Zone Sediments Research Articles

Navigating Greenhouse Gas Emission Unknowns: A Hydroacoustic Examination of Mediterranean Climate Reservoirs

AbstractInland aquatic systems, such as reservoirs, contribute substantially to global methane (CH4) emissions; yet they are among the most uncertain contributors to the total global carbon budget. Reservoirs generate significant amounts of CH4 within their bottom sediment, where the gas is stored and can easily escape via ebullition. Due to the large spatial and temporal variability associated with ebullition, CH4 fluxes from these aquatic systems are challenging to quantify. To address these uncertainties, six different water storage reservoirs, with average flux rates ranging between 20 and 678 mg CH4 m−2 d−1, were hydro‐acoustically surveyed using a previously established technique to investigate the spatial variability of free gas stored at the sediment surface that could be released as bubbles. Sediment samples and vertical profiles of temperature and dissolved oxygen were also collected to understand their respective influences on sediment gas formation. We found that the established relation used to determine sediment gas storage via the sonar technique, which relied solely on acoustic backscatter (Svmax), tended to underestimate gas storage in shallower, siltier sediment zones and overestimate gas storage in coarser (>2 mm) sediment zones. In response, we introduce an improved model, incorporating gas and sediment type as correction factors for gas attenuation effects on Svmax values. The extended model is able to elucidate patterns within the gas volume data, revealing clearer trends across different sediment types. This research provides valuable data and methodological insights that can enhance the accuracy of greenhouse gas modeling and budget assessments for reservoirs.

GEOLOGICAL CONDITIONS OF FORMATION AND DISTRIBUTION OF GAS-GEOCHEMICAL FIELDS IN BOTTOM SEDIMENTS OF THE LAPTEV-SIBERIAN SEA ZONE OF THE EAST ARCTIC SHELF

Gas composition of bottom sediments of the Laptev-Siberian Sea geostructural zone (LSZ) was determined to include: helium and hydrogen in concentrations of 0.0028–0.2092 and 0.0012–0.8727 cm3/kg, hydrogen sulfide – 0.0006–0.0072, carbon monoxide – 0.0016–0.0577, carbon dioxide – 0.1482–21.1602, methane – 0.0017–8.3047 and its homologues (in total) – 0.00001–0.0355 cm3/kg. It was found that the values of average concentrations of gases in bottom sediments increase with the depth of their occurrence and exceed the anomaly criteria identified for the East Arctic shelf by 2.6–27.7 times, including: CO2, CO and H2S – by 2.6, 3.0 and 3.4 times, ΣC2–C5 and He – by 9.3 and 10.8 times, CH4 – by 27.7 times; this actually indicates a high degree of gas saturation of bottom sediments of the region. The formation of CO2, CO, H2S, H2, CH4 and ΣC2–C5 anomalies in sediments of the upper and the base of the middle sampling horizon is determined by relatively high contents of sapropelic and humic organic matter and gas influx from the lower horizon. Distribution of anomalies with maximum concentrations of natural gases and He in sediments of the lower horizon, with minimum contents of Corg, is associated with zones of faults, large dislocations, tectono-magmatic and seismic activity, which are the main routes of diffusion-migration of gas transfer to bottom sediments. Formation of concentrations of gases and their anomalies in sediments of the LSZ follows the rules of additivity, i.e. successive accumulation of migratory natural gases of different genesis with prevalence of gas phase and isotopic indicators of more gas-saturated parental source, epigenetic and syngenetic to sediments. It was found that maximum values of average gas saturation with CH4, ΣС2–С5, He and H2 in LSZ are typical for bottom sediments of the flanks of troughs, CO and CO2 – for the arch parts of uplifts. In sediments of monoclinal folds (structural terraces), minimal values of average gas saturation are observed, with the exception of the South Anyui Fault Zone. In general, gas saturation of LSZ sediments is determined by the complex impact of geological factors, with the major ones being: gas content of rock complexes and gas saturation of underlying sediments, fault and fold tectonics, a high degree of tectono-magmatic and seismic activity, a geostructural position, coal content, oil and gas content, as well as the depth of occurrence, organic saturation and material composition of OM in bottom sediments. The influence of the latter predetermined the formation and distribution of five geochemical fields of CH4, three of CO, ΣС2–С5, He and one of CO2, and one of H2 in LSZ.

Pollution and Ecological Risk Assessment of Potentially Toxic Elements in Sediments Along the Fluvial-to-Marine Transition Zone of the Don River

The quality of sediments in the mixing zone of river freshwater and marine saline water as an important geochemical barrier for potentially toxic elements (PTEs) remains poorly understood. This study aims to analyze the current pollution with PTEs and associated ecological risks in sediments of the Don River delta and the surrounding area of the Taganrog Bay of the Sea of Azov (Russia). The PTE content was determined in fifty-four collected samples using the WDXRF and assessed using geochemical and ecotoxicological indicators. The source of Cr, Mn, Ni and Pb is mainly river runoff, and Cu, Zn and Cd are from a variety of anthropogenic sources. As shown by the assessment of the geoaccumulation index (Igeo), single pollution index (PI) and contamination factor (CF), these elements are the priority pollutants. According to these estimates, high and very high contamination of sediments in the estuarine zone of the Don River with Cd and Pb was detected in 72–94% and 2–57% of samples, respectively. However, environmental risks are determined almost exclusively by the level of Cd. Total contamination as assessed by the Nemerow pollution index (NPI), modified degree of contamination (mCd) and metal pollution index (MPI) is of concern in 83–98% of the samples studied. The most heavily polluted sediments are in the vicinity of residential areas of the Taganrog Bay. Despite the lower average pollution levels of deltaic sediments, freshwater biota are exposed to higher potential toxic risks of adverse effects by PTE, particularly from Ni and Pb. Thus, the complex hydrological regime and uneven anthropogenic impact predetermine the geochemical state of the sediments of the estuarine zone of the Don River.

New data on two rare East Asian cladocerans, Coronatella trachystriata (Chen, Zhang & Liu, 1994) and Nedorhynchotalona chiangi Kotov & Sinev, 2011 (Cladocera: Anomopoda: Chydoridae)

Two rare East Asian cladocerans, Coronatella (Coronatella) trachystriata (Chen, Zhang et Liu, 1994) and Nedorhynchotalona chiangi Kotov & Sinev, 2011, were found in Qili Lake on the border of Anhui and Jiangsu Provinces of China. Morphology of the species was studied by scanning electron microscopy for the first time, revealing unique morphological features: valve sculpture as a system of ridges in C. (C.) trachystriata and head shield with only lateral head pores present in N. chiangi. Both species have numerous adaptations for a benthic mode of life. They were found in a pelagic plankton sample during strong wind action, but were absent in littoral samples. Our data suggest that both species inhabit bottom sediments in a deeper zone of lakes at some distance from the shore, usually not sampled during cladoceran faunistic surveys. Morphology and distribution of the species are discussed.

Model of time-distance curve of electromagnetic waves diffracted on a local feature in the georadar study of permafrost zone rock layers

In GPR (georadar) studies, one of the most popular procedures for determining electromagnetic waves propagation velocity in a rock mass is the selection of theoretical hyperbolic time-distance curves and subsequent comparison with the time-distance curve obtained from a GPR measurement. This procedure is based on the model of homogeneous medium, but nowadays the subject of GPR study is often inhomogeneous media, such as horizontally layered media characteristic of loose permafrost zone sediments. The paper presents the findings of studying the formation of hyperbolic time-distance curves of georadar impulses in a horizontally layered medium without taking into account the dispersion and absorption of electromagnetic waves. On the basis of geometrical optics laws, formulas were derived to calculate the shape of the hyperbolic lineup of georadar impulses reflected from a local feature in a multilayer frozen rock mass. On the example of a permafrost zone rock mass containing a layer of unfrozen rocks, the effect of the thicknesses of rock layers and their relative dielectric permittivity on the apparent dielectric permittivity resulting from the calculation of the theoretical hyperbolic time-distance curve was shown. The conditions under which it is impossible to determine the presence of a layer of unfrozen rocks from a hyperbolic time-distance curve are also presented. The established regularities were tested on synthetic georadar radargrams calculated in the gprMax software program. The findings of the theoretical studies were confirmed by the comparison with the results of the analysis of the georadar measurements computer simulation data in the gprMax system (the relative error was less than 0.5%).

Natural sorting of sediments in the wave run-up zone works for microplastics as well

The distribution of plastic pollution in the marine environment is highly variable in time and space, making it difficult to assess pollution levels. This study shows that mixing and natural sorting of material in the wave run-up zone of a sandy beach results in a relatively stable abundance of microplastics in the size range 0.5–2 mm (S-MPs). Based on 175 samples collected over 14 months during 42 monitoring surveys at 6 stations along the shore of the Vistula Spit (Baltic Sea), the mean abundance of S-MPs was found to be 64 ± 36 items/kg DW (98.6 % fibers), with a coefficient of variation of only 56 % over more than one year. Statistical tests confirmed its independence from current wind speed, significant wave height, mean sediment grain size, sediment sorting, percentage of certain sand fractions, month, season, or location along the shore. It can therefore be used as a suitable indicator for long-term monitoring of increasing plastic pollution in the marine environment.

Oil and Gas Content of the South Caspian Basin

Abstract —We have compiled maps of areal isotope composition changes and constructed graphs of gas HC distribution depending on the stratigraphic age of the host rocks and graphs of isotope composition changes depending on the depth of sampling to study the hydrocarbon potential of the deep-seated oil and gas pools of the South Caspian Basin. The genesis of gas was studied using the techniques elaborated by M. Schoell and A. James. Two stages of hydrocarbon formation have been established by study of various kinds of gas manifestation. The first stage (Miocene–Eocene) began in the deposits underlying the Productive Series and continued up to the deposits of the latter. This stage was characterized by a frequent change in the directions of both downward and upward movements of gases. The second stage of hydrocarbon formation (Anthropogene–Pliocene) began in the deposits of the Productive Series and was characterized by a change in the regional geodynamic setting. Avalanche sedimentation and the predominance of downward movements over upward ones favored the accumulation of thick sediments at the time when the Productive Series formed. The sedimentation and tectonic processes (downwarping) in the deep-water zone of the basin led to harsh thermobaric conditions in the sedimentary strata. A detailed analysis of the results of gas survey in the deep-water zone of the South Caspian Basin has shown gas generation with a predominance of two components, methane and ethane. Study of the trends of temporal and areal hydrocarbon migration and of the areas of oil and gas generation makes it possible to reveal structures with evidence for large and giant hydrocarbon reserves. We have established that gas hydrocarbons in the bottom and upper-section sediments of the southern Caspian Sea are intimately related to the sources of hydrocarbons, their migration, and other processes running in the deep-seated sediments and in the upper section.

Moho Depth and Crustal Velocity Structure Beneath Stations RTC and TAM from Teleseismic Receiver-Function Analysis

We apply the P-wave receiver-function technique to invert teleseismic data to investigate the S- wave velocity structure beneath stations RTC and TAM in West Africa. Teleseismic waveform receiver function analysis is a widely used technique for studying crustal structure beneath broadband seismic stations. Our results show that the crust beneath RTC is relatively complex with large velocity fluctuations. In the upper crust, a low velocity layer extends from 8 to 12 km deep. At Tamanrasset crustal structure east and west of the station differ. We find a high-velocity zone between 2 and 8 km to the east that we attribute to a high conductivity unit corresponding to intrusions described in the literature. We find no similar feature west of the station. Our velocity models for RTC and TAM are consistent with their differing tectonic environments. TAM, on a stable craton, displays a fairly homogeneous velocity structure while RTC, on thick sediments in an ocean-continent transition zone, has more heterogeneous structure. This structural difference is reflected as well by the depth to Moho, ~20 km at RTC and nearly 38 km at TAM, although both have gradational velocity increases with depth.

Impact of elevated CO2 on microbial communities and functions in riparian sediments: Role of pollution levels in modulating effects

The impact of elevated CO2 levels on microorganisms is a focal point in studying the environmental effects of global climate change. A growing number of studies have demonstrated the importance of the direct effects of elevated CO2 on microorganisms, which are confounded by indirect effects that are not easily identified. Riparian zones have become key factor in identifying the environmental effects of global climate change because of their special location. However, the direct effects of elevated CO2 levels on microbial activity and function in riparian zone sediments remain unclear. In this study, three riparian sediments with different pollution risk levels of heavy metals and nutrients were selected to explore the direct response of microbial communities and functions to elevated CO2 excluding plants. The results showed that the short-term effects of elevated CO2 did not change the diversity of the bacterial and fungal communities, but altered the composition of their communities. Additionally, differences were observed in the responses of microbial functions to elevated CO2 levels among the three regions. Elevated CO2 promoted the activities of nitrification and denitrification enzymes and led to significant increases in N2O release in the three sediments, with the greatest increase of 76.09 % observed in the Yuyangshan Bay (YYS). Microbial carbon metabolism was promoted by elevated CO2 in YYS but was significantly inhibited by elevated CO2 in Gonghu Bay and Meiliang Bay. Moreover, TOC, TN, and Pb contents were identified as key factors contributing to the different microbial responses to elevated CO2 in sediments with different heavy metal and nutrient pollution. In conclusion, this study provides in-depth insights into the responses of bacteria and fungi in polluted riparian sediments to elevated CO2, which helps elucidate the complex interactions between microbial activity and environmental stressors.

Resolving spatially complex interactions between hydrodynamics and biogeochemical processing in a large reservoir with metalimnetic oxygen deficits

Deoxygenation in the deep water of stratified lakes and reservoirs due to climate warming and human activities poses a threat to crucial limnetic ecosystem services. Metalimnetic oxygen minima (MOM) typically occurs during the mid to late stages of limnetic stratification. To investigate the mechanism of MOM during stably stratified periods in the Panjiakou Reservoir, northern China, four years of in-situ monitoring was conducted in parallel with longitudinal-vertical 2D modeling. The model simulated the hydrodynamic, water quality, algal, and DO processes in 2017 and 2020, and was calibrated and verified by the measurements. Three scenarios were designed to test the impact of hydrological processes and the high oxygen-consuming sedimentation zones (HOCSZ). We concluded that the stratification and the corresponding advection generated in the metalimnion are the driving forces of MOM in the reservoir, and the limnetic eutrophication-related benthic HOCSZ are the seedbeds of the metalimnetic hypoxia. This unique spatial setting driving the biogeochemical processing and MOM dynamics required a new generation of modelling, incorporating spatial inhomogeneities of sediment characteristics and a sophisticated resolution of hydrodynamics. Metalimnetic horizontal advection, hypolimnetic upwelling currents, sedimentation hot spots and the formation of high oxygen consumption zones became the major initiation processes leading to MOM. The numerical modeling not only represented the occurrence, development, and extinction of MOM but also comprehensively explained the spatial differences in the vertical morphology of MOM and its inter-annual variations. Our studies help to identify management strategies to mitigate the impacts of MOM on aquatic ecological security and drinking water quality, thus supporting the optimization of reservoir regulations.

Age and Composition of the Middle–Upper Jurassic Sediments in the Central Zone of the Polousnyi Terrane (Northern Yakutia)

Age and Composition of the Middle–Upper Jurassic Sediments in the Central Zone of the Polousnyi Terrane (Northern Yakutia)

Трансформация радиоактивного загрязнения донных отложений Калининградского залива в период 2011–2023 гг.

The article presents the data of radioecological research of the bottom sediments in the Russian zone of the Vistula Lagoon in 2011–2023. According to research, the specific activity of 137Cs in the bottom sediments of the Lagoon was in the range of 3,9–165 Bq/m3. 137Cs is the main technogenic radionuclides that makes the greatest contribution to the pollution of the Lagoon. Contamination of the bottom sediments with 137Cs is determined by the redistribution of mainly post-Chernobyl fallout. The 137Cs accumulation was recorded in the northern deep-water part of the Primorskaya Bay. According to observations, the effective half-life of 137Cs activity in the sediments of the Lagoon is 10,4–42 years. The content of natural radionuclides is: 226Ra – from 9,0 to 35,3; 232Th – from 3,8 to 43,2; 40K from 227 to 715 Bq/kg. The NRN specific activity in the sediments of the Lagoon did not exceed 153 Bq/kg, which was significantly lower than the established safe level (370 Bq/kg), allowing their handling without restrictions. The correlations between the content of 40K, 226Ra, 232Th in the bottom sediments of the Lagoon were established with the type of sediment

Impact of seasonal variations in fronts on suspended sediments transport off the coastal area of Fujian Province

The Zhejiang-Fujian (Zhe-Min) coastal muddy area plays a crucial role in facilitating sediment exchange through a cross-front. The mud depocenter off the Zhe-Min coastal area is a source of suspended sediment that can be transported to the continental shelf of the East China Sea (ECS). Although the front of the inner shelf of the ECS has been extensively reported, the cross-front material transport off the coastal area of Zhe-Min in summer has not been well studied, especially using measured data. To reveal how the front controls the transport of suspended sediment, this study focuses on the impact of fronts on the dispersion of suspended sediment off the coastal area of Fujian Province in different seasons. The results indicate that the front acts as a barrier, inhibiting the dispersion of suspended sediment into the sea. The high-concentration suspended sediment is mainly found to the northwest of the front, with an average SSC of 8.5 mg/L in winter and 3.1 mg/L in summer. The suspended sediment concentration (SSC) follows a V-shaped distribution along the cross-isobath transects, with lower SSC observed at the 50-m isobath compared with the shallow water area and the deep water area. The SSC at the front was the lowest, with an average concentration of 2.3 mg/L in winter and 1.9 mg/L in summer. The front is crucial for the development of the Zhe-Min coastal muddy area. The winter monsoon is strong, resulting in a sufficient supply of suspended sediments in the muddy area and a high transport flux of suspended sediments in the nearshore. The front hinders the dispersion of high-concentrated sediment from the nearshore to the offshore, resulting in the deposition of fine-grained sediments in the nearshore and the formation of an inner shelf muddy sedimentary zone. The findings of this study will help improve our understanding of the sediment source-to-sink processes in the ECS and land–sea interactions.

Impacts of bridge constructions on channel dynamics and sediment aggradation: An integrated discussion, West Bengal, India

Channel dynamics, including channel migration, erosion, and deposition, is a significant geomorphological phenomenon. It has been noted that the Gish River exists with its widest extension between 1913 and 2021, causing a bottleneck situation. The section G4 (Gish-4) experienced the most significant squeezing character over time. The catchment landslide-induced sediments, mostly transported in the monsoon by 1st and 2nd order streams, deposited at the beds near the rail and road bridges of the rivers Lish, Gish, and Chel. Landslide susceptibility mapping (LSM) and sediment transport index (STI) maps specify the zones of sediment generation and aggradation. Results of low ‘b” value 0.77 + /−0.04 specify active tectonics and instability of the area. A petrographic analysis of landslide samples and river bed sediments justifies that the landslide connected streams are continuously transported and deposited in the river bed. In the Himalayan foothill rivers like Lish, Gish, and Chel, channel planform dynamics may be the result of landslide occurrences, that induce huge sediments in the rivers and sediment transport index indicates the deposition of the sediments near rail and road bridges in spatio-temporal scale.

Impacts of oyster farms on sediment-associated mercury and methylmercury concentrations and health risks in an estuarine, mangrove forest, Zhanjiang Bay, China

Estuarine sediments serve as significant reservoirs for mercury (Hg) and methylmercury(MeHg), which can also interconvert in the external environment. The release of Hg in response to human activities raises concerns about its potential ecological and human health effects. Sediment samples were collected in December 2021 from four locations (sites), and Hg cycling by measuring the concentrations of, and controls on, the spatial distribution of total Hg (THg) and methylmercury (MeHg) in high-tidal zone (HTZ) and mid-tidal zone (MTZ) sediments of a mangrove forest (MF) and oyster farm (OF) was examined in northwestern Zhanjiang Bay, including simultaneous determination of sediment particle size, oxidation-reduction potential (Eh), pH, total organic carbon (TOC), sulfide concentration (S2-), and sulfate reducing bacteria (SRB). The research results indicated that concentrations of both THg and MeHg ranged between 20.0–104.0 ng/g and 0.011–0.277 ng/g in the sediments, respectively. The highest methylation potentials within the MF and OF were in sediments located approximately 10–15 cm below the surface. MeHg in the HTZ of the OF was likely derived from exogenous inputs as Hg methylation appears limited, and the formation of MeHg depended not only on the amount of inorganic mercury available for methylation in SRB, but also on the TOC, pH, Eh and S2- content in the sediment. A risk assessment of MeHg during the anthropogenic disturbance of this estuaries conducted on individuals eating oysters demonstrated that health risks are low.

Organic carbon oxidation and the associated pyrite formation in deep sediments at the Nankai subduction zone

The preservation of organic carbon (OC) in marine sediments is crucial for Earth's climate by sequestering CO2. While OC is mostly remineralized before it reaches the seafloor, a notable fraction is buried in deep-sea sediments, particularly at subduction zones known for their enhanced sedimentation rates that promote OC burial. The mechanisms behind OC recycling and decomposition within subduction zone sediments are governed by biologically mediated redox reactions involving a range of electron acceptors, which facilitate the sequential oxidation of OC. However, direct evidence regarding such effects on OC in deep sediments remains limited. In this study, we examine the contents of pyrite and trace metals of molybdenum (Mo), vanadium (V), and cesium (Cs) in organic-rich deep sediments from the Nankai subduction zone. We find that the pyrite, sulfate, diagenetic illite, and OC contents covary in Unit V, highlighting the important role of organoclastic sulfate reduction and biotic smectite-to-illite reaction at 60–70 °C in OC oxidation and pyrite formation. The profiles of Mo, V, and Cs also align with these processes in the same interval. Our findings contribute to an in-depth understanding of OC dynamics in subduction zones, emphasizing the complex interactions within deep sediments that may influence the global carbon cycle.

A benthic source of isotopically heavy Ni from continental margins and implications for global ocean Ni isotope mass balance

Nickel (Ni) is a bio-essential element for phytoplankton in the modern oceans, and yet, the global ocean mass balance of Ni has puzzled scientists for decades. Many estimates of total Ni output flux are larger than the total Ni input flux to the ocean. The measurement of Ni stable isotopes (δ60Ni) in earth materials may inform our understanding of ocean biogeochemistry and redox conditions in both the modern ocean and the geological past. An ocean Ni stable isotope imbalance has also concerned scientists, with a global ocean δ60Ni of +1.4 ‰ which is notably heavier than the major source of Ni to the oceans from rivers. Recent efforts to resolve Ni and δ60Ni imbalances have focused on the role which manganese (Mn) oxides play in marine Ni cycling, both in the water column and in marine sediments. Manganese oxide rich marine sediments can supply isotopically heavy dissolved Ni to porewater fluids and seawater, but the source of the isotopically heavy porewater Ni remains unclear. Here we present porewater trace metal concentrations and δ60Ni from two sites from the continental margin off southern California. Porewater Ni concentrations are up to roughly 100-fold higher than deep seawater concentrations (∼1 μM compared to 10 nM, respectively). Porewater δ60Ni is near 0 ‰ in the subsurface region where Ni concentrations are highest, suggesting dissolution of lithogenic material from sediments. Porewater δ60Ni increases dramatically towards the sediment-water interface with values of up to +2.66 ‰, which to our knowledge are the heaviest Ni isotope compositions ever reported for natural materials. Measurements of porewater and sediment Ni and Mn concentrations suggest that Ni is released to porewaters in the Mn-reducing zone, and then removed by newly precipitated Mn oxides as Mn and Ni move towards the oxygenated zone of sediments. A simple Rayleigh model suggests a Ni isotope fractionation of factor of -0.61 ‰ for Ni sorption onto Mn oxides, while a diffusion-reaction model suggests a Ni isotope fractionation of -1.80 to -0.96 ‰, always with preferential adsorption of lighter Ni isotopes. This flux of Ni toward the sediment-water interface, coupled with preferential removal of lighter Ni isotopes in marine sediments, provides evidence supporting an isotopically heavy benthic source of new Ni to the oceans, which we estimate has a magnitude of 0.65 × 108 to 1.66 × 108 moles/year. We find that a benthic flux such as measured here over just 0.27-2.70 % of the ocean seafloor could mix with the river δ60Ni of +0.8 ‰ to achieve the observed deep ocean δ60Ni of +1.4 ‰. This study reveals the similarities in how rivers and continental margin sediments supply heavy Ni isotopes to the ocean. In both continental rivers and margin sediments, terrigenous Ni is released with an δ60Ni near 0.1 ‰, but lighter isotopes are captured by precipitation onto oxides so that the dissolved flux to the ocean is isotopically heavier than the terrigenous material from which Ni was released, and in the case of margin sediments may be heavier than even bulk seawater δ60Ni. We thus recognize continental margin sediments with active Mn cycling as a ‘new’ source of isotopically heavy dissolved Ni to the ocean.

SEASONAL DYNAMICS OF CHEMICAL AND MICROBIOLOGICAL CHARACTERISTICS OF BOTTOM SEDIMENTS IN THE SEA ESTUARY OF A SMALL RIVER IN THE SEVASTOPOL REGION (BY THE EXAMPLE OF THE CHERNAYA RIVER, CRIMEA)

The annual dynamics of (1) chloroform-extractable substances (CES) and petroleum hydrocarbons (PH) in riverside fluvial sediments, in the bottom sediments of the mixing zone of river and sea waters, and in the bottom sediments of the marine area, and (2) the abundance of hydrocarbon-oxidizing (HOB) and heterotrophic (HB) bacterial groups in the bottom sediments of the marine area and riverside sediments is analysed. The maximal content of CES was found in the marine area (450±17.5 mg/100 g), and the minimal one - in the river part (127.6±10.9 mg/100 g), in the mixing zone of river and sea waters - 370±37.9 mg/100 g. The average concentrations of PH are distributed similarly to the concentrations of CES: the maximal values (127.5±10.9 mg/100 g) are detected in marine ground, the values for the sediments of the mixing zone are slightly lower (103.1±9.4 mg/100 g), and the minimal values (54.8±23.9 mg/100 g) are detected in river sediments. The physicochemical characteristics of bottom and coastal sediments are presented. The abundance of HB in the bottom sediments of the marine area varied from 7.5•103 to 2.5•106 cells/g, respectively, and from 9.5•103 to 9.5•108 cells/g in the river area. There was no seasonal variability in the abundance of HB at both areas. Hydrocarbon-oxidizing bacteria were registered in 100 % of the samples of bottom and riverside sediments of the designated water areas. The abundance of HOB varied from 25 to 2.5•104 cells/g in the marine zone and from 25 to 4.5•103 cells/g in the river zone. The maximal values of HOB abundance in the riverside sediments were recorded during the flood period (February-April).

Presence and implications of petrogenic organic carbon in High Himalayan Crystalline lake sediment

AbstractTwelve lacustrine sediment samples from a relict lake in the Kalla Glacier valley were co-dated using AMS radiocarbon (14C) and infrared stimulated luminescence (IRSL) dating methods. In general, the radiocarbon ages of bulk organic matter were older by a minimum of 1500 years compared to (age depth) modeled luminescence ages after fading corrections. This is observed for the first time in the lake sediments of High Himalayan Crystalline zone. A combination of lipid n-alkane data, Raman spectra and geochemical proxies suggested that this was due to ancient organic carbon (OCancient) that is a mixture of pre-aged (OCpre-aged) and petrogenic (OCpetro) organic carbon within older glacial moraine debris that served as sediment source to the lake. Raman spectra suggest the presence of moderate to highly graphitized OCpetro in all the profile samples. The OCpetro contributed 0.064 ± 0.032% to the sediment and the lake stored 2.5 ± 0.7 Gg OCpetro at variable rates during the last 16 kyr, with the mean burial flux 160 kg OCpetro yr−1. This study implies (1) employing another independent dating method in addition to radiocarbon method using bulk sediment organic matter, if the carbon content is low, to observe any discrepancy, and (2) a need to investigate on the fate of OCpetro as many such small lakes become relict in this region.

Southernmost limit of felsic magmatism along North Almora Thrust in the Himalayan domain

We present significant findings of the Kausani Granite Gneiss within the Inner Lesser Himalayan Sedimentary Zone (iLHSZ) just north of the North Almora Thrust (NAT). The Kausani Granite Gneiss body lies within the quartzite of the Someshwar Formation and has a tectonized contact and a discordant relationship on the north side. Detailed seismic profiling across the body also confirms a similar result. Cathodoluminescence images of zircon from the Kausani body show no inheritance of older cores. The U–Pb ages from the zircon populations separated from the Kausani body give a crystallization age of 1866 ± 3 Ma. Along with the Upalda granite gneiss and Toneta granite gneiss near the Alakhnanda Thrust in the Garhwal Himalaya and the Dungeshwari granite gneiss near the Dailekh Thrust in Nepal, the Kausani Granite Gneiss north of NAT Kumaun Himalaya forms a major terrain boundary. These gneissic bodies mark the southernmost extent of felsic magmatism at NAT, rather than the Main Central Thrust. An about 1.8 billion years‐old magmatic event in the LHSZ suggests that it is a currently active continental margin inside the ‘Greater India’ region, now situated in the Himalayan domain. However, the Pb‐loss modelling of the U–Pb zircon data reveals thermal events during the Himalayan Orogeny (~45 Ma).