Lignin, an industrial by-product that is abundant, renewable and has aromatic ring characteristics, is regarded as an ideal raw material for the synthesis of two-dimensional graphene materials. However, the sustainable development of graphene produced from lignin faces thorny challenges such as environmental pollution, low yield, cumbersome steps and harsh conditions. In this study, low-energy, green, large-scale one-step preparation of sulfur-doped graphene was achieved by co-blending lignin and sodium alginate into a fully biomass-based film, followed by easy-to-operate laser etching. Among them, alkaline lignin not only served as a carbon source but also acted as a sulfur doping source, avoiding the use of additional sulfur doping reagents. The results showed that the sheet resistance of graphene gradually decreased with the increase of laser power. The sheet resistance of graphene prepared when the laser power was 90% was as low as 8 Ω sq−1, which provided an inherent advantage for the subsequent assembly of flexible micro-supercapacitors. The specific capacitance and high energy density of the resulting supercapacitor were as high as 88.29 mF cm−2 and 12.26 μW h cm−2, respectively. This method successfully developed a sustainable and low-energy graphene preparation method, paving the way for the sustainable development of flexible energy storage devices.
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