Geopolymer concrete (GPC) holds significant potential for building fire safety design due to its green, low-carbon, and high-temperature resistant properties. In practical applications, concrete structures often face multiaxial composite loads. Therefore, investigating the composite stress performance of high-strength geopolymer concrete (HGPC) after exposure to high temperatures is crucial for assessing structural damage and enhancing fire prevention measures. This paper examines the compressive shear performance of HGPC at various temperatures T (20°C, 200°C, 400°C, 600°C) and stress ratios k (0.15, 0.3, 0.45, 0.6). The study analyzes failure patterns, shear load-displacement curves, shear strengths and their components, and peak shear deformation. Failure criteria are proposed to describe the damage patterns of HGPC under compressive shear loading after high temperatures. Additionally, the damage evolution process is evaluated using the energy method. The results show that HGPC damage surfaces penetrate the coarse aggregate at room temperature under compression-shear composite loading but shift to the aggregate-mortar interface at 600°C. Shear stiffness, peak shear strength, and residual strength increase with higher stress ratios but decrease with rising temperatures. Temperature affects peak shear strength by over 95 %, significantly more than the stress ratio. The shear strength decreases more slowly than compressive strength up to 400°C but more rapidly beyond 400°C. The cohesive strength of HGPC decreases with increasing stress ratio under different temperatures, while contact friction strength exceeds 50 % of peak shear strength. Shear dilation strength generally increases, then decreases, peaking at k = 0.45. The failure criterion based on the modified twin shear unified strength theory aligns best with experimental results. Furthermore, an increased stress ratio retarded the development of damage evolution, which was first accelerated and then slowed with rising temperature.