Salt Hydrate Phase Change Materials Research Articles

Evolving Thermal Energy Storage Using Hybrid Nanoparticle: An Experimental Investigation on Salt Hydrate Phase Change Materials for Greener Future

Thermal energy storage (TES) assisted with phase change materials (PCM)s seeks greater attention to bridge the gap between energy demand and supply. PCM has its footprint toward efficient storage of solar energy. Inorganic salt hydrate PCMs are propitious over organic PCMs in terms of energy storage ability, thermal conductivity, and fireproof, however the major issue of supercooling and poor optical absorbance remains. This research investigates commercialized inorganic salt hydrate PCM with phase transition temperature of 50 °C, thermal conductivity of 0.593 W m−1 K which is favoured with melting enthalpy of 190 J g−1, and 2–3 °C of supercooling. Mixture of graphene: silver at a proportion of (1:1) is used as the hybrid nanomaterial to further enhance the thermal conductivity, optical absorbance, and thermal stability. Hybrid nanocomposites are developed via two‐step process involving direct mixing and ultrasonication. Morphological behaviour, chemical stability, optical property, thermal property, thermal reliability, and stability of the developed nanocomposite samples are experimentally analysed. As a result, sustainable TES materials with thermal conductivity of 0.937 W m−1 K, optical absorbance of 0.8, increased energy storage potential is formulated. Subsequently a numerical simulation is conducted to illustrate the potential of the developed nanocomposite in transfer of heat energy.

Experimental investigation on the performance of binary carbon-based nano-enhanced inorganic phase change materials for thermal energy storage applications

Phase change materials (PCMs) are considered potential resources for Thermal energy storage (TES) applications. However, the PCMs are limited because of their lower thermal conductivity, resulting in a significant decrease in heat transport and energy storage capability. The foremost objective of the present research is to formulate a novel salt hydrate PCM filled with binary carbon-based nanoparticles (graphene and multi-walled carbon nanotubes) at various weight concentrations and examine the thermophysical properties. A two-step approach is used to formulate binary nanomaterials dispersed salt hydrate PCM. The formulated binary nanocomposite's thermo-physical properties like morphological behaviour, thermal stability, chemical stability, melting enthalpy, optical performance, rate of heat transfer and thermal reliability were characterized. The binary nanoparticle-enhanced nanocomposites can form a decent thermal network, resulting in a remarkable enhancement in thermal conductivity by 160 % (1.2 W/mK) compared to pure salt hydrate. Moreover, a remarkable improvement in optical absorptance and a reduction in optical transmittance by 82.55 % for 0.7 wt% graphene and 0.07 wt% MWCNT enhanced salt hydrate PCM (SAHGrM-0.07) than pure salt hydrate PCM. In addition, the formulated nanocomposites possess excellent heat storage capability, chemical and thermal stability after 300-thermal cycling. The binary carbon-based nanoparticle-enhanced salt hydrate nanocomposites offered acceptable thermal and chemical stability, thermal reliability, and heat transmission characteristics, by this means reflecting its appropriateness for medium-temperature solar TES applications.

High Power Density Thermal Energy Storage With Phase Change Material in Enhanced Compact Heat Exchangers

Abstract Performance of a novel ultracompact thermal energy storage (TES) heat exchanger, designed as a microchannel finned-tube exchanger is presented. With water as the heating–cooling fluid in the microchannels, a salt hydrate phase change material (PCM), lithium nitrate trihydrate (LiNO3 · 3H2O), was encased on the fin side. To establish the hypothesis that small-length-scale encasement (<3 mm) of PCM substantially enhances heat transfer to yield very high power-density energy storage, heat exchanger designs with 10 and 24 fins/inch were considered. They were subjected to thermal cycling, or repeated heating (melting) and cooling (freezing), with inlet fluid flow mimicking diurnal variation between 42 °C and 25 °C (representing typical arid-region conditions) over an accelerated time period. By employing salt self-seeding to obviate subcooling during cooling or recrystallization, the TES was found to exhibit stable long-term (100 heating–cooling cycles) operation with very high PCM-side heat transfer coefficients (∼100–500 W/m2 K) and storage power density (∼160–175 kW/m3). In fact, with optimization of heating–cooling fluid flowrate for given charging–discharging time period and exchanger size, power density >300 kW/m3 can be achieved. The results clearly establish that highly compact heat exchangers used as TES units can provide very high-performance alternatives to conventional ones.

Preparation, characterisation and property modification of a calcium chloride hexahydrate phase change material slurry with additives for thermal energy transportation

Efficient thermal energy distribution and rational energy management are effective solutions to address the significant and fast-ascending energy consumption in building heating, ventilation, and air conditioning (HVAC). Phase change material (PCM) slurries with excellent thermal energy transportation and storage characteristics have been recognised as promising secondary refrigerants to simultaneously facilitate efficient heat/cold transport and effective thermal energy storage in air conditioning systems. Among various PCM slurries, salt hydrate PCM slurries have attracted increasing attention in recent years due to their many inherent advantages. This paper presented the preparation, characterisation, and property modification of a CaCl2·6H2O slurry based on a methodology proposed for optimal salt hydrate PCM slurry development. Theoretical modelling was first carried out to assess the availability of salt hydrate PCM slurries based on the phase diagram and solid fraction, followed by a series of property measurements to reveal the mechanisms and address the problems behind the phase transition, crystal particle morphology, stability and rheologic characteristics, using nucleating agents, surfactants and stabilisers. It was found that the salt hydrate PCM slurry developed provides a unit volume enthalpy twice that of water over the phase change temperature range of 5°C, together with acceptable fluidity. The results also showed that the PCM particle size can be well controlled, and the slurry can be stabilised, with the assistance of surfactants and stabilisers. Compared to other types of PCM slurries, the proposed salt hydrate PCM slurry has the advantages of being cost-effectiveness, easy preparation, adjustable phase change temperature, etc., which is promising to facilitate energy saving and rationalisation in building HVAC.

Influence of metal encapsulation on thermophysical properties and heat transfer in salt hydrate phase change material for air conditioning system

Phase change materials (PCM) are gaining increasing attention as a cold energy storage technology for air conditioning systems due to their potential to reduce electrical grid loading, energy consumption, and electricity costs. However, realizing the full potential of PCM-based cold energy storage in practical applications is constrained by low cold energy transfer efficiency within air conditioning systems. This study addresses this challenge by exploring the encapsulation of salt hydrate PCM using six different metals to enhance heat transfer efficiency. Additionally, the corrosion behaviors of the PCM towards these metals were thoroughly evaluated. Notably, copper demonstrated the highest corrosion rate, and the resulting corrosion products, particularly from copper and brass, were found to substantially reduce the energy storage capacity of PCM. Moreover, PCM encapsulated into aluminum alloy exhibited higher heat transfer efficiency than that of stainless steel. In light of these findings, aluminum alloy is recommended as the optimal choice for PCM encapsulation, given its corrosion resistance and minimal effect on thermal properties. This research provides crucial insights for selecting appropriate metals to enhance the efficiency and durability of air conditioning systems utilizing salt hydrate PCM.

Experimental investigation on nucleating agent for low temperature binary eutectic salt hydrate phase change material

The melting enthalpy and melting temperature have a significant impact on the latent heat that results from phase change materials (PCMs) used for thermal energy storage. Among the PCMs that are currently on the market, inorganic salt hydrates have greater thermal conductivity and latent heat than organic PCMs. However, the problem of salt hydrates' degree of supercooling limits their use in energy storage devices. Using sodium carbonate decahydrate (SCD) and sodium phosphate dibasic dodecahydrate (SPDD), a low temperature inorganic-inorganic eutectic salt hydrate PCM with a higher melting enthalpy and intended phase transition temperature is developed in this research study. The eutectic SCD/SPDD salt hydrate PCM eutectic point and the eutectic composition of salt hydrate PCMs to operate at low temperature range is numerically determined using Schrader equation. By numerical methods we obtain the 68 wt% of SCD with 32 wt% of SPDD to exhibit eutectic SCD/SPDD composite with eutectic melting temperature of 26.2 °C and melting enthalpy of 210.6 J/g. The synthesised eutectic PCM are characterised to explore their chemical stability, latent heat, melting point and their shortcoming due to degree of supercooling. A good way to get around the problem of the supercooling degree is to disperse the nucleating agents. In order to assess the type and degree of supercooling, the produced eutectic PCM composition is experimentally evaluated at 1–10% utilising borax, alumina, and sodium sulphate dodecahydrate as nucleating agents. However, for building cooling applications PCM with minimal degree of supercooling, with the ability to release low enthalpy during discharging is an advantage.

Microcapsule fabrication by ATRP at the interface of non-aqueous emulsions.

We present soft-template encapsulation of salt hydrate phase change materials (PCMs) using modified silica particles to both stabilize emulsions and serve as initiators for organocatalyzed photoredox ATRP. The resulting core-shell structures have high core loading and are robust to thermal cycling. Critically, this strategy eliminates the need for a reagent in the core phase, thus preserving purity, and offers the ability to tailor shell composition for desired applications.

Advancements and Challenges in Enhancing Salt Hydrate Phase Change Materials for Building Energy Storage: Optimization Methodologies and Mechanisms

Advancements and Challenges in Enhancing Salt Hydrate Phase Change Materials for Building Energy Storage: Optimization Methodologies and Mechanisms

Energizing the Thermal Conductivity and Optical Performance of Salt Hydrate Phase Change Material Using Copper (II) Oxide Nano Additives for Sustainable Thermal Energy Storage

Due to intermittent nature of solar energy, scientists and researchers are working to develop thermal energy storage (TES) systems for effectively use the solar energy. One promising avenue involves utilizing phase change materials (PCMs), but primary challenge lies in their limited thermal conductivity, which results in slower heat transfer rate and lower thermal energy storage density. The present research work demonstrates, to develop and explore a PCM composite by embedding salt hydrate and coper (II) oxide to enhance the heat transfer mechanism for potential utilization of TES material. The optical behavior, and thermal conductivity were analyzed by using Ultraviolet visible spectrum, and thermal property analyzer. The developed copper oxide dispersed PCM composite displayed the thermal conductivity was energized up to 71.5 % without affecting the other properties. Also, the optical absorptance was remarkably enhanced and the transmittance reduced to 87 %. Increasing the concentration of copper oxide nanoparticles in the salt hydrate PCM improves the optical absorptivity and heat conductivity. With these extraordinary abilities the nanocomposite could play a significant role in progress of sustainable TES with significance to contribute towards sustainable development goal of affordable and clean energy and climate change.

Energizing eutectic salt hydrate phase change material using 2D carbon based graphene nanoparticle

Energy being the strongly depended source for development and industrialization, their storage in any form tends to bridge the gap between demand and supply. Renewable energy technology systems now include energy storage as a crucial component. Thermal energy storage is a technique that stores thermal energy by heating or cooling a storage medium. This allows the energy to be used for heating and cooling purposes later on. The present study develops ternary inorganic salt hydrate eutectic phase change material (EPCM) that is intended for cooling buildings. Melting temperature, melting enthalpy and eutectic composition proportion of inorganic salt hydrate of sodium carbonate decahydrate (SCD), sodium phosphate dibasic dodecahydrate (SPDD), and sodium sulphate decahydrate (SSD) are determined using the eutectic melting point theory. Ternary EPCM is synthesised experimentally in accordance with the percentage of salt hydrates. Graphene nanoplatelets are distributed at different weight concentrations of 0.3%, 0.6%, and 0.9% in order to further improve the thermal performance; at higher concentration above 0.9% the graphene nanoplatelets tends to agglomerate. In order to assess the chemical stability and thermal properties of prepared nanoparticle dispersed PCMs, are experimentally assessed. Findings confirm the ternary EPCM's chemical stability and raise its latent heat with graphene nanoplatelets.

Smoothing cooling demand of buildings with PCM thermal batteries

Escalating energy tariffs and peak cooling demands due to climate change along with expanding use of variable renewable energy supply are presenting new challenges and opportunities for air conditioning system operation and control. This research presents the outcome of an investigation into the use of a thermal battery using salt-hydrate phase change material (PCM) in commercial buildings. A 1.2 m3 modular thermal battery using 15 °C melting temperature salt-hydrate PCM has been designed and fabricated. Its cooling performance and feasibility of integration into a chilled water-cooling system of commercial buildings has been comprehensively investigated. This storage unit can accommodate approximately 52 kWh of energy, featuring a rapid heat discharge rate of 32.58 kW during the initial 30 min to effectively address sudden cooling demands. The overall heat discharge rate closely aligns with simulation results, reaching approximately 96% accuracy. This has been achieved through optimisation of the heat exchanger design through mathematical simulation, detailed testing to match various operational scenarios and evaluation of economic and peak load shifting benefits. The results demonstrate the environmental and economic effectiveness of the PCM thermal battery as an independent component in building cooling systems. It provides a timely response to peak cooling demand and improves thermal comfort of the buildings.

MXene-based eutectic salt hydrate phase change material for efficient thermal features, corrosion resistance & photo-thermal energy conversion

Salt hydrate phase change materials (PCMs) possess low thermal conductivity, degree of supercooling, lack of corrosion resistance and poor photo thermal conversion ability. To overcome these challenges, a two dimensional, chemically stable, optically & thermally efficient MXene@eutectic salt hydrate composite PCM is developed for effective harnessing of solar energy and thermal energy storage (TES) applications. Low temperature eutectic salt hydrate PCM with phase transition temperature of 27.6 °C and 216 J/g melting enthalpy is developed using sodium sulphate decahydrate (SSD) and sodium phosphate dibasic dodecahydrate (SPDD) based on Schrader equation. Advanced 2D layered material, MXene (Ti3C2) is synthesised from MAX phase (Ti3AlC2). Furthermore, MXene based PCM nanocomposite is developed with binary eutectic PCM of SSD/SPDD at different weight fractions through two step technique. Developed nanocomposite PCM exhibits better chemical stability, high optical absorbance of (1.1), low transmissibility (10.2 %), reliable thermal conductivity (0.621 W/m⋅K), improved melting enthalpy (161.2 J/g) and considerable cycle stability. The optical absorbance and thermal conductivity demonstrated a superior photo-thermal conversion capability and thermal networks for the developed MXene based composite sample at 0.9 wt% of MXene. The above properties are experimentally inferred by evaluating the developed MXene@ eutectic salt hydrate and base eutectic PCM under the solar simulator. The interfacial attraction between the two dimensional MXene nano flakes and the developed eutectic PCM ensures a promising ability to trap solar energy effectively for thermal regulation in a sustainable direction. Subsequently, the effect of MXene with SSD/SPDD in regard to the issue of corrosion is explored for copper and aluminium metal surface.

Hybrid Polymer Salogels for Reversible Entrapment of Salt-Hydrate-Based Thermal Energy Storage Materials.

One of the challenges preventing wide use of inorganic salt hydrate phase change materials (PCMs) is their low viscosity above their melting point, leading to leakage, phase segregation, and separation from heat exchanger surfaces in thermal management applications. The development of a broad strategy for using polymers that provide tunable, temperature-reversible shape stabilization of a variety of salt hydrates by using the lowest possible polymer concentrations is hindered by differences in solubility and gelation behavior of polymers with change in the type of ion. This work addressed the challenge of creating robust, temperature-responsive shape-stabilizing polymer gels (i.e., salogels) using a low cost PCM, calcium chloride hexahydrate (CaCl2·6H2O, CCH). Due to the extremely high (9 M) concentration of chloride ions and the tendency to salting-out polymer chains, the previous strategy of using single-polymer salogels was not successful. Thus, this work introduced a strategy of using two polymers, poly(vinyl alcohol) and ultrahigh molecular weight polyacrylamide (PVA and PAAm, respectively), along with borax as a cross-linker to achieve temperature-reversible, shape-stable salogels. This system resulted in robust salogels whose gel-to-sol transition temperature (Tgel) was tunable within an application-relevant range of gelation temperature (30-80 °C). This behavior was enabled by a synergistic combination of dynamic covalent cross-links between PVA units and entanglements of PAAm chains which were combined into a single hybrid network. The hybrid salogels had <5 wt % polymer content, maintaining ∼95% of the heat of fusion of the pure PCM. Importantly, the noncovalent nature of gelation supported thermo-reversibility of gelation, shape stability, and retention of thermal properties over 50 melting/crystallization cycles.

Investigation of Thermal Performance and Chemical Stability of Metal Infused Salt Hydrate Phase Change Material for Thermal Energy Storage

Thermal energy storage (TES) is a technique that is considered a very desirable technology with a high potential to overcome the gap between demand and supply. Phase change materials (PCMs) are considered to be a highly favourable thermal energy storage materials. Besides that, PCM has certain drawbacks, such as lower thermal conductivity and higher light transmission; owing to this, the heat transfer rate and energy storage density are less. The performance of the PCMs can be improved by adding highly conductive nanoparticles. In this study, various weight percentages (0.1% - 5.0%) of Copper (II) oxide nanoparticles are dispersed with salt hydrate phase change materials with melting temperature 50 °C and investigated the thermal and chemical properties using Thermogravimetric analyzer, thermal conductivity analyzer, and Fourier transform infrared spectrum. Results shows that the prepared nanocomposites have chemically and thermally stable up to 467 °C. The thermal conductivity was increased by 62.64%, at 3.0 wt% Copper (II) oxide with salt hydrate PCM. The developed nanocomposites have better thermophysical properties than pure salt hydrate, which may be applied for TES applications like solar water heating, photovoltaic thermal systems, and electronic cooling systems.

Optical performance and chemical stability evaluation of new era phase change material: Activated by hybrid nanoparticle

Inorganic salt hydrate phase change materials (PCMs) are ahead of organic PCMs in terms of energy storage ability and safety as they are non-flammable. However the major hindrance with inorganic PCM are degree of supercooling and low thermal conductivity though better than organic PCM. The common technique to enhance the thermal conductivity is via dispersion of metal and carbon nanoparticle. Though they enhance the thermal conductivity of the nanocomposite, with continuous operation the nanoparticle agglomerate and settles down owing to their density. Henceforth, in the current research work we conduct an experimental investigation to enhance the optical and thermal performance of commercialised inorganic salt hydrate PCM using metal-carbon hybrid nanoparticle. We disperse graphene silver nanoparticle at different weight ratio adopting a two-step method followed by probe sonication to ensure uniform dispersion. We achieve a highly stable nanocomposite with 584% increase in optical absorbance of electromagnetic waves and 86% decrease in transmittance. Thermal management of electronic gadgets has evolved to be a major consideration of research as overuse of gadgets lead to rapid temperature rise and is in need of passive cooling system. Henceforth the newly developed nanocomposite phase change materials (PCMs) not only acts as thermal batteries but can also be opted as energy materials for thermal regulation and heat mitigation.

Experimental investigation on triggering solidification of supercooled sodium acetate trihydrate with extra water and different thickening agents by local cooling

Addition of extra water or thickening agents can reduce the phase segregation of salt hydrate phase change materials, but may influence the supercooling stability and crystallization of the mixture solution for supercooled thermal storage. Triggering solidification of supercooled sodium acetate trihydrate (SAT) is experimentally investigated by local cooling method (using a 72 W semiconductor refrigerator) with the addition of extra water as well as 7 thickening agents, i.e. carboxymethyl cellulose (CMC), gelatin, urea, starch, polyvinyl alcohol (PVA), polyacrylamide (PAM) and xanthan gum (XG). The water content in SAT water solution ranges from 40.01 % (only crystal water content, no extra water) to 50 % (9.99 % extra water). The mass ratio of thickening agents to SAT is between 0.25 % and 3 %. The results show that 44 % water content SAT solution can effectively alleviate the phase segregation and also has relatively short induction period for crystallization initialization with the discharging temperature as high as 51.8 °C. Among the 7 thickening agents, gelatin, CMC, starch and XG present better performances than urea, PVA and PAM for alleviation of phase segregation. Each additive has its suitable mass proportion considering the triggering and discharging performances. With the same local cooling power of 72 W, SAT samples containing 1 % gelatin present the highest discharging temperature (Tdis) of 55.8 °C as well as shorter induction period (τin) of 1.1 min; 2 % CMC samples have the discharging temperature as high as 55 °C and induction period of 11 min; the amount of starch has slight effect on triggering performances and the relatively better proportion is 0.25 % with Tdis = 52 °C and τin = 1.6 min; the suitable XG content is 0.5 % with Tdis = 49.2 °C and τin = 7.3 min under present conditions. The obtained results are helpful in selecting SAT additives for phase segregation reduction, better triggering and discharging performances based on supercooled thermal storage.

Microencapsulation of a salt hydrate phase change material by resorcinol formaldehyde through electrohydrodynamic disintegration of coaxially layered filament

Uniform microcapsules of size on the order of 100 nm with CaCl2.6H2O at the core and resorcinol formaldehyde as the shell was made by electro hydrodynamically disintegrating the coaxially layered filament. The shell thickness was varied by changing the flow ratio. The effect of shell thickness on the phase change temperature and the heat flow at its peak value during the DSC scan were reviewed to ascertain the extent of thermal equilibration, and the fraction of PCM melting at the peak value of heat flow. The integrity of the shell was evaluated by sustained dipping in deionized water for a month. The DSC scan was repeated after several heating-cooling cycles to understand the cycle life of the microcapsules.

Thermal performance and corrosion resistance analysis of inorganic eutectic phase change material with one dimensional carbon nanomaterial

The inherent thermal characteristics, supercooling phenomenon, and corrosion issues associated with salt hydrate phase change materials (PCMs) limit their practical applications. In this research work, we report a newly formulated eutectic salt hydrate PCM using a) sodium sulphate decahydrate (SSD) & b) sodium phosphate dibasic dodecahydrate (SPDD); with a focus on customizing its properties to enhance its suitability for low temperature thermal regulation (achieving a melting point of 27.8 °C and a high heat storage capacity of 215 J/g). Additionally, we have successfully reduced the degree of supercooling and introduced corrosion resistant properties to this PCM. To enhance both the thermal energy transfer rate and optical absorbance of the eutectic PCM, we have incorporated one-dimensional (1D) multiwall carbon nanotube (MWCNT) at various weight fractions, extending up to 0.9 %, utilizing a two-step method. The dispersion and chemical stability of SSD/SPDD + MWCNT nanocomposite are verified through the morphological visual and spectral peaks obtained in Fourier transfer infrared spectroscopy. Additionally, studies evaluating the optical and thermal property reveal a substantial 500 % increase in absorbance, a notable 77.9 % reduction in transmissibility, a thermal conductivity increase from 0.464 W/m⋅K to 0.742 W/m⋅K (reflecting a 59.9 % increment), and the retention of a consistent melting enthalpy of 218.6 J/g. This stability is attributed to the intermolecular interaction with MWCNT. Similary, the degree of supercooling (ΔTs) for the SSD/SPDD EPCM containing MWCNT decreased to 2.2 °C from 16.5 °C, marking an 86 % reduction compared to the pure eutectic salt solution. Furthermore, this composite demonstrated enhanced thermal and chemical stability throughout 200 thermal cycles. Auxiliary ANSYS simulation, with transient boundary condition, are provided to analyze the heat transfer interactions between the thermic fluid and the newly developed PCM when integrated into a thermal regulation system. Subsequently, a corrosion analysis of the developed eutectic PCM and the nanocomposite eutectic PCM exhibits a corrosion rate of 0.018 mpy, well below the permissible level (<5mpy). The insights gained from the development of this nanocomposite PCM offer valuable guidance for the design and creation of tailored eutectic PCM for low-temperature thermal regulation systems, resulting in significant energy savings.

Incorporating phase change materials in geothermal energy piles for thermal energy storage

Introduction&#x0D; Geothermal energy piles (GEPs) are foundation elements that are installed in the ground to support the weight of the building to a competent strata. Energy loops are installed into the piles to allow heat rejection or extraction via the circulation of fluid through the loops. In winter, low-grade heat is extracted from the ground (source) and transferred to the building (sink) to achieve space heating. Conversely, in summer, heat is removed from the building and rejected into the ground to achieve space cooling. The system relies on the temperature gradient between the ground and the ambient air temperature; where in winter, the ground temperature is higher than the air temperature, while in summer, the opposite is true. Thus, the system can sustainably and continuously supply the heating and/or cooling demand of a building once the temperature gradient between the ambient air and the ground is maintained. To improve the sustainability and performance of the system, the heat energy rejected into the ground can be stored and used at a later time when space heating is required [1]. Energy storage substances such as phase change materials (PCMs) can be incorporated into energy piles to store the heat that is rejected into the ground to improve the performance of the GEP system [2]. PCMs are materials that stores or releases heat energy during phase transition. Many researchers including [3,4] have reported using PCMs in buildings to improve thermal comfort and minimise the energy demand during heating and cooling periods, however, not much work has been done with regard to incorporating them into pile foundations to improve the performance of GEP systems.&#x0D; Thus, this study carried out a laboratory experiment to investigate the effect of the addition salt hydrate PCM on the energy performance of geothermal energy piles.&#x0D; Laboratory test and procedure&#x0D; In this study, lab-scaled models of energy piles were constructed, with and without PCM. The piles are characterised by a length and a diameter of 300 mm and 100 mm, respectively. In order to add PCM into the piles, the PCM was encased and sealed in a PVC tube with an inner and an outer diameter of 6mm and 8mm, respectively. The same size of PVC tube was used for the energy loops. The energy loop (U-shape), and the encased PCM incorporated tubes are attached together and placed in the mould prior to concreting, for the pile model with PCM (see Figure 1a). Whereas only the energy loop was installed in the control sample.&#x0D; In the test setup, a layer of sand (220mm thick) was placed and compacted in an insulated wooden box (520mm × 520mm × 520mm). Afterwards, the pile was then installed at the center of the box and then filled with sand, in layers and compacted. An insulation sheet was used to cover the top of the box to prevent heat loss and the ambient air temperature influencing the tests’ results. Water at a temperature of 32°C, was circulated through the pile continuously for a duration of 4 days (96 hours). Instrumentations were installed in the pile and soil to monitor and record the changes in temperature during the tests (see Figure 1b).&#x0D; Results and discussion&#x0D; Figure 1c shows the results comparing the average energy rejected, and stored, in the ground for the piles with and without PCM. The maximum heat energy stored at the beginning of the test was found to be about 460W and 360W for the control and PCM piles. However, at the end of the tests, the energy stored was 230W and 430W for the control and PCM pile, with an average energy stored as shown in Table 1. The addition of salt hydrate PCM absorbs the heat rejected into the pile, consequently improving its thermal performance by about 22% in comparison to the control pile. Similarly, the magnitude of temperature developed in the pile and surrounding soil were observed to be lower in the pile with PCM. This can ultimately reduce the induced stresses and strains induced in a pile due to heat energy extraction or rejection.&#x0D; &#x0D; Conclusion&#x0D; This paper investigated the feasibility of using salt hydrate PCM in energy piles for heat storage. It was found that the energy rejected in a pile with PCM increases by up to 22% compared to a non-PCM pile.

Experimental investigation of the solar latent heat thermal energy storage system integrated with salt hydrate phase-change materials

To achieve rational utilization of renewable energy sources, a solar latent heat thermal energy storage system for hot water application was developed in this study. The feasibility of the salt hydrates using in the solar heating was assessed and the comparative experimental investigation was conducted under various operating conditions. It shows that the higher flow rate and radiation accelerate the melting process of the phase-change material. The time taken for the storage medium to reach phase transition was reduced by approximately 48.9%; meanwhile, the collector efficiency was enhanced by approximately 10.2% as the flow rate increased from 10 g/s to 30 g/s. The accumulated charging energy increased by approximately 10.9% when the radiation increased from 850 W/m2 to 920 W/m2, resulting in a prolonged heat release process. The test results suggest the promising potential of the salt hydrates for the solar water heating applications.