addition of 0.1 %, 0.15 % and 0.2 % Lys, respectively. Meanwhile, the oxymyoglobin (Fe2+) levels increased from 21.14 % to 22.63 %, 23.83 %, and 23.53 %, while the metmyoglobin (Fe3+) levels decreased from 44.69 % to 40.28 %, 41.21 %, and 41.63 % with the addition of 0.1 %, 0.15 % and 0.2 % Lys, respectively. Additionally, the addition of Lys increased total sulfhydryl and active sulfhydryl contents, and decreased the levels of reactive oxygen species (ROS) (P<0.05). The particle size and the absolute value of the ζ-potential increased with the addition of Lys, reaching maximum values of 534.39 nm and −13.73 mV, respectively. The molecular dynamics results suggested that Lys can bind to myoglobin (Mb) through hydrophobic interactions and hydrogen bonds, forming a stable Lys-Mb complex, acting as a protective shield to prevent the entry of ROS and other oxidizing agents. Finally, the addition of 0.15 % Lys resulted in the highest surface hydrophobicity, which was 5.79 μg. The multispectral results indicated that Lys primarily induces changes in the secondary and tertiary structures of Mb through interactions with tyrosine residues. These changes stabilized the free-moving rings within the amino acid residues of Mb, thereby improving the structural stability of Mb and ultimately enhancing the color stability of pork. In summary, Lys improved meat color stability through a dual mechanism of antioxidation and interaction with Mb to alter its conformational stability.

Hypervelocity impact against aluminium Whipple shields in the shatter regime with systematic parameter variation: An experimental and numerical study

Aluminium Whipple shields are commonly used to protect spacecraft against hypervelocity impacts (HVIs) from orbital debris and micrometeoroids. Since numerical models nowadays are vital in the design process of protective shields, experimental studies of HVI are important to ensure that the numerical methods are robust and capable of accurately describing a range of impact conditions and material responses. The shatter regime is the transition velocity range between ballistic impact and hypervelocity impact, typically defined from 3 to 7 km/s. In this region, the debris cloud generated by the impact transitions from a few large, solid fragments at the lower end of the velocity range, to a high number of smaller fragments and partial melting of the projectile at the higher velocities. In this study, an experimental campaign of 22 normal impacts of spherical AA1100 projectiles on AA6061-T6 Whipple shields is performed, where the impact velocity and bumper thickness are systematically varied to study the change in debris cloud characteristics and shield damage. Impact velocities from 2.6 to 5.0 km/s are investigated, combined with bumper thicknesses of 1.0, 1.5 and 2.0 mm. Analysis of the experimental results is conducted using high-speed camera footage of the debris clouds and post-impact analysis of bumpers and rear walls. A numerical model is then established using the Smoothed Particle Hydrodynamics (SPH) method in the IMPETUS Solver, and the numerical results are compared to the experimental data. The simulations are able to capture the main trends found in the experimental study, and show a similar level of damage as the experiments when varying the impact velocity and bumper thickness. The simulations have somewhat smaller fragments generated in the debris cloud than in the experiments, leading to slightly less damage inflicted on the rear wall.

Dentist's perception and usage of Personal Protective Equipment –A Cross sectional survey

Introduction: Personal protective equipment (PPE) refers to protective clothing, helmets, gloves, face shields, goggles, facemasks and/or respirators or other equipment designed to protect the wearer from injury or the spread of infection or illness. The usage of PPE among health care professionals is increased after Covid 19. Dentists poses high risks to infection due to largernumber of droplets generated during dental procedures. The perception and the usage of Personal Protective Equipment among the dentists may not be same. Hence an online cross-sectional questionnaire survey was conducted among the dentists on perception and usage of Personal Protective Equipment. Materials and methods: A cross sectional only survey using 20closed-ended questionnaire was conducted to assess the perception and usage of Personal Protective Equipment among dentists. A total of 388 dentists were included in the survey. The study subjects were classified into 3 groups. Group A-Practitioner alone (in Clinic/Hospital), Group B-Academician (Working in academic institution alone without practice) and Group C- Both (clinician and academician). Results: Most of the dental practitioners who are affiliated to dental colleges as well as having or working in clinician (Group C) had received formal training or demonstration regarding donning and doffing of PPE compared to individual practitioners or academician (Group A and B) and it is statistically significant (P&lt;0.05) and many private practitioner’s faced shortage of PPE compared to academician and both (Private practitioners and academician) which is statistically significant (P&lt;0.05) Conclusion: Compared to Group A and B academician and clinician individually dental professionals who are working as both academician and clinician (Group C) have better perception and know the proper usage of PPE which might be because of the exposure in both college and clinical setup.

Advanced Electrospun Composites Based on Polycaprolactone Fibers Loaded with Micronized Tungsten Powders for Radiation Shielding.

Exposure to high levels of radiation can cause acute, long-term health effects, such as acute radiation syndrome, cancer, and cardiovascular disease. This is an important occupational hazard in different fields, such as the aerospace and healthcare industry, as well as a crucial burden to overcome to boost space applications and exploration. Protective bulky equipment made of heavy metals is not suitable for many advanced purporses, such as mobile devices, wearable shields, and manned spacecrafts. In the latter case, the in-space manufacturing of protective shields is highly desirable and remains an unmet need. Composites made of polymers and high atomic number fillers are potential means for radiation protection due to their low weight, good flexibility, and good processability. In the present work, we developed electrospun composites based on polycaprolactone (polymer matrix) and tungsten powder for application as shielding materials. Electrospinning is a versatile technology that is easily scalable at an industrial level and allows obtaining very lightweight, flexible sheet materials for wearables. By controlling tungsten powder size, we engineered homogeneous, stable and processable suspensions to fabricate radiation composite shielding sheets. The shielding capability was assessed by an in vivo model on prototype composite sheets containing 80 w% of W filler in a polycaprolactone (PCL) fibrous matrix by means of irradiation tests (X-rays) on mice. The obtained results are promising; as expected, the shielding effectivity of the developed composite material increases with the thickness/number of stacked layers. It is worth noting that a thin barrier consisting of 24 layers of the innovative shielding material reduces the extent of apoptosis by 1.5 times compared to the non-shielded mice.

Awareness of ocular hazards among welders in Bindura, Zimbabwe

Occupational health issues are the highest among workers in developing nations. This study aimed to assess the awareness of ocular hazards among welders in Bindura. An observational cross-sectional design with a validated structured self-administered questionnaire was used to assess the awareness of ocular hazards among 400 welders. Among the 400 welders, 397(99.3%) were males and their ages ranged from 19 – 56 with a mean age of 36 ± 8 years. Most (35%) of them, 140 had been involved in welding for 6-10 years. The most common type of welding among the participants was arc welding (87.8%). Majority (99.3%) of the welders were aware that welding without the use of protective equipment is a potential source of ocular hazards. Many welders had access to protective face shields and used them all the time (84.5%). The most common condition was ocular foreign bodies (17.7%), followed by Arc eye (4.8%). Awareness about welding as a source of ocular hazard depends on the type of welding used (p &lt; 0.05). The awareness of ocular hazards among welders in Bindura is high. Although, protective devices are provided, regular utilization needs to be encouraged and enforced.

Head and neck ice hockey injuries in children: an analysis of the NEISS database

ObjectiveOur objective was to describe non-concussion head and neck ice hockey injuries in children in the US. MethodsThis is a retrospective cohort study using data from the NEISS database. The NEISS database was reviewed from 2010 to 2021 for injuries in the head, neck, mouth, eye, and ear related to ice hockey in children 1–18 years old. Records where the only injury was a concussion or internal head injury were removed. Frequencies were calculated and chi-squared tests were performed. Results475 children were included, with mean age of 13.1 years old (95 % CI 12.7–13.4), and 426 (89.7 %) were male. Females were significantly younger with mean age 11.8 years versus 13.2 years for males (t = −2.4, df = 473, p = .018). 110 (23.2 %) injuries were related to hockey sticks, 92 (19.4 %) involved a fall, and 32 (6.7 %) were subsequent to body checking. 301 of the injuries (63.4 %) were lacerations, 71 (14.9 %) contusions or abrasions, and 26 (5.5 %) strains and sprains. The type of injury varied according to head and neck region (p < .001). 231 (82.8 %) of facial injuries, 16 (76.2 %) of ear injuries, and 33 (62.3 %) of oral injuries were lacerations. Eight (1.7 %) patients were admitted or observed overnight, while the rest were discharged home. ConclusionFemale ice hockey players sustain injuries at younger ages than males, which may reflect the loss of older girls from the sport. In older boys, injury rates may reflect the loss of mandated full face protective shields.

Numerical study on structured sandwich panels exposed to spherical air explosions

There is a need to develop innovative protective shield structures to withstand extreme loads, such as impact and blast loading. Sandwich structures that absorb significant kinetic energy as strain energy through plastic deformation offer superior protection. This study conducts a numerical analysis of structured sandwich protective structures subjected to airblast loads using finite element modeling. First, an experimental result from the literature was used to validate and verify finite element models of an architected sandwich structure modeled in Abaqus/Explicit software. Second, parametric studies were conducted on sandwich structures with additional layers of insert plates and newly proposed core topologies for viable shield protection against airblast loading. The finite element analysis results indicated that, under the same impulsive load, the control sandwich panel exhibited higher kinetic energy, demanding a proportionally larger internal energy. Conversely, sandwich structures with additional inner core insert plates dissipated the imposed kinetic energy more efficiently, due to the inelastic plastic deformation of the proposed core configurations. Moreover, the energy absorption capacity and back sheet displacement time-history were significantly improved by dense-hierarchical inner core configurations. Additionally, the parametric study analysis showed that increasing the number of insert plates and designing the core topology of cellular walls to be redundant, dense-hierarchical, and braced against buckling significantly reduced core collapse mechanisms such as folding, buckling, and crushing. However, despite these benefits, a reversed effect on the areal specific energy absorption index was observed.

Sarcoidosis and Cancer: The Role of the Granulomatous Reaction as a Double-Edged Sword.

Background/Objectives: The relationship between sarcoidosis and the occurrence of neoplasia deserves to be investigated, but this relation has been observed in different and heterogeneous populations, leading to conflicting data. To clarify the causal relationship between these two diseases, different risk factors (e.g., smoking), concurrent comorbidities, corticosteroid therapy, and metastasis development-as an expression of cancer aggressiveness-were investigated. Methods: In a retrospective study on 287 sarcoidosis outpatients at the Pneumological Department of the Gemelli Foundation (Rome, Italy) between 2000 and 2024, the diagnosis of cancer was recorded in 36 subjects (12.5%). Results: The reciprocal timeline of the diseases showed three different scenarios: (1) cancer preceding sarcoidosis or sarcoid-like reactions (63.8%); (2) cancer arising after sarcoidosis diagnosis (8.3%); and (3) sarcoidosis accompanying the onset of malignancy (27.8%). Only two subjects with sarcoidosis and cancer showed metastasis, and one of them was affected by lymphoma. Conclusions: These data suggest that granulomatous inflammation due to sarcoidosis may assume an ambivalent role as a "double-edged sword", according to the M1/M2 macrophage polarization model: it represents a protective shield, preventing the formation of metastasis through the induction of immune surveillance against cancer while, on the other hand, it can be a risk factor for carcinogenesis due to the persistence of a chronic active inflammatory status. Low-dose steroid treatment was administered in only 31.6% of the cancer-sarcoidosis subjects for less than six months to control inflammation activity, with no promotive effect on carcinogenesis observed.

Blood-Brain-Barrier (BBB) Targeting Nanoparticulate Drug Delivery Modules to Treat Cerebrovascular Disorders: Current State of the Art

Blood Brain Barrier (BBB) provides a protective shield for the human nervous system, facilitating essential biochemical processes while also acting as a strong defense mechanism against pathogens and harmful substances, including drugs. While this barrier protects the brain, it makes it difficult to deliver therapeutics to treat cerebral diseases such as ischemia and acute arterial thrombosis, both of which cause significant global mortality and morbidity. The urgent need for thrombolytic agents to treat cerebral ischemia emphasizes the importance of drugs that can efficiently penetrate the BBB. However, conventional thrombolytics have limitations due to low BBB permeability. To overcome this barrier, various nanoparticle-based targeting strategies have been developed. These nano-technological solutions provide advantages such as enhanced permeability, decreased toxicity risks, and increased bioavailability when compared to other drug delivery methods.

Conjugated diamine cation based halide perovskitoid enables robust stability and high photodetector performance

Low-dimensional lead halide materials have proved to be intrinsically stable semiconductor materials. However, the development of one-dimensional (1D) perovskites or perovskitoids with both robust water stability and high optoelectronic performance still faces significant challenges. Here, we report a new class of 1D (TzBIPY)Pb2X6 (X = Cl, Br, I) perovskitoids featuring a π-conjugated diamine cation (TzBIPY = 2,5-di(pyridin-4-yl)thiazolo[5,4-d]thiazole). The TzBIPY2+ cation with delocalized electrons directly contributes to the electronic structure and hence reduces the band gap. Especially, the Br-based material exhibits enhanced carrier separation and transport capacity, benefiting from the improved electronic conjugation together with a type II intramolecular heterojunction between conjugated organic cations and Pb–X octahedra. The (TzBIPY)Pb2Br6 photodetector exhibits an impressive photocurrent on/off ratio of 8.1 × 105, which is much superior to the previous three-dimensional (3D) perovskite benchmark. Additionally, the π-conjugated cations serve as dense protective shields for vulnerable Pb–X inorganic lattice against being attacked by water, thus demonstrating exceptional stability even immersed in water for over 3000 h.