Rotary dehumidification, a key method for continuous solid adsorption dehumidification, is extensively utilised in various industrial and practical applications. The performance of the adsorbent within the desiccant wheel is a major determinant of its energy efficiency in practical applications. While studies on Metal Organic Frameworks (MOFs) and polymer desiccant wheels exist, the majority of rotary dehumidification systems continue to employ traditional adsorbents like silica gel and zeolite, which are plagued by low dehumidification capacity and high energy consumption issues. Super hygroscopic hydrogel, enhanced with a hygroscopic agent, has gained prominence in air treatment because of its outstanding hygroscopicity and low regeneration temperature. With the goal of integrating advanced materials into practical engineering applications and mitigating the heat and mass transfer loss and adsorption/desorption performance degradation due to volume expansion and viscous agglomeration post-water uptake in large-scale super hygroscopic hydrogel applications, this study successfully developed a hydrogel wheel, measuring 350 mm in diameter and 200 mm in thickness, using a honeycomb-shaped glass fibre paper substrate. Experimental findings demonstrate that the hydrogel desiccant wheel outperforms both the MOF and commercial low-temperature silica gel wheels under all tested environmental conditions. This advantage is particularly noticeable at 15 °C and 30 % Relative Humidity (RH), where the moisture content differential (Δd) in the hydrogel system is 2.96 g/kg, 1.89 times greater than the MOF system’s 1.56 g/kg and 5.19 times higher than the silica gel’s 0.57 g/kg. Furthermore, the controlled variable method was used to assess the impact of each operational parameter on the hydrogel wheel’s performance in both low and high moisture conditions, offering design insights for engineering applications.
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