A 3D-printed electrochemical oxygen gas sensor was developed using a Pt nanoparticle-decorated N-doped carbon (PtNC) catalyst and an ionic liquid gel electrolyte incorporated with polyethyleneimine. At first, N-doped carbon particles were synthesized hydrothermally, followed by the decoration of a tiny amount of Pt nanoparticles using a microwave reactor. The working electrode was printed with a composite of high-impact polystyrene (HIPs), graphite powder (Gr), and a PtNC catalyst (HIPs/Gr/PtNC), then counter and reference electrodes were separately printed without the PtNC catalyst. The sensing materials were characterized using various analytical methods, including SEM, XPS, Raman, ICP-AES, CV, and EIS. Prior to detecting oxygen gas, the 3D sensor surface was pretreated with potential cycling in an acidic solution. Additionally, a composite gel electrolyte was prepared by incorporating polyethyleneimine into an ionic liquid, which was then coated onto the sensor surface to enhance sensitivity and ensure long-term stability. The analytical parameters using the final sensor were optimized in terms of Pt contents, 3D-printing polymer type, and ionic liquid gel concentration. The amperometric measurements demonstrated a wide dynamic range from 0.1 % to 100 % with the detection limit of 0.13 ± 0.05 % at a 90 % response time of 3.6 ± 0.4 s. To validate the reliability of the proposed sensor, the measurement of O2 content was performed for room air and standard oxygen gas, revealing reliable and stable results for six months.
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