Shallow Subsurface Of Mars Research Articles

Water Ice Resources on the Shallow Subsurface of Mars: Indications to Rover-Mounted Radar Observation

The planet Mars is the most probable among the terrestrial planets in our solar system to support human settlement or colonization in the future. The detection of water ice or liquid water on the shallow subsurface of Mars is a crucial scientific objective for both the Chinese Tianwen-1 and United States Mars 2020 missions, which were launched in 2020. Both missions were equipped with Rover-mounted ground-penetrating radar (GPR) instruments, specifically the RoPeR on the Zhurong rover and the RIMFAX radar on the Perseverance rover. The in situ radar provides unprecedented opportunities to study the distribution of shallow subsurface water ice on Mars with its unique penetrating capability. The presence of water ice on the shallow surface layers of Mars is one of the most significant indicators of habitability on the extraterrestrial planet. A considerable amount of evidence pointing to the existence of water ice on Mars has been gathered by previous researchers through remote sensing photography, radar, measurements by gamma ray spectroscopy and neutron spectrometers, soil analysis, etc. This paper aims to review the various approaches utilized in detecting shallow subsurface water ice on Mars to date and to sort out the past and current evidence for its presence. This paper also provides a comprehensive overview of the possible clues of shallow subsurface water ice in the landing area of the Perseverance rover, serving as a reference for the RIMFAX radar to detect water ice on Mars in the future. Finally, this paper proposes the future emphasis and direction of rover-mounted radar for water ice exploration on the Martian shallow subsurface.

Complex Brines and Their Implications for Habitability.

There is evidence that life on Earth originated in cold saline waters around scorching hydrothermal vents, and that similar conditions might exist or have existed on Mars, Europa, Ganymede, Enceladus, and other worlds. Could potentially habitable complex brines with extremely low freezing temperatures exist in the shallow subsurface of these frigid worlds? Earth, Mars, and carbonaceous chondrites have similar bulk elemental abundances, but while the Earth is depleted in the most volatile elements, the Icy Worlds of the outer solar system are expected to be rich in them. The cooling of ionic solutions containing substances that likely exist in the Icy Worlds could form complex brines with the lowest eutectic temperature possible for the compounds available in them. Indeed, here, we show observational and theoretical evidence that even elements present in trace amounts in nature are concentrated by freeze–thaw cycles, and therefore contribute significantly to the formation of brine reservoirs that remain liquid throughout the year in some of the coldest places on Earth. This is interesting because the eutectic temperature of water–ammonia solutions can be as low as ~160 K, and significant fractions of the mass of the Icy Worlds are estimated to be water substance and ammonia. Thus, briny solutions with eutectic temperature of at least ~160 K could have formed where, historically, temperature have oscillated above and below ~160 K. We conclude that complex brines must exist in the shallow subsurface of Mars and the Icy Worlds, and that liquid saline water should be present where ice has existed, the temperature is above ~160 K, and evaporation and sublimation have been inhibited.

Critically testing olivine‐hosted putative martian biosignatures in the Yamato 000593 meteorite—Geobiological implications

On rocky planets such as Earth and Mars the serpentinization of olivine in ultramafic crust produces hydrogen that can act as a potential energy source for life. Direct evidence of fluid-rock interaction on Mars comes from iddingsite alteration veins found in martian meteorites. In the Yamato 000593 meteorite, putative biosignatures have been reported from altered olivines in the form of microtextures and associated organic material that have been compared to tubular bioalteration textures found in terrestrial sub-seafloor volcanic rocks. Here, we use a suite of correlative, high-sensitivity, in situ chemical, and morphological analyses to characterize and re-evaluate these microalteration textures in Yamato 000593, a clinopyroxenite from the shallow subsurface of Mars. We show that the altered olivine crystals have angular and micro-brecciated margins and are also highly strained due to impact-induced fracturing. The shape of the olivine microalteration textures is in no way comparable to microtunnels of inferred biological origin found in terrestrial volcanic glasses and dunites, and rather we argue that the Yamato 000593 microtextures are abiotic in origin. Vein filling iddingsite extends into the olivine microalteration textures and contains amorphous organic carbon occurring as bands and sub-spherical concentrations <300nm across. We propose that a martian impact event produced the micro-brecciated olivine crystal margins that reacted with subsurface hydrothermal fluids to form iddingsite containing organic carbon derived from abiotic sources. These new data have implications for how we might seek potential biosignatures in ultramafic rocks and impact craters on both Mars and Earth.

A Simple Instrument Suite for Characterizing Habitability and Weathering: The Modern Aqueous Habitat Reconnaissance Suite (MAHRS).

The shallow subsurface of Mars is extremely interesting as a possible microbial habitat because it becomes temporarily wet, it is shielded from radiation, and mixing by aeolian processes could provide the sources of energy and nutrients necessary for sustaining microbial life in it. The Modern Aqueous Habitat Reconnaissance Suite (MAHRS) was developed primarily to search for potentially habitable environments in the shallow subsurface of Mars and to study weathering, but it can also be used to search for potentially habitable environments in the shallow subsurface of other planetary bodies such as the Icy Worlds. MAHRS includes an instrument developed to measure regolith wetness and search for brine in the shallow subsurface of Mars, where it is most likely to be found. The detection of brine can aid in our understanding not only of habitability but also of geochemistry and aqueous weathering processes. Besides the regolith wetness sensor, MAHRS includes an electric field sensor, an optical microscope, and a radiometer developed to characterize the near-surface environment and study mixing by aeolian processes. MAHRS was designed to aid in the selection of optimum areas for sample collection for return to Earth.

Results from the dynamic albedo of neutrons (DAN) passive mode experiment: Yellowknife Bay to Amargosa Valley (Sols 201–753)

The Mars Science Laboratory (Curiosity rover) Dynamic Albedo of Neutrons (DAN) experiment detects neutrons for the purpose of searching for hydrogen in the shallow subsurface of Mars. DAN has two modes of operation, active and passive. In passive mode, the instrument detects neutrons produced by Galactic Cosmic Ray interactions in the atmosphere and regolith and by the rover's Multi-Mission Radioisotope Thermoelectric Generator. DAN passive data from Yellowknife Bay to Amargosa Valley (sols 201 through 753) are presented and analyzed here. Water equivalent hydrogen (WEH) estimates from this portion of Curiosity's traverse range from 0.0 wt. % up to 15.3 wt. %. Typical uncertainties on these WEH estimates are ∼0.5 wt. % but in some cases can be as high as ∼4.0 wt. % depending on the specific circumstances of a given measurement. Here we also present a new way of reporting results from the passive mode of the experiment, the DAN passive geochemical index (DPGI). This index is sensitive to some key geochemical variations, but it does not require assumptions about the abundances of high thermal neutron absorption cross section elements, which are needed to estimate WEH. DPGI variations in this section of the traverse indicate that the shallow regolith composition is changing on both the local (∼meters) and regional (∼100 s of meters) scales. This variability is thought to be representative of the diverse composition of source regions for sediments within the crater floor. Kolmogorov-Smirnov Tests on the populations of WEH estimates and DPGI values demonstrate there are statistically significant differences between nearly all of the geologic units investigated along the rover's traverse. We also present updated previous DAN passive results from Bradbury Landing to John Klein that make use of revised DAN active mode results for calibration, however, no qualitative changes in the interpretations made in Tate et al. (2015b) are incurred.

Combined electromagnetic geophysical mapping at Arctic perennial saline springs: Possible applications for the detection of water in the shallow subsurface of Mars

Perennial springs at the Gypsum Hill site on Axel Heiberg Island in the Canadian Arctic (79°24′N, 90°44′W) represent a high-fidelity analogue to hydrothermal systems that might exist on Mars. The springs were surveyed using an electromagnetic induction sounder (EMIS) and ground penetrating radar (GPR). Both instruments probed the subsurface to a depth of approximately 3m. Lateral EMIS soundings were performed every metre along a 400m long reconnaissance line roughly oriented SW-NE and extending through 23 active springs and 1 dry outlet to measure electrical conductivity. Two distinct zones were identified within the survey area on the basis of these data: in the southwest portion, sharp conductivity peaks correspond to isolated springs with well-defined outlets, flowing over dry rocky soil; in the northeast portion, the springs are fed by a pervasive network of saline fluids, resulting in high background readings and muddy surface conditions. These observations are consistent with vertical EMIS sounding data which showed that the brine body feeding the saline springs can be found closer to the ground surface towards the northeast portion of the survey site. In areas of high electrical conductivity, the GPR data exhibits strong scattering. The noisy areas are sharply defined and interpreted to correspond to narrow vertical conduits feeding individual spring outlets. The EMIS is a rugged instrument that could be included as payload in future rover-based Mars exploration missions aiming at probing the shallow subsurface for the presence of brine pockets.

Detección de salmueras en Marte mediante espectroscopia Raman

In the last few years, water ice and perchlorate salts capable of melting this ice and producing liquid solutions have been discovered at the surface and shallow subsurface of Mars. In addition to via melting of ice, perchlorate salts may also form liquid solutions by absorbing water vapor when the relative humidity is above a certain threshold in a process known as deliquescence. Formed either by melting or deliquescence, liquid solutions (brine) are the most likely way of liquid water activity on the Martian surface and in the shallow subsurface and are therefore important to understand the habitability of Mars. Using Raman spectroscopy, we provide reference spectra of various mixing states of liquid water, water ice and calcium perchlorate, all of which can occur during brine formation. We focus on the perchlorate symmetric stretching band and the O-H stretching vibrational band to distinguish brine from crystalline salt and water ice. We show that perchlorate brines can be identified by analyzing the peaks and their widths in the decomposed Raman spectra of the investigated samples. This serves as an important reference for future in-situ Raman spectrometers on Mars, such as those on the ExoMars and Mars 2020 rovers and can aid in the detection of brine formation on Mars.

Effects of Simulated Space Radiation on Immunoassay Components for Life-Detection Experiments in Planetary Exploration Missions

The Life Marker Chip (LMC) instrument is part of the proposed payload on the ESA ExoMars rover that is scheduled for launch in 2018. The LMC will use antibody-based assays to detect molecular signatures of life in samples obtained from the shallow subsurface of Mars. For the LMC antibodies, the ability to resist inactivation due to space particle radiation (both in transit and on the surface of Mars) will therefore be a prerequisite. The proton and neutron components of the mission radiation environment are those that are expected to have the dominant effect on the operation of the LMC. Modeling of the radiation environment for a mission to Mars led to the calculation of nominal mission fluences for proton and neutron radiation. Various combinations and multiples of these values were used to demonstrate the effects of radiation on antibody activity, primarily at the radiation levels envisaged for the ExoMars mission as well as at much higher levels. Five antibodies were freeze-dried in a variety of protective molecular matrices and were exposed to various radiation conditions generated at a cyclotron facility. After exposure, the antibodies' ability to bind to their respective antigens was assessed and found to be unaffected by ExoMars mission level radiation doses. These experiments indicated that the expected radiation environment of a Mars mission does not pose a significant risk to antibodies packaged in the form anticipated for the LMC instrument.

The influence of van der Waals forces on the state of water in the shallow subsurface of Mars

Microscopic liquid layers of water can evolve via adsorption on grain and mineral surfaces at and in the soil of the surface of Mars. The upper parts of these layers will start to freeze at temperatures clearly below the freezing point of bulk water (freezing point depression). A sandwich structure with layers of ice (top), liquid water (in between) and mineral surface (bottom) can evolve. The properties of the interfacial water (of adsorption water and premelted ice) on grain surfaces are described by a sandwich-model of a layer of liquid-like adsorption water between the adsorbing mineral surface layer and an upper ice layer. It is shown that the thickness or number of mono-layers of the interfacial water (of adsorption water and premelted ice) depends on temperature and atmospheric relative humidity. The derived equations for the sandwich model fit well to a known phenomenological relation between thickness of the liquid layer and relative humidity, and can be a tool to estimate or to determine for appropriate materials Hamaker's constant for van der Waals interactions on grains and in porous media. The curvature of grain surfaces is shown to have no remarkable effects for particles in the μm-range and larger. The application of these equations to thermo-physical conditions on Mars shows that the thickness of frost-layers, which can evolve over several hours on cooling surface parts of Mars, is typically of the order or a few tenths of one millimeter or less. This is in agreement with observations. Furthermore, an equation is derived, which relates the freezing point depression for van der Waals force governed interfacial water to the value of the Hamaker constant, to the latent heat of solidification, to the mass density of water ice, and to the thickness of the liquid-like layer. Again, this equation fits well to a known phenomenological relation between freezing point depression and thickness of the liquid-like layer. The derived equation shows that the lower limiting temperature of the liquid phase can reach about 180 K under martian conditions having an atmospheric water content of around 10 pr μm. An “Equilibrium Moisture Content” (EMC)/“Equilibrium Relative Humidity” (ERH) relation for the water content of martian soil has been derived, which relates, for equilibrium conditions, soil water content and atmospheric relative humidity. This relation indicates that the content of liquid interfacial water in the upper surface of Mars can reach up to 10% by weight and more in course of saturation during night hours, and it can be of about 2% by weight during the dry daytime hours.

Water ice permafrost on Mars: Layering structure and subsurface distribution according to HEND/Odyssey and MOLA/MGS data

To elucidate the nature of permafrost in the shallow subsurface of Mars, we analyze jointly neutron albedo from the High Energy Neutron Detector (HEND) on the Mars Odyssey spacecraft and near‐IR (1064‐nm) surface reflectance from the Mars Orbiter Laser Altimeter (MOLA) on Mars Global Surveyor. The first dataset measures the content of hydrogen (in the form of water or hydroxyl) in the soil, and the second yields the flux of absorbed solar energy by the surface. We identify a statistically–significant negative cross‐correlation between these data at latitudes poleward of 40° latitude in the northern hemisphere and in the latitude band 40°–60° in the southern hemisphere, which we interpret as evidence for the presence of stable water ice under a dry equilibrium top layer (ETL). We deduce an empirical relation between near‐IR reflectance and thickness of this ETL, which allows the burial depth of the water ice table to be estimated with km‐scale spatial resolution. We observe no correlation between neutron and near‐IR albedo within the southern hemisphere poleward of 60° latitude. While it is known from previously analyzed neutron and gamma‐ray data that subsurface water ice is present within this region and is covered by a layer of dry regolith, the absence of a correlation indicates that the thickness of this layer is not controlled by an equilibrium condition between the ice table and atmosphere.

A study of P‐band synthetic aperture radar applicability and performance for Mars exploration: Imaging subsurface geology and detecting shallow moisture

Over the past decade, orbital images of the Martian surface revealed key evidence about the history of the planet environment (craters, faults, paleo‐lakes, and rivers), partially hidden under a widespread layer of aeolian deposits. Furthermore, several recent observations and studies support the hypothesis that water could be found in the shallow subsurface of Mars. Low‐frequency synthetic aperture radar (SAR) has demonstrated its subsurface imaging capabilities on Earth, especially in arid regions. While SAR potentials for Mars exploration have already been widely discussed, we present here results of a theoretical and parametric study, based on the experience we gained from terrestrial surveys on Mars analog test sites, which evaluates the capabilities of a P‐band (430 MHz) SAR for Mars exploration for both shallow subsurface geology mapping and moisture detection. We suggest that a P‐band polarimetric SAR can probe the first meters of the Martian subsurface to reveal the dust‐covered geology and to monitor moisture changes over large scales.

A possible terrestrial analogue for haematite concretions on Mars.

Recent exploration has revealed extensive geological evidence for a water-rich past in the shallow subsurface of Mars. Images of in situ and loose accumulations of abundant, haematite-rich spherical balls from the Mars Exploration Rover 'Opportunity' landing site at Meridiani Planum bear a striking resemblance to diagenetic (post-depositional), haematite-cemented concretions found in the Jurassic Navajo Sandstone of southern Utah. Here we compare the spherical concretions imaged on Mars to these terrestrial concretions, and investigate the implications for analogous groundwater-related formation mechanisms. The morphology, character and distribution of Navajo haematite concretions allow us to infer host-rock properties and fluid processes necessary for similar features to develop on Mars. We conclude that the formation of such spherical haematite concretions requires the presence of a permeable host rock, groundwater flow and a chemical reaction front.

Electrically conducting, Ca‐rich brines, rather than water, expected in the Martian subsurface

If Mars ever possessed a salty liquid hydrosphere, which later partly evaporated and froze down, then any aqueous fluids left near the surface could have evolved to become dense eutectic brines. Eutectic brines, by definition, are the last to freeze and the first to melt. If CaCl2‐rich, such brines can remain liquid until temperatures below 220°K, close to the average surface temperature of Mars. In the Martian subsurface, in intimate contact with the Ca‐rich basaltic regolith, NaCl‐rich early brines should have reacted to become Ca‐rich. Fractional crystallization (freezing) and partial melting would also drive brines toward CaCl2‐rich compositions. In other words, eutectic brine compositions could be present in the shallow subsurface of Mars, for the same reasons that eutectic magma compositions are common on Earth. Don Juan Pond, Antarctica, a CaCl2‐rich eutectic brine, provides a possible terrestrial analog, particularly because it is fed from a basaltic aquifer. Owing to their relative density and fluid nature, brines in the Martian regolith should eventually become sandwiched between ice above and salts beneath. A thawing “brine sandwich” provides one explanation (among many) for the “young gullies” recently attributed to seepage of liquid water on Mars. Whether or not brine seepage explains the gullies phenomenon, dense, CaCl2‐rich brines are to be expected in the deep subsurface of Mars, although they might be somewhat diluted (temperatures permitting) and of variable salt composition. In any case, they should be good conductors of electricity.

Strength of Faults on Mars from MOLA Topography

The stresses which must be maintained on faults bounding the rift topography at Tempe Fossae—the “North Tempe Rift” (NTR)—and Valles Marineris (VM) on Mars are estimated, using a simple elastic model and topographic data from the Mars Orbiter Laser Altimeter (MOLA). The absence of rift-flank uplift at the NTR is consistent with an elastic thickness, T e , of 20 km or greater at the time of rift formation. The maximum resolved shear stresses on bounding faults due to this topography do not therefore exceed 20 MPa, similar to the inferred strength of terrestrial faults. Elastic thickness estimates at VM are mostly around 50 km or greater. Therefore, for canyon widths of ∼400 km, the bounding faults of VM, if present, must be able to withstand stresses of up to approximately 100 MPa. However, if the fault-controlled sections of the canyons do not exceed 150 km in width, as suggested by geomorphological analysis, the fault strength required is only 20 MPa. Although the maximum resolved shear stresses required to support the topography at VM may need to be greater than the stresses which terrestrial faults can support, at least some faults on Mars are no stronger than similar features on Earth. This observation is consistent with the existence of liquid water in the shallow subsurface of Mars at the time the faults were active. On Venus, plate tectonics is probably prevented by the frictional resistance to motion across strong faults. On Mars, it is more likely that the large thickness of the elastic layer of the lithosphere and the possible positive buoyancy of the crust are responsible for the observed lack of plate tectonics.