Routine observations of surface ozone (O3) and its precursors (NO, NO2, NOx) were taken over Bengaluru, a southern megacity, India, for 4 years period between January 2015 and December 2018. The seasonal variations of O3, NO, NO2, and NOx have been analysed to understand the short-term variability of the pollutants at this site. The magnitude of O3 varied significantly by season, with maximum concentration during winter (13.07 ppbv) and minimum concentration during monsoon (9.52 ppbv). The highest concentration was observed in the post-monsoon season (17.38 ppbv) for NO, while NO2 and NOx showed the highest (41.75, 50.42 ppbv) in the winter season. The lowest concentrations of NO (5.70 ppbv), NO2 (30.43 ppbv) and NOx(36.28 ppbv) were observed in summer. An estimate was performed to determine the site's VOC-NOx sensitivity, using the TNMHC/NOX ratio as a photochemical measure. This ratio indicates that the study region is NOX responsive in all seasons. Analysis was done on the effects of meteorological factors such as temperature, water vapour, and ventilation coefficient on pollutants. Higher correlation of O3 with temperature showed the role of photochemical reactions in the formation of ozone and water vapour content leads to the removal of ozone concentration. The influence of meteorological variables on NO2 and TNMHC did not appear to be very significant. An analysis of CAMS data with real-time measurements of ozone and oxides of nitrogen showed that ozone is significantly correlated, while nitrogen oxides are not significantly correlated with CAMS data.
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