Sensitive High-resolution Ion Microprobe Dating Research Articles

Reconsidering initial Pb in titanite in the context of in situ dating

Abstract In situ U-Pb dating of titanite, which can preserve trace-element records of various petrologic processes but also incorporates significant initial Pb, has proliferated in recent years. The widespread use of titanite data to construct tectonic P-T-t paths warrants careful assessment of the available dating techniques, as well as attention to the assumptions that underpin the U-Pb data analysis. This contribution provides the first direct comparison of the two major analytical methods [SHRIMP (SIMS) and LA-ICP-MS] for in situ U-Pb titanite dating. A set of well-characterized titanite grains from Harrisville, New York, in the Adirondack Mountains were analyzed for U-Th-Pb isotopes along the same cross-grain traverses by Sensitive High Resolution Ion Microprobe (SHRIMP) and LA-ICP-MS. Both LA-ICP-MS and SHRIMP data sets define approximately linear arrays on the Tera-Wasserburg Concordia (semi-total Pb/U) diagram and would commonly be interpreted as representing a single date population with minor scatter. However, previous studies have suggested that Adirondack titanite actually records two regionally well-defined thermal events, ~50–100 m.y. apart. When titanite data arrays are treated in detail, attempts to determine concordia-intercept ages by robust three-dimensional linear regression produce large uncertainties and/or poor fit statistics that suggest that the data are not, in fact, isochronous. Grain-by-grain analysis of U-Pb titanite data shows that different subsets of titanite (determined by additional geochemical and microstructural data) show different patterns of U-Pb data. By comparing predictions for Pb-ingrowth evolution paths in Tera-Wasserburg diagrams with observed data, it is possible to recognize both a change in initial Pb composition and Pb loss in the Adirondack titanite U-Pb data set. This study provides an example of how greater geochronologic detail can be extracted from large in situ U-Pb titanite data sets. Even when precise dates are not recovered, geological processes and events that cause data scatter can be recognized through analysis of U-Pb data patterns using the Tera-Wasserburg diagram.

U-Pb detrital zircon ages of Cambrian–Ordovician sandstones from the Taebaeksan Basin, Korea: Provenance variability in platform shelf sequences and paleogeographic implications

Abstract The early Paleozoic paleogeography of East Gondwanan terranes, including the North China Craton (NCC), is contentious, primarily reflecting the paucity of integrated geochronological, biogeographic, and tectonic data sets. Our new sensitive high-resolution ion microprobe data from 14 sandstones of the Taebaeksan Basin, Korea, indicate that its platform shelf sequences, typified by trilobite faunal assemblages diagnostic of the NCC, record the vestige of coeval arc magmatism. Detrital zircons analyzed from the sandstones yielded Eoarchean to Early Ordovician ages, which define three distinct types of distribution patterns characterized by: (1) double peaks at ca. 1.85 Ga and 2.50 Ga diagnostic of basement rocks in the NCC; (2) minor peaks at ca. 1.75, 1.6, and 1.2–1.1 Ga in addition to double peaks; and finally (3) a scattered array of late Paleoproterozoic to Neoproterozoic zircons lacking double peaks. The marked contrasts among the three types reflect significant changes in provenance, most likely linked to variations in paleo-water depths during the “Sauk” transgression. Longshore- or onshore-directed currents, associated with an increase in water depth, apparently brought outboard oceanic detritus and benthic trilobites into the relatively flat outer shelf of the Taebaeksan Basin. As a result, fine-grained sandstones received a large amount of detritus from distal sources, yielding mixed signatures in zircon age patterns and trilobite assemblages. Excluding the basal sandstone-conglomerate unit, five siliciclastic formations contain syndepositional zircon populations, and their weighted mean 206Pb/238U ages decrease upsection from 512 ± 5 Ma to 483 ± 2 Ma, indicating a sedimentary influx from contemporaneous volcanic activity. In conjunction with arc-related bulk-rock geochemistry and juvenile Nd isotopic signature, early Paleozoic detrital zircons likely represent the first-cycle detritus supplied for ∼30 m.y. from the proto-Japan arc that initially formed at ca. 520 Ma. Together with the occurrence of ca. 700–500 Ma detrital Pacific Gondwana zircons in fine-grained sandstones, Paleozoic arc-sourced detritus suggests that the Korean Peninsula was paleogeographically linked to an ancient convergent margin, perhaps extending from the Terra Australis orogen.

SHRIMPDB: a new geoanalytical database for U-Th-Pb geochronological data from SHRIMP measurements

This paper introduces a novel web-based database, SHRIMPDB, to support the efficient reutilization of U-Th-Pb geochronological data from sensitive high-resolution ion microprobe (SHRIMP) measurements. In order to provide complete data content that can be reutilized by Earth scientists, a new data model containing analytical data and relevant sample metadata is proposed according to analyses of measurement procedures and the data characteristics of SHRIMP. Vivid data visualization, real-time data query interfaces (including a novel and intuitive polygonal region search), and a pragmatic data management module are designed and implemented using web-based and cloud GIS-based technologies, which provide a platform for Earth scientists to efficiently curate and share SHRIMP data on the internet. An incentive that encourages geochronologists to contribute data is suggested through cooperation between SHRIMPDB and the Beijing SHRIMP center. The database is currently under evaluation at the Beijing SHRIMP center. SHRIMPDB is globally available online at http://202.198.17.27/shrimpdb/home .

The Betic Ophiolites and the Mesozoic Evolution of the Western Tethys

The Betic Ophiolites consist of numerous tectonic slices, metric to kilometric in size, of eclogitized mafic and ultramafic rocks associated to oceanic metasediments, deriving from the Betic oceanic domain. The outcrop of these ophiolites is aligned along 250 km in the Mulhacén Complex of the Nevado-Filábride Domain, located at the center-eastern zone of the Betic Cordillera (SE Spain). According to petrological/geochemical inferences and SHRIMP (Sensitive High Resolution Ion Micro-Probe) dating of igneous zircons, the Betic oceanic lithosphere originated along an ultra-slow mid-ocean ridge, after rifting, thinning and breakup of the preexisting continental crust. The Betic oceanic sector, located at the westernmost end of the Tethys Ocean, developed from the Lower to Middle Jurassic (185–170 Ma), just at the beginning of the Pangaea break-up between the Iberia-European and the Africa-Adrian plates. Subsequently, the oceanic spreading migrated northeastward to form the Ligurian and Alpine Tethys oceans, from 165 to 140 Ma. Breakup and oceanization isolated continental remnants, known as the Mesomediterranean Terrane, which were deformed and affected by the Upper Cretaceous-Paleocene Eo-Alpine high-pressure metamorphic event, due to the intra-oceanic subduction of the Jurassic oceanic lithosphere and the related continental margins. This process was followed by the partial exhumation of the subducted oceanic rocks onto their continental margins, forming the Betic and Alpine Ophiolites. Subsequently, along the Upper Oligocene and Miocene, the deformed and metamorphosed Mesomediterranean Terrane was dismembered into different continental blocks collectively known as AlKaPeCa microplate (Alboran, Kabylian, Peloritan and Calabrian). In particular, the Alboran block was displaced toward the SW to occupy its current setting between the Iberian and African plates, due to the Neogene opening of the Algero-Provençal Basin. During this translation, the different domains of the Alboran microplate, forming the Internal Zones of the Betic and Rifean Cordilleras, collided with the External Zones representing the Iberian and African margins and, together with them, underwent the later alpine deformation and metamorphism, characterized by local differences of P-T (Pressure-Temperature) conditions. These Neogene metamorphic processes, known as Meso-Alpine and Neo-Alpine events, developed in the Nevado-Filábride Domain under Ab-Ep amphibolite and greenschists facies conditions, respectively, causing retrogradation and intensive deformation of the Eo-Alpine eclogites.

Recurrent rare earth element mineralization in the northwestern Okcheon Metamorphic Belt, Korea: SHRIMP U–Th–Pb geochronology, Nd isotope geochemistry, and tectonic implications

Rare earth element (REE) mineralization is hosted within Neoproterozoic alkaline metaigneous rocks in the northwestern part of the Okcheon Metamorphic Belt (OMB), a polymetamorphosed fold-and-thrust belt transecting the Paleoproterozoic Gyeonggi and Yeongnam Massifs in the southern Korean Peninsula. The principal carrier phase of REEs is allanite. Allanite grains can be subdivided into several types based on the texture and mineral assemblage including quartz, K-feldspar, biotite, britholite, apatite, fergusonite, andradite, magnetite, zircon, titanite and fluorite. Electron microprobe analysis of allanite clearly distinguishes sample-to-sample variations in total REEs, Ca, Al, Fe and Y but the textural varieties from each rock sample do not show marked differences in those elements. Sensitive high-resolution ion microprobe dating of allanite and zircon reveals a complex history of multistage mineralization. Allanite grains from REE ores yielded Late Ordovician (444.6±8.0Ma), Permian to Triassic (ca. 300–220Ma) and Early Jurassic (199–183Ma) 208Pb/232Th ages. These multiple age components often coexist in single grains showing slight differences in backscattered electron brightness. The Ordovician components have distinctly higher Th/U than the younger domains in the same rock sample. The cores and rims of zircon from a syenite hosting REE ore bodies yielded Neoproterozoic (858.2±6.3Ma) and Early Jurassic (ca. 190Ma) 206Pb/238U ages, respectively. The Early Jurassic ages (194–187Ma) also obtained from zircon grains from granites taken from dykes occurring close to the ores and a drill core indicate the correspondence between granitic magmatism and REE mineralization. The Neoproterozoic zircon inheritance (weighted mean=853.9±3.8Ma) in these granites is in sharp contrast to the dominant Paleoproterozoic inherited zircon from the widespread earliest Middle Jurassic granites enclosing the mineralized zone. The geotectonic significance of the Late Ordovician event recorded in the allanite, as well as in detrital zircon from the OMB, is still unclear but its temporal coincidence with intraplate volcanism and arc-related igneous activity, respectively, reported from the southwestern edge of the adjacent Taebaeksan Basin and the southwestern Gyeonggi Massif is noteworthy. The following Permian–Triassic and Early Jurassic mineralization events are probably linked to the continental suturing between the North and South China blocks and subsequent post-orogenic magmatism, and arc magmatism resulting from the paleo-Pacific plate subduction, respectively. Sub-grain Sm–Nd isotopic analyses of allanite by laser ablation multiple collector ICPMS yielded initial εNd values plotting along the Nd isotopic evolution path of the Neoproterozoic metaigneous rocks, indicating that REEs originating from the host rock have been recycled during multistage mineralization events. The profound differences in inherited zircon ages and Nd isotopic compositions between the Early and Middle Jurassic granites may reflect the presence of a major thrust-bounded crustal structure beneath the OMB.

Ti-in-zircon thermometry and crystallization modeling support hot Grenville granite hypothesis

Quantitative modeling of crystallization histories using the program rhyolite-MELTS indicates that zircon crystallization in 1.0 to 1.2 Ga Grenville granitoids with Zr concentrations of 300–1200 ppm begins at 930–1000 °C, and always after onset of crystallization of most other phases (pyroxenes, feldspars, quartz, apatite, ilmenite). Zircon saturation temperatures, calculated from whole-rock compositions and Zr concentrations for modeled samples, range from 835 to 997 °C. Zircon in the two samples with the highest Zr (1201 and 829 ppm) analyzed by sensitive high-resolution ion microprobe (SHRIMP) yielded Ti contents of 10–77 ppm, corresponding to Ti-in-zircon temperatures as high as 1035 °C and 915 °C, respectively. These are among the highest Ti-in-zircon temperatures recorded in magmatic rocks. The modeling and SHRIMP data support the hypothesis that high-Zr Grenville granites are hot granites, and support tectonic models that invoke high-temperature (>900 °C) crustal conditions for generation of Grenville magmas.

Integrated pressure–temperature–time constraints for the Tso Morari dome (Northwest India): implications for the burial and exhumation path of UHP units in the western Himalaya

AbstractNorthward subduction of the leading edge of the Indian continental margin to depths greater than 100 km during the early Eocene resulted in high‐pressure (HP) quartz‐eclogite to ultrahigh‐pressure (UHP) coesite–eclogite metamorphism at Tso Morari, Ladakh Himalaya, India. Integrated pressure–temperature–time determinations within petrographically well‐constrained settings for zircon‐ and/or monazite‐bearing assemblages in mafic eclogite boudins and host aluminous gneisses at Tso Morari uniquely document segments of both the prograde burial and retrograde exhumation path for HP/UHP units in this portion of the western Himalaya. Poikiloblastic cores and inclusion‐poor rims of compositionally zoned garnet in mafic eclogite were utilized with entrapped inclusions and matrix minerals for thermobarometric calculations and isochemical phase diagram construction, the latter thermodynamic modelling performed with and without the consideration of cation fractionation into garnet during prograde metamorphism. Analysis of the garnet cores document (M1) conditions of 21.5 ± 1.5 kbar and 535 ± 15 °C during early garnet growth and re‐equilibration. Sensitive high resolution ion microprobe (SHRIMP) U–Pb analysis of zircon inclusions in garnet cores yields a maximum age determination of 58.0 ± 2.2 Ma for M1. Peak HP/UHP (M2) conditions are constrained at 25.5–27.5 kbar and 630–645 °C using the assemblage garnet rim–omphacite–rutile–phengite–lawsonite–talc–quartz (coesite), with mineral compositional data and regional considerations consistent with the upper P–T bracket. A SHRIMP U–Pb age determination of 50.8 ± 1.4 Ma for HP/UHP metamorphism is given by M2 zircons analysed in the eclogitic matrix and that are encased in the garnet rim. Two garnet‐bearing assemblages from the Puga gneiss (host to the mafic eclogites) were utilized to constrain the subsequent decompression path. A non‐fractionated isochemical phase diagram for the assemblage phengite–garnet–biotite–plagioclase–quartz–melt documents a restricted (M3) P–T stability field centred on 12.5 ± 0.5 kbar and 690 ± 25 °C. A second non‐fractionated isochemical phase diagram calculated for the lower pressure assemblage garnet–cordierite–sillimanite–biotite–plagioclase–quartz–melt (M4) documents a narrow P–T stability field ranging between 7–8.4 kbar and 705–755 °C, which is consistent with independent multiequilibria P–T determinations. Th–Pb SHRIMP dating of monazite cores surrounded by allanite rims is interpreted to constrain the timing of the M4 equilibration to 45.3 ± 1.1 Ma. Coherently linking metamorphic conditions with petrographically constrained ages at Tso Morari provides an integrated context within which previously published petrological or geochronological results can be evaluated. The new composite path is similar to those published for the Kaghan UHP locality in northern Pakistan, although the calculated 12‐mm a−1 rate of post‐pressure peak decompression at Tso Morari would appear less extreme.

Mid- to Late Cambrian docking of the Río de la Plata craton to southwestern Gondwana: age constraints from U–Pb SHRIMP detrital zircon ages from Sierras de Ambato and Velasco (Sierras Pampeanas, Argentina)

Abstract: The Early Palaeozoic stratigraphy and tectonic history of the Eastern Sierras Pampeanas of central Argentina are complicated by metamorphism and deformation resulting from the Pampean (545–510 Ma) and Famatinian (490–440 Ma) orogenies. We report U–Pb sensitive high-resolution ion microprobe dating of detrital zircons in two metasedimentary successions exposed at Quebrada de La Cébila ( c . 28°45'S, 66°25'W): the Ambato and the La Cébila metamorphic complexes. The Ambato zircons record age peaks corresponding to Pampean (530 ± 10 Ma), Brasiliano ( c . 570 and c . 640 Ma), Grenville ( c . 950 to c . 1025 Ma) and minor Neoarchaean ages. Similar peaks are also apparent in the La Cébila sample but it additionally contains Palaeoproterozoic zircons ( c . 2.1 Ga) corresponding to the age of the Rio de la Plata craton, from which they are considered to have been sourced. Our interpretation is that the protolith of the Ambato complex was deposited prior to juxtaposition with the craton and is older than the Early Ordovician La Cébila metamorphic complex. We infer that the craton reached its current relative position in the Mid- to Late Cambrian, after the main Pampean tectonothermal event (530–520 Ma) and before deposition of the La Cébila protolith and the Achavil Formation (Sierra de Famatina), which contain comparable detrital zircon populations.

Calc-alkaline I-type plutons in the eastern Pontides, NE Turkey: U–Pb zircon ages, geochemical and Sr–Nd isotopic compositions

The Köprübaşı intrusion from the eastern Pontides of NE Turkey consists of granodiorite and monzogranite, and contains a number of mafic microgranular enclaves (MMEs). We report here U–Pb zircon age, geochemical and Sr–Nd isotopic data for these rocks in order to determining magma sources and magma production processes. On the basis of U–Pb zircon sensitive high-resolution ion microprobe dating (SHRIMP), the magma emplacement age of the granodiorite is 79.3 ± 1.4 Ma. The rocks of the pluton are calc-alkaline, metaluminous to peraluminous characteristics, and display features of I-type granites. They are enriched in large ion lithophile elements (LILE) and light rare earth elements (LREE) with negative Eu anomalies (Eu/Eu* = 0.60–0.76), but are depleted in high field strength elements (HFSE). They have small range of 87Sr/ 86Sr ( i) (0.7067–0.7070) and ɛ Nd( i) (−3.2 to −4.4) values. Fractionation of plagioclase, hornblende and Fe–Ti oxides played an important role in the evolution of the Köprübaşı intrusion. A relatively shallow intrusion depth (∼2–8 km) was estimated from the Al-in-hornblende geobarometry. All these characteristics, combined with the low values of K 2O/Na 2O, SiO 2, Al 2O 3/(FeO T + MgO + TiO 2) and (Na 2O + K 2O)/(FeO T + MgO + TiO 2), suggest an origin by dehydration melting from a metabasaltic lower crustal source.

The contribution of the sensitive high-resolution ion microprobe (SHRIMP) to lunar geochronology

The sensitive high-resolution ion microprobe (SHRIMP) developed at the Australian National University (ANU) was the first of the high-resolution ion microprobes. The impact of this instrument on geochronological research over the last twenty years has been immense. This is particularly so for lunar geochronology where it has opened up avenues of research that were not possible using conventional TIMS techniques. The great advantage of SHRIMP is that it provides a means for determining precise U–Pb isotopic ratios on selected micron-size areas on polished grains of zircon and other U-bearing minerals. One of the first projects undertaken on the newly invented SHRIMP I was an investigation of U–Pb ages of lunar zircon. Using SHRIMP, multiple analyses could be made on areas of individual zircons to test the stability of U–Pb systems in shocked grains. Also, by analysing grains “ in situ”, textural relationships between the analysed zircon and the components of the sample breccia could be used in the interpretation of the SHRIMP data. As a result of this research it was realised that most lunar zircons have ages up to 500 Ma older than the Imbrium and Serenitatis impacts at ca. 3.9 Ga, demonstrating that the zircons have not been affected by the these impact events although heating and shock effects have profoundly disturbed other dating systems. This has opened the way for research into the early lunar magmatic and bombardment record. For example, recent SHRIMP results have revealed profound differences in the ages of zircons from breccias from the Apollo 14 and Apollo 17 sample sites, raising new questions about the evolution of lunar magmatism. Also, multiple SHRIMP analyses on complex lunar zircons have shown that these grains can record U–Pb disturbance by later impact events. SHRIMP U–Pb age determinations on phosphates in lunar meteorites has identified lunar events not recognised in samples from the Apollo program. SHRIMP-based research on lunar materials is ongoing and, in combination with other chemical and structural evidence, continues to stimulate new ideas on the early evolution of the Moon.

U–Pb and40Ar–39Ar geochronology of the Baiyunshan gneiss (central Guangdong, south China): constraints on the timing of early Palaeozoic and Mesozoic tectonothermal events in the Wuyun (Wuyi-Yunkai) Orogen

AbstractComposite Sensitive High Resolution Ion Microprobe (SHRIMP) U–Pb zircon and40Ar–39Ar step-heating biotite-hornblende ages are used to provide constraints on the timing and origin of the felsic gneissic rocks in the Baiyunshan Mountains region and to elucidate their tectonothermal history. SHRIMP dating and CL imaging of zircons give magmatic zircon crystallization ages between Late Ordovician and Early Silurian (c.453.5 Ma, 446 Ma, and 439 Ma) for three representative felsic gneisses, suggesting that most of the Baiyunshan gneiss cannot represent basement rocks of the Cathaysia Block as previously thought. Including the present age information, a synthesis of available age data for regional Wuyun (Wuyi-Yunkai) events reflects the emergence of orogen-wide magmatism that could be syn-orogenic and have occurred mainly between 460 and 420 Ma in the South China Block. Inherited zircons are abundant, with ages clustering at late Mesoproterozoic (1189–1017 Ma) and middle Mesoproterozoic (772 Ma), which reveals that the Baiyunshan orthogneiss samples a crustal basement containing significant igneous or recycled components related to the Rodinia amalgamation and break-up. A SHRIMP date of 212 ± 12 Ma from a white rim of zircon provides evidence for metamorphic overprinting of an Indosinian tectonothermal event on the Baiyunshan gneiss. Incremental heating experiments with six biotite samples and one hornblende sample from a variety of metamorphic rocks yielded two distinct40Ar–39Ar age groups: 150–155 and 94–98 Ma. The older ages are similar to zircon U–Pb dates for widespread granitic intrusions in central Guangdong. We attribute them to Late Jurassic magmatism-induced thermal resetting of the biotite K–Ar system. On the other hand, the younger age group is interpreted to record either cooling through the biotite closure temperature of ~300–350 °C or a second resetting of biotite Ar isotopes atc.94–98 Ma due to contemporaneous magmatic activity. Our present age data suggest that the Maofengshan orthogneiss was exhumed to 8 to 10 km crustal levels atc.150 Ma, whereas the eastward components of gneissic rock masses appear to have passed upward through the same crustal depth synchronously or later (byc.94 Ma). Exhumation of middle crustal-level rocks in the study area sincec.155 Ma is roughly coeval with exhumation of gneissic rocks from elsewhere in the Wuyun Orogen, suggesting a large-scale mechanism for the exhumation pulse related to the Yanshanian extensional tectonic regime.

Petrology, Sr–Nd–Hf isotopic geochemistry and zircon chronology of the Late Palaeozoic volcanic rocks in the southwestern Tianshan Mountains, Xinjiang, NW China

Abstract: The Late Palaeozoic volcanic rocks, mainly consisting of basalt, trachyte, trachy-andesite, andesite and rhyolite, widely distributed in the southwestern Tianshan Mountains, have been proven to be formed during Late Devonian to Late Carboniferous time (>361–313 Ma) based on zircon sensitive high-resolution ion microprobe dating. The geochemistry demonstrates that the studied volcanic rocks represent a continental arc formed during the subduction of the Palaeo-southern Tianshan Ocean. The ε Hf(T) values of zircons in these volcanic rocks vary from +1.4 to +15.6 with weighted average values of +9.5 (Late Devonian), +8.9 (Early Carboniferous) and +10.3 (Late Carboniferous), suggesting a depleted mantle origin. However, the Late Devonian basaltic samples have negative ε Nd(T) values (from −5.16 to −3.07) and high initial 87 Sr/ 86 Sr ratios (0.7073–0.7098), whereas the Early Carboniferous volcanic rocks mostly have positive ε Nd(T) values (from −0.18 to +3.07) with low initial 87 Sr/ 86 Sr ratios (0.7044–0.7067), and the Late Carboniferous volcanic rocks are characterized by high ε Nd(T) values (+2.79 to +5.89) and low initial 87 Sr/ 86 Sr ratios (0.7032–0.7054). The assimilation–fractional crystallization (AFC) model is used to explain the isotope characteristics of the Late Devonian volcanic rocks in the southwestern Tianshan Mountains. Calculation shows that the Late Devonian samples could be formed by the AFC process between depleted mantle and continental crust. The Carboniferous basaltic rocks originated by partial melting of the mantle wedge. Supplementary material: Data are available at http://www.geolsoc.org.uk/SUP18378 .

Characterisation of igneous terranes by zircon dating: implications for UHP occurrences and suture identification in the Central Rhodope, northern Greece

The occurrence of ultra high pressure (UHP) and high pressure (HP) relicts associated with oceanic material suggests the presence of a suture zone within the Rhodope Massif. Characterisation of the accreted igneous terranes and their relationship with the UHP/eclogite occurrences provide new constraints on the location of this suture. Single-zircon evaporation and sensitive high-resolution ion microprobe dating of orthogneiss protoliths define two groups of intrusion ages: Permo-Carboniferous and Late Jurassic–Early Cretaceous. Structurally, the Late Jurassic gneissic complex overthrust a unit with Permo-Carboniferous orthogneisses. A “melange zone” marked by mylonites, eclogites, amphibolites, and UHP micaschists separates these two units. We interpret these observations in terms of two distinct igneous terranes, the Thracia (Permo-Carboniferous) and Rhodope (Late Jurassic) terranes, separated by the Nestos suture, and assembled during the closure of an oceanic basin of the Tethys. Geochemically, the Late-Jurassic rocks are akin to subduction magmatism, possibly the same subduction that caused the UHP metamorphism of metasediments within the “melange zone”. Observed UHP–HP relicts are restricted to the tectonic contact zone, suggesting that a single subduction/collison event can explain the occurrences of UHP relicts and eclogites in the Central Rhodope, and that subducted rocks are exhumed only within the Nestos suture.

U-Pb zircon SHRIMP ages, geochemical and Sr-Nd isotopic compositions of the Early Cretaceous I-type Sarıosman pluton, Eastern Pontides, NE Turkey

The petrogenesis and U-Pb SHRIMP zircon ages of the Late Cretaceous Sarıosman pluton in the Eastern Pontides is investigated by means of whole-rock Sr-Nd isotope data with field, petrographic and whole-rock geochemical studies. The bulk of the I-type Sarıosman pluton consists of biotite-hornblende monzogranite, with minor quantities of porphyritic hornblende-biotite monzogranite. The biotite-hornblende monzogranite contains a number of mafic microgranular enclaves (MMEs) of quartz monzodiorite composition. U-Pb zircon sensitive high-resolution ion microprobe dating (SHRIMP) dates the magma emplacement age of the biotite-hornblende monzogranite at 82.7±1.5 Ma. The rocks of the pluton show high-K calc-alkaline, metaluminous to slightly peraluminous characteristics, and are enriched in large ion lithophile elements (LILE) and light rare earth elements (LREE) relative to high field strength elements (HFSE), thus displaying features of arc-related granitoids. Chondrite-normalised rare earth-element (REE) patterns have concave upward shapes (La/_{cn}/Lu_{cn}= 10.1-17.4) with pronounced negative Eu anomalies (Eu/Eu*= 0.61-0.80). Initial \epsilon_{Nd} values vary between -3.0 and -4.1 and initial ^{87}Sr/^{86}Sr values between 0.7062 and 0.707. The MMEs are characterised by higher Mg-numbers (27-29) and lower values of both SiO_2 (56-58 wt percent) and aluminium saturation index (0.9-1.0), compared to the monzogranites. Fractionation of plagioclase, hornblende and Fe-Ti oxides played an important role in the evolution of the Sarıosman pluton. The crystallisation temperatures of the melts ranged from 700 to 800 °C and a relatively shallow intrusion depth (~2 to 7 km) is estimated from the Al-in-hornblende geobarometry. The geochemical and isotopic compositions of the Sarıosman pluton suggest an origin through dehydration melting of mafic lower crustal source rocks.

Enigmatic sedimentary–volcanic successions in the central European Variscides: a Cambrian/Early Ordovician age for the Wojcieszów Limestone (Kaczawa Mountains, SW Poland) indicated by SHRIMP dating of volcanic zircons

AbstractMetamorphosed volcanic and sedimentary successions in the central European Variscides are, in many areas, poorly biostratigraphically constrained, making palaeotectonic interpretations uncertain. In such instances, geochronological data are crucial. Sensitive high resolution ion microprobe (SHRIMP) dating of volcanic zircons from a quartz–white mica schist (interpreted as deformed metavolcaniclastic/epiclastic rock) within the stratigraphically controversial Wojcieszów Limestone of the Kaczawa Mountains (Sudetes, SW Poland), near to the eastern termination of the European Variscides, has yielded an age of 498 ± 5 Ma (2σ error), corresponding to late Cambrian to early Ordovician magmatism in that area and constraining the depositional age of the limestones. The new SHRIMP data are not consistent with the recent revision of the age of the Wojcieszów Limestone based on Foraminifera findings that ascribed them to a Late Ordovician—Silurian or even younger interval. They are though, consistent with sparse macrofossil data and strongly support earlier interpretations of the lower part of the Kaczawa Mountains succession as a Cambrian–Early Ordovician extensional basin‐fill with associated initial rift volcanic rocks, likely emplaced during the breakup of Gondwana. Copyright © 2008 John Wiley & Sons, Ltd.

Petrology, geochronology, and tectonic implications of c . 500 Ma metamorphic and igneous rocks along the northern margin of the Central Asian Orogen (Olkhon terrane, Lake Baikal, Siberia)

A significant portion of the continental crust of northern Eurasia is thought to have formed during the evolution of the Central Asian Orogenic Belt at the time of accretion of continental terranes and island arcs. Records of this event are well preserved within the Siberian craton–Central Asian Orogenic Belt transition zone in Lake Baikal region, particularly in the Olkhon terrane. Our results establish granulite-facies conditions for peak metamorphism in the Olkhon terrane, and indicate that the granulites were derived from island arc mafic volcanic rocks and back-arc basin sediments. Sensitive high-resolution ion microprobe dating of metamorphic zircons from two mafic granulites yielded 238 U/ 206 Pb ages of 507 ± 8 and 498 ± 7 Ma, and magmatic zircons from syntectonic syenite yielded an age of 495 ± 6 Ma. The main metamorphic event occurred at about 500 Ma, and was probably related to collision of the Barguzin microcontinent with the Siberian craton. Ages from 535 to 2750 Ma for detrital zircon cores in early Palaeozoic metasediments of the Olhkon terrane were obtained. Archaean ages of detrital zircons in such metasediments suggest that the Barguzin microcontinent was originally part of the Aldan Province of the Siberian craton that was detached in late Mesoproterozoic, and reattached to the craton during early Palaeozoic collision.

Mesozoic tectonics in the Eastern Block of the North China Craton: implications for subduction of the Pacific plate beneath the Eurasian plate

Abstract The Jiao-Liao massif is located in the hanging wall of the north-dipping Dabie–Sulu suture zone and is an important part of the Eastern Block of the North China Craton. Several important tectonic models for the tectonic evolution of Eastern Asia rely on critical information from the Jiao-Liao massif. This paper combines new sensitive high-resolution ion microprobe (SHRIMP) U–Pb zircon ages of the Dandong Granite in the southern Liaoning Province, China, with extensive field data for the eastern North China Craton, including the Bohai Bay Basin. Combined with other recent SHRIMP dating, we use this information to summarize the Mesozoic tectonic reactivation and evolutionary processes of the Jiao-Liao massif of the Eastern Block of the North China Craton. In this study we identify a c . 160 Ma episode of partial melting of Palaeoproterozoic plutons in the Jiao-Liao massif. Cathode luminescence and backscatter electron imagery reveal c . 167–157 Ma magmatic euhedral single zircons and magmatic zircon rims surrounding c . 2100 Ma cores in the Dandong Granites near the Liaonan Neoarchaean terrane. This partial melting is probably related to in situ remelting of ancient lower continental material, mostly the North China Craton. The Dandong plutons are aligned in a NE–SW direction and are extensively deformed by subhorizontal ductile thrust-related shearing and subsequent NNE–SSW trending folds. Here, we show that for the Dandong area the first deformation occurred between 195 and 193 Ma, based on K–Ar and 40 Ar/ 39 Ar ages of muscovites from east–west-trending shear zones on the Liaodong Peninsula. Based on the field relationships between the plutons and structural fabrics, a range from 153 to 145 Ma is defined as the duration of the second deformation in the Dandong Granites. The third deformation is marked by the formation of NNE–SSW strike-slip faults between 135 and 95 Ma. This deduced age range is similar to an 40 Ar/ 39 Ar age range of 128–132 Ma of initial sinistral strike-slip faulting of the Tan-Lu fault in Anhui Province and to a biotite cooling age of 100±2.3 Ma of the Yilan–Yitong segment of the Tan-Lu fault in the Jilin Province. These faults are transtensive and controlled the formation of pull-apart basins. However, during the third deformation, some metamorphic core complexes in Eastern China formed in the overlapping area between the large-scale sinistral faults. Our SHRIMP data also indicate that the Liaodong basement and its Early Mesozoic magmatism are similar to the Jiaodong basement and its Mesozoic magmatism. Therefore, the Early Mesozoic evolution of the Liaodong area, similar to that of the Jiaodong area, was also closely related to the Sulu orogen in the Early Mesozoic and to the Pacific subduction throughout the Mesozoic.

New insights into the history and origin of the southern Maya block, SE México: U–Pb–SHRIMP zircon geochronology from metamorphic rocks of the Chiapas massif

The histories of the pre-Mesozoic landmasses in southern Mexico and their connections with Laurentia, Gondwana, and among themselves are crucial for the understanding of the Late Paleozoic assembly of Pangea. The Permian igneous and metamorphic rocks from the Chiapas massif as part of the southern Maya block, Mexico, were dated by U–Pb zircon geochronology employing the SHRIMP (sensitive high resolution ion microprobe) facility at Stanford University. The Chiapas massif is composed of deformed granitoids and orthogneisses with inliers of metasedimentary rocks. SHRIMP data from an anatectic orthogneiss demonstrate that the Chiapas massif was part of a Permian (∼ 272 Ma) active continental margin established on the Pacific margin of Gondwana after the Ouachita orogeny. Latest Permian (252–254 Ma) medium- to high-grade metamorphism and deformation affected the entire Chiapas massif, resulting in anatexis and intrusion of syntectonic granitoids. This unique orogenic event is interpreted as the result of compression due to flat subduction and accretionary tectonics. SHRIMP data of zircon cores from a metapelite from the NE Chiapas massif yielded a single Grenvillian source for sediments. The majority of the zircon cores from a para-amphibolite from the SE part of the massif yielded either 1.0–1.2 or 1.4–1.5 Ga sources, indicating provenance from South American Sunsas and Rondonian-San Ignacio provinces.

U-Pb SHRIMP data on the crystallization age of the Gran Paradiso augengneiss, Italian Western Alps: Further evidence for Permian magmatic activity in the Alps during break-up of Pangea

New U-Pb Sensitive High Resolution Ion MicroProbe (SHRIMP) ages from two augengneiss samples of the Gran Paradiso Massif in the Italian Western Alps yielded well-defined Late Permian crystallization ages of 269.0±6.5 Ma and 270.2±5.0 Ma. The ages provide further evidence that the Gran Paradiso augengneiss is not Variscan basement but reflects post-Variscan magmatic activity related to the break-up of Pangea after the Variscan orogeny eventually leading to the formation of Neo-Tethys. The Gran Paradiso Massif belongs to the so-called internal massifs, which are marked by extension-related bimodal magmatism during the Permian and Mesozoic. Furthermore, the Late Permian ages suggest that the Gran Paradiso Massif did not belong to the same pre- Alpine tectonic domain as the External massifs (as part of the European plate margin), which are characterized by Variscan basement.

Significance of Devonian–Carboniferous igneous activity in Tasmania as derived from U–Pb SHRIMP dating of zircon

A series of new Sensitive High-Resolution Ion MicroProbe (SHRIMP) U – Pb ages is presented for Palaeozoic (mainly Devonian and Carboniferous) granites from Tasmania. In virtually all instances the new ages are significantly older than previously determined Rb – Sr and K – Ar ages, even though the level of emplacement had been thought to be too shallow to allow loss of radiogenic daughter products. In two extreme cases, granite bodies at South West Cape and Elliott Bay that had previously yielded Carboniferous Rb – Sr and Early Devonian K – Ar ages, respectively, are now both shown to be Late Cambrian. In northeast Tasmania, granitic activity in the Blue Tier Batholith lasted for about 22 million years, with I-type magmas being followed by S-types only toward the end of that time. The exclusively I-type granites of the Scottsdale Batholith formed about 10 million years after the initiation of igneous activity in the Blue Tier Batholith, and were emplaced over a comparatively short time interval (4 – 5 million years). The new data confirm a previously held view, based on Rb – Sr analysis, that the economically important Lottah Granite crystallised roughly 9 million years later than the nearby Poimena Granite and, therefore, could not have been derived by magmatic fractionation of the latter. A regional deformation equated with the Tabberabberan Orogeny has been dated at about 390 Ma in northeastern Tasmania, based on the presence or absence of a northwest-trending foliation in the different granite bodies. The oldest granites occur in the northeast of Tasmania, with an irregular progression of ages to the west coast. A trend of this type could have arisen in an arc-free or arc-related environment. If the latter applies, either flat subduction or processes associated with the amalgamation of eastern and western basement terranes might be the controlling mechanism. Eastern Tasmania experienced a trend from mafic I-type to progressively more felsic, largely S-type igneous activity, but the trend for western Tasmania is not as obvious. The trend for eastern Tasmania is an exception to the general rule for the Lachlan Orogen, possibly signifying that the mid-crust was relatively cool when the first I-type granites were generated. Crustal thickening during the Tabberabberan Orogeny may have been a prerequisite for the generation of later, more felsic, S- and I-types.