Vadose Research Articles

Elucidating biogeochemical characterization of nitrogen in the vadose zone integrating geochemistry, microorganism, and numerical simulation

A thorough comprehension of nitrogen biogeochemical processes in the vadose zone is crucial for the effective prevention and remediation of soil-groundwater system contamination. Despite the growing research on this subject, the full scope of nitrogen biogeochemical characterization in different geological environments remains poorly understood. This study addresses this knowledge gap by integrating geochemical, microbiological and numerical simulation approaches to gain a deeper insight into nitrogen biogeochemistry in agriculture. Our findings indicate the biogeochemical behavior of nitrogen in the vadose zone is mediated by microorganisms, driven by hydraulics, influenced by geological conditions and environmental factors. Along the groundwater flow, NH4+-N was found to be heavily accumulated in the topsoil of 0–40 cm, while NO3−-N was transported and driven by hydrodynamics from both vertical and horizontal directions. Microbial diversity, species composition and functional microorganisms were significantly influenced by soil depth, rather than geomorphological types. Oxidation-reduction potential (ORP), total organic carbon (TOC), soil moisture (MOI), bicarbonate (HCO3−), and ferrous (Fe2+) were identified as the principal environmental factors that regulate nitrogen metabolism and the dominant biochemical processes, encompassing nitrogen fixation, nitrification, and denitrification. Driven by hydrodynamics, NH4+-N, NO2−-N and NO3−-N tend to form distinct biochemical reaction zones in the vertical vadose zone. These areas are dynamic and subject to geomorphologies. It should be noted that NO3−-N can migrate towards groundwater from the clayey sand in the Alluvial Plain, which presents a potential risk of groundwater contamination. The fissure structure of loess may serve as the major transport pathway for groundwater nitrogen contamination in the Loess Tableland. This finding highlights the importance of integrating microbiology, geochemistry and hydraulics to elucidate the biogeochemical processes of nitrogen in the vadose zone with a dynamic mindset.

Mapping the Future: Revealing Habitat Preferences and Patterns of the Endangered Chilean Dolphin in Seno Skyring, Patagonia.

Species distribution modeling helps understand how environmental factors influence species distribution, creating profiles to predict presence in unexplored areas and assess ecological impacts. This study examined the habitat use and population ecology of the Chilean dolphin in Seno Skyring, Chilean Patagonia. We used three models-random forest (RF), generalized linear model (GLM), and artificial neural network (ANN)-to predict dolphin distribution based on environmental and biotic data like water temperature, salinity, and fish farm density. Our research has determined that the RF model is the most precise tool for predicting the habitat preferences of Chilean dolphins. The results indicate that these dolphins are primarily located within six kilometers of the coast, strongly correlating with areas featuring numerous fish farms, sheltered waters close to the shore with river inputs, and shallow productive zones. This suggests a potential association between dolphin presence and fish-farming activities. These findings can guide targeted conservation measures, such as regulating fish-farming practices and protecting vital coastal areas to improve the survival prospects of the Chilean dolphin. Given the extensive fish-farming industry in Chile, this research highlights the need for greater knowledge and comprehensive conservation efforts to ensure the species' long-term survival. By understanding and mitigating the impacts of fish farming and other human activities, we can better protect the habitat and well-being of Chilean dolphins.

Understanding Salinity Intrusion and Residence Times in a Small-Scale Bar-Built Estuary under Drought Scenarios: The Maipo River Estuary, Central Chile

The Maipo River estuary is a low-inflow bar-built estuary that includes a protected wetland, which harbors a rich ecosystem. The estuary and wetland have been threatened by a persistent drought for more than a decade, which has resulted in greater salinity intrusion and increased residence times. Previous studies have described salinity and pollutants in estuaries; however, almost all have focused on deeper and/or wider estuaries with dimensions much larger than those of the small-scale Maipo River estuary. In this study, we used the numerical model FVCOM to simulate the dynamics of the Maipo River estuary under drought scenarios and explored the interactions between river discharge and tides in terms of saline intrusion and particle dispersal. The model was validated against observations collected during a field campaign near the river mouth. The simulations successfully reproduced the water surface elevation but underestimated salinity values, such that the vertical salinity structure observed in the field was not captured by the model in this shallow and morphologically complex estuary. Consequently, our model results provide qualitative insight related to salinity and baroclinic dynamics. Results of maximum saline intrusion showed an exponential decay with increasing river discharge, and the analysis of salinity intrusion time series revealed that droughts may cause permanent non-zero salinity levels in the estuary, potentially affecting ecological cycles. The incorporation of passive tracers showed that decreasing river discharge increases the residence time of particles by allowing the tracers to re-enter the estuary. Model results showed the formation of accumulation zones (hotspots) in the shallower zones of the estuary.

Vapor-phase transport of per and polyfluoroalkyl substances: Processes, modeling, and implications

An increasing number of studies have demonstrated the presence of per and polyfluoroalkyl substances (PFAS) in the vapor phase. It is therefore important to consider the potential for vapor-phase transport of PFAS in soil and the vadose zone and to investigate the processes impacting the retention and transport of volatile PFAS in soil. It is also critically important to evaluate existing models and develop new models as needed for their application to PFAS vapor-phase transport. The objectives of the present work were to provide an overview of vapor-phase transport processes and modeling, with a specific focus on their relevance for PFAS, and to discuss implications for mass discharge to groundwater, vapor intrusion, and soil vapor extraction. Decades of research have been devoted to the retention and transport of legacy volatile organic contaminants in the vadose zone. This work provides an abundant source of information concerning the many factors and processes of relevance, and insights into the development and application of mathematical modeling. However, given the unique properties of PFAS, there is a need to conduct research to investigate vapor-phase transport of PFAS and to develop PFAS-specific models. We highlight with illustrative examples that vapor-phase transport can be significantly more rapid than aqueous-phase advective transport, which can result in enhanced mass discharge to groundwater.

Aquifer vulnerability valorization via DRASTIC index-based assessment within litho-facies of a coastal environment

Determining the degree of an aquifer’s susceptibility to pollutants is an important tool for policy planning in subterranean water administration and conservation. In this work, subterranean water vulnerability was appraised with the use of DRASTIC methodology, which employs seven parameters: depth to groundwater (D); net groundwater recharge (R); aquifer media (A); soil media (S); topography (T); influence of vadose zone (I); and hydraulic conductivity (C). Different ratings were given to each parameter based on the hydro-geological and geo-electrical information obtained from the study area. Geo-electrostratigraphic data was acquired with vertical electrical soundings and electrical resistivity tomography surveys. The results demonstrated the existence of geoelectrical layers with variable resistivities ranging from high to low, with variable curve types. Longitudinal conductance measures indicated moderate subterranean water protective capacity. Analysis of DRASTIC vulnerability indices showed that the aquifer indicated moderate to high vulnerability to contamination. Vulnerability maps were generated to indicate locations of high vulnerability, the goal being to prevent indiscriminate haphazard and wildcat abstraction of groundwater in such locations. The quality category index (QCI) generated for the DRASTIC model indicated that underground water susceptivity is dependent on all 7 parameters employed in the model, with the most critical determinants being the depth to aquifer (D), net recharge (R), aquifer media (A), and impact of the vadose zone (I). The work recommends that anthropogenic activities that could contaminate groundwater resource be halted as the resource is indicated by DRASTIC models as being vulnerable.

Early Warning of Regional Groundwater Pollution： A Case Study for Plain Area of Barkol-Yiwu Basin

Groundwater pollution early warning is an effective means for regional groundwater pollution prevention. The groundwater pollution early warning model coupled with the current situation of groundwater quality, groundwater quality variation trend, and groundwater pollution risk were applied to the plain area of Barkol-Yiwu Basin, and the regional scale groundwater pollution early warning was realized by combining the early warning of groundwater quality status and trend. The TOPSIS method based on comprehensive weight was used to evaluate the current situation of groundwater quality. The variation trend of groundwater quality was analyzed by calculating the trend interpolation results of 18 in-situ groundwater quality monitoring wells. The groundwater vulnerability map, groundwater pollution load map, and groundwater function value map were superimposed using the superposition index method to evaluate groundwater pollution risk. The results showed that the groundwater quality was good and relatively good, and the poor groundwater quality in some areas was mainly affected by the shallow groundwater depth and the large porosity of the vadose zone. Groundwater quality was stable from 2011 to 2022, mainly due to the leakage of wastewater generated by industries and agriculture into groundwater, resulting in the deterioration of groundwater quality in some areas. Groundwater pollution risk was generally low, and the dual effects of high vulnerability and high pollution load of groundwater led to local areas with high pollution risk. The early warning level of groundwater pollution was generally low, and the heavy and highly heavy warning areas accounted for 16.4% and 17.5% of the study area, respectively, mainly distributed in Xiamaya Township of Yiwu County and northern Santanghu Town, Dahongliuxia Township, and Dahe Town of Barkol County. The quaternary sediments exposed were mainly sandy pebbles, with developed pores and strong water permeability. The interception and adsorption capacity of pollutants were weak. Pollutants produced by industries, agriculture, and life easily leaked into groundwater aquifers, resulting in poor groundwater quality and high risk of groundwater pollution, which ultimately led to a high early warning level of groundwater pollution in some areas. The research on early warning of groundwater pollution provided an important theoretical basis for the development of groundwater pollution remediation.

Geologic and Tectonic Controls on Deep Fracturing, Weathering, and Water Flow in the Central California Coast Range

AbstractThe creation of fractures in bedrock dictates water movement through the critical zone, controlling weathering, vadose zone water storage, and groundwater recharge. However, quantifying connections between fracturing, water flow, and chemical weathering remains challenging because of limited access to the deep critical zone. Here we overcome this challenge by coupling measurements from borehole drilling, groundwater monitoring, and seismic refraction surveys in the central California Coast Range. Our results show that the subsurface is highly fractured, which may be driven by the regional geologic and tectonic setting. The pervasively fractured rock facilitates infiltration of meteoric water down to a water table that aligns with oxidation in exhumed rock cores and is coincident with the adjacent intermittent first‐order stream channel. This work highlights the need to incorporate deep water flow and weathering due to pervasive fracturing into models of catchment water balances and critical zone weathering, especially in tectonically active landscapes.

Characteristics of the Fault Damage Zone From High‐Resolution Seismic Imaging Along the Palos Verdes Fault, California

AbstractThe distribution and intensity of fault damage zones provides insight into fault activity and its relationship to fluid flow in the crust. Presently, measures of the in‐situ distribution of fault damage remain limited and along‐strike studies are rare. This study focuses on an offshore section Palos Verdes Fault damage zone that spans 28 km, near Los Angeles, California. To investigate the previously unresolved shallow (∼400 m below the seafloor) fault damage zone we use densely spaced (∼500 m line separation) newly collected sparker multichannel seismic lines and sub‐bottom profiles. The combination of high‐resolution acquisition methods and specialized seismic processing workflows provide improved imaging of shallow faulting. We apply a multi‐trace similarity technique to identify discontinuities in the seismic data that may be attributed to faults and fractures. This fault detection approach reveals diverse fault damage patterns on adjacent seismic profiles. However, a discernible damage zone pattern emerges by stacking multiple damage detection profiles along strike. We find that peak damage identified in this way corresponds to the active main fault strand, confirmed in this study, and thus the technique may be useful for identifying active fault strands elsewhere. Additionally, we observe that the variable width of the damage zone along strike is controlled by fault obliquity. Furthermore, our observations reveal a correlation between fault damage and seafloor fluid seeps visible in the water column, suggesting that damage plays a role in controlling fluid flow around the fault.

A Statistical Approach for the Assessment of Saturated Hydraulic Conductivity Values of Unsaturated Urban Soils Obtained by Field Infiltration Tests

An evaluation and interpretation of the obtained results focusing the hydraulic conductivity of anthropogenic saturated soil, k, has been performed on an urban area vadose zone. Four methods have been used to quantify the hydraulic conductivity: the tube infiltrometer (TI), the double ring infiltrometer (DRI), the minidisk infiltrometer (MDI) and the inversed auger (IA). This study comprises (a) a comparative analysis of the results obtained by each method between several trials performed at the same location and at distinct locations within the plot, (b) a comparative analysis of the results of all methods, and (c) a statistical analysis regarding the correlation between k as a dependent variable and the infiltration area A as the main independent variable. To select the k values close or corresponding to the saturation state for TI and IA methods, a domain of validity was defined. A new parameter, k* = k/A, was introduced which represents the hydraulic conductivity corresponding to an infiltration surface unit (1 cm2). An increase in this ratio with the increase in the infiltration area, within the same method or between different methods, indicates the heterogeneity of the terrain but especially the fact that the infiltration area no longer represents the main independent variable on which the hydraulic conductivity depends for the saturated state.

Mapping and assessment of groundwater pollution risks in the main aquifer of the Mostaganem plateau (Northwest Algeria): utilizing the novel vulnerability index and decision tree model.

Water plays a pivotal role in socio-economic development in Algeria. However, the overexploitations of groundwater resources, water scarcity, and the proliferation of pollution sources (including industrial and urban effluents, untreated landfills, and chemical fertilizers, etc.) have resulted in substantial groundwater contamination. Preserving water irrigation quality has thus become a primary priority, capturing the attention of both scientists and local authorities. The current study introduces an innovative method to mapping contamination risks, integrating vulnerability assessments, land use patterns (as a sources of pollution), and groundwater overexploitation (represented by the waterhole density) through the implementation of a decision tree model. The resulting risk map illustrates the probability of contamination occurrence in the substantial aquifer on the plateau of Mostaganem. An agricultural region characterized by the intensive nutrients and pesticides use, the significant presence of septic tanks, widespread illegal dumping, and a technical landfill not compliant with environmental standards. The critical situation in the region is exacerbated by excessive groundwater pumping surpassing the aquifer's natural replenishment capacity (with 115 boreholes and 6345 operational wells), especially in a semi-arid climate featuring limited water resources and frequent drought. Vulnerability was evaluated using the DRFTID method, a derivative of the DRASTIC model, considering parameters such as depth to groundwater, recharge, fracture density, slope, nature of the unsaturated zone, and the drainage density. All these parameters are combined with analyses of inter-parameter relationship effects. The results show a spatial distribution into three risk levels (low, medium, and high), with 31.5% designated as high risk, and 56% as medium risk. The validation of this mapping relies on the assessment of physicochemical analyses in samples collected between 2010 and 2020. The results indicate elevated groundwater contamination levels in samples. Chloride exceeded acceptable levels by 100%, nitrate by 71%, calcium by 50%, and sodium by 42%. These elevated concentrations impact electrical conductivity, resulting in highly mineralized water attributed to anthropogenic agricultural pollution and septic tank discharges. High-risk zones align with areas exhibiting elevated nitrate and chloride concentrations. This model, deemed satisfactory, significantly enhances the sustainable management of water resources and irrigated land across various areas. In the long term, it would be beneficial to refine "vulnerability and risk" models by integrating detailed data on land use, groundwater exploitation, and hydrogeological and hydrochemical characteristics. This approach could improve vulnerability accuracy and pollution risk maps, particularly through detailed local data availability. It is also crucial that public authorities support these initiatives by adapting them to local geographical and climatic specificities on a regional and national scale. Finally, these studies have the potential to foster sustainable development at different geographical levels.

Computationally efficient Watershed-Scale hydrological Modeling: Integrating HYDRUS-1D and KINEROS2 for coupled Surface-Subsurface analysis

Watershed flow processes consist of partitioning, movement, storage, and redistribution of water fluxes in space and time. However, the integrated modeling of these processes is challenging due to computational burden, extensive data requirements, and/or reliance on simplifying assumptions. This study introduces a novel and computationally efficient modeling framework that leverages two state-of-the-art process-based models: HYDRUS-1D (H1D) for unsaturated flow and KINEROS2 (K2) for overland flow. The framework extends a hillslope-scale coupled H1D-K2 model to simulate watershed-scale processes, where H1D replaces the three-parameter Parlange’s infiltration equation in the event-based K2 model. Boundary condition switching is employed to account for surface ponding and water exchange between the two model domains. The structure of the coupled watershed-scale H1D-K2 model consists of a cascade of connected rectangular planes, channel elements, and 1D soil profiles to simulate 1D overland flow, infiltration, unsaturated zone flow, and recharge. Computational efficiency relative to HYDRUS-2D is achieved through a dynamic time-stepping approach and dimensionality reduction. The watershed scale model improved the computational time by 14.3% and 47% compared to the corresponding Hillslope scale H1D-K2 and HYDRUS-2D, respectively. The performance and efficiency of the new watershed model are demonstrated using benchmark watershed and/or hillslope simulations. Calibrated hydrographs and water balance components using Walnut Gulch Experimental Watershed data, showed excellent agreement with observed data with a Nash-Sutcliffe coefficient (NSC) greator than 0.8 and Pearson correlation coefficient (R2) greater than 0.92.

Geospatial based groundwater resources susceptibility and contamination risk mapping for Yeşilköy aquifer, Cyprus

In rural areas where the goals of sustainable agriculture are intertwined with the availability and supply of groundwater resources, it becomes imperative to perceive and search the status of groundwater resource’s susceptibility to contamination. A well-known overlay & index method, the DRASTIC model that assesses the state of susceptibility to contamination using vulnerability index map has been applied to the Yeşilköy aquifer. The seven different hydro-geologic parameters; aquifer media, vadose zone, and soil media, surface topography, recharge capacity, water table depth, and the hydraulic conductivity maps were overlaid to find the vulnerability of the aquifer. Results depicted that the aquifer is categorized into two vulnerability zones; low and moderate. The available susceptibility of the aquifer due to ongoing anthropogenic activities like agriculture was also studied by implementing the Weighted Arithmetic Water Quality Index (WQI) method. The aquifer’s overall water quality was “poor water quality”. Hence, there was no significant relationship between WQI and the vulnerability of the aquifer. A modification of the DRASTIC to enhance the relationship with WQI is proposed by utilizing the Analytic Hierarchy Process (AHP), as one of the successful multi-criteria decision-making models. The modification of the DRASTIC model with AHP revealed that the performance of the DRASTIC model was improved and the correlation between WQI and the DRASTIC vulnerability index was significantly enhanced. The results also show that the effective contributing parameters for groundwater vulnerability in the Yeşilköy aquifer were the aquifer media and the vadose zone. On the other hand, the water table’s depth and topography were almost independent of the aquifer’s vulnerability.

Internal heat source in the vadose zone: A comprehensive exploration through theoretical spectral analysis and practical application into thermal diffusivity and hydraulic flux in a Quaternary soil water layer

AbstractThis groundbreaking study introduces a scientifically robust method for assessing internal heat generation in shallow, unsaturated aquifers, highlighting the intricate interplay between internal heat, thermal diffusivity, and hydraulic flux. The research pioneers a novel approach employing time‐frequency spectral analysis to address challenges posed by conventional methods that rely solely on prescribed thermal diffusivity and hydraulic flux for evaluating internal heat over time. Rooted in a solid theoretical framework supported by meticulous temperature and heat flux observations, the method adeptly incorporates the concept of an unknown internal heat. The study systematically explores three distinct boundary conditions, showcasing versatility: one with fixed temperatures at the inlet and outlet, another with known temperature at the inlet and no heat flux at the outlet, and a third with a prescribed inlet temperature and constrained outlet heat flux. The estimation of internal heat, coupled with prescribed thermal diffusivity and hydraulic flux, harnesses in‐situ temperature and heat flux spectra through an innovative inverse stochastic spectral approach. A notable feature of this research lies in its ability to strategically handle various parameters, including prescribed thermal diffusivity, hydraulic flux, variations in target depth, significant frequency components, and boundary conditions. The variation assessment findings emphasize the diverse range when predicting internal heat generation based on prescribed thermal diffusivity and hydraulic flux. This study facilitates the determination of potential internal heat magnitudes at different depths and provides profound insights into in‐situ conditions within the vadose zone.

Hydrology Outweighs Temperature in Driving Production and Export of Dissolved Carbon in a Snowy Mountain Catchment

AbstractTerrestrial production and export of dissolved organic and inorganic carbon (DOC and DIC) to streams depends on water flow and biogeochemical processes in and beneath soils. Yet, understanding of these processes in a rapidly changing climate is limited. Using the watershed‐scale reactive‐transport model BioRT‐HBV and stream data from a snow‐dominated catchment in the Rockies, we show deeper groundwater flow averaged about 20% of annual discharge, rising to ∼35% in drier years. DOC and DIC production and export peaked during snowmelt and wet years, driven more by hydrology than temperature. DOC was primarily produced in shallow soils (1.94 ± 1.45 gC/m2/year), stored via sorption, and flushed out during snowmelt. Some DOC was recharged to and further consumed in the deeper subsurface via respiration (−0.27 ± 0.02 gC/m2/year), therefore reducing concentrations in deeper groundwater and stream DOC concentrations at low discharge. Consequently, DOC was primarily exported from the shallow zone (1.62 ± 0.96 gC/m2/year, compared to 0.12 ± 0.02 gC/m2/year from the deeper zone). DIC was produced in both zones but at higher rates in shallow soils (1.34 ± 1.00 gC/m2/year) than in the deep subsurface (0.36 ± 0.02 gC/m2/year). Deep respiration elevated DIC concentrations in the deep zone and stream DIC concentrations at low discharge. In other words, deep respiration is responsible for the commonly‐observed increasing DOC concentrations (flushing) and decreasing DIC concentrations (dilution) with increasing discharge. DIC export from the shallow zone was ~66% of annual export but can drop to ∼53% in drier years. Numerical experiments suggest lower carbon production and export in a warmer, drier future, and a higher proportion from deeper flow and respiration processes. These results underscore the often‐overlooked but growing importance of deeper processes in a warming climate.

A historical overview of experimental hydrology in China

AbstractThe history of experimental hydrology in China is important but poorly documented. Here we review 94 papers (86 of these in Chinese) from the CNKI and Web of Science websites to chronicle the history of experimental studies in China before 2000. Professor Wei‐Zu Gu—the focus of this Special Issue—factors heavily into this history. Perhaps more than any country, the experimental hydrology history of China is influenced by socioeconomic development and political change. Our analysis shows 4 main periods of development associated with (1) an early development stage before 1949, the founding year of People's Republic of China (PRC), (2) an initial period of rapid transition in experimental studies in China (1949–1965), (3) a struggling and recovering stage for during and shortly after the Cultural Revolution, from 1965 to 1978, and (4) significant progress associated with new policies for reform and opening up in China from 1978 to 2000, that included contributions of Wei‐Zu Gu and other scientists. In terms of experimental hydrological findings, two notable contributions are a mathematical description of saturation overland flow derived from streamflow and precipitation data and calculated water storage deficit in the unsaturated zone by Zhao and Zhuang (1963), several years before its process‐based ‘discovery’ in the USA (and elsewhere) and the ‘interface runoff generation law’ of Yu (1985) which was ahead of its time in understanding linking the notion of the commonality of all runoff forms. In terms of model development stemming from experimental studies, the development of the Xinanjiang Model of Zhao (1980) was a significant achievement, later partly adopted into the VIC model in the USA and the ARNO model in Europe. Finally, the Hydrohill catchment developed by Wei‐Zu Gu led the way for the rapid rise in process studies and internationalization of experimental hydrology in China. Overall, the experimental hydrological studies from 1949 to 2000 had a strong engineering focus, with many links to water conservation construction and management.

Dual clumped isotopes (Δ47 and Δ48) reveal non-equilibrium formation of freshwater cements

Low-Mg calcite, precipitating from meteoric fluids, is a common mineral that forms in a variety of near-surface diagenetic environments. However, recent studies, based on a combination of analyses of δ18O and Δ47 values, have suggested that this mineral might form in disequilibrium and consequently yield kinetic bias in Δ47-derived temperatures and fluid δ18O values. Here, we use dual clumped isotope proxies (Δ47 and Δ48) to investigate the influence of kinetic isotope effects within different meteoric diagenetic zones of Holocene and Pleistocene carbonates from the southern Florida and the Dominican Republic. In the Miami Oolite, the primary aragonite ooids and secondary low-Mg calcite cements in the bulk sample were separated from each other and their isotopic compositions (δ13C, δ18O, Δ47 and Δ48 values) were measured. The Δ47 and Δ48 values of the separated aragonite are consistent with the modern ooid sediments and in approximate equilibrium with the surface seawater. In contrast, the low-Mg calcite cement shows the higher Δ48 and lower Δ47 values, than expected, with the disequilibrium arising as a result of CO2 degassing in the vadose zone. Such deviations of Δ47 and Δ48 values are also observed in low-Mg calcite vadose cements in the Dominican Republic. While low-Mg calcites formed in the lower freshwater phreatic zone in the Dominican Republic have the Δ47- and Δ48-derived temperatures close to expected, the same mineral forming near the water-table and upper phreatic zone shows much higher Δ48-derived temperatures (up to ∼ 90 °C). The possible origin of such elevated temperatures can be attributed to non-equilibrium processes caused by changes in pH and pCO2, mediated by microbial sulfate reduction. Such differential kinetic behavior of Δ48 values between vadose and phreatic zones could be used as a proxy marker for the presence and the location of a water-table. This study demonstrates the great potential of dual clumped isotopes in the investigation of meteoric diagenesis and will help understand the alteration of ancient sequences and the interpretation of stable C isotope trends that they contain.

Quantifying the Impacts of Density-Dependent Flow on Surface Water–Groundwater Interaction in a Riparian Setup

Surface Water–Groundwater (SW–GW) interaction is a crucial aspect of the hydrological cycle and requires accurate modeling for reliable predictions. In many basic hydrological models and calculations, it is common to assume that the water density is constant. However, density-dependent flow, which accounts for changes in water density, plays a significant role in various hydrological processes. This study aims to quantify the effects of density-dependent flow on SW–GW interaction and evaluate the sensitivity of dominant hydrological drivers to density-dependent flow. Our simulations using the HydroGeoSphere model revealed that neglecting density-dependent flow in SW–GW interaction can lead to inaccurate estimations of water and solute balances. In particular, including density-dependent flow in the model yielded more realistic salinity distributions under gaining river scenarios and captured the gradual expansion of freshwater lenses under losing river scenarios. The results also indicated that under non-density-dependent flow, more saline groundwater is exposed to evapotranspiration, resulting in higher solute mass storage and a more saline unsaturated zone. Further, surface recharge and pumping rates played crucial roles in salinity distribution. This study highlights the critical importance of incorporating density-dependent flow in simulations, providing valuable insights for improving the accuracy of predictions and effectively managing water and solute balances in floodplain aquifers.

Характеристика сучасного стану іхтіофауни озера Котлован як малої штучної водойми м. Дніпро

Purpose. To investigate the current state of nearshore and pelagic communities of ichthyofauna of an artificial water body: Lake Kotlovan in the city of Dnipro. To develop a set of recommendations and bioreclamation measures to improve and maintain a balanced ecological state of the water body, to increase its recreational value. Methodology.The study of ichthyofauna was carried out in the lake Kotlovan (total area 13.4 hectares), which was artificially created in the late 1960s and 1970s, located in the Industrial District of Dnipro in the area of industrial development. The study was carried out in September 2021 - October 2022 in three main nearshore biotopes of the water body. Ichthyological samples were collected in the nearshore shallow water zone with a small-mesh (fry) seine of 15 meters long with a mesh size of 7 mm in the wings and 3 mm in the codend. Fish selected for further analysis were preserved in a 4.5% formalin solution. Processing and analysis of the collected samples were carried out at the research center “Aquatic Bioresources and Aquaculture” of the Dnipro State Agrarian and Economic University (DSAEU). Generally accepted methods of mathematical analysis were used to process the results. The study was carried out in accordance with the Program for conducting scientific fisheries research of the Scientific Research Center “Aquatic Bioresources and Aquaculture” of the DSAEU for 2022–2026. Findings. The peculiarities of the species composition and distribution of the spontaneously formed ichthyofauna of an artificial water body under the impact of negative factors - discharges of enterprises, communal and household effluents and active recreation - have been established. Ichthyofauna of the lake Kotlovan is impoverished and represented by only 10 species (4 families). The composition of the ichthyofauna lacks bottom-dwelling fish and some littoral species (representatives of the familiesCobitidae, Siluridae, Syngnathidae, Gasterosteidae, Gobiidae), a certain deformation of the taxonomic structure was observed. The absence of individual families of ichthyofauna is an atypical situation for most water bodies in this region. This is due to the artificial development of ichthyofauna and the complex negative effect of the anthropogenic factor and internal trophic relationships. Recommendations on bioreclamation measures for the development of a stable ichthyocenosis with the improvement of the trophic structure and ecological condition of the artificial water body have been developed. Originality. The species composition of the ichthyofauna of an artificially created completely isolated water body in the city of Dnipro, which has existed for about 50 years, was determined for the first time. The current structure of fish groups according to species composition, conservation status, relative abundance, type of feeding and origin were investigated. A high level of the infestation of bleak Alburnus alburnus and silver bream Blicca bjoerkna with ligulosis and perch Perca fluviatilis with eustrongylidosis was observed. Measures and recommendations for improving the state of the ichthyofauna of Lake Kotlovan and increasing the recreational value of the water body were proposed. Practical value. Based on the conducted study, it is possible to evaluate and forecast the future state of the ichthyofauna of small, artificially created and isolated water bodies under anthropogenic pressure. The proposed bioreclamation measures will allow increasing the stability of ichthyocenosis and improving water quality as well as the conditions for recreation of residents, recreational fishing within the boundaries of a large city (a complex of ecosystem services). Keywords: city of Dnipro, artificial water body, ichthyofauna, bioreclamation, biotope, recreation, ecosystem services.

Population structure of the bivalve Aequiyoldia eightsii (Jay, 1839) in the shallow water zone of Admiralty Bay (King George Island, Antarctic Peninsula)

Population structure of the bivalve Aequiyoldia eightsii (Jay, 1839) in the shallow water zone of Admiralty Bay (King George Island, Antarctic Peninsula)

Estimating the saturated hydraulic conductivity of the vadose zone with an automatic infiltration data logger for the BEST algorithm

Estimating the saturated hydraulic conductivity of the vadose zone with an automatic infiltration data logger for the BEST algorithm