In this study, Ce2[Zr1x(Ba1/3Ta2/3)x]3(MoO4)9 (CZ1xTx, x = 0.01 ∼ 0.1) ceramics were synthesized via the solid-state method at temperatures ranging from 650 °C to 850 °C. XRD and Rietveld refinement analyses revealed that CZ1xTx ceramics exhibit a single phase with the space group R3-c, and the cell volume increases with higher doping content. SEM results indicate that CZ0.98T0.02 ceramics exhibit a highly regular and uniform grain shape. The CZ0.98T0.02 ceramics displayed optimal performance at 800 °C, exhibiting εr = 10.40, Q×f = 76,893 GHz, and τf = 14.61 ppm/°C. Additionally, the P-V-L theory was employed to establish correlations between ceramic chemical bonds and performance attributes. The results showed that the Ce-O bond predominantly influences εr while the Mo-O bond correlates with Q×f and τf. Furthermore, far-IR reflection spectra unveiled ion displacement polarization as the primary mechanism in CZ1xTx ceramics. Finally, based on CZ0.0.98T0.02 ceramics, a patch antenna applicable to the S-band was designed and fabricated, evidencing the vast potential of this ceramic in industrial applications.
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