Sedimentary Target Rocks Research Articles

Morphometric and structural parameters of impact craters in Algeria: Control of sedimentary target rocks and effect of post impact process

The Earth Impact Database (EID) currently includes four impact craters located in Algeria. These craters are well-exposed, morphologically visible, partially covered and all situated in a vast, very arid Saharan geological domain devoid of any vegetation cover. Consequently, they can be easily identified using the TanDEM-X digital elevation model and Alsat-1B satellite images. The aim of this work is to identify the characteristics of sedimentary target rocks that control the morphometric and structural parameters of Algerian craters, as well as the effects of post-impact processes. Crater exposure, type, and structure (depth-diameter ratio, rim-to-floor height, central peak and moat diameters), outline (circular, polygonal, elongated) and impactite types are therefore discussed. Relative or stratigraphic dating and erosion/burial rates are estimated for the craters. Results indicate that Amguid and Talemzane are simple, well-preserved young craters, closer to a pristine state. Tin Bider is a complex exposed structure showing an irregular outline with a well-developed central peak and two rings. Ouarkziz is a transitional crater; based on its diameter alone it is classified as a complex crater; however, a topographic central peak is not observed. A deep formation uplift is detected in the central zone, interpreted as a stratigraphic peak where the uplift has not reached significant heights to form a clearly visible peak. This may be due to the reduced diameter of Ouarkziz, which is smaller than what has always been described.

Magnetic Properties of Impact UHPHT Glasses, Melt Rocks, Suevitic Breccia and Target Rocks of the Giant Kara Meteorite Crater (Pay-Khoy, Arctic Seashore, Russia)

The shock waves can strongly change the physical properties of the target rock minerals including their density and magnetism which determine petrochemical properties of impactites finely as a rule are resulted in astroblemes contours on geophysical maps. Following to the aero-magnetic mapping data the non-magnetic sedimentary rocks of the Kara target create a zero and negative magnetic field with an average intensity of -1 nT, against the background the southwestern region of the Kara astrobleme provides the positive magnetic anomalies with an intensity of 1 to 3 nT which are in a good correspondence with the Pay-Khoy ridge structure general orientation. The Kara dome is characterised with an isometric negative anomaly of intensity -5 nT. Here we present the magnetic properties of the different kinds of the Kara impactites including impact ultra-high pressure high temperature (UHPHT) melt glasses, melt rocks and suevitic breccia compare to sedimentary target rocks. The petrophysical measurements presented the specific magnetic susceptibility of the impactites in the range of 8 to 48×10-8 SI units, where the UHPHT glasses have the limits from 9 to 38×10-8 SI units (15×10-8 SI units, in average). The sedimentary target is characterised with essentially lower level of magnetic susceptibility – no higher than 15×10-8 SI units, where limestone has it about zero. Following to the similar level of the iron content within the impactites and target rocks the magnetism of the Kara impact melts is explained rather by changing of magnetic properties by the impact process. One of the possible source of magnetism can be partially an iron-containing matter of the asteroid component in the form of pyrrhotine accompanied with Ni and Co impurities. Also, we cannot exclude partial presence of magnetic iron component directly within the quenched impact glasses including UHPHT variety.

Varieties of Impactites and Impact Diamonds of the Kara Meteorite Crater (Pay-Khoy, Russia)

Impact diamonds are technical material with valuable mechanical properties. Despite of a quite long story from their discovery and huge diamond storages at the Popigai astrobleme (Siberia, Russia) they were not involved into industrial production, first of all because of remoteness of objects, complexity of extraction and economically more favourable synthesis of technical diamonds in the seventies of the past century. However, due to the high hardness of impact diamonds and also to the high demand of new carbon materials, including nanomaterials, the interest towards this type of natural diamonds is significantly increased in the recent years. Although the mentioned Popigai astrobleme is situated in a remote part of Russia it has been studied in more details. At the same time, the less known Kara giant meteorite crater (Pay-Khoy, Russia) is situated essentially closer to the industrial infrastructure of the European part of Russia. This astrobleme, similarly to Popigai, is enriched in impact diamonds as well. But, till recent years it was not deeply studied using modern analytical methods. During our studies in 2015 and 2017 at the territory of the Kara meteorite crater we have distinguished and described 5 varieties of impactites – bulk melt impactites which form cover-like and thick dike bodies; melt ultrahigh-pressure vein bodies and at least 3 types of suevites formed after specific sedimentary target rocks. These varieties have typomorphic features regarding the crystallinity and mineral composition. It was found that all of them have high concentration of microdiamonds formed by high-pressure high temperature pyrolysis mechanism from precursor materials like coal and organic relicts. Using a set of modern mineralogical methods we have found two principal types of diamond morphologies within the Kara impactites – sugar-like after coal diamonds and diamond paramorphs after organic relicts. The Kara diamonds have several accompanying carbon substances including newly formed graphite, glass-like carbon and probably carbyne. The studied diamondiferous Kara impactites provide an essentially novel knowledge of impact processes in sedimentary targets.

Hyperspectral imaging of drill core from the Steen River impact structure, Canada: Implications for hydrothermal activity and formation of suevite‐like breccias

AbstractHyperspectral imaging can be used to rapidly identify and map the spatial distributions of many minerals. Here, hyperspectral mapping in three wavelength regions (visible and near‐infrared, shortwave infrared, and thermal infrared) was applied to drill cores (ST001, ST002, and ST003) penetrating a continuous sequence of crater‐fill breccias from the Steen River impact structure in Alberta, Canada. The combined data sets reveal distinct mineralogical layering, with breccias derived predominantly from sedimentary rocks overlying those derived from granitic basement. This stratigraphy demonstrates that the breccias were not appreciably disturbed following deposition, which is inconsistent with formation models of similar breccias (suevites) by explosive impact melt–fluid interaction. At Steen River, volatiles from sedimentary target rocks were an inherent part of forming these enigmatic breccias. Approximately three quarters of terrestrial impact structures contain sedimentary target rocks; therefore, the role of volatiles in producing so‐called suevitic breccias may be more widespread than previously realized. The hyperspectral maps, specifically within the SWIR wavelength region, also delineate minerals associated with postimpact hydrothermal activity, including ammoniated clay and feldspar minerals not detectable using traditional techniques. These nitrogen‐bearing minerals may have originated from microbial processes, associated with oil‐ and gas‐producing units in the crater vicinity. Such minerals may have important implications for the production of habitable environments by impact‐induced hydrothermal activity on Earth and Mars.

Evidence of impact melting and post-impact decomposition of sedimentary target rocks from the Steen River impact structure, Alberta, Canada

Hypervelocity bolide impacts deliver vast amounts of energy to the Earth's near surface. This crustal process almost universally includes sedimentary target rocks; however, their response to impact is poorly understood, in part because of complexities due to layering, pore space and the presence of volatiles that are difficult to model. The response of carbonates to bolide impact remains contentious, yet whether they melt or decompose and liberate gases by the reaction CaCO3(s) → CaO(s) + CO2(g)↑, has significant implications for post-impact climatic effects. We report on previously unknown carbonate impact melts at the Steen River impact structure, Canada, and the first description of naturally shocked barite, BaSO4. Carbonate melts are preserved as groundmass-supported calcite-rich clasts, sampled from an up to 164 m thick, continuous sequence of crater-fill polymict breccias. Electron microscopy reveals fluidal- and ocellar-textured calcite and barite, intimately associated with silicate melt, consistent with these phases being in the liquid state at the same time. Raman spectroscopy and electron backscatter diffraction (EBSD) mapping confirm the presence of high-pressure phases – reidite and coesite – within some Steen River carbonate melt-bearing breccias. These minerals attest to the strong shock provenance of the breccia and provide constraints on their shock history. Preservation of reidite lamellae in zircon indicates a shock pressure >30 GPa <60 GPa and temperatures <1473 K. In addition to melting, we present compelling evidence for widespread (70–100%) decomposition of carbonate target rocks, mixed as lithic clasts into hot impact breccias. In this context, decomposition occurs strictly post-impact due to thermal equilibration-related heating. We demonstrate that this mechanism for CO2 outgassing is likely more widespread than previously recognized. The presence of andradite-grossular garnet serve as mineralogical markers of decomposition, analogous to limestone-replacing skarn deposits. Ca-rich garnet may therefore prove an important indicator mineral for post-shock decomposition of carbonate-bearing target rocks at other craters. These findings significantly advance our understanding of how sedimentary rocks respond to hypervelocity impact, and have wide-reaching implications for estimating the amount and timing of climatically-active volatile release due to impact events.

A previously unrecognized high-temperature impactite from the Steen River impact structure, Alberta, Canada

Abstract Here, we report a previously unrecognized impactite from the Steen River impact structure in Alberta, Canada, which was intersected by continuous diamond drill core into the allochthonous proximal deposits of this buried 25-km-diameter complex crater. A suite of high-temperature minerals defines the matrix, formed by grain growth in a solid state by static recrystallization of an originally clastic matrix, deposited at temperatures ≥800 °C. This rock type is predominantly a result of the recrystallization of target material driven by the acceleration of hot gasses from volatilized sedimentary cover mixed with variably shocked crystalline basement. Approximately one-third of terrestrial impact structures occur in mixed target rocks; therefore, this type of impactite may be more common than previously realized. Contact metamorphism between entrained sedimentary target rocks and the juxtaposed hot matrix resulted in carbonate decomposition to form a rare spinel-group mineral, magnesioferrite. In crater environments, magnesioferrite has been found in the distal Chicxulub (Mexico) ejecta and may prove a novel indicator mineral for impact into carbonate-bearing target rocks.

Rare metals on shatter cone surfaces from the Steinheim Basin (SW Germany) – remnants of the impacting body?

AbstractThe ~3.8 km Steinheim Basin in SW Germany is a well-preserved complex impact structure characterized by a prominent central uplift and well-developed shatter cones that occur in different shocked target lithologies. Scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy and electron probe microanalysis have revealed, for the first time, the occurrence of rare metals on the Steinheim shatter cone surfaces. Shatter cones produced from the Middle Jurassic (Aalenian) Opalinus Claystone (‘Opalinuston’), temporarily exposed in the central uplift in spring 2010, and shatter cones in Upper Jurassic (Oxfordian) limestones from the southeastern crater rim domain are commonly covered by faint coatings. The Opalinus Claystone shatter cone surfaces carry coatings dominated by Fe, Ca, P, S and Al, and are covered by abundant small, finely dispersed microparticles and aggregates of native gold, as well as locally elevated concentrations of Pt. On several surfaces of the claystone shatter cones, additional Fe, Ni and Co was detected. The Ca–Mn-rich coatings on the limestone shatter cone surfaces locally include patches of Fe, Ni, Co, Cu and Au in variable amounts and proportions. The intriguing coatings on the Steinheim shatter cones could either stem from the impacted Lower Jurassic to Palaeogene sedimentary target rocks; from the crystalline-metamorphic Variscan crater basement; or, alternatively, these coatings might represent altered meteoritic matter from the Steinheim impactor, possibly an iron meteorite, which may have been remobilized during post-impact hydrothermal activity. We here discuss the most plausible source for the rare metals found adherent to the shatter cone surfaces.

The effects of meteorite impacts on the availability of bioessential elements for endolithic organisms

Abstract– Meteorite impacts, one of the most ubiquitous processes in the solar system, have the ability to destroy as well as create habitats for life. The impact process can increase the translucency and porosity of the target substrate, as well as mobilize biologically relevant elements within the substrate. For endolithic organisms, this process has important implications, especially in extreme environments where they are forced to seek refuge in the interior of rocks. Here, we show that unshocked target rocks and rocks that have experienced pressures up to about 80 GPa from the Haughton impact structure, Devon Island, Canada, possess a small, but discernible change in bulk chemistry within the major oxide analysis. However, changes in the distribution of elements did occur with increasing shock level for both the sedimentary and crystalline target. Both the crystalline and sedimentary target rocks contain significant amounts of glasses at higher shock levels (up to about 95% by volume), which would improve the availability of these elements to potential microbial endoliths as glasses are more easily dissolved by organic acids. The implication that impact events do not impoverish their capacity to serve as a “substrate” through volatilization is important with respect to analogous impact structures on Mars. After the deleterious effects of the direct meteorite impact, any microorganisms on Mars would have benefited from the input of heat, the mobilization of a possible frozen groundwater system, as well as increased translucency, porosity, and trace nutrient availability of the target substrate.

Melt in the impact breccias from the Eyreville drill cores, Chesapeake Bay impact structure, USA

– The center of the 35.3 Ma Chesapeake Bay impact structure (85 km diameter) was drilled during 2005/2006 in an ICDP–USGS drilling project. The Eyreville drill cores include polymict impact breccias and associated rocks (1397–1551 m depth). Tens of melt particles from these impactites were studied by optical and electron microscopy, electron microprobe, and microRaman spectroscopy, and classified into six groups: m1—clear or brownish melt, m2—brownish melt altered to phyllosilicates, m3—colorless silica melt, m4—melt with pyroxene and plagioclase crystallites, m5—dark brown melt, and m6—melt with globular texture. These melt types have partly overlapping major element abundances, and large compositional variations due to the presence of schlieren, poorly mixed melt phases, partly digested clasts, and variable crystallization and alteration. The different melt types also vary in their abundance with depth in the drill core. Based on the chemical data, mixing calculations were performed to determine possible precursors of these melt particles. The calculations suggest that most melt types formed mainly from the thick sedimentary section of the target sequence (mainly the Potomac Formation), but an additional crystalline basement (schist/gneiss) precursor is likely for the most abundant melt types m2 and m5. Sedimentary rocks with compositions similar to those of the melt particles are present among the Eyreville core samples. Therefore, sedimentary target rocks were the main precursor of the Eyreville melt particles. However, the composition of the melt particles is not only the result of the precursor composition but also the result of changes during melting and solidification, as well as postimpact alteration, which must also be considered. The variability of the melt particle compositions reflects the variety of target rocks and indicates that there was no uniform melt source. Original heterogeneities, resulting from melting of different target rocks, may be preserved in impactites of some large impact structures that formed in volatile-rich targets, because no large melt body exists, in which homogenization would have taken place.

Impact fracturing and structural modification of sedimentary rocks at Meteor Crater, Arizona

Meteor Crater provides a rare opportunity to study impact deformation of sedimentary target rocks and isolate those features from preexisting tectonic deformation and impact‐generated reactivation of preexisting tectonic features. This study reports over 2500 new measurements of orientations of bedding, faults, and fractures in crater walls and in surrounding bedrock. Target rocks are characterized by horizontal bedding planes that are cut by at least three prominent sets of preimpact tectonic fracture systems. The crater rim is also cut by three distinct groups of fractures: radial, concentric, and conical fractures. When the crater rim is restored to preimpact condition, the radial and concentric fractures resemble preimpact fracture populations, indicating that crater wall deformation and rim uplift were partly accommodated by activation of preexisting fractures. In contrast, the conical fractures are dissimilar to the preimpact fractures and apparently formed as a direct result of impact deformation. Some of the preimpact fractures were transformed into tear faults during the impact event, and motion along those faults appears to have controlled the geometry of the impact deformational features. The crater rim is, thus, square in plan view rather than circular. Faults occurring in the crater diagonals are prominent ones, allowing greater vertical displacement. The deformation pattern of Meteor Crater is different from that at Lonar Crater, which was excavated in basalt with fewer preimpact fractures. The differences between deformation at Meteor Crater and Lonar Crater may reflect the same disparities seen in simple craters produced in different target lithologies on Mars and other planetary surfaces.

Structural evolution of the 40 km wide Araguainha impact structure, central Brazil

Abstract— The 40 km wide Araguainha structure in central Brazil is a shallowly eroded impact crater that presents unique insights into the final stages of complex crater formation. The dominant structural features preserved at Araguainha relate directly to the centripetal movement of the target rocks during the collapse of the transient cavity. Slumping of the transient cavity walls resulted in inward‐verging inclined folds and a km‐scale anticline in the outer ring of the structure. The folding stage was followed by radial and concentric faulting, with downward displacement of kilometer‐scale blocks around the crater rim. The central uplift records evidence for km‐scale upward movement of crystalline basement rocks from the transient cavity floor, and lateral moment of sedimentary target rocks detached from the cavity walls. Much of the structural grain in the central uplift relates to structural stacking of km‐scale thrust sheets of sedimentary strata onto the core of crystalline basement rocks. Outward‐plunging radial folds indicate tangential oblate shortening of the strata during the imbrication of the thrust sheets. Each individual sheet records an early stage of folding and thickening due to non‐coaxial strains, shortly before sheet imbrication. We attribute this folding and thickening phase to the kilometer‐scale inward movement of the target strata from the transient cavity walls to the central uplift. The outer parts of the central uplift record additional outward movement of the target rocks, possibly related to the collapse of the central uplift. An inner ring structure at 10–12 km from the crater center marks the extent of the deformation related to the outward movement of the target rocks.

Trace element concentrations in the Mexico‐Belize ejecta layer: A link between the Chicxulub impact and the global Cretaceous‐Paleogene boundary

Abstract— Four exposures of Chicxulub impact ejecta along the Mexico‐Belize border have been sampled and analyzed for major and trace element abundances.The ejecta deposits consist of a lower spheroid bed, containing clay and dolomite spheroids, and an upper diamictite bed with boulders and clasts of limestone and dolomite. The matrix of both beds is composed of clay and micritic dolomite. The rare earth element (REE) compositions in the matrix of both units show strong similarities in concentrations and pattern. Furthermore, the Zr/TiO2 scatter plot shows a linear correlation indicating one source. These results indicate that the basal spheroid bed has the same source and was generated during the same event as the overlying diamictite bed, which lends support to a single‐impact scenario for the Albion Formation ejecta deposits.The elevated concentrations of non‐meteoritic elements such as Sb, As, U, and Zn in the matrix of the lower spheroid bed are regarded to have been derived from the sedimentary target rocks at the Chicxulub impact site. The positive Eu and Ce anomalies in clay concretion and in the matrix of the lower part of the spheroid bed in Albion Island quarry is probably related to processes involved in the impact, such as high temperature and oxidizing conditions.Analogous trace element anomalies have been reported from the distal Cretaceous‐Paleogene (K/T) boundary clay layer at different sites. Thus, the trace element signals, reported herein, are regarded to support a genetic link between the Chicxulub impact, the ejecta deposits along the Mexico‐Belize border, and the global K/T boundary layer.

Proceedings of the Workshop on Impact Craters as Indicators for Planetary Environmental Evolution and Astrobiology

Four exposures of Chicxulub impact ejecta along the Mexico-Belize border have been sampled and analyzed for major and trace element abundances. The ejecta deposits consist of a lower spheroid bed, containing clay and dolomite spheroids, and an upper diamictite bed with boulders and clasts of limestone and dolomite. The matrix of both beds is composed of clay and micritic dolomite. The rare earth element (REE) compositions in the matrix of both units show strong similarities in concentrations and pattern. Furthermore, the Zr/TiO2 scatter plot shows a linear correlation indicating one source. These results indicate that the basal spheroid bed has the same source and was generated during the same event as the overlying diamictite bed, which lends support to a single-impact scenario for the Albion Formation ejecta deposits. The elevated concentrations of non-meteoritic elements such as Sb, As, U, and Zn in the matrix of the lower spheroid bed are regarded to have been derived from the sedimentary target rocks at the Chicxulub impact site. The positive Eu and Ce anomalies in clay concretion and in the matrix of the lower part of the spheroid bed in Albion Island quarry is probably related to processes involved in the impact, such as high temperature and oxidizing conditions. Analogous trace element anomalies have been reported from the distal Cretaceous-Paleogene (K/T) boundary clay layer at different sites. Thus, the trace element signals, reported herein, are regarded to support a genetic link between the Chicxulub impact, the ejecta deposits along the Mexico-Belize border, and the global K/T boundary layer. (Less)

Shock reequilibration of fluid inclusions in Coconino sandstone from Meteor Crater, Arizona

This study examines the effects of natural shock metamorphism on fluid inclusions trapped in porous sedimentary target rocks and compares these results to previous experimental work on single crystal quartz. Samples of shock metamorphosed Coconino sandstone were collected from Barringer Meteorite Crater (Meteor Crater, Arizona) and classified based on their shock features into the six shock stages described by Kieffer [S.W. Kieffer, 1971. Shock metamorphism of the Coconino sandstone at Meteor Crater, Arizona, Journal of Geophysical Research 76, 5449-5473.]. The frequency of two-phase fluid inclusions decreases dramatically from unshocked samples of Coconino sandstone through shock stages 1a, 1b, and 2. No two-phase fluid inclusions were observed in shock stage 3 or 4 samples. However, the total number of grains containing fluid inclusions remains approximately the same for shock stages 1a–2, suggesting that two-phase fluid inclusions reequilibrated during impact to form single-phase inclusions. In shock stages 3 and 4, the total number of inclusions also decreases, indicating that at these higher shock pressures fluid inclusions are destroyed by plastic deformation and phase changes within the host mineral. Entrained quartz grains within a shock stage 5 sample contain two-phase inclusions, emphasizing the short duration of melting associated with the impact and the heterogeneous nature of impact processes. These results are similar to those observed in single-crystal experiments, although inclusions survive to slightly higher shock pressures in samples of naturally shocked Coconino sandstone. Results of this study suggest that the rarity of fluid inclusions in meteorites does not preclude the presence of fluids on meteorite parent bodies. Instead, fluid inclusions trapped during alteration events may have been destroyed due to shock processing. In addition, loss of fluids from inclusion vesicles along fractures and microcracks may lead to shock devolatilization, even in unsaturated target rocks.

The Rock Elm meteorite impact structure, Wisconsin: Geology and shock-metamorphic effects in quartz

The Rock Elm structure in southwest Wisconsin is an anomalous circular area of highly deformed rocks, ∼6.5 km in diameter, located in a region of virtually horizontal undeformed sedimentary rocks. Shock-produced planar microstructures (PMs) have been identified in quartz grains in several lithologies associated with the structure: sandstones, quartzite pebbles, and breccia. Two distinct types of PMs are pres ent: P1 features, which appear identical to planar fractures (PFs or cleavage), and P2 features, which are interpreted as possible incipient planar deformation features (PDFs). The latter are uniquely produced by the shock waves associated with meteorite impact events. Both types of PMs are oriented parallel to specific crystallographic planes in the quartz, most commonly to c (0001), ξ{11\batchmode \documentclass[fleqn,10pt,legalpaper]{article} \usepackage{amssymb} \usepackage{amsfonts} \usepackage{amsmath} \pagestyle{empty} \begin{document} \(\overline{2}\) \end{document}2}, and r / z {10\batchmode \documentclass[fleqn,10pt,legalpaper]{article} \usepackage{amssymb} \usepackage{amsfonts} \usepackage{amsmath} \pagestyle{empty} \begin{document} \(\overline{1}\) \end{document}1}. The association of unusual, structurally deformed strata with distinct shock-produced microdeformation features in their quartz-bearing rocks establishes Rock Elm as a meteorite impact structure and supports the view that the presence of multiple parallel cleavages in quartz may be used independently as a criterion for meteorite impact. Preliminary paleontological studies indicate a minimum age of Middle Ordovician for the Rock Elm structure. A similar age estimate (450–400 Ma) is obtained independently by combining the results of studies of the general morphology of complex impact structures with estimated rates of sedimentation for the region. Such methods may be applicable to dating other old and deeply eroded impact structures formed in sedimentary target rocks.

Cloud Creek structure, central Wyoming, USA: Impact origin confirmed

Abstract— The circular Cloud Creek structure in central Wyoming, USA is buried beneath ˜1200 m of Mesozoic sedimentary rocks and has a current diameter of ˜7 km. The morphology/morphometry of the structure, as defined by borehole, seismic, and gravity data, is similar to that of other buried terrestrial complex impact structures in sedimentary target rocks, e.g., Red Wing Creek in North Dakota, USA. The structure has a fault‐bordered central peak with minimum diameter of ˜1.4 km, composed predominantly of Paleozoic carbonates thickened by thrust faulting and brecciation, and is elevated some 520 m above equivalent strata beyond the outer rim of the structure. There is a ˜1.6 km wide annular trough sloping away from the central peak (maximum structural relief, 300 m) and terminated by a detached, fault‐bounded, rim anticline. The youngest rocks within the structure are Late Triassic (Norian?) clastics and these are overlain unconformably by post‐impact Middle Jurassic (Bathonian?) sandstones and shales. Thus, the formation of the Cloud Creek structure is dated chronostratigraphicly as ˜190 ± 20 Ma.Reported here for the first time are measurements of planar deformation features (PDFs) in shocked quartz grains in thin sections made from drill cuttings recovered in a borehole drilled at the southern perimeter of the central peak. Other, less definitive microstructures consistent with impact occur in samples collected from boreholes drilled into the central peak and rim anticline. The shock‐metamorphic evidence confirms an impact origin for the Cloud Creek structure.

Aerial crystallization of hematite in impact bombs from the Araguainha astrobleme, Mato Grosso, central Brazil

Abstract— Optical and scanning electron microscope (SEM) observations of hematite impact bombs from the Araguainha astrobleme in central Brazil reveal an aerodynamically stable microstructure, which is interpreted to reflect the aerial crystallization of hypervelocity melt globules derived from Fe‐rich sedimentary target rocks. The bombs are composed of an aggregate of preferentially oriented conic units with different degrees of packing, giving rise to porous and massive hematite varieties. These varieties generally occupy the front and rear of the bombs, respectively. Quartz fragments with planar deformation features are common in the porous domains and represent ejected solid particles captured by the bombs during cooling. The absence of typical contorted shapes in these bombs reflects the lack of spin during their ballistic trajectory. The bombs are enriched in Rh (4×); Ru, Ir, and Pd (5×); and Pt (&gt;30×) relative to the indigenous level of target sediments. This suggests the presence of a projectile‐derived component in their constitution. Single composition oxidic bombs (pure hematite and pure silica) predominate in this occurrence, indicating that a mechanism of segregation has operated in the ejected melt volumes.

Shock metamorphism of quartz in nature and experiment: II. Significance in geoscience*

Abstract— The occurrence of shock metamorphosed quartz is the most common petrographic criterion for the identification of terrestrial impact structures and lithologies. Its utility is due to its almost ubiquitous occurrence in terrestrial rocks, its overall stability and the fact that a variety of shock metamorphic effects, occurring over a range of shock pressures, have been well documented. These shock effects have been generally duplicated in shock recovery experiments and, thus, serve as shock pressure barometers. After reviewing the general character of shock effects in quartz, the differences between experimental and natural shock events and their potential effects on the shock metamorphism of quartz are explored. The short pulse lengths in experiments may account for the difficulty in synthesizing the high‐pressure polymorphs, coesite and stishovite, compared to natural occurrences. In addition, post‐shock thermal effects are possible in natural events, which can affect shock altered physical properties, such as refractive index, and cause annealing of shock damage and recrystallization. The orientations of planar microstructures, however, are unaffected by post‐impact thermal events, except if quartz is recrystallized, and provide the best natural shock barometer in terms of utility and occurrence. The nature of planar microstructures, particularly planar deformation features (PDFs), is discussed in some detail and a scheme of variations in orientations with shock pressure is provided. The effect of post‐impact events on PDFs is generally limited to annealing of the original glass lamellae to produce decorated PDFs, resulting from the exsolution of dissolved water during recrystallization. Basal (0001) PDFs differ from other PDF orientations in that they are multiple, mechanical Brazil twins, which are difficult to detect if not partially annealed and decorated. The occurrence and significance of shock metamorphosed quartz and its other phases (namely, coesite, stishovite, diaplectic glass and lechatelierite) are discussed for terrestrial impact structures in both crystalline (non‐porous) and sedimentary (porous) targets. The bulk of past studies have dealt with crystalline targets, where variations in recorded shock pressure in quartz have been used to constrain aspects of the cratering process and to estimate crater dimensions at eroded structures. In sedimentary targets, the effect of pore space results in an inhomogeneous distribution in recorded shock pressure and temperature, which requires a different classification scheme for the variation of recorded shock compared to that in crystalline targets. This is discussed, along with examples of variations in the relative abundances of planar microstructures and their orientations, which are attributed to textural variations in sedimentary target rocks. Examples of the shock metamorphism of quartz in distal ejecta, such as at the K/T boundary, and from nuclear explosions are illustrated and are equivalent to that of known impact structures, except with respect to characteristics that are due to long‐term, post‐shock thermal effects. Finally, the differences between the deformation and phase transformation of quartz by shock and by endogenic, tectonic and volcanic processes are discussed. We confirm previous conclusions that they are completely dissimilar in character, due to the vastly different physical conditions and time scales typical for shock events, compared to tectonic and volcanic events. Well‐characterized and documented shock effects in quartz are unequivocal indicators of impact in the natural environment.

Neodymium and strontium isotopic study of Australasian tektites: New constraints on the provenance and age of target materials

Nd and Sr isotopic studies of Australasian tektites provide information on the age and provenance of the target materials and allow us to characterize the target area and the impact process leading to tektite formation. ϵ Nd values of australites, splash-form indochinites, and Muong Nong-type indochinites are indistinguishable within analytical uncertainty and average -11.5 ϵu. Depleted mantle Nd model ages fall within the narrow range of 1490–1620 Ma, indicating that the source material was derived dominantly from a Proterozoic crustal terrane. ϵ Sr values are variable and are correlated with the geographic location of the tektite samples. Analyses of four Muong Nong-type (or layered) indochinites from a single locality in eastern Thailand yield an isochron age of 167 ± 12 Ma (2σ). A correlation of Rb Sr fractionation with Sr model ages indicates that the last major Rb/Sr fractionation event experienced by the target materials occurred 175 ± 15 Ma ago. We interpret this age as the time of deposition of sedimentary target rocks and consider the compositional layering observed in Muong Nong-type tektites to reflect compositional variability inherited from Jurassic sediments. The Nd and Sr isotopic data provide evidence that all Australasian tektites were derived from a single sedimentary formation with a narrow range of stratigraphic ages close to 170 Ma. We suggest that all of the Australasian tektites were derived from a single impact event, and that the australites represent the upper part of a melt sheet ejected at high velocity, whereas the indochinites represent melts formed at a lower level in the target material which were distributed closer to the area of impact. The impact site is inferred to be within an area of Jurassic sedimentary bedrock, which spans the geopolitical boundaries between northern Cambodia, southern Laos, and southeastern Thailand.

Reflection study of the Haughton impact crater

The western flank of the Haughton impact crater was imaged with a 10.25‐km‐long multifold reflection profile. The seismic waves mapped 10 acoustic discontinuities in the stratified sedimentary target rocks. The impact disturbed the entire 1900 m of the highly competent Paleozoic strata. The average seismic velocity of over 6000 m/s exhibited by these rock units is a clear indication of the undisturbed impact area's unusually high elastic strength. The dynamic and destructive forces of the cratering process are manifested on the seismic profile by a dense and complex system of faults. These steeply dipping faults penetrated the sedimentary rocks but showed no recognizable extension into the crystalline basement. The recognition of normal faults 3 km west of the faulted annulus suggests a structural diameter of 24 km, some 4 km larger than postulated from earlier geological data. It has been found that the surface morphologically distinct ring zones do not have seismically recognizable subsurface signatures. In the central interior region of the crater, coherent reflection signals are lacking. However, some weak local acoustic discontinuities are recognized. The underlying crystalline basement rocks did not exhibit any seismically mappable impact related zones of alteration.