Remote sensing techniques (e.g., terrestrial laser scanning and digital photogrammetry) have been developed and applied rapidly in recent years for identification and analysis of rock mass characteristics. A direct validation of these digital measurements against well-constrained datasets obtained from conventional survey methods is reported here. A high-resolution digital outcrop model (DOM) generation method for rock exposures based on unmanned aerial vehicle (UAV) photogrammetry integrated with a structure from-motion (SfM) technique was introduced. A digital procedure based on mathematical algorithms for discontinuity detection, trace mapping and quantitative discontinuity characterization was established. The proposed method was applied to two rock slopes (from Greece and China) and fundamental discontinuity parameters, i.e., the orientation, number of sets, trace length, set spacing, linear frequency, areal frequency and areal intensity were statistically extracted and calculated. Their values were compared with carefully planned manual measurements, i.e., individual discontinuity measurements, scanline method, and window sampling method on the same sites. The results of two sites showed that most deviations are less than 5° for dip direction and dip angle, 0.13 m for exposed discontinuity length, 0.37 m for set spacing, 0.09 m-1 for linear frequency, 0.06 m-2 for areal frequency, and 0.15 m-1 for areal intensity. These deviations are reasonable and acceptable, which confirmed the reliability and accuracy of the developed method. With improved efficiency and workability comparing to conventional methods especially in difficult surveying environments, the UAV-SfM Photogrammetry can potentially become a routine method for on-site rock mass characterization.