Salt Spray Chamber Research Articles

ЗАЩИТНЫЕ СВОЙСТВА МОДИФИЦИРОВАННЫХ БИТУМНЫХ ПРАЙМЕРОВ ДЛЯ ПРОТИВОКОРРОЗИОННОЙ ЗАЩИТЫ СЕЛЬСКОХОЗЯЙСТВЕННОЙ ТЕХНИКИ И ОБОРУДОВАНИЯ

In order to protect agricultural machinery from atmospheric corrosion during the nonworking period, it is possible to use bitumen primers (BP), which are compositions of petroleum bitumen with the addition of solvents and, possibly, other additives. The protective properties of compositions based on the bitumen primer "Orgkrovlya No. 1" diluted with white spirit with modifying additives on samples of 08kp steel were studied in the work. Accelerated corrosion tests in 0.5 M NaCl solution showed the following: dilution of BP with 40 wt. % white spirit when applied in one layer leads to a decrease in the protective efficiency to 75%, 67 wt. % - to 37%; the introduction of additives (5 wt.%) of P2 paraffin into the diluted BP with 40 wt. % white spirit increases its protective efficiency (Z) to 98%, KO-SZhK - up to 87%, Emulgin - up to 94%; When diluting BP with 67 wt.% white spirit, the maximum Z = 60% is provided by the addition of 1 wt.% drying oil +1 wt.% POOM. Accelerated tests in the G-4 heat and humidity chamber and the salt spray chamber showed the best results for BP coatings diluted with 40 wt.% white spirit and with the addition of 5 wt.% P2 paraffin. The highest values of protective efficiency in the G-4 heat and humidity chamber for BP diluted with 67 wt.% white spirit are provided by coatings with 2 wt.% drying oil (Z = 97%), 5 wt.% POOM (Z = 97%), 1 wt.% drying oil +1 wt.% POOM (Z = 96%). According to the 9-month results of full-scale bench tests of modified BP diluted with 40 wt.% white spirit, the best results are provided by the coating with the addition of 5 wt. % paraffin P2 and Emulgin. These 2 additives effectively protect steel in a concentrated solution (200 g/l) of mineral fertilizer borofoska.

Micronized Shell-Bioaggregates as Mechanical Reinforcement in Organic Coatings.

Shells are primarily composed of calcite and aragonite, making the inclusion of micronized shells as bio-based fillers in organic coatings a potential means to enhance the mechanical properties of the layers. A water-based coating was reinforced with 5 wt.% Acanthocardia tuberculata powder, 5 wt.% Mytilus galloprovincialis powder, and 5 wt.% of an LDPE/ceramic/nanoceramic composite. An improvement in abrasion resistance was achieved using micronized seashells, as demonstrated by the Taber test (evaluating both weight loss and thickness reduction). Additionally, Buchholz hardness improved with powders derived from Mytilus galloprovincialis. No significant differences were observed among the samples in terms of color and gloss after 200 h of UV-B exposure. However, the delamination length from the scratch after 168 h of exposure in a salt spray chamber indicated that the addition of particles to the polymeric matrix resulted in premature degradation, likely due to the formation of preferential paths for water penetration from the scratch. This hypothesis was supported by electrochemical impedance spectroscopy measurements, which revealed a decrease in total impedance at 0.01 Hz shortly after immersion in a 3.5% NaCl solution. In conclusion, the particle size and shape of the micronized shells improved abrasion resistance without altering color and gloss but led to a decrease in the coating's isolation properties.

Effect of Copper and Nickel Content on the Corrosion Mechanisms in Ferritic Matrix Gray Cast Irons under Simulated Marine Environments

This article investigated the influence of copper (Cu) and nickel (Ni) on atmospheric corrosion in gray cast iron under simulated marine conditions. The goal was to compare the effect of Cu and Ni addition in castings with weathering steels. Selected alloys were cast, cut, prepared, and heat-treated for microstructure homogenization. Accelerated corrosion tests were conducted using a salt spray chamber. Corroded samples were analyzed for corrosion thickness and deposits using scanning electron microscopy, X-ray diffraction, and electrochemical techniques. The results indicate that alloying elements significantly affect corrosion processes. In the long-term, Cu had a greater impact on the corrosion mechanisms than Ni. Both Cu and Ni exhibited similar effects on the corrosion mechanisms in gray cast iron and weathering steels. In the initial and final stages, the behavior was comparable to that of weathering steels, but in the intermediate stage, it differed from the literature, suggesting the presence of an additional mechanism between these stages.

Facile design of PTFE-kaolin-based ternary nanocomposite as a hydrophobic and high corrosion-barrier coating

Abstract Superhydrophobic nanostructured coatings are a promising technology in construction engineering. This study developed a hydrophobic film through a simple mixing method, utilizing kaolin and polytetrafluoroethylene as additive particles, 1H,1H,2H,2H-perfluoro-decyl triethoxysilane as a modifier, and epoxide resin and polyamide curing agent as adhesives. By controlling variables, it was determined that the C1P0.2EP coating immersed in a 3.5 wt% NaCl solution for 1, 3, and 7 days exhibited the maximum impedance radii of 47,373, 20,334, and 1,982 Ω·cm2, respectively. It also demonstrated the highest Bode modulus values, the largest E corr, and the smallest I corr. Furthermore, after 300 h in a salt spray chamber with a 3.5 wt% NaCl solution, the C1P0.2EP coating showed no rust spots or bubbles, demonstrating its excellent corrosion resistance. Moreover, wear resistance tests and self-cleaning experiments were conducted on the C1P0.2EP coating. The results showed that after 100 friction cycles, the surface exhibited no visible scratches, and the contact angle of the coating decreased by only 4°. Additionally, neither soil particles nor dirty water adhered to the coating, indicating that the C1P0.2EP hydrophobic coating possesses not only excellent corrosion resistance but also superior wear resistance and self-cleaning capabilities.

Complementary corrosion protection of cast AlSi7Mg0.3 alloy using Zr-Cr conversion and polyacrylic/siloxane-silica multilayer coatings

Aluminium cast alloy AlSi7Mg0.3 is a lightweight metal commonly used in automotive, aeronautical and mechanical applications. It has good corrosion resistance but, under harsh operative conditions, would benefit from additional protection. In this study, a corrosion-protective multilayer coating system for AlSi7Mg0.3 based on hexafluoro-zirconated trivalent chromium coating (Zr-CrCC) and polyacrylic/siloxane-silica (PEHA-SS) coating was developed. The Zr-CrCC was formed by immersion of the substrate in a commercial conversion bath (SurTec® 650). PEHA-SS synthesis was based on organic precursors (2-ethylhexyl acrylate and [3-(methacryloyloxy)propyl]trimethoxysilane) and an inorganic precursor, tetraethyl orthosilicate. After deposition on AlSi7Mg0.3, each coating was first characterised individually, followed by the analysis of the multilayer using scanning electron microscopy and energy-dispersive X-ray spectroscopy. The adhesion of the coatings was evaluated with a cross-hatch cut test. The corrosion studies in sodium chloride solution using electrochemical impedance spectroscopy and salt spray testing showed that the multilayer system is superior to individual Zr-CrCC and PEHA-SS coatings. After 4 months in 0.1 M NaCl, the multilayer-coated samples exhibited the impedance at 10 mHz in the range of GΩ cm2, while scribed samples withstood the corrosion attack in a salt spray chamber for one week. Thus, albeit only about 100 nm thick, the Zr-CrCC deposited between the substrate and a 9-micrometre thick barrier sol-gel PEHA-SS coating acts as an active corrosion protection interlayer and contributes to the overall protectiveness of the multilayer system.

Assessing the Impact of Sepiolite-Based Bio-Pigment Infused with Indigo Extract on Appearance and Durability of Water-Based White Primer.

The objective of this study is to evaluate how two varying amounts of sepiolite-based powder, infused with indigo extract, affect the appearance and durability of a water-based, white primer. To examine the influence of this eco-friendly pigment on the coatings' overall appearance, assessments were performed for color, gloss, and surface roughness. Additionally, the coatings were investigated through optical and electron microscopic observations, to evaluate the distribution of the pigment within the polymer matrix. The effect of the pigment on the coating's durability was assessed through accelerated tests, including exposure in a salt spray chamber and a UV-B chamber. These tests aimed to evaluate the emergence of defects and changes in the appearance of the samples over time. Furthermore, the impact of different quantities of sepiolite-based powder on the coating's ability to act as a barrier was assessed using liquid resistance tests and contact angle measurements. These evaluations aimed to understand how the coating responded to various liquids and its surface properties concerning repellency or absorption. In essence, this study underscores the considerable influence of the eco-friendly pigment, demonstrating its capacity to introduce unique color and texture variations in the paint. Moreover, the inclusion of the pigment has enhanced the coating's color stability, its ability to act as a barrier, and its overall durability when exposed to harsh environments.

Anticorrosion composite coating based on silver phosphate/poly-phenylene sulfide with excellent hydrophobicity and antimicrobial properties

Combating microbial contamination has been one of the hottest topics in the scientific community. Therefore, antibacterial materials have been rapidly developed and widely used in recent decades. However, developing corrosion-resistant coatings with both hydrophobic and antimicrobial properties remains challenging. This study innovatively mixed polyphenylene sulfide (PPS) resin with Ag3PO4/SiO2 filler, and prepared a hydrophobic antibacterial coating with enhanced corrosion resistance on the tinplate surface through a simple spraying strategy. After testing, the water contact angle of the composite coating is 139.7° ± 1°, and the sliding angle is less than 5° ± 1°. Compared with the pure PPS coating, the corrosion current of the composite coating was reduced by 4 orders of magnitude, with an impedance of 788740 Ω·cm2. After 200 h testing in a salt spray chamber, it still showed excellent corrosion resistance. Excellent hydrophobicity and anti-corrosion properties effectively reduce the adhesion of water, thereby preventing microorganisms from forming biofilms on the coating surface and corroding the substrate. In addition, bacterial tests show that the coating has excellent antibacterial efficacy, effectively inhibiting the reproduction of E. coli and S. aureus, providing a second line of defense to prevent bacteria from adhering to the substrate. Therefore, the multi-faceted characteristics make PPS composite coatings have broad application prospects.

Durability of Single Lap Friction Stir Welded Joints between S355-J0 Steel and AA5083 Aluminum Alloy–Mechanical Tests

This study aims to investigate a friction stir welded joint between steel and aluminum alloy. FSW is nowadays one of the most interesting joining techniques due to the possibility of connecting materials and thicknesses that are difficult or impossible to weld with traditional techniques. The main advantage is that materials are not affected by thermal cycle problems during solidification and cooling, and the absence of fumes and pollution during the process favors the quality of the welded joint. The life of metal joints could be greatly reduced in a corrosive environment since the less noble material will tend to increase its corrosion rate, while the nobler one will reduce its electrochemical dissolution. Accelerated aging tests (i.e., salt fog test) are used to estimate the lifetime of metal joints in highly aggressive environments. The aim of the present work is to evaluate the durability at a long aging time in the salt spray test (according to ASTM B117) of carbon steel/aluminum alloy joints, obtained by FSW. In this first part, mechanical test results are reported. A deep metallographic and chemical investigation is going to be reported in part two. The current research work investigates the welding direction and residence time in the salt spray chamber. The breakage of all tested samples, evaluated after the tensile tests were carried out, always occurs at the interface of the joint, regardless of the change of direction of the weld on the advancing or retreating side. The welding direction influences the breakage of the joint only before the aging treatment. Specifically, specimens produced in advance are characterized by increased joint strength. On the other hand, the factor that influences the performance of the joints is the exposure time where, starting from the first point of aging, i.e., after two months, there is a decrease in the maximum load of 40%, and the effect of corrosion leads to a significant deterioration of the weld which remains almost similar until the last point of aging.

Protection of steel hooks embedded in glass-fiber-reinforced concrete against macrocell corrosion

This study evaluated the corrosion behavior of steel hooks embedded in GFRC, which were protected by a zinc-rich (96% Zn) galvanizing coating. The coating provided the hooks with active cathodic protection and a passive physical shield. Macrocell corrosion may form when the anode is smaller than the total steel surface. Thus, the steel hooks at the embedment juncture were additionally sealed against water ingress and air exchange using a construction sealant. The study was conducted in three phases in a salt-spray chamber. First, the electrogalvanized steel hooks embedded in GFRC were allowed to freely corrode for 7 days. In the second phase, the electrogalvanized steel hooks were painted with the zinc-rich coating and observed over 7 days. In the third phase, the steel hooks were protected by the zinc-rich coating together with a primer and construction sealant, and observed over 7 days. To evaluate the electrogalvanized hooks and the corrosion products formed, the thickness of the material was measured. Corrosion on the metal surface was inferred by studying the surface morphology of the hooks at various points of contact and after different periods of time.

Investigation on moisture absorption behavior on GFRP and neat epoxy systems in hygrothermal salt fog aging

This work investigates the moisture absorption behavior in epoxy matrix composites reinforced with glass fibers, used in repairs of offshore topside metal pipelines exposed to aging in saline environment. The materials used were a bicomponent DGEBA epoxy and a woven bidirectional E-glass fabric. In order to simulate the harsh environment, the composites were exposed to accelerated hygrothermal aging tests in three independent salt spray chambers at temperatures of 35, 55 and 70 °C and the materials had their mass gain monitored. The moisture absorption of the neat epoxy resin was also investigated and correlated with that of the composites. Thermal analyses by Differential Scanning Calorimetry (DSC) and Dynamic Mechanical Thermal Analysis (DMTA) were performed to evaluate the curing state of the polymeric materials tested and the effects of temperature on the material's post-curing. Fourier-Transform Infrared (FTIR) analyses were performed to investigate the occurrence of post-curing, hydrolysis and thermo-oxidation processes during aging. As expected, it was seen that temperature increased diffusivity for both the composite and the unreinforced epoxy matrix. The neat epoxy resin presented a decrease in moisture absorbed with temperature, evidencing the effect of post-curing on moisture absorption. Furthermore, from the thermal analyses, it was observed the presence of an interphase between matrix and fibers with a Tg higher than the bulk matrix. Non-Fickian models confirmed structural changes caused by temperature and moisture in the materials. A modification of the Berens-Hopfenberg (BH) non-Fickian model was proposed to account for post-curing effects on moisture absorption.

Proposição de variação do cobrimento nominal das armaduras baseada na classe de agressividade ambiental (CAA) de exposição de concretos

Abstract The physical and chemical protection of steel reinforcement afforded by the cover is a consequence of the quality of the concrete and its thickness, with a long-term impact on durability and service life. This study proposed variations in cover based on environmental aggressivity class (EAC) of exposure considering concretes of prescribed compressive strength classes (C20/C25/C30/C40). To this end, concrete mixtures were subjected to accelerated testing in salt spray chambers or carbonation. Accelerated testing was kept for periods long enough to reach each EAC cover level. Thus, the effect of each EAC, from mild to severe, was determined on the physical and mechanical characteristics of each mixture. It was determined that the required reinforcement cover varied linearly with compressive strength. This denoted the possibility of using more than one class of concrete and cover for each EAC. It should be noted that the difference in required cover became greater when using concrete with a strength class higher than C30. Still, it was noticed that the chloride ions attack s was more severe than carbonation and was, for most of the test cases, the determinant factor in minimum cover thickness to ensure the desired durability.

Physical and Chemical Properties of High-Temperature Silicone-Based Polymer Coatings Applied on Different Surface Roughnesses

High-temperature coatings play a crucial role in protecting surfaces exposed to extreme temperatures, corrosion, and other harsh environments. This paper focuses on the physical and chemical properties of solvent-borne and water-borne high-temperature silicone-based polymer coatings applied on two types of surface roughness of carbon steel plates. The corrosion protection performance of the coatings was characterized using a salt spray chamber, humidity chamber, electrochemical impedance spectroscopy (EIS) measurements, and differential scanning calorimetry (DSC). The physical properties of high-temperature coatings were determined using the Shore D hardness method and cross-cut adhesion tests. This study investigates the effects of different surface preparation methods on coating adhesion, which is considered to be a crucial property of organic coatings for corrosion protection durability. The thermal stability of the coating was tested using furnace cyclic testing. The results show that high-temperature coatings in general exhibit excellent thermal stability, high adhesion strength, and good resistance to warm and humid environments, except in the conditions of a salty atmosphere. This study reveals that coating performance is affected by the composition and surface preparation method. This study can be useful for coating manufacturers and researchers interested in understanding the physical and chemical properties of high-temperature coatings and their applications in various environments.

Designing a self-healable nano-structured thin film based on sustainable cerium-loaded ZIF8-MOF particles

Progressing the anti-corrosion performance of thin-film coatings has always been the focus of researchers. In this research, a novel high-resistance inorganic coating against corrosion was developed. For this aim, the steel plates treated with the Mn ion-containing zinc phosphate conversion coating were prepared and then covered with a layer of crystalline MOF nanoparticles. A robust self-healing effect was provided by the cerium cations loaded into the MOF thin coating, pores. FE-SEM, BET, XRD, and XPS were applied as the main analyses to characterize the successful formation of the conversion coating and the MOF grown on its layer. The uniformly grown MOF single crystals (particle size: 200–300 nm) could cover the porosities of the zinc phosphate coating so that no rust was detected after 600 h of keeping the sample in a very aggressive environment (salt spray chamber). Also; based on PDP results, the modified coating (ZPMnMOFCe) showed a sixty-fold drop in the corrosion rate compared to the uncoated plate. Meantime; after 24 h of exposure, its log|Z|10mHz was two orders of magnitude higher than that for the untreated mild steel.

Hybrid epoxy-SiO2/GO nanosheets anti-corrosive coating for aeronautic aluminum Al6061-T5

AbstractThe mechanical and anti-corrosive evaluation of a hybrid epoxy resin–SiO2 and graphene oxide (GO) are presented. Three composite materials were prepared with 0%, 0.1 wt% and 0.5 wt% GO concentrations. The hybrid material was prepared by the sol-gel process incorporating the silica particles in situ within the epoxy resin (ER) matrix and previously that ER was functionalized with carboxyl groups using abietic acid and labeled as functionalized epoxy resin. The deposition of the three hybrids in aluminum 6061 substrates was made by blade coating, measuring wet and dry film thickness. The study of mechanical properties involved adhesion, pencil scratch hardness, and abrasion test methods where the incorporation of 0.5 wt% of GO improved the mechanical properties considerably. The anti-corrosive properties of the coatings were evaluated through electrochemical impedance spectroscopy and accelerated corrosion using a salt spray chamber showing that GO forms an anti-corrosive barrier increasing the operation life of the coatings in corrosive environments. Anti-ice properties were related to the contact angle measurement from which the GO concentrations showed more hydrophobic behavior. All the tests were carried out according to ASTM standards. The incorporation of 0.5% of GO showed a significant improvement in the mechanical and anti-corrosive results, improving corrosion resistance up to 500 h. The abrasion tests had an increase in 35%, its hardness up to 9H, and the wear index improved by 29.14% compared with composites with 0.1 wt% of GO and without GO. The HREF1 and HREF5 materials do present an increase in the contact angle thanks to the incorporation of graphene oxide. The results of electrochemical impedance spectroscopy and the impedance curves show a better behavior for the HREF5 composite due to the difference in resistance over time.

Influence of Catalytic Infrared Radiation on the Protective Properties of Industrial Epoxy Primers.

The application of organic coatings is a common way of protecting metal substrates against corrosion. To dry the coating faster, catalytic infrared radiation (IR) can be applied. This paper aims to assess the differences in the physical, chemical, and corrosion properties of primer coatings dried with catalytic infrared radiation, compared to the same coatings dried under atmospheric conditions. Corrosion properties were characterized using humidity and a salt spray chamber, as well as electrochemical impedance spectroscopy (EIS), preceded by open circuit potential (OCP) measurement. Pencil hardness, cross-cut, and pull-off adhesion tests were used to compare the properties of examined primers before and after testing in the corrosion acceleration chambers. The microstructure and distribution of chemical composition were studied by scanning electron microscope (SEM) with energy-dispersive X-ray spectroscopy (EDX) together with Fourier-transform infrared spectroscopy (FTIR). Phase transitions in the coating were determined by differential scanning calorimeter (DSC). Infrared-dried primers achieved a higher curing degree. Therefore, their mechanical and corrosion properties are superior when compared to the same coatings dried under atmospheric conditions.

Corrosion surface morphology‐based methodology for fatigue assessment of offshore welded structures

AbstractThis work employed a novel corrosion‐based fatigue model to determine the fatigue life of offshore welded structures to enable the fatigue assessment of welds under corrosive conditions. In addition to the material's ultimate strength, endurance limit, and stress ratio (mean stress effect), the model includes a corrosion factor concept to account for the impact of corrosion pits on the fatigue performance of welded S355 steel, which is the novel contribution in this paper. X‐ray computed tomography scans of corroded S355 specimens in a salt spray chamber were characterized. Surface texture characterization was employed to obtain surface roughness, size, and aspect ratio of corrosion pits. The corrosion factor was determined based on notch and surface fatigue theories using the characterized pit size, aspect ratio, and surface roughness. Fatigue S‐N curves were then predicted for critical pits and compared against the fatigue code DNVGL‐RP‐C203 and experimental data from the literature. The novel approach combining corrosion characterization method with corrosion‐based fatigue model for the prediction of fatigue S‐N curves provided a minor deviation of only 2.8% between predicted and measured data. This approach can potentially be integrated into predictive frameworks for the remaining life assessment of offshore structures.

INCIDENCE OF HEAT TREATMENT ON THE CORROSIVE BEHAVIOR OF AISI 316L AUSTENITIC STAINLESS STEEL

Heat treatments of AISI 316L samples were conducted at 900°C with slow cooling in air to induce varied precipitation of chromium-rich carbide particles at grain boundaries, resulting in a microstructure susceptible to intergranular corrosion. The corrosion behavior of the material in this state was investigated in a salt spray chamber containing 5% NaCl. The temperature inside the chamber was set at 35°C, while the saturated air temperature was recorded at 47°C. Samples were periodically extracted for observation and analysis using a stereoscopic magnifying glass, optical microscope, and scanning electron microscope. The results revealed the detrimental effect of chloride ions on the corrosion behavior of these stainless steels. Metallographic examination of corroded specimens after the salt spray test confirmed that the passive layer's breakdown was responsible for the intergranular corrosion occurring along preferential paths of chromium carbides.

The Corrosion of Mn Coatings Electrodeposited from a Sulphate Bath with Te(VI) Additive and Influence of Phosphate Post-Treatment on Corrosion Resistance

Manganese coatings are excellent for the cathodic protection of steel against corrosion. Although manganese is more electrochemically active than widely used protective coatings of zinc, the exceptional resistance of manganese coatings in neutral and basic media is determined by the film of insoluble corrosion products, which forms on the surface of manganese and greatly suppresses its further corrosion. It is known that the electrodeposition process of Mn coatings from sulphate electrolytes is positively affected by some additives of chalcogenide (S, Se and Te) compounds in the electrolyte. However, a more detailed study on the corrosion properties of Mn coatings electrodeposited from sulphate bath with Te(VI) additive is lacking. In this work, the measurements of free corrosion potential and potentiodynamic polarization in a neutral NaCl solution, as well as the corrosion resistance properties of obtained Mn coatings, were evaluated in a salt spray chamber. It was obtained that the best corrosion resistance was shown by Mn coatings, electrodeposited at the cathodic current density of 15 A⋅dm−2 and at higher temperatures (60 and 80 °C). Meanwhile, the corrosion resistance of phosphated Mn coatings, obtained from a room temperature bath, increased about 5 times and reached up to 1000 h until corrosion of the steel substrate occurred.

Mercaptosilane as additive orpretreatment in acoating system for steel

The application of paints is one of the most used protection methods for metals, but the loss of adhesion of the paint film is a commonly observed failure. In order to avoid this deterioration different silanes are studied as adhesion promoters between paints and metals.The aim of this paper was to study the adhesion promotion of mercaptopropyl-trimethoxysilane in a protection system for steel. Two strategies were used in order to incorporate the silane: as an additive in an epoxypolyamide water-borne paint, and as a pretreatment before painting. Adhesion tests were performed during exposure of the painted steel panels in the salt spray chamber. Blistering and rusting degrees were also evaluated during the panel's exposure in the salt spray and humidity chambers. Besides, electrochemical (corrosion potential measurements and ionic and polarization resistances) and service exposure tests were performed.The results show that depending on the environmental conditions, it is better to incorporate the silane in the paint or as a pretreatment. Moreover, the results also depend on the silane concentration and the time of hydrolysis before pretreatment or its incorporation in the paint.

Strengthening the mechanical characteristics and cathodic delamination resistance of fiber-reinforced polymer through chemical surface modification of glass fibers.

This work aims to scrutinize the effect of the silanization of glass fibers (GF) on the mechanical properties and cathodic disbonding resistance of an epoxy composite coating. Successful silanization was approved based on different characterization techniques, including Fourier transform infrared spectra, field emission-scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy, and thermogravimetric analysis. Tensile strength measurement exhibited a significant effect of silanization on the mechanical performance of the fiber-reinforced polymer (FRP). FE-SEM cross-sectional images illustrated improved interfacial bonding between the epoxy matrix and GF upon silanization. Pull-off measurements revealed improved wet adhesion strength of the FRP to the mild steel surface after exposure to the salt spray chamber when the GF were silanized. In addition, silanization revealed enhanced resistance to cathodic delamination (CD). Electrochemical impedance spectroscopy and electrochemical noise assessments proved silanization's significant influence on the FRP's CD resistance.