Rough Solid Surface Research Articles

Clathrate Hydrate-Solid Surface Adhesive Shear Strength Measurements on Carbon Steel Surfaces.

Oil and gas flowlines operating in subsea or cold terrestrial environments face the risk of forming hydrate deposits and plugs. The pressure differential across a hydrate plug can cause the plug to detach from the pipe wall and travel through the pipeline, potentially impacting a bend or inline equipment, causing damage or injury to personnel. Therefore, the hydrate-solid adhesive shear strength is of interest in estimating the maximum allowable differential pressure across a plug during depressurization procedures before the plug is likely to detach from the pipe wall. Quantifying the changes in adhesive shear strength with time and operational conditions is essential in estimating the potential of hydrate deposits to slough from the pipe wall. This work used a force meter with a cylindrical "pig-style" probe mounted to a single axis motorized test stand to measure the force required to dislodge model THF structure II hydrate plugs in carbon steel pipes. Profilometry measurements were used to quantify the mean surface roughness and relative peak frequency of the pipe surfaces. Contact angle measurements were performed of a water droplet on pristine, sanded, and corroded pipe surfaces immersed in nonpolar solvents. The adhesive shear strength of the hydrate plugs was measured for different subcoolings, solid surface roughness, and surface wettabilities. Subcooling was shown to impact the hydrate-solid adhesive shear strength, and a mixed adhesive/cohesive failure mechanism was observed at the highest subcooling tested. The surface roughness and wettability were also shown to influence the hydrate-solid adhesive shear strength, with readily wetting corroded and sanded carbon steel surfaces resulting in greater interface adhesive strength than the pristine carbon steel system. This is likely due to a Wenzel wetting mode at the interface, resulting in a higher ratio of actual to apparent wetted area as well as establishing a mechanical interlocking mechanism.

Study on trapping behaviour of SiO2-containing droplets on the solid surface

The dynamic behaviour of droplets impacting solid surfaces exists in nature, production, and life. In this paper, for the first time, the molecular dynamics method is used to simulate capturing the behaviour of nanodroplets containing SiO2 on solid surfaces. The dynamic behaviour of nanodroplets impacting solid surfaces is analysed when the initial falling velocity v0 of the droplet is 0.3–1.5 nm·ps−1 and for different particle size ds, mass fraction φs of SiO2, and solid surfaces with various wettability. The contact angles of droplets containing SiO2 nanoparticles on the solid surface were measured, and the simulated values closely matched experimental results. The results show that the droplets on the smooth solid surface are completely captured after impact when v0 = 0.3–1.1 nm·ps−1. When v0 = 1.2–1.5 nm·ps−1, the droplet is fragmented, and the fragmentation ratio ns increases with the mass fraction φs. The droplet fragments when v0 = 1.4–1.5 nm·ps−1 on the rough solid surface when the ratio of the side length of the square column to the droplet diameter is 0.07, while the pure water droplet directly bounces and does not fragment. There is a linear relationship between the minimum height of the centre of mass and the mass fraction in the process of droplet impact. The maximum droplet’s spreading factor value in the spreading stage βmax increases with mass fraction φs and v0. When the spreading factor of droplets increases to βc ≈ 3.02, the droplet fragments. The droplet spreading presents the Wenzel state on the rough solid surface. Moreover, the pinning effect affects the droplet falling into the square column gap surface, hindering droplet spreading. Therefore, the rough surface has better catching ability for the droplet than the smooth surface, while the speed range that can be caught is larger. These results provide a theoretical basis for related engineering applications.

Microvesicle-Embedded Solid-liquid Composite Coating for the Tribological Behavior Regulation and Long-Acting Lubrication.

Friction interfaces in liquid-embedded composite lubrication coatings commonly comprise a combination of discontinuous fluid films and rough solid contact surfaces, which together ensure easy shearing and a prolonged wear life. However, achieving high efficacy in mixed lubrication poses a challenge due to the conflicting nature of enhanced migration freedom for the liquid lubricant and increased mechanical strength of the solid matrix. Recent efforts have focused on incorporating reinforcing fillers to develop multicomponent, multiphase composites that can address this paradox. Here, we describe a modified attapulgite (APT) with strong biphasic wettability via the oil decompressive osmosis treatment on APT nanocontainers grafted with long nonpolar alkyl chains. This modified APT enables control over the size, distribution, and mobility of lubricant droplets by constructing a Pickering emulsion and toughens the solid-phase matrix through dispersion strengthening. Additionally, the introduction of APT induces the formation of a solid tribofilm during friction, which possesses a higher oil adsorption capacity, as verified through first-principles calculations based on density functional theory (DFT). Consequently, the fluid films can be replenished by the fracture of nanocontainers and adsorption from the bulk phase; further comprehensive and effective regulation of the friction interface leads to low friction and wear.

Increase in the efficiency of electricity production with a thermoelectric generator (TEG)

Currently used TEG modules have low efficiency of about 5%. The energy generated by the TEG module depends on the temperature difference between the module surfaces. Heat exchange between the heat source and the module surface takes place through the contact between two rough solid surfaces. This creates contact resistance. It can be reduced by using a substance filling the empty spaces between the contact surfaces and applying pressure. During the tests, the efficiency of electricity generation with a thermoelectric generator was measured (TEG) at various pressure forces. The tests were carried out at a pressure force of 250 N, 500 N, 750 N and 1000 N. The selected values of pressure do not exceed the limit value arising from the thermoelectric generator (TEG) design. A copper element constituting the heat source was heated in a furnace. Next, it was pressed at an adequate force to the generator, which was placed on a water cooler. The impact of conductive materials placed between the faces of the heat source and the TEG on the generation of electricity was examined. At low forces, the use of a thermal pad as an intermediary substance does not result in improved heat transfer in the heat source—TEG generator system. Better filling of voids is provided by thermally conductive paste due to its properties.

Statistical laws of stick-slip friction at mesoscale

Friction between two rough solid surfaces often involves local stick-slip events occurring at different locations of the contact interface. If the apparent contact area is large, multiple local slips may take place simultaneously and the total frictional force is a sum of the pinning forces imposed by many asperities on the interface. Here, we report a systematic study of stick-slip friction over a mesoscale contact area using a hanging-beam lateral atomic-force-microscope, which is capable of resolving frictional force fluctuations generated by individual slip events and measuring their statistical properties at the single-slip resolution. The measured probability density functions (PDFs) of the slip length δxs, the maximal force Fc needed to trigger the local slips, and the local force gradient {k}^{{prime} } of the asperity-induced pinning force field provide a comprehensive statistical description of stick-slip friction that is often associated with the avalanche dynamics at a critical state. In particular, the measured PDF of δxs obeys a power law distribution and the power-law exponent is explained by a new theoretical model for the under-damped spring-block motion under a Brownian-correlated pinning force field. This model provides a long-sought physical mechanism for the avalanche dynamics in stick-slip friction at mesoscale.

Flow Regimes and Types of Solid Obstacle Surface Roughness in Turbulent Heat Transfer Inside Periodic Porous Media

Flow Regimes and Types of Solid Obstacle Surface Roughness in Turbulent Heat Transfer Inside Periodic Porous Media

Wetting model of rough solid surfaces and the effect of aggregate properties on epoxy resin binder-aggregate interface wetting

In order to study the effect of aggregate characteristics on the wetting of epoxy resin binder-aggregate interface, based on the Wenzel model and Cassie model, this paper established a new wetting model of the irregular rough surface. The model regularizes the rough solid surface and can calculate the wetting depth and apparent contact angle between different irregular rough solids and liquids. The texture parameters of aggregates, the surface tension of test liquids and the contact angles of different liquids-aggregates were tested by laser confocal tester and optical contact angle measuring instrument. It was found that the surface texture parameters of different aggregates were quite different. The relative error between the apparent contact angle calculated by the prediction model and the contact angle measured by the test was less than 15 %, indicating that the prediction model had excellent prediction effect. Through the analysis of the wetting model, it is found that the surface tension of the test liquid, the lithology of the solid aggregate, the surface roughness and the texture structure are the important control parameters affecting the wetting. The surface morphology of rough solid can be designed by changing the resolution k and depth H of micropores, so as to control the wettability of solid aggregate surface and epoxy resin aggregate.

High speed water droplet impact erosive behavior on dry and wet pulsed waterjet treated surfaces

During water droplet impact onto a dry or wet rough solid surface, several phenomena affect the surface erosion process, such as splashing, crown formation, and small droplet emission to name a few. These phenomena have been extensively studied for various simple target surface geometries. However, droplet impact studies on complex irregular and asymmetric target surface topographies resulting from a waterjet treatment have never been conducted. Furthermore, very limited reports are found on the role of target surface topography and water droplet deformation development on the resulting target stress state. In the present study, high speed droplet impingements on surfaces exhibiting coarse topographical features associated with ultrasonic pulsed waterjet treatment are modeled to understand the underlying mechanisms causing erosion. Impacts on surfaces with various roughness values and water film thicknesses are modeled using a three-dimensional coupled Eulerian–Lagrangian approach. A detailed comparative analysis of the model with experimental ultrasonic pulsed waterjet erosion features and material loss is provided. It was found that the synclastic curvature of the modeled coarse surface features increases the shock wave's strength as many compression wavelets are simultaneously emitted at each water droplet contact location with the surface, resulting in concentrated high-pressure zones. The ultrasonic pulsed waterjet treated surface features and water film thickness also greatly influence the onset of water droplet splashing, subsequent finger, secondary droplet characteristics, and crown stability. According to the numerical results, strong splashing patterns and droplet breakup are generated and create high stress zones capable of accelerating surface erosion, explaining the enhanced performance of ultrasonic pulsed waterjet process.

Determining air-water interfacial areas for the retention and transport of PFAS and other interfacially active solutes in unsaturated porous media

The objective of this work was to determine the methods that produce the most representative measurements and estimations of air-water interfacial area specifically for the retention and transport of PFAS and other interfacially active solutes in unsaturated porous media. Published data sets of air-water interfacial areas obtained with multiple measurement and prediction methods were compared for paired sets of porous media comprising similar median grain diameters, but one with solid-surface roughness (sand) and one without roughness (glass beads). All interfacial areas produced with the multiple diverse methods were coincident for the glass beads, providing validation of the aqueous interfacial tracer-test methods. The results of this and other benchmarking analyses demonstrated that the differences in interfacial areas measured for sands and soil by different methods are not due to errors or artifacts in the methods but rather the result of method-dependent differential contributions of solid-surface roughness. The contributions of roughness to interfacial areas measured by interfacial tracer-test methods were quantified and shown to be consistent with prior theoretical and experiment-based investigations of air-water interface configurations on rough solid surfaces. Three new methods for estimating air-water interfacial areas were developed, one based on the scaling of thermodynamic-determined values and the other two comprising empirical correlations incorporating grain diameter or NBET solid surface area. All three were developed based on measured aqueous interfacial tracer-test data. The three new and three existing estimation methods was tested using independent data sets of PFAS retention and transport. The results showed that the method based on treating air-water interfaces as smooth surfaces as well as the standard thermodynamic method produced inaccurate air-water interfacial areas that failed to reproduce the multiple measured PFAS retention and transport data sets. In contrast, the new estimation methods produced interfacial areas that accurately represented air-water interfacial adsorption of PFAS and associated retention and transport. The measurement and estimation of air-water interfacial areas for field-scale applications is discussed in light of these results.

Effects of solid particle surface roughness on particle velocity fluctuation in multi-zone waste heat recovery heat exchanger

The velocity fluctuation affects the safe operation of the heat exchanger when the particles flow through the heat exchanger. The particle flow model of heat exchanger is established based on the discrete element method to investigate the correlation between surface roughness and particle velocity fluctuation. Many studies have used static friction coefficients to characterize the particle roughness. The particle velocity fluctuation in heat exchanger is analyzed, and the effects of the static friction coefficient on the particle velocity fluctuation are studied. The results showed that when the particles flow stably, the force chain structure between the particles is a process of breaking and rapidly reconstructing. This force characteristic of the particles causes the constant fluctuation of the particle velocity, which fluctuation frequency varies from 0.05 Hz to 0.08 Hz. The velocity fluctuations of the particles located at the top of the heat exchanger are particularly violent. The direction of the force chain distribution gradually moves horizontally with the increase of the static friction coefficient, and the velocity fluctuation in the vertical orientation becomes more intense. The amplitude of velocity fluctuation increases from 0.6 × 10−3 m/s to 1.3 × 10−3 m/s. The results are helpful to understand the dynamic behavior of particle in heat exchanger during flow and provide the basis for subsequent improvements.

Dynamics of Sliding Friction between Laser-Induced Periodic Surface Structures (LIPSS) on Stainless Steel and PMMA Microspheres.

In this work, we investigated the sliding friction measured between poly(methyl methacrylate) (PMMA) colloidal probes with two different diameters D (1.5 and 15 μm) and laser-induced periodic surface structures (LIPSS) on stainless steel with periodicities Λ of 0.42 and 0.9 μm, when the probes are elastically driven along two directions, perpendicular and parallel to the LIPSS. The time evolution of the friction shows the characteristic features of a reverse stick-slip mechanism recently reported on periodic gratings. The morphologies of colloidal probes and modified steel surfaces are geometrically convoluted in the atomic force microscopy (AFM) topographies simultaneously recorded with the friction measurements. The LIPSS periodicity is only revealed with smaller probes (D = 1.5 μm) and when Λ takes the largest value of 0.9 μm. The average value of the friction force is found to be proportional to the normal load, with a coefficient of friction μ varying between 0.23 and 0.54. The values of μ are rather independent of the direction of motion, and they reach their maximum when the small probe is scanned on the LIPSS with the larger periodicity. The friction is also found to decrease with increasing velocity in all cases, which is attributed to the corresponding decrease of the viscoelastic contact time. These results can be used to model the sliding contacts formed by a set of spherical asperities of different sizes driven on a rough solid surface.

Experimental study of the mechanism of nanofluid in enhancing the oil recovery in low permeability reservoirs using microfluidics

Due to the low porosity and low permeability in unconventional reservoirs, a large amount of crude oil is trapped in micro-to nano-sized pores and throats, which leads to low oil recovery. Nanofluids have great potential to enhance oil recovery (EOR) in low permeability reservoirs. In this work, the regulating ability of a nanofluid at the oil/water/solid three-phase interface was explored. The results indicated that the nanofluid reduced the oil/water interfacial tension by two orders of magnitude, and the expansion modulus of oil/water interface was increased by 77% at equilibrium. In addition, the solid surface roughness was reduced by 50%, and the three-phase contact angle dropped from 135° (oil-wet) to 48° (water-wet). Combining the displacement experiments using a 2.5D reservoir micromodel and a micro-channel model, the remaining oil mobilization and migration processes in micro-to nano-scale pores and throats were visualized. It was found that the nanofluid dispersed the remaining oil into small oil droplets and displaced them via multiple mechanisms in porous media. Moreover, the high strength interface film formed by the nanofluid inhibited the coalescence of oil droplets and improved the flowing ability. These results help to understand the EOR mechanisms of nanofluids in low permeability reservoirs from a visual perspective.

Interfacial Instability-Induced (3I) Adhesives through "Mediator" Solvent Diffusion for Robust Underoil Adhesion.

Underoil adhesives are intensively needed in case of oil spill caused by pipeline rupture, but remain a challenge owing to the obstruction of oil layer or their swelling in oil. Herein, a general solvent diffusion principle is demonstrated by introducing dual-soluble "mediator" solvents to develop a new type of interfacial instability-induced (3I) adhesives, achieving effective underoil adhesion on various substrates and blocking the oil leakage within seconds. Microscopic characterization reveals a fast and dynamic solvent exchange process that destroys the oil layer by liquid-liquid interfacial diffusion between the "mediator" solvent and oil, enabling 3I adhesives to contact the solid surfaces directly. The principle of interfacial instability-induced liquid replacement is quite different from typical immiscible liquid replacement and is not restricted by the surface tension of solvents, surface energy, and roughness of solid surfaces, successfully directing the construction of a series of effective 3I adhesives with commercially available feedstocks. This study provides a unique clue for the design of next-generation adhesives in complex environments.

Tailoring intrinsic hydrophobicity and surface energy on rough surface via low‐T Cassie–Wenzel wetting transition method

AbstractWettability is an important parameter of micro/nanostructured composites. The measurement of apparent contact angle is strongly affected by surface roughness, which induces some challenges to study the intrinsic hydrophobicity correlating to the nature of chemistry. Carbon‐Nafion composites exhibited about 30° decrease in apparent contact angle from 30 to 10°C due to the condensation of water vapor into cavities, suggesting a significant Cassie–Wenzel wetting transition phenomenon. The focus of this work has been on the first‐time use of a low‐T Cassie–Wenzel wetting transition method to evaluate Young's (ideal) contact angle and surface free energy. A maximum Young's contact angle (113°) and minimum total surface energy (12 mJ/m2) were determined at Nafion content of 70 wt%, indicating the orientation effect that sulfonate groups in Nafion preferentially pointed toward polar carbon. This approach provided the reasonable prediction of intrinsic hydrophobicity, especially when a rough solid surface is not easily wetted by liquids.

Interfacial Segregation, Structure, and Diffusion ofn-Alkane Mixture Films Adsorbed on Smooth and Rough Gold Surfaces

The compositional, structural, and diffusional properties of equal-weight mixtures of liquid n-hexane and n-hexadecane films supported on atomically smooth and rough gold surfaces are explored with the use of temperature-controlled, canonical, molecular dynamics simulations at 315 K. Preferential adsorption of n-hexadecane molecules is found in the region next to the solid surface. The selective molecular segregation effect is much stronger at the smooth Au(111) surface, where it is accompanied by pronounced layering exhibited in the density profile of the adsorbed film normal to the surface, which shows the formation of two well-defined interfacial liquid layers. For both the smooth and rough solid surfaces, in the region of the first layer located about 5 Å from the solid surface, the alkane molecules order with their axis oriented parallel to the adsorbing surface, thus maximizing the attractive physisorption energy. The orientational ordering is accompanied by the formation of ordered domains in the first liquid-film layer, with the molecules in each domain lying parallel to each other. The interfacial domain ordering is frustrated in the alkane mixture film adsorbed on the rough surface. Reduced diffusive motion is found for molecules located near the solid surfaces. However, in the region of the first adsorbed layer of the liquid film adsorbed on the smooth surface, the rate of diffusion, particularly of the hexane molecules, is larger than at the rough surface. It is found that the smaller, hexane, molecules diffuse through channels at the boundaries between the ordered domains formed by the hexadecane molecules. For the rough surface case, where the domain ordering is frustrated, such interdomain boundary channels do not form and consequently the domain boundary-assisted diffusion of the smaller molecules is not operative there, resulting in a smaller diffusion rate.

Confinement Effects on the Spatially Inhomogeneous Dynamics in Metallic Glass Films.

This work develops the elastically collective nonlinear Langevin equation theory to investigate, for the first time, the glassy dynamics in capped metallic glass thin films. Finite-size effects on the spatial gradient of structural relaxation time and glass transition temperature (Tg) are calculated at different temperatures and vitrification criteria. Molecular dynamics is significantly slowed down near rough solid surfaces, and the dynamics at location far from the interfaces is sped up. In thick films, the mobility gradient normalized by the bulk value obeys the double-exponential form since interference effects between two surfaces are weak. Reducing the film thickness induces a strong dynamic coupling between two surfaces and flattens the relaxation gradient. The normalized gradient of the glass transition temperature is independent of vitrification time scale criterion and can be fitted by a superposition function as the films are not ultrathin. The local fragility is found to remain unchanged with location. This finding suggests that one can use Angell plots of bulk relaxation time and the Tg spatial gradient to characterize glassy dynamics in metallic glass films. Our computational results agree well with experimental data and simulation.

A solution for mixed elastohydrodynamic lubrication modeling considering effects of solid particles and surface roughness

To investigate the effects of solid particles on the point contact mixed lubrication, this paper aims to introduce solid particles into rough interfaces under mixed hydrodynamic lubrication. Statistical three-body micro-contact is utilized in modeling mixed EHL. The model is verified by comparing results without considering particles and roughness with those from classical EHL formula. Factors, such as particle physical parameters, surface roughness and operating condition acting on the system are discussed. The results show that the distribution of hydrodynamic pressure and oil film thickness on the point contact with particles still show typical characteristics of elastohydrodynamic lubrication. The physical parameters of particles and operating condition change the proportion of each part to the load carrying capacity, where an increase in particle size, concentration and surface orientation parameters increases the load ratio of particle and conversely an increase in surface roughness and sliding velocity decreases it. Both an increase in particle size and surface roughness result in an increase in the minimum oil film thickness, with the effect of surface roughness being more significant. In addition, the shear strength, size and concentration of the particles play an important role in the friction characteristics.

How surface roughness promotes or suppresses drop splash

This work presents an experimental study on the splashing behaviors of drops impinging on rough solid surfaces. Most prior studies have shown the increase in surface roughness can promote the occurrence of a drop splash. Interestingly, we found two opposite effects of surface roughness on the drop splash that the increase in surface roughness can promote splash of low-viscosity drops but suppress splash of high-viscosity drops. According to the wetting state of the spreading lamella on rough surfaces, the splash regime can be classified into two modes: corona splash and prompt splash. It is found that the increase in surface roughness can promote the prompt splash but suppress the corona splash. The increase in surface roughness could provide wide channels for air to escape and suppress the corona splash. Meanwhile, the larger surface roughness could also disrupt the expanding lamella and promote the prompt splash. The dimensionless parameter Ohr can be used to distinguish two splash regimes, and the critical value Ohrc is obtained from experimental results, at which the splash regime changes from the prompt to corona splash. Emphatically, we obtain the splash criteria in two regions, which could reflect the opposite effects of surface roughness on the drop splash and successfully characterize the splashing behaviors in this work and previous studies. The results of this work are expected to provide valuable insights to control the drop splash in industrial applications.

Robust electrical contacts integrating a liquid metal bridge for mechanical switches

Intrinsic roughness of solid surfaces causes a series of inevitable shortcomings in the use of mechanical electrical contacts, among which one of the most fatal is the repulsive electrodynamic force arising from high currents. A large contact force coming from a heavy holding mechanism helps to suppress the repulsive effect whereas the mechanism consumes energy and remains to be challenging for a compact switching device. Here, a liquid metal (LM) bridge is introduced to wet solid electrodes to eliminate contact issues. Four instability patterns induced by the electromagnetic pinch effect are identified to characterize LM bridge’s response to high currents. Simulation results reveal that an inner vortex caused by uneven distributions of current density and electrodynamic volume force leads to the rupture of a necked LM bridge. With a uniform structure, a cylindrical LM bridge is proved to be robust with respect to an impulse current higher than 10 kA, exceeding a commercial compact relay by a factor of more than 10 in terms of current withstand performance. Our research facilitates compact and energy-saving switch equipment and has a potential to realize arbitrary desired levels of high current withstand without the use of a holding mechanism. This paper also offers deep insights into the high current applications of LM from the perspective of fluid related physical mechanisms.

Prediction of nanoscale thermal transport and adsorption of liquid containing surfactant at solid–liquid interface via deep learning

HypothesisRecent advances in deep learning (DL) have enabled high level of real-time prediction of thermophysical properties of materials. On the other hand, molecular dynamics (MD) have been long used as a numerical microscope to observe detailed interfacial conditions but require separate simulations that are computationally costly. Hence, it should be possible to combine MD and DL to obtain high resolution interfacial details at a low computational cost. ExperimentWe proposed a novel DL encoding–decoding convolutional neural network (CNN) coupled with MD to realize the mapping from micro solid–liquid interface geometry to molecular temperature and density distribution of liquid containing surfactant. A multi-nanoscale optimization scheme was further proposed to reduce the uncertainty of DL prediction at the expense of local details to obtain more resilient predictors. FindingsThe statistical results showed that the proposed CNN had high prediction accuracy and could reproduce the heat transfer and adsorption phenomena under the influence of various factors including liquid composition, wettability, and solid surface roughness, while the computational efficiency was greatly improved. Our DL method with the support of multi-nanoscale learning strategies can achieve the fast and accurate visualization and prediction of various interfacial properties of liquid and assist for interfacial material design.