Sediment Mobility Research Articles

Microbial mediated hardening of a Central Mediterranean upper shelf seafloor during the MIS 5.5; a possible post global warming scenario?

Higher sea level and sea surface temperature than at present have been inferred for the Last Interglacial (MIS 5.5, 135–116 ka), making it a good analogue for modeling the climate response of the environment to global warming in the near future. With the aim of predicting the possible evolution of some central Mediterranean shallow sandy seabeds, a MIS 5.5 biocalcarenite was investigated (Gulf of Taranto, Italy). Limited post-depositional diagenesis affected this deposit, which represents an infralittoral sandy seabed, with local vegetation and relatively high energy conditions. Medium-coarse sand sized bioclasts, with a negligible quantity of siliciclastic, compose the sediment that also hosts large shells of mollusks. Micritic cements are widespread, often in continuum with the micritized part of the shells, showing non-isopachous aphanitic and filamentous rims, aphanitic micro-mounds, vacuolar peloidal menisci, and aphanitic pore-filling matrix. All these cements consist of submicrometer anhedral or nanospheroidal crystals of low-Mg calcite, mixed with a smaller amount of irregular plate-like crystals of saponite. Micritic cements are also rich in mineralized filamentous, tubular, and subspherical bacterial bodies. This highlights the occurrence of an epilithic and endolithic microbial community forming a biofilm that stabilized the mobile sediment as consequence of the microbial mediated early cement precipitation. This led the synsedimentary hardening of some parts the mobile sandy substrate, the settlement of sessile taxa - such as Spondylus gaederopus, oysters, serpulids and barnacles, together with endofaunal organisms. Early micritic cementation is common in modern tropical climate, whereas is substantially absent in the modern Mediterranean. Consequently, its presence in the MIS 5.5 deposit confirms warmer sea water temperature compared to today (estimated at ca +2 °C) and suggests that similar hardening of mobile substrates may occur in the near future as a response to global warming.

Vanadium redox speciation in the acid-extractable phase of Krka River estuary surface sediment

This study investigated the redox speciation and mobility of V in the acid-extractable fraction of surface sediments from the Krka River estuary using an optimized IC-UV/Vis analytical method. The separation of V(IV) and V(V) redox species was done using anion-exchange based chromatographic method, while pseudo-total V concentrations were measured using HR ICP-MS analytical instrumentation. Extracted V concentrations from the sediment fraction (pH = 5, HCl) and determined pseudo-total V concentrations were used to calculate the Enrichment Factor (EF) and Risk Assessment Code (RAC), indicating potential anthropogenic influence and environmental risk. A simple PHREEQC model was developed to asses V speciation in the oxic bottom seawater layer simulating possible remobilization of the leached sediment phase. The results of the study show that minor fraction of V is present in the acid-extractable phase across the surface sediment of Krka River estuary. Higher V mobility is mostly observed at locations rich with clay minerals, terrigenous input, and carbonates. Anthropogenic influence was linked to higher enrichment but lower mobility, suggesting binding to less mobile sediment phases (reducible, organic and residual fractions). The predominance of reduced V(IV) species in the acid-extractable sediment fraction indicates a potentially low V toxicity risk in the sediments of Krka River estuary, even in cases of high potential remobilization of V. However, the model predicted complete oxidation of V(IV) to V(V) upon remobilization into the oxic bottom water layer. This highlights the complexity of V behavior in natural estuarine systems, where the toxicity risks of possible V remobilization still remain unclear. Results of this study demonstrate the need for the strengthening efforts in speciation of V in the mobile sediment phase to obtain a cohesive outlook on its potential toxicity and biogeochemical cycling.

Mobilization of phosphorus in sediments of eutrophic lakes induced by elevated sulfate levels

Elevated sulfate levels in eutrophic lakes have been observed to induce the release of endogenous phosphorus. While previous studies have predominantly examined its impact on iron-bound phosphorus (FeP), the influence on organic phosphorus (OP), a crucial active phosphorus component in sediments, remains poorly understood. In this study, mesocosms were established with lactate supplementation and varying sulfate concentrations to explore sulfate reduction and its impacts on phosphorus mobilization in freshwater sediments. Lactate addition induced hypoxia and provided substrates, thereby stimulating sulfate reduction with a decline of sulfate levels, an increase of sulfide concentrations, and fluctuations of sulfate-reducing bacteria. Meanwhile, concentrations of total dissolved phosphorus and phosphate were dramatically promoted during lactate decomposition, with a higher sulfate concentration associated with greater phosphorus elevation, correlating with the decrease of total phosphorus in sediment. The increase in phosphorus of the overlying water was partly attributed to FeP release from the sediment, confirmed by a decrease in its sediment content. FeP release was ascribed to dissimilatory reduction of iron oxides or chemical reduction mediated by sulfides in anoxic sediments, leading to the desorption and subsequent release of phosphorus. Evidences included the proliferation of iron-reducing bacteria, a decrease in Fe(II) concentrations in sediment pore- water, and the continuous accumulation of solid iron sulfides in surface sediments. Furthermore, OP mineralization in sediment also contributed to the increase in phosphorus in water columns, confirmed by a reduction in its content and the abundance of fermentation bacteria in surface sediment. Notably, the decrease in OP content accounted for >80 % of the total phosphorus reduction in surface sediment in the end. Thus, sulfur cycling plays a critical role in iron and phosphorus cycling, significantly stimulating not only the mobilization of FeP but also OP in sediments, with OP mineralization potentially being the primary contributor to endogenous phosphorus release.

Geomorphology and sediment mobility on sand banks: A study of Dogfish Bank, Hecate Strait, Northeast Pacific Ocean

AbstractMovement of sediment along shallow continental shelves is a natural process with wide‐ranging environmental and economic implications, making it of high importance to marine spatial planning efforts in the offshore. Development of marine renewable energy, for instance, requires detailed understanding of the morphodynamics of mobile bedforms to select foundation types and ensure safe installation of infrastructure in shallow shelf environments. This study evaluates geomorphology and sediment mobility of Dogfish Bank (< 20 mbsl) in the Hecate Strait offshore British Columbia, Canada, using hydroacoustic and airborne bathymetric data combined with seismic profiles and grain‐size information. These data reveal current‐swept features ranging from sediment‐depleted lag to sediment‐abundant sand ridges and dunes, with sand ribbons and furrows in‐between. Seismic reflection data show up to 15 m of surficial sand concentrated beneath north‐aligned sand ridges that dominate the bathymetry of northwest Hecate Strait. Sand ribbons (typically understood sediment‐limited features in shallow marine environments) are notably maintained over seabed with comparable sand thickness to adjacent dunes (i.e. sediment‐abundant features), suggesting local spatial variability in hydrodynamics and sediment characteristics (principally grain size) influence expression of mobile bedforms. Repeat mapping between 2008 and 2019 shows dunes and ribbons both migrate northwards, with largest seafloor changes along northeast‐facing lee sides of dunes, matching closely with published models of sediment mobility which suggest northward bedform migration is largely driven by storms. Median total migration distance is 164 m (northward) for dunes (time‐averaged rate of 14.9 m/year). Sand ribbons show less migration (median northward distance of 73 m) and migrate in a depth‐dependent manner. Because sand ribbons are typically flow‐parallel features, their lateral migration likely results from varying current directions and flow acceleration over shallower seabed. Sand ribbon migration should therefore a consideration in studies examining seabed change, particularly when they are formed over unconsolidated sediment.

Autogenic Formation of Bimodal Grain Size Distributions in Rivers and Its Contribution to Gravel‐Sand Transitions

AbstractRiverbeds often fine downstream, with a gravel‐bedded reach, a relatively abrupt gravel‐sand transition (GST), and a sand‐bedded reach. Underlying this behavior, bed grain size distributions are often bimodal, with a relative paucity (gap) around the range 1–5 mm. There is no general morphodynamic model capable of producing the grain size gap and gravel‐sand transition autogenically from a unimodal sediment supply. Here we use a one‐dimensional morphodynamic model including size‐specific bedload and suspended load transport, to show that bimodality readily evolves autogenically even under unimodal sediment feed. A GST forms when we include a floodplain width that abruptly increases at some point. Upstream of the transition, non‐gap gravel ceases to move and gap sediment is preferentially transported. At the transition, non‐gap sand rapidly deposits from suspension, enhancing gap sediment mobility and diluting its presence on the bed.

A mathematical model for bedrock incision in near‐threshold gravel‐bed rivers

AbstractGravel‐bed rivers that incise into bedrock are common worldwide. These systems have many similarities with other alluvial channels: they transport large amounts of sediment and adjust their forms in response to discharge and sediment supply. At the same time, the occurrence of bedrock incision implies behaviour that falls on a spectrum between fully detachment‐limited ‘bedrock channels’ and fully transport‐limited ‘alluvial channels’. Here, we present a mathematical model of river profile evolution that integrates bedrock erosion, gravel transport and the formation of channels whose hydraulic geometry is consistent with that of near‐threshold alluvial channels. We combine theory for five interrelated processes: bedload sediment transport in equilibrium gravel‐bed channels, channel width adjustment to flow and sediment characteristics, abrasion of bedrock by mobile sediment, plucking of bedrock and progressive loss of gravel‐sized sediment due to grain attrition. This model contributes to a growing class of models that seek to capture the dynamics of both bedrock incision and alluvial sediment transport. We demonstrate the model's ability to reproduce expected fluvial features such as inverse power law scaling between slope and area, and width and depth consistent with near‐threshold channel theory, and we discuss the role of sediment characteristics in influencing the mode of channel behaviour, erosional mechanism, channel steepness and profile concavity.

Evidence for littoral convergence and sediment delivery to Mattole submarine canyon, Northern California

At geologic timescales, a significant proportion of the sediment eroded from continents is transferred from rivers to littoral cells, then through submarine canyons to deep ocean basins. Accumulation and occasional discharge of sediment from canyon headwall regions is a likely driver for the sediment gravity flows believed to be responsible for much of this mass transport, but the responsible mechanisms and event timescales in canyon heads are imprecisely defined, largely due to the drowning of canyon heads since the last glaciation and the resulting dearth of modern depositional environments to observe. We investigated a littoral cell adjacent to Mattole submarine canyon in Northern California to better understand the influence of bathymetry and coast shape on sediment trajectories and hypothesize that canyon heads promote littoral sediment accumulation due to bathymetric sheltering of the adjacent coast from waves and convergence of littoral cells exposed to varying wave direction. The uppermost gullies of Mattole Canyon extend to the littoral cell, and a train of sediment waves within the uppermost thalweg of Mattole Canyon suggests that gravity-driven flows of shore-derived sediment may have recently occurred. Mattole Canyon and nearby Mendocino Canyon flow into the deep Mendocino Channel, which has the highest observed Late Holocene sediment accumulation rates in Northern California. We documented the beach slope, grain size, and sediment provenance along 15 km of coast adjacent to Mattole Canyon and conducted numerical wave modeling to infer the dominant direction and magnitude of sediment transport, relative wave sheltering by bathymetry, and estimated sediment mobility in the vicinity of the canyon head over a multi-year period. South of the canyon headwall, in the vicinity of the Mattole River outlet, coarser sediment rich in metasandstone clasts and steeper beach slopes coincide with decadal-scale beach accretion. North of the canyon head, sediments are generally finer, beaches are flatter, clast lithologies include more quartz and mudstone grains, and there is decadal-scale net erosion. Wave modeling suggests the Mattole headwall region is subject to sustained sheltering from waves due to canyon bathymetry, littoral sediment convergence above the canyon head for much of a typical year, and occasional bed entrainment of sediment in the canyon’s uppermost gullies by large waves. Larger winter waves from the northwest likely result in net southerly drift north of the canyon head, with a high likelihood of preferentially transporting fine-grained, more quartz-rich sediment towards the Mattole headwall. Smaller summer swells from the west and south likely results in net northerly transport of metasandstone clast-rich Mattole River-derived sediment towards the canyon head. The imbalance in seasonality in wave conditions, coast shape, and sediment delivery by the Mattole River and other coastal creeks is broadly consistent with the spatial patterns in grain size, mineralogy, slope, and beach width that we observe in the vicinity of the canyon, and the net delivery of sediment to the Mattole Canyon head. An approximate mass balance of sediment flux from coastal streams feeding Mattole River littoral cell suggests that sediment volumes likely accumulate in the canyon headwall region that could supply several density flow events in a typical decade. These findings highlight the importance of the connectivity of the canyon to the nearshore region for the processes and products in canyons and fans. We hypothesize that feedbacks between canyon bathymetry, sediment accumulation, and mass evacuating flows promotes the long-term persistence of canyon systems.

Ecological risk assessment of heavy metals (Pb, Cd, Cr, Ni, Zn, Fe) and metalloid (As) in surface sediment of Anzali International Wetland, Iran

ABSTRACT This study aimed to assess the metal concentration, mobility, bioavailability, ecological risk, and toxicity in the surface sediment of Anzali International Wetland. Contamination and ecological risk were evaluated using parameters such as Global Contamination Factors (GCF), Risk Assessment Code (RAC), Toxic Unit (TU), sum of Toxic Units (ΣTUs), Toxic Risk Index (TRI), ecological risk (ER), Risk Index (RI), and modified Hazard Quotients (MHQ). Heavy metal mean concentrations (mean ± SD) ranked as follows: Zn (95.46 ± 20.71) > Cr (19.79 ± 2.79) > Ni (18.49 ± 5.23) > Pb (13.97 ± 3.20) > As (6.45 ± 1.87) > Cd (0.90 ± 0.34). Cd exhibited high mobility and bioavailability, while Cr, Pb, Zn, Ni, and As mainly existed in residual fractions, indicating low bioavailability and minimal ecological risk. Ecological risk assessment identified “moderate” to “considerable” risk potential for Cd at specific sites. The Risk Index categorized Anzali sediment as having “low” to “moderate” risk potential (150 < RI < 300). Values of RI, ΣTUs, and MHQ suggested low to moderate risk potential and low toxicity in the sediment. Global Contamination Factor (GCF) values indicated high contamination (12.53 to 79.11). Recommendations include installing effective sewage treatment plants and promoting proper agricultural practices to mitigate metal toxicity in Anzali Wetland and also protect human and environmental health.

Fine Sediment in Mixed Sand‐Silt Environments Impacts Bedform Geometry by Altering Sediment Mobility

AbstractGeometric characteristics of subaqueous bedforms, such as height, length and leeside angle, are crucial for determining hydraulic form roughness and interpreting sedimentary records. Traditionally, bedform existence and geometry predictors are primarily based on uniform, cohesionless sediments. However, mixtures of sand, silt and clay are common in deltaic, estuarine, and lowland river environments, where bedforms are ubiquitous. Therefore, we investigate the impact of fine sand and silt in sand‐silt mixtures on bedform geometry, based on laboratory experiments conducted in a recirculating flume. We systematically varied the fraction of sand and silt for different discharges, and utilized an acoustic Doppler velocimeter to measure flow velocity profiles. The final bed geometry was captured using a line laser scanner. Our findings reveal that the response of bedforms to an altered fine sediment percentage is ambiguous, and likely depends on, among others, bimodality‐driven bed mobility and sediment cohesiveness. When fine, non‐cohesive material (fine sand or coarse silt) is mixed with the base material (medium sand), an increased dune height and length is observed, possibly caused by the hiding‐exposure effect, resulting in enhanced mobility of the coarser material. However, weakly cohesive fine silt suppresses dune height and length, possibly caused by reduced sediment mobility. Finally, in the transition from dunes to upper stage plane bed, there are indications that the bed becomes unstable and dune heights vary over time. The composition of the bed material does not significantly impact the hydraulic roughness, but mainly affects roughness via the bed morphology, especially the leeside angle.

Evaluating the Effect of Morphologic Units on Fractional Sediment Mobility and Bedload Transport in a Small Pool‐Riffle Reach

AbstractThis study examines the spatial pattern of fractional sediment mobility and assesses the influence of morphologic units on bedload transport in a small pool‐riffle reach with limited supply. Using a 2D hydraulic model and a subsurface‐based sediment transport model, shear stresses, fractional sediment mobility, and bedload transport were examined for flow events ranging in magnitude between 0.2Qbf and 1.5Qbf. Results reveal that while spatial variations in shear stress decrease as discharge increases, only a small proportion of the bed experiences high transport rates. At the reach scale, riffles are the primary morphological unit contributing to fully mobile sediment for all size fractions. However, at a subunit scale, there is evidence of sediment transport reversal for grains &gt;32 mm at flows near or exceeding bankfull discharge in association with shear stress reversal. These transport reversals are important for maintaining pools despite their infrequent occurrence in the study reach. Sediment transport maps indicate that bed morphology considerably influences sediment transport at low to moderate flows. During these events, the shear stress is sensitive to local bed topography and partial mobility is the dominant transport process. In contrast, variations in bedload transport rates decrease during high flows when the flow is less sensitive to variations in bed topography and the bed becomes fully mobile.

Estimation of bed material transport in gravel‐bed streams using the virtual velocity approach: Insights from the North‐Western Himalayas, India

AbstractThis study focuses on evaluating the sediment mobility and transport patterns in two Himalayan rivers (Aglar and Paligad Rivers) during monsoon and non‐monsoon flows. The virtual velocity approach involving the measurements of the bed proportional mobility (Y), active layer depth (ds), displacement length and virtual velocity of mobilized grains was employed. Both local (0.5 m subsections) and wetted cross‐sectional average parameters were used. While using local parameters the total annual bed material transport was estimated to be 67 100 (±20 400 t) and 18 400 t (±6000 t) in the Aglar and Paligad Rivers, respectively. Of this, nearly 60% of transport occurred during the monsoon and the overall contribution of partial transport (PT) remained low (&lt;6%). However, based on cross‐section average parameters, total transport was estimated to be 42 300 (±15 800 t) and 12 200 t (±4700 t), in Aglar and Paligad, respectively, with nearly 79% and 68% occurring during the monsoon. Moreover, the contribution of PT increased to nearly 18% and 29% for the Aglar and Paligad Rivers, respectively. Additionally, the dependence of PT on Y and full transport on ds results in an abrupt shift in transport rates at the transition from partial to full transport, causing discontinuity in transport curves. Therefore, a unified function was proposed to represent the extent of transport for both partial and full transport, yielding continuous transport curves. These findings are particularly relevant for efficient river management as the region houses several hydropower plants and is highly vulnerable to climate change.

Elevated lead mobility in sediments of a eutrophic drinking water reservoir during spring and summer seasons: Insights from isotopic signatures

Lead (Pb) pollution in sediments remains a major concern for ecosystem quality due to the robust interaction at the sediment/water interface, particularly in shallow lakes. However, understanding the mechanism behind seasonal fluctuations in Pb mobility in these sediments is lacking. Here, the seasonal variability of Pb concentration and isotopic ratio were investigated in the uppermost sediments of a shallow eutrophic drinking lake located in southeast China. Results reveal a sharp increase in labile Pb concentration during autumn-winter period, reaching ∼ 3-fold higher levels than during the spring-summer seasons. Despite these fluctuations, there was a notable overlap in the Pb isotopic signatures within the labile fraction across four seasons, suggesting that anthropogenic sources are not responsible for the elevated labile Pb concentration in autumn-winter seasons. Instead, the abnormally elevated labile Pb concentration during autumn-winter was probably related to reduction dissolution of Fe/Mn oxides, while declined labile Pb concentration during spring-summer may be attributed to adsorption/precipitation of Fe/Mn oxides. These large seasonal changes imply the importance of considering seasonal effects when conducting sediment sampling. We further propose a solution that using Pb isotopic signatures within the labile fraction instead of the bulk sediment can better reflect the information of anthropogenic Pb sources.

Turning The Tide: Live-Bed Scale Experiments Of Bar-Dominated Estuaries And Effects Of Dredging On Intertidal Habitat

Many large sand-dominated estuaries and tidal basins have complex channel and bar patterns, wherein a continuous deep channel suitable for shipping is rarely naturally present, which requires dredging. The intertidal area has important, often protected habitats for macro-benthic species, wader birds and other species. The question is to what degree channel and shoal dimensions and the amount of intertidal area are affected by dredging and disposal for access to ports. While numerical modelling is conducted for these systems with some success, complementary scale experiments with live beds have challenged the fields of coastal engineering and coastal morphodynamics for over a century. Compared to scale models for rivers, the scale issues in tidal experiments are more complicated and very few attempts have been pursued. For example, Reynolds (1889) conducted the first scale experiments of an estuary by a periodic sea level fluctuation, but found that even fine sand was hard to mobilize, while the bed surface was dominated by ripples rather than bars. Similarly, Tambroni et al. (2005) carefully scaled sediment mobility in a converging channel and obtained large-scale morphological patterns with gentle bars nearly overwhelmed by ripples. Stefanon et al. (2010) present a careful attempt at erosive tidal channel network development in a scale model with low-density sediment, which showed unexplained, over-large scour holes at channel junctions. The key issues for tidal experiments are to obtain sufficient sediment mobility (expressed as Shields or Rouse number) and to avoid over-large ripples and scours, and to this end classic river scale modelling is inadequate. Here we assess whether our recent innovation solves these scale issues. The objective of this abstract is to elucidate the scaling of experiments that enable study of morphodynamic estuaries in many aspects including effects of sediment management by dredging.

Unraveling the Coupled Dynamics between DOM Transformation and Arsenic Mobilization in Aquifer Systems during Microbial Sulfate Reduction: Evidence from Sediment Incubation Experiment

Geogenic arsenic (As)-rich groundwater poses a significant environmental challenge worldwide, yet our understanding of the interplay between dissolved organic matter (DOM) transformation and arsenic mobilization during microbial sulfate reduction remains limited. This study involved microcosm experiments using As-rich aquifer sediments from the Singe Tsangpo River basin (STR) and Jianghan Plain (JHP), respectively. The findings revealed that microbial sulfate reduction remarkably increased arsenic mobilization in both STR and JHP sediments compared to that in unamended sediments. Moreover, the mobilization of As during microbial sulfate reduction coincided with increases in the fluorescence intensity of two humic-like substances, C2 and C3 (R = 0.87/0.87 and R = 0.73/0.66 in the STR and JHP sediments, respectively; p &lt; 0.05), suggesting competitive desorption between DOM and As during incubation. Moreover, the transformations in the DOM molecular characteristics showed significant increases in CHOS molecular and low-O/C-value molecular intensities corresponding to the enhancement of microbial sulfate reduction and the possible occurrence of methanogenesis processes, which suggests a substantial bioproduction contribution to DOM components that is conducive to As mobilization during the microbial sulfate reduction. The present results thus provide new insights into the co-evolution between As mobilization and DOM transformations in alluvial aquifer systems under strong microbial sulfate reduction conditions.

Short-Term Foredune Dynamics in Response to Invasive Vegetation Control Actions

Efforts to control the spread of invasive alien species (IAS) in coastal dunes are essential to protect biodiversity and maintain the integrity of the ecosystem. However, the timing and extent of these control measures often do not consider their potential impact on dune morphodynamics. This study investigated how IAS control measures can affect sand dune mobility. Research involved monitoring short-term morphological and vegetation changes using close-range remote sensing along with historical wind data. Findings revealed that changes in vegetation cover significantly impacted dune system evolution, notably increasing sand mobility when IAS vegetation was removed. Considering the seasonal wind regime, dominated by offshore winds in the summer, removing vegetation during this period can promote seaward sediment transport, potentially resulting in sediment loss to the beach. These findings highlight the importance of understanding sediment mobility patterns when planning vegetation control actions within dune restoration strategies.

ИССЛЕДОВАНИЕ ПРОЦЕССА ОСВЕТЛЕНИЯ ЯБЛОЧНОГО СУСЛА С ПРИМЕНЕНИЕМ РАЗЛИЧНЫХ ВСПОМОГАТЕЛЬНЫХ СРЕДСТВ

The quality of clarification of apple must from various varieties of apples of domestic and foreign breeding, different ripening periods, growing at the Research and Breeding Collection of Genetic Resources of Horticultural Crops, located in the Central Joint Stock Company, Krasnodar, was studied. Sampling of apples was carried out at optimal ripeness from different sides of the tree crown in relation to the cardinal directions. Apple processing was carried out using a crusher-grinder, followed by pressing the pulp on a hydraulic press. The enzyme preparations SQzyme PCL, Grainzyme NL and Fructozyme R were used in the experiments. Apple must was clarified using bentonite (BENTOVIN), plant (pea) and animal (gelatin) protein. As a result of the studies, it was established that self-clarification of the must without the use of enzyme preparations was slow. Slow self-clarification with the formation of voluminous loose and mobile sediments was observed only in certain variants (Ekzotika, Orfey, Liberti, Renet Platona). The addition of enzyme preparations, especially SQzyme PCL, contributed to an increase in must yield by 12-17 % relative to the control. The most “responsive” to the use of enzyme preparations were apples of the varieties Dzhin, Ekzotica, Orfey, Margo, Prikubanskoe, Bagryanets Kubani, Liberti, Renet Platona, forms 12/1-20-16 and 12/1-20-33. With the addition of enzyme preparations in the pulp, the rate of must extraction increased. Gradual clarification was noted in the next 3-4 hours. The greatest increase in must yield was noted during the processing of apple varieties such as Enterprise, Margo, Ketni, Renet Platona – by 12-17 % compared to the control (without the use of enzyme preparations). The use of only one sorbent – bentonite, animal or vegetable protein – did not lead to high-quality clarification of the must at the given dosages. At the same time, complex processing made it possible to significantly improve the quality of clarification and reduce the turbidity of the must. The highest quality clarification of the must, regardless of the apple variety, was obtained by complex treatment of the pulp with enzyme preparations followed by dosing of proteins and bentonite. Key words: APPLE MUST, CLARIFICATION, ENZYME PREPARATIONS, BENTONITE, PROTEIN SORBENTS

Mechanisms of cadmium release from manganese-rich sediments driven by exogenous DOM and the role of microorganisms

Dissolved organic matter (DOM) is a crucial component of natural sediments that alters Cd sequestration. Nevertheless, how different types of DOM fuel Cd mobilization in Mn-rich sediments has not been elucidated. In the present study, four typical DOM, fluvic acid (FA), bovine serum albumin (BSA), sodium alginate (SA), and sodium dodecyl benzene sulfonate (SDBS), were used to amend Cd-contaminated sediment to study their effects on Cd/Mn biotransformation and microbial community response. The results demonstrated that different DOM drive microbial community shifts and enhance microbially mediated Mn oxide (MnO) reduction and Cd release. The amendment of terrestrial- and anthropogenic-derived DOM (FA and SDBS) mainly contributed to enriching Mn-reducing bacteria phylum Proteobacteria, and its abundance increased by 38.16–74.47 % and 56.41–73.98 %, respectively. Meanwhile, microbial-derived DOM (BSA and SA) mainly stimulated the abundances of metal(loid)-resistant bacteria phylum Firmicutes. Accompanied by microbial community structure, diversity, and co-occurrence network shifts, the DOM concentration and oxidation-reduction potential changed, resulting in enhanced Cd mobilization. Importantly, FA stimulated Cd release most remarkably, probably because of the decreased cooperative interactions between bacterial populations, stronger reduction of MnOs, and higher aromaticity and hydrophobicity of the sediment DOM after amendment. This study linked DOM types to functional microbial communities, and explored the potential roles of different DOM types in Cd biotransformation in lake sediments.

Spatiotemporal variability of suspended sediment concentration in the coastal waters of Yellow River Delta: Driving mechanism and geomorphic implications

Satellite images have revealed a significant decline in the suspended sediment concentration (SSC) near surface in the coastal waters of Yellow River Delta (YRD) in recent years. However, there is limited information on the spatial disparity in SSC distributions and its dynamic mechanism. In this study, we utilize a well-calibrated SSC retrieval algorithm and a depth-averaged numerical modeling approach to investigate the delta and sub-delta scale variation trends and driving mechanisms of SSC in the coastal waters of YRD over the past few decades. The results of this study demonstrate the existence of high turbidity zones in coastal waters of the northern abandoned delta and the active lobe of the YRD. These zones have experienced general decreasing trends of SSC at the interannual timescale. Additionally, the distribution of SSC is significantly higher in dry seasons compared to that in wet seasons. The magnitude and varying trends of SSC are strongly influenced by the total bottom shear stress (BSS) caused by combined effects of waves and currents, although the wave-induced BSS is found to be less significant that the current-induced one, but vary more significantly due to wind forcing in the Bohai Sea. Furthermore, the grain size of seabed sediments plays a dominant role in the sediment mobilization and resuspension processes over interannual and longer timescales. The distribution of high BSS and sediment mobility zones align with the active areas for morphological changes with the YRD exhibiting net accretion in the active river mouth and erosion in the abandoned delta lobes. These findings highlight the multiscale variations and the close relationship between SSC and BSS, providing valuable insights into sediment dynamics with geomorphic evolution in highly human-interfered deltaic systems.

Spatial Distribution, Ecological Risk Assessment, and Source Identification of Metals in Sediments of the Krka River Estuary (Croatia)

To evaluate the level of contamination and predict the potential toxicity risk, selected metal concentrations (Cd, Pb, Cr, Mn, Co, Ni, Cu, Zn, and As) were determined in 40 surface sediment samples from the stratified karstic Krka River estuary (Croatia). In addition, diffusive gradients in thin films (DGT) probes were deployed in situ to understand the mobilization mechanisms and bioavailability of metals in the sediment. The results show significant spatial differences between the upper and lower estuary, with the latter being more affected by anthropogenic pollution. The pollution assessment using the enrichment factor (EF), the geoaccumulation index (Igeo), and the pollution load index (PLI) showed a strong enrichment of metals in the lower part of the estuary, especially of Mn, Cu, Zn, Pb, and As. The statistical analysis (PCA) revealed the former ferromanganese factory and the port as major sources of pollution in the area. Nickel, Co, and Cr, although slightly elevated, may be attributed to the natural origin. The metal mobility in the estuarine sediment was primarily governed by early diagenetic processes (aerobic organic matter mineralization, Fe and Mn oxyhydroxide reduction), which caused the release of metals from the sediment into the pore water and subsequently into the overlying water column.

Microplastic infiltration into mobile sediments

This study investigates the dynamics of microplastic infiltration into non-stationary sandy sediments, a pressing environmental concern due to the rising prevalence of microplastics in aquatic ecosystems. An annular flume was used to simulate riverine bedform motion, examining the suspension and infiltration of denser-than-water microplastic particles, including polyvinyl chloride (PVC), polyamide (PA), and polylactide (PLA). The experiments focused on various particle sizes (ranging from 0.2 to 5 mm in diameter) and bedform migration speeds, known as celerities. The findings indicate that particle size is a significant factor influencing the depth of infiltration and distribution within sediment layers, whereas the impact of bedform celerities and particle densities appears less significant. This research provides novel insights into the behavior of microplastics in dynamic sedimentary environments, highlighting the intricate interaction between microplastic characteristics and sedimentary processes. The results contribute to an enhanced understanding of microplastic distribution and accumulation in riverine systems, offering crucial data for developing predictive models and formulating potential remediation strategies for microplastic pollution.