Saturation Limit Research Articles

Impacting Atmospheres: How Late-stage Pollution Alters Exoplanet Composition

The atmospheric composition of exoplanets is often considered as a probe of the planet’s formation conditions. How exactly the initial chemical memory may be altered from the birth to the final state of the planet, however, remains unknown. Here, we develop a simple model of pollution of planetary atmosphere by the vaporization of infalling planetesimals of varying sizes and composition (SiO2 inside 1 au and H2O outside 1 au), following their trajectory and thermal evolution through the upper advective and radiative layers of a sub-Neptune-class planet during the late stage of disk evolution. We vary the rate of pollution by changing the solid content of the disk and by dialing the level of disk gas depletion, which in turn determines the rate of planetary migration. We find that pollution by silicate grains will always be limited by the saturation limit set by the thermal state of the atmosphere. By contrast, pollution by water ice can lead to ∼2–4 orders of magnitude variation in the atmospheric water mass fraction depending on the solid and gas content of the disk. Both cases suggest that post-formation pollution can erase the initial compositional memory of formation. Post-formation pollution can potentially transform sub-Neptunes with H/He-dominated envelopes that initially formed beyond the ice line to water worlds (i.e., with a water-enriched envelope) when the disk gas is depleted by ≳2 orders of magnitude, allowing gentle migration. We additionally discuss the expected C/O ratio profile under pollution by water and refractory carbon species.

Mechanisms of Increasing Weld Depth during Temporal Power Modulation in High‐Power Laser Beam Welding

Understanding the fundamental mechanisms of action for increasing weld depth during temporal power modulation in laser beam welding could allow dissimilar rotational welding without the introduction of concomitant turbulence, but with enhanced intermixing. The investigations are conducted on 30 mm‐diameter round bars of stainless steel alloy 1.4301 and nickel base alloy 2.4856 utilizing a 16 kW disk laser beam source. Modulation frequencies are 0/50/100/200 Hz at low, medium, and high amplitudes of laser beam power. The influence on the process and weld characteristics is investigated through high‐speed imaging with grayscale analysis, keyhole depth measurements, metallographic sections, and energy‐dispersive X‐ray spectroscopy analysis. The objectives are successfully achieved, and the underlying mechanism is maintaining the keyhole depth at a higher level for modulation frequencies of 200 Hz and a high amplitude of laser beam power, which is related to the keyhole inertia. Based on this, a novel welding mode with a constant keyhole depth is proposed. Furthermore, up to 20% increase in weld depth is achieved, a saturation limit for the modulation frequency is identified, intermixing within the weld is enhanced, and a model for predicting the weld depth based solely on measurements of the surface width is developed.

Static actuator-sharing algorithm for concurrent control of multiple plasma properties

Abstract Simultaneous regulation of multiple properties in next-generation tokamaks like ITER and Fusion Pilot Plant (FPP) may require the integration of different plasma control algorithms. Such integration requires the conversion of individual controller commands into physical actuator requests while accounting for the coupling between different plasma properties. This work proposes a tokamak and scenario-agnostic actuator-sharing algorithm (ASA) to perform the above-mentioned command-request conversion and, hence, integrate multiple plasma controllers. The proposed algorithm implicitly solves a quadratic programming (QP) problem formulated to account for the saturation limits and the relation between the controller commands and physical actuator requests. Since the constraints arising in the QP program are linear, the proposed ASA is highly computationally efficient and can be implemented in the tokamak plasma control system (PCS) in real time. Furthermore, the proposed algorithm is designed to handle real-time changes in the control objectives and actuators’ availability. Nonlinear simulations carried out using the Control Oriented Transport SIMulator (COTSIM) illustrate the effectiveness of the proposed algorithm in achieving multiple control objectives simultaneously.

Incipient fault detection for the spindle bearing of a cement grinding machine based on vibrational resonance

Abstract The spindle bearing of a circulation fan is an important component of a cement grinding machine. In addition to the faults on the spindle bearing, impeller wear and ash accumulation may cause dynamic unbalance and complex vibration interference as noise, which decreases the accuracy of fault detection based on vibrational signals and traditional signal processing-based methods at the early stage of a bearing fault. To address this issue, this paper presents a new fault detection method for the spindle bearing by utilizing extra injected noise and vibrational resonance. To enhance the fault signature and resonance performance, the nonlinear system of the traditional vibrational resonance is replaced by a new hybrid steady-state system, and the underdamped term is considered in the new system. The proposed system provides more possibilities to achieve resonance by adjusting the system parameters and overcomes the limitations of output saturation caused by the classical bistable system. The proposed method is validated by analyzing the collected vibration signals from a spindle bearing of a circulation fan in practice and is compared with other noise-elimination fault detection methods. The results demonstrate the effectiveness and superior performance of the proposed method.

Influence of BN microstructure on oxidation of SiC/BN/SiC composites

AbstractThis study investigates the effects of boron nitride (BN) coating characteristics on the subsurface oxidation behavior of SiC/SiC composites in high‐temperature, water‐rich environments. Three types of coatings were examined: a crystalline stoichiometric BN, an amorphous BN, and a Si‐doped amorphous BN, the latter two containing 5–10 at% of oxygen and carbon. High‐resolution imaging and chemical analysis techniques were used to probe microstructural changes after oxidation at 1000°C for 1 or 12 h in flowing 20 vol% H2O, focusing on effects of coating thickness. Complementary chemical thermodynamic calculations and models for reaction‐ and transport‐controlled recession were used to interpret the experimental findings. Crystalline BN coatings produce open recession channels without forming borosilicate glass, a consequence of carbothermal reduction arising from C/CO produced through concomitant SiC oxidation. The combination of active oxidation and the relatively thick coatings in this system (ca. 1 µm) leads to a recession rate controlled by the intrinsic BN volatilization rate rather than the rate of gas transport. In contrast, amorphous coatings, both undoped and Si‐doped, readily oxidize to form borosilicate glasses that replace the BN. Broadly, the recession lengths increase with coating thickness. In the early stages, while the glass is boria‐rich and thus permeable to environmental oxidants, recession is controlled by the BN oxidation rate. As boria volatilizes, the silica concentration in the glass increases, eventually reaching the saturation limit and precipitating solid silica on the internal surfaces, essentially arresting further recession.

Probing the magnetic fields of starspots with transit mapping

Starspots, regions of strong magnetic fields, serve as indicators of stellar activity and the dynamo mechanism at play in the interior of stars. The magnetic fields of main-sequence stars play a crucial role in driving stellar activity. An effective approach to better understanding stellar magnetic fields and activity lies in the detailed characterisation of starspot properties. We propose a new method for estimating the magnetic fields of starspots that employs modelling techniques of planetary transit mapping, which provides estimates of the size, intensity, and location of spots on the stellar photosphere. A starspot's maximum magnetic field was calculated using the linear relationship with the spot flux deficit, $ spot $ (the spot's brightness times its area) and the well-characterised relation for sunspots determined in this work, $B_ spot (G). Applying this relationship to previously mapped spots on the photospheres of 14 FGK and M stars yields spot maximum magnetic fields ranging from 2700 G to 4600 G, with an overall average of $3900 400$ G. We looked for correlations between starspot magnetic fields and stellar properties.\ We did not find any correlation between a spot's mean extreme magnetic field and effective temperature, nor the differential shear. However, a weak anti-correlation is seen between the spots' magnetic field and stellar age as well as between the magnetic field and the rotation period. When compared with previous results of small-scale magnetic field measurements, the B values obtained here are basically constant and near the saturation limit found for rapid rotators. This implies that it is not the intensity of the magnetic field of starspots that decreases with age but rather the filling factor. This result offers a unique window into the magnetic dynamo of stars.

Preparation and characterization of fumed silica added PMMA denture base materials

This study was carried out to investigate the chemical, mechanical, and structural properties of increasing amounts of fumed silica added to PMMA denture base material. The effect of adding fumed silica at three different concentrations (0.5%, 1%, and 2% by weight) to PMMA was studied using Fourier transform infrared spectroscopy (FTIR), dynamic mechanical analysis (DMA), density, flexural strength, hardness, atomic force microscopy (AFM), and scanning electron microscopy (SEM). The results showed that the highest flexural strength values (105.64 MPa) and hardness (20.07 microvickers) were obtained with 1% wt. of fumed silica material. According to DMA results, fumed silica samples containing 1% wt. had the highest energy storage (3.24 GPa at 30 °C) and glass transition temperature. As a result, fumed silica in PMMA denture base material reached its maximum saturation limit at 1% wt. A more brittle behavior was observed in samples containing 2% fumed silica, which accumulated on the surface, as confirmed by AFM. The molecular bonds at the resin-fumed silica interface weaken due to the agglomeration of fumed silica. Consequently, the flexural strength and hardness decrease, along with the glass transition temperature and storage modulus. The potential applications of this research are vast, inspiring further exploration and innovation in denture-based materials.

Solubility-controlled early age hydration of carbonate-activated slag: Underlying mechanisms and acceleration via seeding

The low environmental impacts and good performance of carbonate-activated binders have attracted substantial interest, while their intrinsically delayed reaction and prolonged setting times constrain widespread implementation. This study aims to investigate the early-age reaction kinetics of carbonate-activated binders, elucidate the underlying mechanisms and propose controlling methods. Results reveal that hydrotalcite and C-A-S-H gel precursors rapidly reach supersaturation within hours, yet precipitation of these phases remains absent. This phenomenon, coupled with high Si/Ca ratios in the pore solution, exhibits characteristics that may contribute to the observed reaction delays. A prolonged induction period and lethargic strength development are observed owing to the lack of strength-giving phases. The hydrotalcite and C-A-S-H concentrations surpass their theoretical solubility thresholds due to rising ionic strength and salt-in effects. The addition of a pH-neutral layered double hydroxide salt accelerates the reaction, confirming seeding impacts control pore solution saturation limits, constituting the underlying accelerator mechanism.

An Exceptionally Salt Tolerant Copoly(Maleimide Sulfobetaine) - Structural Requirements for Ultra-Salt Tolerance.

Zwitterionic polymers are an important class of polymers with far-ranging applications. In the widely studied poly(meth)acrylate and poly(meth) acrylamide-based zwitterions, properties can be tuned by changing the nature of substituents attached to ammonium ions. However, these changes influenced salt tolerance of zwitterionic polymers only to a limited extent. Upon adding salt these polymers expanded in solution initially. Further increase in salt concentration caused the polymer chains to shrink similar to the common water soluble, uncharged polymers thereby deteriorating the viscosity of aqueous solutions. In contrast to the conventional poly(meth)acrylate and poly(meth)acrylamide-based zwitterions, zwitterionic copolymaleimides showed substituent dependent salt-tolerant nature. In the absence of any substituent on the polymer backbone such as zwitterionic poly(ethylene-alt-maleimide) (ZI-PEMA) the viscosity of salt solutions increased both with the increasing salt concentration as well as the concentration of polymer. This is likely due to the continuous expansion of polymer coil in salt solutions with increasing salt concentration caused primarily by the rigidity of the polymer backbone. ZI-PEMA also enhanced the saturation limit of mono- and divalent salts like sodium chloride and hydrated calcium bromide in water. This property is useful for various applications like fish curing, for making high-density fluids, refrigeration, etc. across various industrial sectors.

Static Compaction for Sustainable Geotechnical Solutions: A Comprehensive Study

The objective of this research is to develop an improved uniaxial static compaction method to address the limitations of the traditional Proctor's dynamic approach for soil compaction. This new approach offers reduced labor, enhanced soil density, and increased compactness. The study compares of static soil compaction characteristics with various soil parameters and explores the concept of Equivalent Static Compaction Energy (ESCE). A diverse range of fine-grained soils with varying range of plasticity was investigated, and a significant correlation of compaction parameters attained by static compaction was observed with the corresponding value of static compaction energy, degree of saturation, void ratio, and plastic limit of soil. The research resulted in the creation of constant-energy curves for static compaction, which were compared to dynamic compaction curves from four compaction attempts. From the study, the ESCE corresponding to standard Proctor, reduced standard Proctor, and reduced modified Proctor tests were found to be within the range of 180-340, 155-308, and 532-664 KJ/ m3, respectively. It was also observed for the static compaction method that after reaching the maximum level of compaction, the dry unit weight of the soil specimen remains constant with further increases in compaction energy.

Prescribed Performance Formation Tracking Control for Underactuated AUVs under Time-Varying Communication Delays

Achieving formation tracking control of underactuated autonomous underwater vehicles (AUVs) under communication delays presents a significant challenge. To address this challenge, a distributed prescribed performance control protocol based on a real-time state information online predictor (RSIOP) is proposed in this paper. First, we innovatively designed an RSIOP to achieve active compensation for the delayed state information of neighboring AUVs. Next, considering formation performance and safety, a low-complexity and practical nonlinear mapping function was used to implement prescribed performance tracking control for the AUV formation. Additionally, the adverse effects of external disturbance uncertainties and input saturation are also considered. Finally, the simulation tests demonstrated that the proposed formation control protocol can successfully achieve the predetermined formation tracking tasks in the presence of time-varying communication delays and external disturbances, while also enabling real-time changes in formation configuration during the process. Throughout, the protocol maintains input saturation limits, and the actual control inputs remain smooth, with no significant oscillations. Furthermore, comparative simulation tests verified the necessity of the RSIOP developed in this study and quantitatively demonstrated that the proposed control method exhibits superior performance in terms of formation control accuracy, error convergence speed, and transient-state constraints.

Needs assessment of military medicine education curriculum in medical students and upcoming challenges

ABSTRACT Introduction: The curriculum of military medicine for medical students of universities of military medical sciences is a priority and a practical goal. Paying attention to the educational needs of students creates vitality and motivation among students for better learning and improving the learning environment. Frequent monitoring and updating of the content of military courses and modern teaching improve the quality and quantity of the military medicine curriculum. Materials and Methods: This applied, inductive, and exploratory descriptive was conducted in a single cross-sectional and qualitative method. The data were collected using the brainstorming method and individual and collective Delphi techniques. The population included the medical students of Baqiyatallah University of Medical Sciences in Tehran, Iran, who completed the course in military medicine. The data were collected by purposive sampling and classified until the saturation limit was reached. EXCEL 2019 and MAXQDA2020 software were used for data analysis. Findings: This research was carried out in collaboration with the military medicine department of the university to identify the needs of students in the military medicine curriculum. First, the findings were collected in 22 axes. In the next step, the needs were prioritized in the four main components of the combat medicine curriculum (1 goal, 2 content, 3 teaching strategy, 4 evaluation), and the results were extracted. Conclusion: Identifying the needs of students; improving the current military medicine curriculum; paying attention to individual differences, interests, and talents of students; and enhancing the motivation and level of satisfaction of students are the study results.

Physicochemical characterization of the metamorphosis of film-forming formulations of betamethasone-17-valerate

Following topical application of a dermatological product, the loss (by evaporation and/or absorption through the skin) of volatile excipients will alter the composition of the formulation remaining on the tissue. This so-called metamorphosis impacts the concentration of the drug in the residual vehicle, (potentially) its physical form therein and, as a result, its uptake into and subsequent permeation through the skin. This research aimed to characterise – using primarily confocal Raman microspectroscopy – the metamorphosis of film-forming formulations of betamethasone-17-valerate (at different loadings) comprised of hydroxypropyl cellulose (film-forming agent), triethyl citrate (plasticizer) and ethanol (solvent). Dissolved and crystalline drug in the films were identified separately by their different characteristic Raman frequencies (1666 cm−1 and 1659 cm−1, respectively). These Raman measurements, as well as optical imaging, confirmed corticosteroid crystallisation in the residual films left after ethanol evaporation when drug concentration exceeded the saturation limit. In vitro release tests of either sprayed or pipette-deposited films into either aqueous or ethanolic receptor solutions revealed drug release kinetics dominated by the residual film post-metamorphosis. In particular, the rate and extent of drug release depends on the concentration of dissolved drug in the residual film, which is limited by drug saturation unless supersaturation occurs. For the simple films examined here, supersaturation was not detected and the solubility limit of drug in the films was sufficient to sustain drug release at a constant flux from the saturated films through a thin silicone elastomer membrane into an aqueous receptor solution for 30 h. Flux values were ∼ 1 μg cm–2h−1 from saturated residual films independent of the amount of crystallized drug present. Flux from subsaturated films was reduced by an amount that was consistent with the lower degree of saturation.

Indicating Saturation Limits of Multi-sensor Satellite Data in Estimating Aboveground Biomass of a Mangrove Forest

Indicating Saturation Limits of Multi-sensor Satellite Data in Estimating Aboveground Biomass of a Mangrove Forest

OSL and radiocarbon dating of core TBF-1 on the outer shelf of the East China Sea and implications for late Quaternary stratigraphic correlation

It is crucial to establish a robust chronology for understanding late Quaternary sedimentation processes and environment changes in response to sea-level fluctuation on shelves. The shelf of the East China Sea (ECS) is featured by huge terrigenous sediment input and striking land -sea interaction during the late Quaternary. However, there remains controversy in chronostratigraphic rebuilding of transgression and regression deposits during eustatic-glacial cycles, mainly due to a lack of reliable dating data. In this study, an extensive comparison of 17 optically stimulated luminescence (OSL) and 15 AMS 14C ages from core TBF-1 (upper 40 m) provides a constraint in chronostratigraphic reconstruction since Marine Isotope Stage (MIS) 5. OSL ages range from 9.5 ± 0.7 to 67.3 ± 4.8 ka at depths from 2.00 to 28.00 m, while 14C ages range from 6645 to 41435 cal a BP at depths from 0.02 to 17.52 m. Regression analysis demonstrates a high level of agreement between OSL and 14C ages, with r2 values of 0.91 and 0.90, respectively. For Holocene sediments (U1), both OSL and 14C methods are applicable in tidal sand ridges, however, it should be noted that 14C ages may exhibit a young bias of up to 3 ka. For pre-Holocene sediments (U6-U2), OSL ages are robust within saturation limitation of OSL signal (De up to ca. 166 Gy), cross-checked by feldspar post-IR IRSL (pIRIR) dating protocol. Nevertheless, the shell 14C ages (11620 and 10390 cal a BP at depths of 13.95–14.56 m) in Last Glacial Maximum (LGM) fluvial sediments of U2 are significantly underestimated, because of their susceptibility to recrystallization and overgrowth, resulting in carbon exchange with environment. While the peaty layer's14C age in deltaic deposition (17.50 m, U5) was determined to be 36420 cal a BP, coincided with OSL age of 39.6 ± 3.9 ka. The chronostratigraphy since MIS 5 for core TBF-1 exhibits a significant correlation with previously published cores SFK-1, DZQ4, and DH02, on the ECS outer shelf. Through the evaluation of those underestimated 14C ages and saturated OSL ages, we re-elucidated the primary sedimentary facies and their respective formation periods. This sedimentary stratigraphic illustration exhibits significant consistency with eustatic-glacial cycles. The renewed chronological framework for ECS shelf allows better correlation between the late Quaternary sedimentary evolution and the land-sea interaction on open shelves dominated by siliciclastic sedimentation.

Spatial and temporal thermal management of a spintronic terahertz emitter

This work presents methods for addressing undesirable thermal effects induced by the pump beam of an oscillator laser to improve the efficiency of a terahertz (THz) spintronic emitter. We explore two approaches: spatial distribution of pump energy using a 2D lens array and temporal modulation of the pump duty cycle. Optimizing the spatial distribution approximately doubles the THz signal by increasing local heat dissipation, delaying the saturation limit. Similarly, temporal spreading of pump pulses by adjusting the duty cycle allows greater thermal relaxation within the heterostructure, enhancing the overall efficiency of THz wave generation.

Numerical algorithm for nonlinearity compensation of hardly constrained actuation for trajectory tracking control of deadzone-included dynamic systems

This paper addresses the control of a nonlinear system affected by deadzone effects, using a constrained actuator. The system itself incorporates a second-order oscillatory dynamic actuator, with an unknown nonlinear input-output relationship. The proposed algorithm not only accommodates the deadzone constraints on control inputs but also considers the actuator's saturation limits in control input calculations. It introduces a trajectory tracking mechanism that, instead of directly following the primary trajectory, adheres to an alternative trajectory capable of stable tracking, gradually converging to the main trajectory while accounting for operational constraints. In practical control systems, the actuator's input-output relationship is often nonlinear and unknown, requiring inversion for model-based control. This paper employs an offline-trained neural network trained on synthetic data to identify and approximate the actuator's behavior. To optimize the control system's performance and ensure stability during sudden error changes, the control input operates in two modes: position and velocity control. This dual-mode control allows for continuous switching between the two, facilitated by an innovative optimization technique based on the gradient descent method with a variable step size. Simulation results validate the effectiveness of the proposed algorithm in controlling systems constrained by hard limits and featuring nonlinear oscillatory actuators, providing a valuable contribution to the field of control systems.

Full‐Color Electroluminescence from ZnO Nanoparticles‐Based Homojunction Diodes

Wide‐bandgap zinc oxide (ZnO)‐based light‐emitting diodes (LEDs) have attracted considerable interest for application in solid‐state lighting; however, the absence of dependable high‐quality homojunction has impeded their progress. A p–n homojunction LED is fabricated in this study using arc discharge‐fabricated N‐doped ZnO nanoparticles (NPs) spin coated over a Ga‐doped ZnO thin film. The homojunction LEDs demonstrate pure ultraviolet (UV) emissions with a narrow linewidth even at elevated temperatures. The UV intensity initially increases as the injection current increases to the saturation limit with a change in the peak position, followed by a decrease at higher injection currents. A proportion of UV light is downconverted into visible light using phosphors. Furthermore, the mixing of phosphors and their application to UV‐LED results in white emission with high color rendering and superior optical stability. Notably, the visible spectral peaks do not discernibly change with variations in the operating current. These findings represent significant advancements in the development of stable p‐type ZnO nanostructures, leading to the development of cost‐effective photonic devices.

New Distributed Consensus Schemes With Time Delays and Output Saturation

Estimates of agents in a distributed consensus control are aligned with a particular value through interacting on communication graphs, which are of particular interest for researchers in the field of multi-agent coordination. Following this pattern, a discrete-time constrained consensus issue with generalized time delays is first established in this article, which is manipulated into an optimization problem via a quadratic performance index introduced as a global objective function. Then, a novel consensus scheme is investigated and proposed for handling this problem, enabling the consensus to approach the desired state globally and rapidly with optimal system property ensured. Besides, to advance the convergence speed and stability in resisting constant bias or oscillation, an adjustment control method is explored to construct a modified consensus scheme; further, to enhance the scene adaptability, fix topologies are extended to switching ones, and the latter is involved to develop another scheme on this basis. Moreover, the convergence and robustness of these three proposed consensus schemes are substantiated by theoretical analysis and numerical simulations. To highlight the practical implementations, the proposed consensus schemes are incorporated with a winner-take-all operation to accomplish multi-agent competitive coordination in a distributed way, and the results embody their effectiveness and superior consensus control ability, along with strong plasticity. <italic xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">Note to Practitioners</i> —This paper is dedicated to investigating and optimizing distributed consensus schemes with time delays and output saturation with application to the competitive coordination of multi-agent systems. On the one hand, the consensus problem with output saturation receives limited attention, and few consensus algorithms consider both saturation limitation and channel gain. On the other hand, most existing studies on consensus with saturation consider simply the dynamic behaviour of agents without employing optimization, thus limiting further improvement of system performance. In this paper, a consensus algorithm is built from an optimization perspective that guarantees the state consensus of a multi-agent system with output constraints and generalized time delays. In addition, a consensus scheme is designed in a discrete-time framework and further modified and perfected along with the idea of considering time delays and expanding diverse topologies. Finally, experiments are conducted by applying the consensus scheme to a winner-take-all operation, with contributions of this paper verified.

Features of the formation of cohesive and adhesive strengths by non-structured and structured polyvinyl acetate films during wood gluing

The formation of a higher number of hydrogen bonds in the structured polyvinyl acetate film compared to the unstructured one was established by means of infrared spectroscopy method. It was concluded that the structured polyvinyl acetate film has a higher cohesive strength than unstructured. It was revealed that the films subjected to moisture loads (with the amount of sorbed moisture lower than the swelling limit of the adhesive film) would show greater cohesive strength compared to the films which were not subjected to moisture loads due to the formation of a higher number of hydrogen bonds. Based on the obtained results, it was predicted that the system "structured film after moisture loads/wood substrate" would exhibit the highest adhesive strength, explained by an increase in the number of hydrogen bonds between the film components and the wood cellulose. It was theoretically predicted that in order to provide high cohesive and adhesive strengths of polyvinyl acetate adhesive joints of wood ensuring, moisture saturation should be lower than the saturation limit of the wood fiber and the adhesive film simultaneously.