Ruthenium (Ru) has the excellent characteristics of oxidation resistance and good chemical stability; therefore, it has been widely used in semiconductor manufacturing, specifically in application as capping layers of extreme ultraviolet lithography (EUV) masks. The main purpose of capping layers is to protect Mo/Si multilayers from EUV radiation, preventing oxidation, damages, and contamination of the multilayers. However, with prolonged use, the EUV mask accumulates heat, resulting in diffusion between Ru and Si. When diffusion reactions occurred, leading to a reduction in the EUV mask's lifetime. In order to study the reaction mechanism, we use in-situ transmission electron microscopy (TEM) to observe the reactions between Ru and Si. In this study, Ru thin film was deposited on silicon substrate by electron gun (E-gun) evaporation. The dynamic formation process of ruthenium silicide has been observed via in-situ TEM. During the heating process, Si atoms diffused into ruthenium thin film at 300 °C, at the same time, Ru atoms will also diffuse into silicon substrate. At 350 °C, due to the interdiffusion effect, Ru2Si is formed in the Ru thin film, and it is observed that Ru2Si3 is embedded in the Si substrate. As the temperature rises to 450 °C, Ru2Si was transformed into RuSi. Finally, at 600 °C, the Ru thin film completely transformed into Ru2Si3. We provide direct evidence of diffusion behaviors and formation mechanism of Ru-Si system for better investigation of EUV masks degradation processes in semiconductor manufacturing and design. Keywords: Ruthenium silicide, in situ TEM, diffusion mechanism, atomic-scale, EUV mask Figure 1. Structural identification of Ru thin film and in-situ heating process of ruthenium silicide formation. (a) Initial EDS mapping of as-deposited Ru thin film on silicon substrate, showing homogenous distribution of each elements. (b) HRTEM image of in-situ heating process during 350oC. (c) Magnified HRTEM image of Ru2Si indicated in blue frame in (b). (d) Corresponding fast Fourier transform (FFT) along [110] zone axis. (e) HRTEM image of in-situ heating process during 600oC. (f) Magnified HRTEM image of Ru2Si3 indicated in yellow frame in (e). (g) Corresponding FFT along [010] zone axis. Figure 1
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