Second-order Topological Superconducting Research Articles

Dislocation Majorana bound states in iron-based superconductors

We show that lattice dislocations of topological iron-based superconductors such as FeTe1−xSex will intrinsically trap non-Abelian Majorana quasiparticles, in the absence of any external magnetic field. Our theory is motivated by the recent experimental observations of normal-state weak topology and surface magnetism that coexist with superconductivity in FeTe1−xSex, the combination of which naturally achieves an emergent second-order topological superconductivity in a two-dimensional subsystem spanned by screw or edge dislocations. This exemplifies a new embedded higher-order topological phase in class D, where Majorana zero modes appear around the “corners” of a low-dimensional embedded subsystem, instead of those of the full crystal. A nested domain wall theory is developed to understand the origin of these defect Majorana zero modes. When the surface magnetism is absent, we further find that s± pairing symmetry itself is capable of inducing a different type of class-DIII embedded higher-order topology with defect-bound Majorana Kramers pairs. We also provide detailed discussions on the real-world material candidates for our proposals, including FeTe1−xSex, LiFeAs, β-PdBi2, and heterostructures of bismuth, etc. Our work establishes lattice defects as a new venue to achieve high-temperature topological quantum information processing.

Generating Many Majorana Corner Modes and Multiple Phase Transitions in Floquet Second-Order Topological Superconductors

A d-dimensional, nth-order topological insulator or superconductor has localized eigenmodes at its (d−n)-dimensional boundaries (n≤d). In this work, we apply periodic driving fields to two-dimensional superconductors, and obtain a wide variety of Floquet second-order topological superconducting (SOTSC) phases with many Majorana corner modes at both zero and π quasienergies. Two distinct Floquet SOTSC phases are found to be separated by three possible kinds of transformations, i.e., a topological phase transition due to the closing/reopening of a bulk spectral gap, a topological phase transition due to the closing/reopening of an edge spectral gap, or an entirely different phase in which the bulk spectrum is gapless. Thanks to the strong interplay between driving and intrinsic energy scales of the system, all the found phases and transitions are highly controllable via tuning a single hopping parameter of the system. Our discovery not only enriches the possible forms of Floquet SOTSC phases, but also offers an efficient scheme to generate many coexisting Majorana zero and π corner modes, which may find applications in Floquet quantum computation.

Corner- and sublattice-sensitive Majorana zero modes on the kagome lattice

In a first-order topological phase with sublattice degrees of freedom, a change in the boundary sublattice termination has no effect on the existence of gapless boundary states in dimensions higher than one. However, such a change may strongly affect the physical properties of those boundary states. Motivated by this observation, we perform a systematic study of the impact of sublattice terminations on the boundary physics on the two-dimensional kagome lattice. We find that the energies of the Dirac points of helical edge states in two-dimensional first-order topological kagome insulators sensitively depend on the terminating sublattices at the edge. Remarkably, this property admits the realization of a time-reversal invariant second-order topological superconducting phase with highly controllable Majorana Kramers pairs at the corners and sublattice domain walls by putting the topological kagome insulator in proximity to a $d$-wave superconductor. Moreover, substituting the $d$-wave superconductor with a conventional $s$-wave superconductor, we find that highly controllable Majorana zero modes can also be realized at the corners and sublattice domain walls if an in-plane Zeeman field is additionally applied. Our study reveals promising platforms to implement highly controllable Majorana zero modes.

Vortex-line topology in iron-based superconductors with and without second-order topology

The band topology of a superconductor is known to have profound impact on the existence of Majorana zero modes in vortices. As iron-based superconductors with band inversion and $s_{\pm}$-wave pairing can give rise to time-reversal invariant second-order topological superconductivity, manifested by the presence of helical Majorana hinge states in three dimensions, we are motivated to investigate the interplay between the second-order topology and the vortex lines in both weak- and strong-Zeeman-field regimes. In the weak-Zeeman-field regime, we find that vortex lines far away from the hinges are topologically nontrivial in the weakly doped regime, regardless of whether the second-order topology is present or not. However, when the superconductor falls into the second-order topological phase and a topological vortex line is moved close to the helical Majorana hinge states, we find that their hybridization will trivialize the vortex line and transfer robust Majorana zero modes to the hinges. Furthermore, when the Zeeman field is large enough, we find that the helical Majorana hinge states are changed into chiral Majorana hinge modes and thus a chiral second-order topological superconducting phase is realized. In this regime, the vortex lines are always topologically trivial, no matter how far away they are from the chiral Majorana hinge modes. By incorporating a realistic assumption of inhomogeneous superconductivity, our findings can explain the recent experimental observation of the peculiar coexistence and evolution of topologically nontrivial and trivial vortex lines in iron-based superconductors.

Floquet second order topological superconductor based on unconventional pairing

We theoretically investigate the Floquet generation of second-order topological superconducting (SOTSC) phase in the high-temperature platform both in two-dimension (2D) and three-dimension (3D). Starting from a $d$-wave superconducting pairing gap, we periodically kick the mass term to engineer the dynamical SOTSC phase within a specific range of the strength of the drive. Under such dynamical breaking of time-reversal symmetry (TRS), we show the emergence of the \textit{weak} SOTSC phase, harboring eight corner modes \ie two zero-energy Majorana per corner, with vanishing Floquet quadrupole moment. On the other hand, our study interestingly indicates that upon the introduction of an explicit TRS breaking Zeeman field, the \textit{weak} SOTSC phase can be transformed into \textit{strong} SOTSC phase, hosting one zero-energy Majorana mode per corner, with quantized quadrupole moment. We also compute the Floquet Wannier spectra that further establishes the \textit{weak} and \textit{strong} nature of these phases. We numerically verify our protocol computing the exact Floquet operator in open boundary condition and then analytically validate our findings with the low energy effective theory (in the high-frequency limit). The above protocol is applicable for 3D as well where we find one dimensional (1D) hinge mode in the SOTSC phase. We then show that these corner modes are robust against moderate disorder and the topological invariants continue to exhibit quantized nature until disorder becomes substantially strong. The existence of zero-energy Majorana modes in these higher-order phases is guaranteed by the anti-unitary spectral symmetry.

Floquet generation of a second-order topological superconductor

We theoretically investigate the Floquet generation of a second-order topological superconducting (SOTSC) phase hosting Majorana corner modes (MCMs), considering a quantum spin Hall insulator with a proximity-induced superconducting $s$-wave pairing in it. Our dynamical prescription consists of the periodic kick in time-reversal symmetry breaking the in-plane magnetic field and fourfold rotational symmetry breaking the mass term in the bulk while these Floquet MCMs are preserved by antiunitary particle-hole symmetry. The first driving protocol always leads to four zero-energy MCMs (i.e., one Majorana state per corner) as a sign of a strong SOTSC phase. Interestingly, the second protocol can result in a weak SOTSC phase, harboring eight zero-energy MCMs (two Majorana states per corner), in addition to the strong SOTSC phase. We characterize the topological nature of these phases by a Floquet quadrupolar moment and Floquet Wannier spectrum. We believe that relying on the recent experimental advancement in the driven systems and proximity - superconductivity, our schemes may be possible to test in the future.

Chiral Dirac superconductors: Second-order and boundary-obstructed topology

We analyze the topological properties of a chiral ${p}+i{p}$ superconductor for a two-dimensional metal/semimetal with four Dirac points. Such a system has been proposed to realize second-order topological superconductivity and host corner Majorana modes. We show that with an additional $\mathsf{C}_4$ rotational symmetry, the system is in an intrinsic higher-order topological superconductor phase, and with a lower and more natural $\mathsf{C}_2$ symmetry, is in a boundary-obstructed topological superconductor phase. The boundary topological obstruction is protected by a bulk Wannier gap. However, we show that the well-known nested-Wilson loop is in general unquantized despite the particle-hole symmetry, and thus fails as a topological invariant. Instead, we show that the higher-order topology and boundary-obstructed topology can be characterized using an alternative defect classification approach, in which the corners of a finite sample is treated as a defect of a space-filling Hamiltonian. We establish "Dirac+$({p}+i{p})$" as a sufficient condition for second-order topological superconductivity.

Kramers pairs of Majorana corner states in a topological insulator bilayer

We consider a system consisting of two tunnel-coupled two-dimensional topological insulators proximitized by a top and bottom superconductor with a phase difference of $\pi$ between them. We show that this system exhibits a time-reversal invariant second-order topological superconducting phase characterized by the presence of a Kramers pair of Majorana corner states at all four corners of a rectangular sample. We furthermore investigate the effect of a weak time-reversal symmetry breaking perturbation and show that an in-plane Zeeman field leads to an even richer phase diagram exhibiting two nonequivalent phases with two Majorana corner states per corner as well as an intermediate phase with only one Majorana corner state per corner. We derive our results analytically from continuum models describing our system. In addition, we also provide independent numerical confirmation of the resulting phases using discretized lattice representations of the models, which allows us to demonstrate the robustness of the topological phases and the Majorana corner states against parameter variations and potential disorder.

First- and Second-Order Topological Superconductivity and Temperature-Driven Topological Phase Transitions in the Extended Hubbard Model with Spin-Orbit Coupling.

The combination of spin-orbit coupling with interactions results in many exotic phases of matter. In this Letter, we investigate the superconducting pairing instability of the two-dimensional extended Hubbard model with both Rashba and Dresselhaus spin-orbit coupling within the mean-field level at both zero and finite temperature. We find that both first- and second-order time-reversal symmetry breaking topological gapped phases can be achieved under appropriate parameters and temperature regimes due to the presence of a favored even-parity s+id-wave pairing even in the absence of an external magnetic field or intrinsic magnetism. This results in two branches of chiral Majorana edge states on each edge or a single zero-energy Majorana corner state at each corner of the sample. Interestingly, we also find that not only does tuning the doping level lead to a direct topological phase transition between these two distinct topological gapped phases, but also using the temperature as a highly controllable and reversible tuning knob leads to different direct temperature-driven topological phase transitions between gapped and gapless topological superconducting phases. Our findings suggest new possibilities in interacting spin-orbit coupled systems by unifying both first- and higher-order topological superconductors in a simple but realistic microscopic model.

Second-order bulk-boundary correspondence in rotationally symmetric topological superconductors from stacked Dirac Hamiltonians

Two-dimensional second-order topological superconductors host zero-dimensional Majorana bound states at their boundaries. In this work, focusing on rotation-invariant crystalline topological superconductors, we establish a bulk-boundary correspondence linking the presence of such Majorana bound states to bulk topological invariants introduced by Benalcazar et al. We thus establish when a topological crystalline superconductor protected by rotational symmetry displays second-order topological superconductivity. Our approach is based on stacked Dirac Hamiltonians, using which we relate transitions between topological phases to the transformation properties between adjacent gapped boundaries. We find that in addition to the bulk rotational invariants, the presence of Majorana boundary bound states in a given geometry depends on the interplay between weak topological invariants and the location of the rotation center relative to the lattice. We provide numerical examples for our predictions and discuss possible extensions of our approach.

Majorana and parafermion corner states from two coupled sheets of bilayer graphene

We consider a setup consisting of two coupled sheets of bilayer graphene in the regime of strong spin-orbit interaction, where electrostatic confinement is used to create an array of effective quantum wires. We show that for suitable interwire couplings the system supports a topological insulator phase exhibiting Kramers partners of gapless helical edge states, while the additional presence of a small in-plane magnetic field and weak proximity-induced superconductivity leads to the emergence of zero-energy Majorana corner states at all four corners of a rectangular sample, indicating the transition to a second-order topological superconducting phase. The presence of strong electron-electron interactions is shown to promote the above phases to their exotic fractional counterparts. In particular, we find that the system supports a fractional topological insulator phase exhibiting fractionally charged gapless edge states and a fractional second-order topological superconducting phase exhibiting zero-energy $\mathbb{Z}_{2m}$ parafermion corner states, where $m$ is an odd integer determined by the position of the chemical potential.

Fractional topological superconductivity and parafermion corner states

We consider a system of weakly coupled Rashba nanowires in the strong spin-orbit interaction (SOI) regime. The nanowires are arranged into two tunnel-coupled layers proximitized by a top and bottom superconductor such that the superconducting phase difference between them is $\pi$. We show that in such a system strong electron-electron interactions can stabilize a helical topological superconducting phase hosting Kramers partners of $\mathbb{Z}_{2m}$ parafermion edge modes, where $m$ is an odd integer determined by the position of the chemical potential. Furthermore, upon turning on a weak in-plane magnetic field, the system is driven into a second-order topological superconducting phase hosting zero-energy $\mathbb{Z}_{2m}$ parafermion bound states localized at two opposite corners of a rectangular sample. As a special case, zero-energy Majorana corner states emerge in the non-interacting limit $m=1$, where the chemical potential is tuned to the SOI energy of the single nanowires.

Floquet second-order topological superconductor driven via ferromagnetic resonance

We consider a Floquet triple-layer setup composed of a two-dimensional electron gas with spin-orbit interactions, proximity coupled to an s-wave superconductor and to a ferromagnet driven at resonance. The ferromagnetic layer generates a time-oscillating Zeeman field which competes with the induced superconducting gap and leads to a topological phase transition. The resulting Floquet states support a second-order topological superconducting phase with a pair of localized zero-energy Floquet Majorana corner states. Moreover, the phase diagram comprises a Floquet helical topological superconductor, hosting a Kramers pair of Majorana edge modes protected by an effective time-reversal symmetry, as well as a gapless Floquet Weyl phase. The topological phases are stable against disorder and parameter variations and are within experimental reach.

Second-Order Topological Superconductors with Mixed Pairing.

We show that a two-dimensional semiconductor with Rashba spin-orbit coupling could be driven into the second-order topological superconducting phase when a mixed-pairing state is introduced. The superconducting order we consider involves only even-parity components and meanwhile breaks time-reversal symmetry. As a result, each corner of a square-shaped Rashba semiconductor would host one single Majorana zero mode in the second-order nontrivial phase. Starting from edge physics, we are able to determine the phase boundaries accurately. A simple criterion for the second-order phase is further established, which concerns the relative position between Fermi surfaces and nodal points of the superconducting order parameter. In the end, we propose two setups that may bring this mixed-pairing state into the Rashba semiconductor, followed by a brief discussion on the experimental feasibility of the two platforms.

Second-Order Topological Superconductivity in π-Junction Rashba Layers.

We consider a Josephson junction bilayer consisting of two tunnel-coupled two-dimensional electron gas layers with Rashba spin-orbit interaction, proximitized by a top and bottom s-wave superconductor with phase difference ϕ close to π. We show that, in the presence of a finite weak in-plane Zeeman field, the bilayer can be driven into a second order topological superconducting phase, hosting two Majorana corner states (MCSs). If ϕ=π, in a rectangular geometry, these zero-energy bound states are located at two opposite corners determined by the direction of the Zeeman field. If the phase difference ϕ deviates from π by a critical value, one of the two MCSs gets relocated to an adjacent corner. As the phase difference ϕ increases further, the system becomes trivially gapped. The obtained MCSs are robust against static and magnetic disorder. We propose two setups that could realize such a model: one is based on controlling ϕ by magnetic flux, the other involves an additional layer of randomly oriented magnetic impurities responsible for the phase shift of π in the proximity-induced superconducting pairing.

Higher-order topological superconductivity: Possible realization in Fermi gases and Sr2RuO4

We propose to realize second-order topological superconductivity in bilayer spin-polarized Fermi gas superfluids. We focus on systems with intralayer chiral $p$-wave pairing and with tunable interlayer hopping and interlayer interactions. Under appropriate circumstances, an interlayer even-parity $s$- or $d$-wave pairing may coexist with the intralayer $p$-wave. Our model supports localized Majorana zero modes not only at the corners of the system geometry, but also at the terminations of certain one-dimensional defects, such as lattice line defects and superfluid domain walls. We show how such topological phases and the Majorana zero modes therein can be manipulated in a multitude of ways by tuning the interlayer pairing and hopping. Generalized to spinful systems, we further propose that the putative $p$-wave superconductor Sr$_{2}$RuO$_{4}$, when subject to uniaxial strains, may also realize the desired topological phase.

Weak-pairing higher order topological superconductors

Conventional topological superconductors are fully gapped in the bulk but host gapless Majorana modes on their boundaries. We instead focus on a new class of superconductors, second-order topological superconductors, that have gapped, topological surfaces and gapless Majorana modes instead on lower-dimensional boundaries, i.e., corners of a two-dimensional system or hinges for a three-dimensional system. Here we propose two general scenarios in which second-order topological superconductivity can be realized spontaneously with weak-pairing instabilities. First, we show that $p_x+ip_y$-wave pairing in a (doped) Dirac semimetal in two dimensions with four mirror symmetric Dirac nodes realizes second-order topological superconductivity. Second, we show that $p+id$ pairing on an ordinary spin-degenerate Fermi sruface realizes second-order topological superconductivity as well. In the latter case we find that the topological invariants describing the system can be written using simple formulae involving only the low-energy properties of the Fermi surfaces and superconducting pairing. In both cases we show that these exotic superconducting states can be intrinsically realized in a metallic system with electronic interactions. For the latter case we also show it can be induced by proximity effect in a heterostructure of cuprate and topological superconductors.

Topological crystalline superconductivity and second-order topological superconductivity in nodal-loop materials

We study the intrinsic fully-gapped odd-parity superconducting order in doped nodal-loop materials with a torus-shaped Fermi surface. We show that the mirror symmetry, which protects the nodal loop in the normal state, also protects the superconducting state as a topological crystalline superconductor. As a result, the surfaces preserving the mirror symmetry host gapless Majorana cones. Moreover, for a Weyl loop system (two-fold degenerate at the nodal loop), the surfaces that break the mirror symmetry (those parallel to the bulk nodal loop) contribute a Chern (winding) number to the quasi-two-dimensional system in a slab geometry, which leads to a quantized thermal Hall effect and a single Majorana zero mode bound at a vortex line penetrating the system. This Chern number can be viewed as a higher-order topological invariant, which supports hinge modes in a cubic sample when mirror symmetry is broken. For a Dirac loop system (four-fold degenerate at the nodal loop), the fully gapped odd-parity state can be either time-reversal symmetry-breaking or symmetric, similar to the $A$- and $B$- phases of $^3$He. In a slab geometry, the $A$-phase has a Chern number two, while the $B$-phase carries a nontrivial $\mathbb{Z}_2$ invariant. We discuss the experimental relevance of our results to nodal-loop materials such as CaAgAs.