Shallow-water Carbonate Research Articles

Facies-related reservoir heterogeneity of grain-supported limestones: insight from the Early Cretaceous Yamama Formation, southern Iraq

Sedimentological investigation of 150 m drill cores and well log analyses, including gamma-ray, resistivity, sonic, neutron, density logs, were conducted to constrain the impact of depositional facies on reservoir quality distribution in limestone succession of the Yamama Formation (Early Cretaceous), Nasiriya Oilfield, southern Iraq. Understanding the factors controlling reservoir heterogeneity in carbonate reservoirs is crucial for developing geological and reservoir models. Nine microfacies were identified: peloidal oncoidal grainstones-rudstones, skeletal cortoids packstones, skeletal dasyclads wackestones, pelletal packstones-grainstones, cortoidal peloidal grainstones, ooidal peloidal grainstones, skeletal grainstones, bioturbated dolomitic wackestones, and spiculitic skeletal mudstones-wackestones. The formation was deposited in open-marine shallow-water carbonate ramp, ranging from the intertidal to outer-ramp during the Berriasian-Valanginian. The depositional ramp was characterized by grainstones shoal barriers in the distal inner-ramp. Sea level fluctuations significantly influenced the vertical facies and reservoir quality distribution. The grain-supported, distal inner-ramp shoal facies formed the reservoir units, while the mud-supported, middle-outer-ramp facies are impervious units. Diagenetic processes, including dissolution of skeletal allochems, physical and chemical compaction, dolomitization, and cementation, have variably affected reservoir quality. Dissolution enhanced porosity by creating vuggs, while compaction and cementation often reduced porosity. Nevertheless, early diagenetic circumgranular calcite and small amount of scattered equant and syntaxial calcite overgrowths helped protecting the grain-supported limestones from physical compaction and thus preserved interparticle pores (≤ 22%) at depth (>3100 m). Conversely, equant calcite cement, which occurs in substantial amounts, has reduced porosity by filling the interparticle and moldic pores. Reservoir heterogeneity of the formation is attributed to depositional facies, which control the texture of the sediments, and to various types of diagenetic alterations.

Lithification of pelletal grains by microbially mediated organomineralization

Fecal pellets are key components of the biological carbon pump and a source of nutrients. When cohesively bound and cemented, they become the most abundant non-skeletal grains in shallow-water carbonates and an important nucleus for ooid formation. Herein, we describe the mineralization processes contributing to pellet cementation using scanning electron microscopy in conjunction with stable isotope and mineralogical analyses of the bulk sediments on Great Bahama Bank, known for its abundance of peloids and fecal pellets. Results show biogenic signatures consistent with the initial stages of organomineralization. These include, curved-tubular filaments and bacilli bacteria associated with extracellular polymeric substances (EPS); fibrils of EPS binding aragonite needles; and the coexistence of decayed EPS with amorphous calcium carbonate that once it develops, coalesces and crystalizes into aragonite. While δ13Cinorg do not show large variations, slightly higher values are observed in areas where pellets are indurated, likely attributed to photosynthetic activity on the pellets. The δ13Corg values tend to be more elevated in indurated pellets, suggesting that heterotrophs are preferentially using enriched carbon sources. In contrast, friable pellets from nearshore areas show more negative δ13Corg values, suggesting microbial exposure to depleted C3 and CAM plant sources. Fingerprints of nitrogen fixation and denitrification are also documented and supported by δ15Norg values. Altogether, these findings suggest that EPS and a microbial consortium, including gut-microbial flora and free-living surface colonizers, are responsible for inducing early cements, which are later complemented by secondary cements. Microorganisms involved in pellet lithification may subsequently also aid in ooid cortex development.

The palaeobiogeographic significance of the Nötsch area (Austria) during the Middle and Late Mississippian based on rugose corals

The Carboniferous of Nötsch (South Austria) is composed of three formations: the Erlachgraben Formation, the Badstub Breccia, and the Nötsch Formation, that yielded abundant corals, several of them being new for that region. The assemblage is composed of 11 rugose coral species (Siphonophyllia sp., Pseudozaphrentoides juddi, Lublinophyllum? sp., Dibunophyllum bipartitum, Arachnolasma cylindrica, Palaeosmilia murchisoni, Aulokoninckophyllum carinatum, Siphonodendron martini, Diphyphyllum furcatum, Solenodendron furcatum, and Solenodendron horsfieldi), two tabulate species (Multithecopora sp. and Palaeacis sp.) and one heterocoral species (Hexaphyllia mirabilis). In addition, five rugosans that are not in our collection have been identified by previous authors (Clisiophyllum sp., Pseudozaphrentoides sp., Caninia sp., “Palaeosmilia isae”, and Lophophyllidium sp.). The rugose and tabulate species are described and figured. A palaeobiogeographic analysis comparing the Mississippian assemblages from Nötsch and other Austrian outcrops with other domains in Central Europe has been performed using hierarchical clustering with Simpson and Dice similarity indices. The statistical comparison of the rugose coral assemblages at the genus level allows a better perception of the distribution of the shallow water carbonate platforms in that part of the Western Palaeotethys during the Visean and Serpukhovian. The results are incorporated in a schematic palaeogeographical map of the studied area for the late Visean.

Paleoecological and paleoenvironmental insights from Ornatorotaliidae (larger foraminifera)

The present study deals with the ecology and phylogenetic relationships among species of the genera Ornatorotalia, Granorotalia, and Risananeiza belonging to the Family Ornatorotaliidae. The microfacies analyses allowed us to assign each taxon to its life paleoenvironment within the shallow-water carbonate setting, and to make a comparison with extant species belonging to the Family Calcarinidae. While different species of Ornatorotalia and Granorotalia thrived only in the inner ramp, Risananeiza spp. possibly inhabited also deeper environments up to the middle ramp. The phylogenetic relationships among genera and species are here briefly discussed, nonetheless it's still impossible to identify any unambiguous ancestor of this group.

Compound-clinoform model for tide-influenced deltas in the mixed siliciclastic–carbonate Cisco Group, Upper Pennsylvanian (Virgilian), Eastern Shelf of the Permian Basin, U.S.A.

ABSTRACT Deltas in the Cisco Group contain significant volumes of potential reservoir sandstones in the Upper Pennsylvanian (Virgilian stage) mixed siliciclastic–carbonate succession in the Eastern Shelf of the Permian Basin. While early studies predominantly supported a river-dominated model for these deltas, our findings establish the presence of tide-influenced deltas characterized by the following features: i) predominant heterolithic lithology, ii) diagnostic structures such as flaser bedding, bidirectional ripple cross-lamination, or double-mud drapes, iii) an abundance of interpreted fluid muds, and iv) elongated bars on the subaqueous platform. Through analysis of 290.2 m of core, we identify six facies associations related to tide-influenced deltaic systems in highstand and falling-stage intervals of the proximal Eastern Shelf: delta plain–tidal flat, distributary channel and distributary-mouth bar (delta front) deposits on the subaerial delta; subaqueous delta topset, subaqueous delta foreset, and prodelta deposits on the subaqueous delta. Moreover, two additional facies associations, transgressive shelf deposits and subtidal shallow-water carbonates, record continuous episodic transgressions in the deltaic packages. Well-log cross sections reveal repetitive stacking of deltas, typical of icehouse systems, and sandstone mapping suggests elongated tidal bars forming the interpreted subaqueous delta platforms. These features suggest a compound-clinoform morphology of the Cisco Group deltas akin to modern tide-influenced deltas that have carbonate banks such as the Gulf of Papua. This compound-clinoform morphology has implications for the elongate geometry and isolation of sandstone reservoirs, impacting fluid migration and storage. Moreover, these insights extend beyond the Cisco Group to other Pennsylvanian and Permian levels on the Eastern Shelf, as well as to other deltas in mixed siliciclastic–carbonate systems in icehouse conditions.

Pervasive calcite veins and cleavage dilation in low-grade metamorphic rocks as a marker of lower Jurassic rift-basin margins: A signature of microbial colonization

We report herein for the first time the occurrence of low-grade metamorphic rocks dilated by the growth of calcite veins induced by microbial communities inhabiting the cleavage planes. This process took place at the rock/sea-water interface in a rocky shore environment when the Hercynian basement rocks of the European-Iberian continental margin in Calabria (Italy) experienced stepwise flooding by a shallow tropical sea in the Early Jurassic, a process which was accompanied by synsedimentary extension, resulting in the birth of the Longobucco Basin. The veins exhibit a multiphase filling history, as, in an early phase, microstromatolites lining the walls of cleavage planes document the initial development of microbial biofilms. Subsequently, the growth of bands of radiaxial fibrous calcite enlarged the cavities through force of crystallization, also producing fissures at a high angle with respect to cleavage, which were in turn enlarged by crystal growth. Carbonate clumped isotope analysis indicates crystallization of calcite from sea water, at temperatures (T47) ranging from c. 33 to c. 44 °C. The inferred palaeoenvironment is that of a rocky coastline, locally with tide pools, where the seawater lapped cliffs made of Palaeozoic metasandstone. Microbially induced mineralization was a very rapid process, as clasts of veined metamorphic rocks are found in only slightly younger Early Jurassic deposits, like the sub-reefal carbonate bodies that grew in the Pliensbachian attached to the Palaeozoic bedrock. The occurrence of low-grade metamorphic rocks bearing calcite veins can be mapped in the field for kilometers, following the high-angle unconformity that separates the shallow-water carbonates from the basement. This microbial overprint therefore is a marker of the margins of a rift basin, where the exposure of basement rock along steep submarine surfaces was the result of footwall unroofing.

Millennial-scale sedimentary evolution of carbonate platforms during the Permian–Triassic boundary hyperthermal event

The millennial-scale response of shallow-water carbonate platforms to the climatic upheaval at the Permian–Triassic boundary (PTB) remains unclear. This study presents three carbonate platform sections across the Permian–Triassic (P–T) boundary in South China and the Lhasa terrane. A total of 14 types of carbonate microfacies were identified, which show that the Liangfengya and Taiping sections in South China were deposited in an inner ramp, and the Wenbudangsang section on the Lhasa terrane was deposited in an outer ramp. Bulk carbonate carbon isotope patterns through the sections are generally characterized by negative excursions (−2.2 to −3.5‰) during the PTB hyperthermal event. These excursions can be divided into four phases (NC1 to NC4), with NC1 before the negative carbon isotope excursion (NCIE) event, NC2 during the initiation phase of the NCIE, NC3 during the body of the NCIE, and the NC4 marking the recovery stage of the NCIE. The pattern of sedimentary changes in each section through the PTB hyperthermal event, and the relationship between these changes and the carbon isotope stages, was established. In the studied sections, the onset of the NCIEs (NC2 stage) preceded evidence for a carbonate production crisis, with the occurrence of anachronistic facies developed after this crisis but prior to the NC3 stage. In detail, our data show that the carbonate production crisis occurred 11 kyr after the onset of the NCIE, and 47 kyr before the first Permian–Triassic mass extinction (PTME), and that the carbonate production crisis may have been closely related to the environmental stresses associated with greenhouse gas emission from the Siberian Traps Large Igneous Province (STLIP).

Pre-shortening reconstruction of the adria microplate: Balanced and restored cross-sections through the Southern Apennines–Dinarides (Central Mediterranean Sea)

The Adria plate and/or microplate has accommodated the differential eastward motion of Africa, Europe-Iberia, since the Jurassic times, and the subsequent convergence between Africa and Eurasia from Middle Cretaceous onwards. Its complex tectonic deformation, responsible of the development of the opposing Apennines and Dinarides thin- and thick-skinned fold and thrust belts, remains poorly constrained, fueling an ongoing debate on the original position of Adria, its pre-compressional continental width, and crustal structure. Here we tackle these uncertainties by analyzing and integrating published structural cross-sections, subsurface data and 2D lithospheric numerical models to build a 758 km long regional balanced and restored cross-sections along a SW-NE transect through the Southern Apennines and Southern Dinarides. Employing the line length method for the sedimentary cover and assuming the preservation of the pre-Triassic continental crustal area, we reconstruct the pre-compressional continental width of Adria. The unfolding of the sedimentary cover along the SW-NE cross-section results in an undeformed continental Adria microplate width of approximately 1050 km, slightly under previous estimations (1175 to 1670 km). The minimum total shortening results in 291 km: 148 km across the Southern Apennines and 143 km across the Southern Dinarides. We then calculate the Adria microplate continental crustal thickness during Middle-Late Jurassic time assuming local isostatic balance, obtaining 23 km for the eastern and central Adria sectors, based on shallow water carbonate sequences. In contrast, the western Adria sector at the Southern Apennines results in a restored pre-Triassic continental crustal thickness of only 7 km, suggesting that the middle and lower crustal layers in this sector may have been partially removed, possibly by mantle delamination during Neogene to Quaternary collisional processes. The results strongly support that the Adria microplate was located to the east of the Pelagian Basin and formed part of the African Plate around the Permian–Triassic boundary interval.

Multiscale discrete fracture network modelling of shallow-water carbonates: East Agri Valley Basin, Southern Italy

We investigate the multiscale geometrical and dimensional properties of fracture and fault networks crosscutting Lower Jurassic to Cretaceous shallow-water carbonate rocks. The carbonates are exposed along the flanks of the Viggiano Mt., on the eastern side of the High Agri Valley Basin of southern Italy. Furthermore, we employ the results of field and digital structural analyses to derive the input parameters for subsequent Discrete Fracture Network modelling (DFN) of geocellular volumes whose dimension and architecture resemble those of the investigated sites. DFN modelling is carried out for geocellular volumes representing the studied bed packages (5m-side volumes), outcrops (50m-side volumes), and reservoir-scale carbonate cliffs (500m-side volumes). Notably, modelling is obtained considering the minimum mechanical aperture value obtained in the field for porosity computations and theoretical values of fracture hydraulic aperture for permeability computations. This is because the mechanical aperture values and roughness profiles collected in the field along single fractures are unreliable due to weathering and localized karst-related dissolution. Our findings reveal that a scale-dependent geometry characterizes the Cretaceous carbonates over three orders of magnitude. These results support previously published data, and contrast with those obtained for the Lower Jurassic carbonates, which suffer of some bias due to the quality of the exposures. After DFN modelling, we show that the amount of computed fracture porosity is mainly due to the SB and NSB fractures, and that equivalent permeability is greater within faulted rock volumes. In terms of horizontal permeability, which is the most reliable result after DFN modelling, we document near isotropic horizontal permeability ellipses at all scales of observations. At individual outcrops, we note that the permeability ellipses are elongated parallel to the dominant fault sets that denotes how localized strain affects the directionality of fluid flow. Finally, we summarize the original data in a conceptual model illustrating the modalities of meteoric fluid infiltration through the vadose zone, and then subsequent horizontal flow in the phreatic zone present within the fracture carbonates at shallow depths.

Boron isotopic compositions of middle Miocene to recent shallow-water carbonates from the South China Sea: Assessing diagenetic effects and implications for paleoclimate changes

The partial pressure of atmospheric CO2 (pCO2) significantly influences global climate change and biological evolution through geological history. Boron isotopic composition (δ11B) in carbonates has been used to reconstruct the paleo-pH of seawater, providing insight into atmospheric pCO2 levels. However, the fidelity of δ11B records in marine carbonates due to diagenesis remains uncertain. Here, to understand how diagenetic processes influence B isotopic records in marine carbonates, we examined B concentrations and δ11B values of modern corals (from Hainan Island), unconsolidated shallow pushcores (Jiuzhang A and Jiuzhang B from Nansha Islands, South China Sea), and a long drillcore (XK-1 from Xisha Islands, South China Sea) covering the Late Miocene to Holocene periods. Our coral samples show a uniform δ11B range (20.16 ± 0.85%), consistent with previously published values for modern corals in other open oceans. The δ11B values of the unlithified carbonate sediments from Jiuzhang A and B pushcores vary within a narrow range (18.70 ± 0.84%), yielding pH and CO2 concentrations consistent with the range between modern and pre-industrial values. Since we did not observe any statistically significant covariations between traditionally established diagenetic proxies (such as δ13C, δ18O, Mn/Sr, and Al/Ca) and δ11B values for non-dolomitized samples in the XK-1 drillcore, we suggest that δ11B values of bulk limestones are not significantly affected by typical diagenesis (meteoric, mixed-diagenetic, and marine diagenetic processes), likely due to limited post-depositional recrystallization of our study carbonates. In contrast, dolomitization significantly decreases δ11B values of bulk carbonates, rendering dolomites unsuitable as archives for reconstructing seawater δ11Bborate values. Our study supports that marine limestone with limited recrystallization or dolomitization have the potential to record ambient seawater pH values with high resolution. The established secular seawater pH variations based on XK-1 δ11B records provide information about ocean acidification over the past 5.1 million years.

Biogeographical patterns of the porcelaneous larger foraminifer Alveolinella quoyi through the integration of fossil data

In the present-day Indo-Pacific coral-reef settings two genera of alveolinoidean porcelaneous larger benthic foraminifera (LBF) occur, namely Alveolinella and Borelis. Alveolinella is represented by a single species, A. quoyi, whose northernmost record is in Okinawa-jima (central Ryukyu Islands, Japan). Although the Indo-Pacific area, and especially the Coral Triangle, is a biodiversity hotspot since the Early Miocene, in-depth investigation on fossil representatives of present-day LBF is limited to a few taxa. To help bridge this knowledge gap, the palaeobiogeographical dynamics of A. quoyi is assessed. Analysis of data from the palaeontological literature shows that its first appearance datum is from the Tortonian (Late Miocene) of East Kalimantan and Papua New Guinea. In the Pliocene–Pleistocene the Indonesian Throughflow constrained the species within the Central Indo-Pacific. Finally, during the Late Pliocene the northward migrants arrived in the shallow-water carbonate settings of Okinawa-jima where the species is still thriving.

The “underfilled trinity model” of foreland basins revisited: reality or myth?

The “underfilled trinity” model of foreland-basin stratigraphy was proposed based on the observation that the initial sedimentary stages along the western and northern front of the western and central Alps were represented by shallow-water carbonates (Calcaires à Nummulites) overlain by hemipelagic marls (Marnes Bleues) and capped by siliciclastic turbidites (Grès d’Annot). Subsequently, this model has been widely accepted and applied in foreland basins worldwide. We here re-investigated the Eocene-Oligocene sedimentary succession of the Western Alps to check its validity. Major geological features of this region include: i) the existence of a Cretaceous-Eocene unconformity spanning more than 25 Myr in the studied sections; ii) a virtually synchronous age of the Calcaires à Nummulites, Marnes Bleues, and Grès d’Annot formations across the Western Alps; iii) a long-term deepening-upward trend, from inner to outer ramp, documented by the Calcaires à Nummulites, followed by the pelagic Marnes Bleues and by the Grès d’Annot turbidites; iv) the provenance of the Grès d’Annot Formation from the Maures-Estérel Massif and/or Corsica-Sardinia block in the south, rather than from the Alpine orogen in the east. By integrating field observations, sedimentological, biostratigraphic, and provenance analyses, we found the Eocene “underfilled foreland” model too simplistic and inadequate to explain the basin evolution in the western Alpine region. Based on the alternative scenario proposed herein, the Annot and Barrême basins formed in the late Eocene (40-35 Ma) in an extensional/transtensional setting during a period of major change in tectonic stress fields across western Europe on the upper plate of the Apennine subduction.

A distinct manganese deposit on a Middle Permian carbonate platform in South China

During the Middle Permian, Earth experienced a period of profound environmental changes, including the final stages of the Late Paleozoic Ice Age (LPIA), global seawater regression, the Guadalupian mass extinction event, and the eruption of the Emeishan Large Igneous Province (ELIP) in South China. These events collectively induced significant shifts in both the environment and biosphere, yielding several geochemical anomalies, including deposition of manganese (Mn) deposits. The link between Middle Permian Mn deposits and the prevailing environmental conditions, however, remains unclear. Here, four sections spanning the Middle Permian Maokou Formation to the Late Permian Longtan Formation in the Zunyi area of northern Guizhou, South China are investigated. Through sedimentological and geochemical analyses, this work aims to elucidate the evolution of sedimentary environments over the Middle to Late Permian. During this period, a transition from a shallow-water carbonate platform in the 1st Member of the Maokou Formation to a deeper, siliceous deposit in its 2nd Member was recorded. This shift results in a pronounced paleogeographic differentiation in the 3rd Member, juxtaposing the shallow-water carbonate platform against a deeper Mn-enriched basin. A number of geochemical proxies indicate a strong hydrothermal signal in the Mn deposits. Combined with positive Eu anomalies and low Sr isotopes, the data underscore the profound influence of hydrothermal input linked with early subaqueous eruptions from the ELIP on the nearby marine environment. A detailed examination of carbon isotope profiles from the Maokou Formation indicates that volcanic influences, shifts in marine ecosystems, and changes in primary production caused the fluctuations of δ13Ccarb and δ13Corg. Moreover, the formation of Mn carbonate in deeper waters effectively sequestered organic C. Collectively, our new data demonstrate that the essential conditions for the development of the carbonate-hosted Mn deposits include drowning of the carbonate platform through an increase in sea level, the availability of a sufficient Mn source, and the presence of a redox-stratified water column.

U-Pb geochronology reveals that hydrothermal dolomitization was coeval to the deposition of the Burgess Shale lagerstätte

Fault-controlled, hydrothermal dolomitization often occurs at margins between shallow-water carbonate platforms and deep-water sedimentary basins. In western Canada, for example, the platform margin between the Cathedral Formation and the Burgess Shale Formation has been dolomitized at temperatures up to ~200 °C, with local magnesite, talc, and clinochlore mineralization. At the same time, the Burgess Shale Formation includes exceptional fossils that provide key evidence of the radiation of the animal phyla during the Cambrian Period (541 to 485.4 Ma). This lagerstätte and Mg-rich minerals within the adjacent and underlying strata, however, have been critically understudied. Here we show, using carbonate U-Pb geochronology, that western Canada was tectonically active and subject to hydrothermal dolomitization during the Middle Cambrian (Miaolingian Epoch) to Middle Ordovician (488.1 ± 18.8 Ma). These results extend the latest stages of rifting along the western margin of Laurentia into the Paleozoic, while also suggesting that the dolomitization of the Cathedral Formation occurred at the same time as the deposition of the Burgess Shale lagerstätte.

COMPOUND CLINOFORM MODEL FOR TIDAL-INFLUENCED DELTAS IN THE MIXED SILICICLASTIC-CARBONATE CISCO GROUP, VIRGILIAN (GZHELIAN), EASTERN SHELF OF THE PERMIAN BASIN, U.S.A.

Deltas in the Cisco Group contain significant volumes of potential reservoir sandstones in the Late Pennsylvanian (Virgilian/Gzhelian) mixed siliciclastic-carbonate succession in the Eastern Shelf of the Permian Basin. While early studies predominantly supported a river-dominated model for these deltas, our findings establish the presence of tide-influenced deltas characterized by the following features: (i) predominant heterolithic lithology; (ii) diagnostic structures such as flaser bedding, bidirectional ripple cross-lamination, or double-mud drapes; (iii) an abundance of interpreted fluid muds; and (iv) elongated bars on the subaqueous platform. Through analysis of 290.2 m of core, we identify six (6) facies associations related to tide-influenced deltaic systems in highstand and falling-stage intervals of the proximal Eastern Shelf: lower-delta-plain/embayed tidal flat, distributary channel and distributary mouth bar/delta front deposits on the subaerial delta; subaqueous delta platform, subaqueou s delta foreset, and prodelta deposits on the subaqueous delta. Moreover, two (2) additional facies associations, transgressive shelf deposits, and subtidal shallow-water carbonates, record continuous episodic transgressions within the deltaic packages. Well-log cross sections reveal repetitive stacking of deltas, typical of icehouse systems, and sandstone mapping suggests elongated tidal bars forming the interpreted subaqueous delta platforms. These features suggest a compound clinoform morphology of the Cisco Group deltas akin to modern tide-influenced deltas that have carbonate banks such as the Gulf of Papua. This compound clinoform morphology has implications for the elongate geometry and isolation of sandstone reservoirs, impacting fluid migration and storage. Moreover, these insights extend beyond the Cisco Group to other Pennsylvanian and Permian levels on the Eastern Shelf, as well as to other deltas in mixed siliciclastic-carbonate systems in icehouse conditions.

Early Mississippian global δ13C excursion is not a diagenetic artifact

Shallow-water platform carbonate δ13C may provide a record of changes in ocean chemistry through time, but early marine diagenesis and local processes can decouple these records from the global carbon cycle. Recent studies of calcium isotopes (δ44/40Ca) in shallow-water carbonates indicate that δ44/40Ca can be altered during early marine diagenesis, implying that δ13C may also potentially be altered. Here, we tested the hypothesis that the platform carbonate δ13C record of the Kinderhookian-Osagean boundary excursion (KOBE), ∼353 m.y. ago, reflects a period of global diagenesis using paired isotopic (δ44/40Ca and clumped isotopes) and trace-element geochemistry from three sections in the United States. There is little evidence for covariation between δ44/40Ca and δ13C during the KOBE. Clumped isotopes from our shallowest section support primarily sediment-buffered diagenesis at relatively low temperatures. We conclude that the δ13C record of the KOBE as recorded in shallow-water carbonate is consistent with a shift in the dissolved inorganic carbon reservoir and that, more generally, ancient shallow-water carbonates can retain records of primary seawater chemistry.

Laser In Situ U–Pb Isotope Dating of Carbonate Rocks in Weijia Guyot in the Western Pacific Ocean and Its Geological Significance

Shallow-water carbonate rocks constitute a crucial component of large guyots, arising in distinct environments and harboring valuable insights into the evolutionary stages of seamount islands as well as the tectonic conditions of the underlying oceanic plate. Laser Ablation Multi-Collector Inductively Coupled Plasma Mass Spectrometry (LA-MC-ICP-MS) was used to conduct in situ U–Pb isotope dating of carbonate minerals with low uranium content collected from Weijia Guyot. This dating approach yielded crucial evidence for the vertical development of the seamount. Our study indicates that shallow-water carbonate rocks in Weijia Guyot had a temporal range between 91 My and 137 My. The carbonate rocks underwent two growth phases, Hauterivian to Barremian and Cenomanian to Turonian, with a hiatus of approximately 20 My. Since the Hauterivian age, the shield volcano of Weijia Guyot is essentially complete, with its seamount top exposed at or near sea level and receiving its first stage of shallow-water carbonate sedimentation. Based on the dating of both shallow-water carbonate rocks and hawaiite within the Weijia Guyot, it is inferred that approximately 10 My elapsed from shield-building volcanism to late alkalic volcanism. During the Turonian age, the main reason for the second phase of shallow-water carbonate rocks in the seamounts was the regional tectonic uplift triggered by the drift of the Weijia Guyot along with the Pacific Plate toward the Society hotspot.

Constraints on the robustness of oyster geochemical proxy data: application to shallow-water carbonates (Lusitanian Basin, W Portugal)

Constraints on the robustness of oyster geochemical proxy data: application to shallow-water carbonates (Lusitanian Basin, W Portugal)

Development and chronology of the Late Jurassic shallow-water carbonate deposits of the Holy Cross Mountains area, central Poland

The Late Jurassic shallow-water carbonates with intervening clayey-marly deeper-water deposits in the Holy Cross Mts. area formed over large bank of the elevated part of the Northern Tethyan Shelf during about 12 myr. They comprise three main successions (I, II and III) deposited partly in different environmental conditions, controlled by tectonic and climatic factors, and still preserved in the north-eastern margin, the north-western margin and the south-western margin of the Holy Cross Mountains. The history of sedimentation is presented according to the concept of the large tectono-stratigraphic units COK, LUK and KVB, which owe their origin to variable rates of tectonic subsidence, as introduced by Kutek (1994) for the area of central Poland. The studied deposits of the COK megasequence corresponding to the Upper Oxfordian and the Lower Kimmeridgian up to the Hypselocyclum Zone consist of coral limestones, various grained (including oolitic) limestones, and micritic limestones formed over the gradually enlarging shallow-water carbonate platform of the Holy Cross Mts. This platform was subsequently subdivided into two elevated areas, separated by a depressed zone in the middle, bounded by the Nowe Miasto–Iłża–Bałtów Fault Zone in the north-east and the Holy Cross Fault System in the south. The younger megasequence LUK with it strongly transgressive character marks the successive stages of the marine transgression which entered the central, lowered part of the area of the Holy Cross Mts. from the west, where it appeared already in the early Hypselocyclum Chron. It successively spread across the Holy Cross Mts. area towards the north-east and south bringing everywhere the deposition of various oyster lumachelles and marls with ammonites at the end of the Hypselocyclum Chron and during the Divisum Chron of the Early Kimmeridgian to the Acanthicum/Mutabilis Chron of the earliest Late Kimmeridgian. The following megasequence KVB is represented by the detrital lumachelles and chalky limestones with nereineids of the Eudoxus Chron of the Late Kimmeridgian marking the development of still younger shallow-water carbonate platform in the uplifted areas in the north-eastern and possibly the south-western margins of the mountains, allegedly subdivided by a deeper area of sedimentation of marly deposits. The youngest Late Jurassic deposits of the Holy Cross Mts., are very fragmentarily preserved, mostly because of Early Cretaceous uplift and erosion. They suggest an initial episode of complete drowning of the carbonate platform which became covered by marly deposits during the Early Tithonian, and the subsequent restoration of shallow-water carbonate sedimentation at the end of the Early Tithonian.

Seismic expression of shallow-water carbonate structures through geologic time

Shallow-water carbonate structures are characterized by different shapes, sizes, and identifying features, which depend, among other factors, on the age of deposition and on the carbonate factory associated with a specific geologic period. These variations have a significant impact on the imaging of these structures in reflection seismic data. This study aims at providing an overall, albeit incomplete, picture of how the seismic expression of shallow-water carbonate structures has evolved through deep time. Here, 297 shallow-water carbonate systems of different ages, spanning from Precambrian to present, with a worldwide distribution of 159 sedimentary basins, have been studied. For each epoch, representative seismic examples of shallow-water carbonate structures are described through the assessment of a selection of discriminating seismic criteria or parameters. The thinnest structures, commonly represented by ramp systems, usually occurred after mass extinction events and are mainly recognizable in seismic data through prograding clinoform reflectors. The main diagnostic seismic features of most of the thickest structures, which are found to be Precambrian, Late Devonian, Middle-Late Triassic, Middle-Late Jurassic, some Early Cretaceous presalt systems, “middle” and Late Cretaceous, Middle-Late Miocene, and Plio-Pleistocene, are steep slopes and reefal facies. Slope-basinal resedimented seismic facies are mostly observed in thick steep-slope platforms, and they are more common, except for megabreccias, in post-Triassic structures. Seismic-scale early karst-related dissolution features are mostly observed in icehouse platform deposits. Pinnacle structures and the thickest margin rims are concentrated in a few epochs, such as Middle-Late Silurian, Middle-Late Devonian, earliest Permian, Late Triassic, Late Jurassic, Late Paleocene, Middle-Upper Miocene, and Plio-Pleistocene, which are all characterized by high-efficiency reef builders.