Sensitive Birefringence Measurement Research Articles

Anisotropic Shear Viscosity of Photoaligned Liquid Crystal Confined in Submicrometer-to-Nanometer-Scale Gap Widths Revealed with Simultaneously Measured Molecular Orientation.

In the context of the use of liquid crystals (LCs) as lubricants and lubricant additives, this study investigates the anisotropic shear viscosity of LCs confined in nanometer-sized gap widths subject to both shearing and photoalignment. The photoalignment is achieved using anisotropically dimerized polyvinyl cinnamate (PVCi) films coated on substrates. We simultaneously measure the viscosity and order parameter of a liquid crystal (4-cyano-4'-pentylbiphenyl) confined and sheared in the gap range of 500 nm down to a few nm. We achieve this simultaneous measurement using an original method that combines a highly sensitive viscosity measurement and a sensitive birefringence measurement. When the LC is sheared in the same direction as the photoalignment (parallel shearing), the order parameter, which is around 0.3 in the bulk state, increases up to around 0.4 at a gap width of less than 50 nm and the viscosity is smaller than half the bulk viscosity. We consider that this increase in the order parameter is due to the highly ordered photoaligned LC layer near the PVCi film, and the viscosity decrease is due to shear thinning of this layer enhanced by both confinement and molecular ordering. In addition, we observe a gradual decrease in viscosity starting at a gap of less than around 300 nm in the parallel shearing. Based on the apparent slip model, we show that the LC layer near the PVCi film can also cause this gradual viscosity decrease. In contrast, when the LC is sheared in the direction perpendicular to the photoalignment direction (perpendicular shearing), the viscosity increases as the gap decreases. We speculate that this is due to the rotational motion of the LC molecules caused by the competing effect of shear alignment and photoalignment. We believe our findings can significantly contribute to a better understanding of the confined LCs utilized for lubrication.

Sensitive birefringence measurement in a high-finesse resonator using diode laser optical self-locking

We demonstrate a new method to measure weak birefringence of dielectric mirrors with excellent spatial resolution and sensitivity (<10-7 radians). We exploit a well-known optical feedback scheme for line-width narrowing and frequency locking of a diode laser to a high-finesse cavity. Feedback comes from the intracavity field which builds up at resonance, selected by its change in polarization with respect to the incident field. This change, due to the residual birefringence of the cavity mirror coatings, was already exploited for birefringence measurements using an active laser-locking scheme. Here we measure the optical feedback rate as a function of rotation angle of one of the cavity mirrors (around the cavity axis). A stable feedback signal is obtained since the laser, as soon as it locks to a cavity resonance, effectively behaves as a monochromatic source. By fitting the data with a theoretical expression, we determine quantitatively the local birefringence vectors of both mirrors, which are around 10-6 radians. Our scheme is simple, works with cavities of very high finesse (F∼105), and is promising for measuring birefringence in gases induced by external fields.

Stress distribution using high sensitive birefringence measurement system : Takayama, Manabu; Takada, Tatsuo; Yoshino, Toshio

Stress distribution using high sensitive birefringence measurement system : Takayama, Manabu; Takada, Tatsuo; Yoshino, Toshio

A new experimental device for sensitive birefringence measurements

AbstractA double beam detection method for the measurement of birefringence in stretching experiments of polymers is developed. By this method a noise free intensity signal is measured allowing a sensitive determination of the absolute birefringence. The efficiency of the experimental device is tested using cis‐1,4‐polybutadiene and butyl‐rubber networks.