Rondane Mountains Research Articles

Chrome-rich spinels in micrometeorites from modern Antarctic sedimentary deposits

Each year, approximately 5000 tons of extraterrestrial material reaches the Earth's surface as micrometeorites, cosmic dust particles ranging from 10 to 2000 μm in size. These micrometeorites, collected from diverse environments, mainly deep-sea sediments, Antarctic ice, snow and loose sediments, and hot deserts, are crucial in understanding our Solar System's evolution. Chrome-rich spinel (Cr-spinel) minerals have gained attention as proxies for studying the extraterrestrial flux in sedimentary deposits, because these robust minerals occur, in various extraterrestrial materials, with compositions characteristic of their parent bodies. A total of 27 Cr-spinel bearing micrometeorites within the size range of 185–800 μm, were identified from approximately 6000 micrometeorites from the Transantarctic Mountains (n = 23) and the Sør Rondane Mountains (n = 4), in Antarctica, containing Cr-spinel (8–120 μm), were examined in this study for geochemical composition and high-precision oxygen isotope ratios to assess alteration and identify potential parent bodies.Oxygen isotopes in the micrometeorite groundmass and in Cr-spinel grains reveal a predominance of ordinary chondritic precursors, with only 1 in 10 micrometeorites containing Cr-spinel minerals showing a carbonaceous chondritic signature. This may be further confirmed by an elevated Al content (> 12 wt% Al2O3) in Cr-spinel from specific carbonaceous chondrite types, but a more extensive dataset is required to establish definitive criteria. The first Cr-spinel bearing particle, in an Antarctic micrometeorite, that can be linked to R-chondrites based on oxygen isotopes, has been documented, demonstrating the potential for R-chondrites as a source of chrome-rich spinels. The study also highlights the potential for chemical modifications and alteration processes that Cr-spinel minerals may undergo during their time on the parent body, atmospheric entry, and terrestrial residence.In the context of the broader micrometeorite flux, the results align with previous findings, showing a consistent contribution of micrometeorites containing Cr-spinel minerals related to ordinary chondrites over the past 2 to 4 million years. This is however a small fraction (∼ 1 %) of the total micrometeorite flux. The study further confirms that Cr-spinel minerals recovered from sedimentary deposits serve as valuable proxies for tracking events related to ordinary chondritic or achondritic materials. However, it is emphasized that Cr-spinel minerals alone cannot serve as exclusive indicators of the overall extraterrestrial flux, especially during periods dominated by carbonaceous chondritic dust in the inner Solar System. To comprehensively understand the complete extraterrestrial flux, additional proxies are needed to trace dust-producing events associated with various Solar System objects. The intricate nature of Cr-spinel compositions, and the potential for alteration processes emphasize the need for further research to refine our understanding of these extraterrestrial markers.

Elemental and oxygen isotopic fractionation recorded in highly vaporized cosmic spherules from Widerøefjellet, Sør Rondane Mountains (East Antarctica)

AbstractUpon passage through Earth's atmosphere, micrometeorites undergo variable degrees of melting and evaporation. Among the various textural and chemical groups recognized among cosmic spherules, that is, melted micrometeorites, a subset of particles may indicate anomalously high degrees of vaporization based on their chemical and isotopic properties. Here, a selection of such refractory element‐enriched cosmic spherules from Widerøefjellet (Sør Rondane Mountains, East Antarctica) is characterized for their petrographic features, major and trace element concentrations (N = 35), and oxygen isotopic compositions (N = 23). Following chemical classification, the highly vaporized particles can be assigned to either the “CAT‐like” or the “High Ca‐Al” cosmic spherule groups. However, through the combination of major and trace element concentrations and oxygen isotopic data, a larger diversity of processes and precursor materials are identified that lead to the final compositions of refractory element‐enriched particles. These include fragmentation, disproportional sampling of specific mineral constituents, differential melting, metal bead extraction, redox shifts, and evaporation. Based on specific element concentrations (e.g., Sc, Zr, Eu, Tm) and ratios (e.g., Fe/Mg, CaO + Al2O3/Sc + Y + Zr + Hf), and variations of O isotope compositions, “CAT‐like” and “High Ca‐Al” cosmic spherules likely represent a continuum between mineral endmembers from both primitive and differentiated parent bodies that experienced variable degrees of evaporation.

Geology defines microbiome structure and composition in nunataks and valleys of the Sør Rondane Mountains, East Antarctica.

Understanding the relation between terrestrial microorganisms and edaphic factors in the Antarctic can provide insights into their potential response to environmental changes. Here we examined the composition of bacterial and micro-eukaryotic communities using amplicon sequencing of rRNA genes in 105 soil samples from the Sør Rondane Mountains (East Antarctica), differing in bedrock or substrate type and associated physicochemical conditions. Although the two most widespread taxa (Acidobacteriota and Chlorophyta) were relatively abundant in each sample, multivariate analysis and co-occurrence networks revealed pronounced differences in community structure depending on substrate type. In moraine substrates, Actinomycetota and Cercozoa were the most abundant bacterial and eukaryotic phyla, whereas on gneiss, granite and marble substrates, Cyanobacteriota and Metazoa were the dominant bacterial and eukaryotic taxa. However, at lower taxonomic level, a distinct differentiation was observed within the Cyanobacteriota phylum depending on substrate type, with granite being dominated by the Nostocaceae family and marble by the Chroococcidiopsaceae family. Surprisingly, metazoans were relatively abundant according to the 18S rRNA dataset, even in samples from the most arid sites, such as moraines in Austkampane and Widerøefjellet ("Dry Valley"). Overall, our study shows that different substrate types support distinct microbial communities, and that mineral soil diversity is a major determinant of terrestrial microbial diversity in inland Antarctic nunataks and valleys.

Local spatial variability in the occurrence of summer precipitation in the Sør Rondane Mountains, Antarctica

Abstract. During the austral summer 2019/2020, three vertically pointing K-band Doppler profilers (Micro Rain Radar PRO, MRR-PRO) were deployed along a transect across the Sør Rondane Mountains, directly south of the scientific base Princess Elisabeth Antarctica. The MRR-PRO devices were placed at locations corresponding to different stages of the interaction between the complex terrain and the typical flow associated with precipitating systems. The radar measurements, alongside information from the ERA5 reanalysis and a set of high-resolution Weather Research and Forecasting (WRF) simulations, have been used to study the spatial variability in snowfall across the transect. Radar observations reveal differences in the frequency of occurrence of virga and surface precipitation above the transect. An analysis of the WRF outputs reveals the presence of a relatively dry layer above the radar locations, reaching a constant altitude of 3.5 km above mean sea level. Due to the complex terrain, the depth of the layer varies across the transect, affecting sublimation and the occurrence of virgae. Combined information from the ERA5 reanalysis, the WRF simulations, and ground-level measurements suggests that orographic lifting enhances precipitation above the highest mountain peaks. Finally, the analysis of the succession of virga and surface precipitation above the sites shows that, in most cases, they represent different stages of the same large-scale events. This study reveals the significant spatial variability in the occurrence of precipitation in a region of complex terrain, emphasizing the importance of collecting snowfall measurements in the mountainous regions of the Antarctic continent.

Geochemical characterization of scoriaceous and unmelted micrometeorites from the Sør Rondane Mountains, East Antarctica: Links to chondritic parent bodies and the effects of alteration

Micrometeorites originate from the interplanetary dust complex and continuously fall to the Earth’s surface in large amounts. About 10 to 20% of micrometeorites are not melted upon reaching the Earth’s surface, preserving the primary features and characteristics of the parent material. Consequently, unmelted micrometeorites, together with scoriaceous micrometeorites, an intermediate form between cosmic spherules and unmelted micrometeorites, are pivotal in documenting the nature and evolution of interplanetary dust as well as the modifications experienced by micrometeorites during atmospheric entry. Based on their petrographic features, here we identified and characterized 64 scoriaceous and unmelted micrometeorites with diameters varying between 90 and 410 μm from fine-grained sediment sampled in the Sør Rondane Mountains of East Antarctica. Based on their size distribution, the micrometeorites from the Sør Rondane Mountains show a clear distinction between unmelted micrometeorites (<300 μm) and cosmic spherules (>400 μm) and imply an accumulation mechanism or exposure history distinct from other collections (e.g., Transantarctic Mountains). Different exposure windows, weathering processes and environmental factors (e.g., snow cover) could affect the size and composition of preserved particles.A selection of the particles (n = 49) was further characterized for geochemical composition and high-precision oxygen isotope ratios to identify potential parent bodies and document their alteration histories. About 63% of the particles, exhibiting both coarse- and fine-grained textures, derive from carbonaceous chondritic precursors. Two particles (∼4%) display anomalously 16O-poor isotopic compositions similar to that previously observed for (giant) cosmic spherules and unmelted micrometeorites, classified as “group 4” particles. These particles are thought to originate from an unidentified chondritic parent body located in a specific region of the protoplanetary disk or may have been characterized by a distinct alteration history, with recent studies linking them to CY carbonaceous chondrites. Only a single fine-grained particle (∼2%) can be assigned to ordinary chondritic parentage with confidence. The partially hydrated fine-grained matrix suggests this particle might be consistent with a Semarkona-like parent body. Approximately 10% of the studied particles exhibit extensive evidence for secondary terrestrial weathering with formation of (hydr)oxides during residence in the Antarctic environment, preventing detailed parent body identification. Ten particles (∼20%) could not be assigned to a specific parent group due to ambiguous oxygen isotope values. Overall, the parent body statistics from this study agree with those reported for different collections of a similar size fraction. Clear associations between textural groups and parent bodies could not be established. Even though unmelted micrometeorites are generally considered pristine and often do not exhibit any obvious petrographic evidence of terrestrial weathering, the chemical and isotopic data obtained here confirm that alteration can occur at the microscale and any data on unmelted particles from Antarctic subaerial collections should be evaluated with caution.

Multiple timings of garnet-forming high-grade metamorphism in the Neoproterozoic continental collision zone revealed by petrochronology in the Sør Rondane Mountains, East Antarctica

The Sør Rondane Mountains (SRM), East Antarctica is located in a key area of Gondwana formation where the East African-Antarctic Orogen and the Kuunga Orogen cross. Timing of peak metamorphism has been considered at ca. 650–600 Ma in the SRM, on which previous tectonic models were built. In this study, timing of garnet-forming metamorphisms is determined using in situ U-Pb dating of zircon and petrochronological approach utilizing distribution coefficient of rare earth elements (DREE) between zircon and garnet and REE patterns of zircon. As a result, we obtained several different periods of garnet-forming metamorphism at ≥600 Ma and ≤580 Ma both from the NE- and SW-terranes. This is the first report of multiple timings of garnet formation detected within single samples from the SRM. The latest garnet formation in each sample is probably caused by regional metamorphism, because the garnets accompany pressure shadows and are wrapped by the penetrative foliation defined mainly by the arrangement of biotite. Therefore, multiple timings of garnet formation during a single metamorphism or polymetamorphism are both likely. In the former case, the SRM may be affected by a single long-lived regional metamorphism. This implies that the regional metamorphism belongs only to the East African-Antarctic Orogeny or that the East African Orogeny continuously transformed into the Kuunga Orogeny in the deep crust. In the latter case, the former regional metamorphism corresponds to the East African(-Antarctic) Orogeny, whereas the latest metamorphism may correspond to the final stage of East African-Antarctic Orogeny or the Kuunga Orogeny. Any temperature drops during these two garnet-forming timings support the polymetamorphism, which needs to be cleared in the future works.

High-K adakitic granite in post-Gondwana collisional stage: example for the Vengen Granite, Sør Rondane Mountains, East Antarctica

High-K adakitic granite in post-Gondwana collisional stage: example for the Vengen Granite, Sør Rondane Mountains, East Antarctica

Multiple post-peak metamorphic fluid infiltrations in southern Perlebandet, Sør Rondane Mountains, East Antarctica

This paper reports multiple fluid infiltration events during retrograde metamorphism in the Sør Rondane Mountains, East Antarctica. Pelitic gneisses from southern part of Perlebandet have cordierite-biotite intergrowth rimming garnet, implying that garnet breakdown occurred by fluid infiltration. Using the Raman peak of CO2 in cordierite and Cl-bearing composition in biotite, this study revealed that the cordierite-biotite intergrowth was formed in equilibrium with one-phase CO2-Cl-H2O fluid. The intergrowth texture is cut by thin selvages composed of Cl-bearing biotite, suggesting Cl-bearing fluid infiltration. Since andalusite is exclusively observed in the selvage, near isobaric cooling path is presumed for the pressure-temperature (P-T) path of these post-peak fluid-related reactions. The inconsistence with counter-clockwise P-T path reported from northern Perlebandet is probably due to the granodiorite/leucocratic granite bodies beneath the studied metamorphic rocks. In order to understand the tectonic evolution at the final stage of Gondwana amalgamation, therefore, effect of hidden igneous rocks needs to be taken into consideration.

Metamorphic rocks with different pressure-temperature-time paths bounded by a ductile shear zone at Oyayubi ridge, Brattnipene, Sør Rondane Mountains, East Antarctica

Metamorphic rocks with different pressure-temperature-time paths bounded by a ductile shear zone at Oyayubi ridge, Brattnipene, Sør Rondane Mountains, East Antarctica

Tectonic division of the Southwestern terrane at the western Sør Rondane Mountains, Dronning Maud Land, East Antarctica, from a viewpoint of zircon U-Pb ages

Tectonic division of the Southwestern terrane at the western Sør Rondane Mountains, Dronning Maud Land, East Antarctica, from a viewpoint of zircon U-Pb ages

Characterization of achondritic cosmic spherules from the Widerøefjellet micrometeorite collection (Sør Rondane Mountains, East Antarctica)

Achondritic micrometeorites represent one of the rarest (ca. 0.5–2.1%) particle types among Antarctic micrometeorite collections. Here, we present major, trace element and oxygen isotope compositions on five vitreous, achondritic cosmic spherules (341–526 µm in size) recovered from the Widerøefjellet sedimentary trap in the Sør Rondane Mountains (SRMs) of East Antarctica. We also present the first iron isotope data for four of these achondritic cosmic spherules. The particles were initially identified based on the atomic concentrations of Fe-Mg-Mn and their distribution in Fe/Mg versus Fe/Mn space, spanning a relatively wide range in Fe/Mg ratios (ca. 0.48–1.72). The Fe/Mn ratios cover a more restricted range (22.4–31.7), comparable to or slightly below the values measured for howardite-eucrite-diogenite (HED) and martian meteorites. One particle (WF1801-AC3) displays an elevated Fe/Mn ratio of ∼78, comparable to the values determined for lunar rocks. The negative correlation observed between the CaO + Al2O3 contents and the Fe/Si ratios of achondritic spherules reflects both the mineralogy of the precursor materials, as well as the extent of volatilization experienced during atmospheric entry heating. This trend suggests that the primary mineralogy of precursor materials may have been compositionally similar to basaltic achondrites. Based on their distribution in Ca/Si versus Al/Si space, we argue that the majority of achondritic cosmic spherules predominantly sample pyroxene- and/or plagioclase-rich (i.e., basaltic) precursor bodies. Such precursor mineralogy is also inferred from their rare earth element (REE) patterns, which show resemblances to fine-grained basaltic eucrites or Type 1 achondritic spherules (n = 3 – av. REEN = 11.2–15.5, (La/Yb)N = 0.93–1.21), pigeonite-rich equilibrated eucrite precursors or Type 2 achondritic spherules (n = 1 – av. REEN = 27.9, (La/Yb)N = 0.10), and possibly Ca-phosphates from (primitive) achondritic bodies (n = 1 – av. REEN = 58.8, (La/Yb)N = 1.59). This is clearly demonstrated for particle WF1801AC-1, which was likely inherited from a fine-grained eucritic precursor body. The pre-atmospheric oxygen isotope composition was reconstructed through compensation of mass-dependent fractionation processes as well as mixing with atmospheric oxygen, using iron isotope data. Two particles (WF1801AC-2, WF1801-AC4) display corrected oxygen isotope compositions (δ18O = 3.7–4.4‰) largely consistent with HED meteorites and may thus originate from HED-like parent bodies. The corrected oxygen isotope compositions (δ18O = 12.6–12.8‰) of the remaining particles (WF1801-AC3, WF1801-AC5) do not correspond to known meteorite fields and may represent two distinct types of unknown achondritic parent bodies or residual atmospheric entry effects. Finally, the abundance (ca. 0.5%) of achondritic cosmic spherules within the Widerøefjellet sedimentary trap is comparable to that observed in the South Pole Water Well (SPWW – ca. 0.5%), Novaya Zemlya glacier (ca. 0.45%) and Transantarctic Mountain (TAM) (ca. 2.1%) collections, confirming their overall rarity in micrometeorite collections. Unambiguous evidence for micrometeorites from the Moon or Mars remains absent from collections to date.

Formation of corundum in direct contact with quartz and biotite in clockwise &lt;i&gt;P–T&lt;/i&gt; trajectory from the Sør Rondane Mountains, East Antarctica

We have found corundum in direct contact with quartz and biotite and as inclusions in garnet in the pelitic gneisses of northern Austkampane in the Northeastern (NE) Terrane of the Sør Rondane Mountains (SRM), East Antarctica. Our samples, which include corundum–bearing gneisses, show petrographic features such as staurolite inclusions in garnet, compositional zoning of orthoamphibole with Al decreasing toward the rims, and late–stage cordierite formation, and these features are characteristic of a clockwise P–T trajectory. The observations are consistent with the proposed regional clockwise P–T evolution of the NE Terrane in the SRM. The corundum and other inclusions observed in the garnet porphyroblasts are interpreted to have formed owing to either staurolite breakdown or metastable crystallization relative to kyanite prior to the peak metamorphism. The close association of biotite and quartz surrounding corundum inclusions suggests fluid– or melt–related processes. These petrographic features imply that the corundum and quartz (rarely observed in high–grade metamorphic rocks) formed as a result of metastable crystallization during the prograde stage of the clockwise P–T evolution of a continental collision zone.

Ultrahigh–temperature metamorphism and melt inclusions from the Sør Rondane Mountains, East Antarctica

This paper reports the first outcrop occurrence of an ultrahigh–temperature (UHT) metamorphic rock from the Sør Rondane Mountains (SRM), East Antarctica. A pelitic gneiss from Balchenfjella, eastern SRM, contains mesoperthite that gave UHT condition (>900 °C) by ternary feldspar thermometry. The UHT mesoperthite is present both in the matrix and as an inclusion in garnet. The garnet also has nanogranitoid inclusions next to the mesoperthite, which are interpreted to be an UHT melt. The re–integrated nanogranitoid composition is plotted in the primary phase region of quartz and classified as granite. Even crystallized nanogranitoids can provide appropriate original melt composition in the An–Ab–Or and Qz–Ab–Or spaces, whereas Mg concentration is enriched due to local retrograde Fe–Mg exchange reaction between the nanogranitoid inclusions and the host garnet. Although metamorphic rocks in the SRM are highly retrogressed, this study revealed that the microstructural evidence of UHT condition is partially preserved. Further investigation of timing and areal extent of UHT metamorphism helps us to understand the tectonic model of the SRM.

Towards physical habitat characterisation in the Antarctic Sør Rondane Mountains using satellite remote sensing

Ice-free areas occupy less than 0.25% of the Antarctic surface, and mainly occur along coastlines, or as inland nunataks protruding from the extensive ice sheet. Their extreme environment and geographical isolation have contributed to the evolution of highly adapted, and largely endemic terrestrial biota. Physical habitat mapping is important to identify the main drivers of spatial variation in soil biodiversity, to predict its response to climate change and to help conservation planning. In this paper we retrieved remotely sensed Land Surface Temperature (LST) and Digital Surface Models (DSM) for the Sør Rondane Mountains in East Antarctica from respectively the Thermal InfraRed Sensor (TIRS) on Landsat 8 and the Pléiades constellation of high resolution optical imagers. Satellite data were combined with ground truth temperature and elevation measurements with the aim to assess the performance of these remotely sensed data. Over a 2 year period, satellite derived LST corresponded to in situ temperature with Mean Average Difference (MAD) of −2.5 K, and Root Mean Squared Difference (RMSD) of 6.3 K. Lower biases were observed for periods when the data loggers were frozen or snow covered (MAD −1.8K) compared to intervals where the devices were not frozen (MAD −4 K), with larger scatter (RMSD 7 K) being observed during the latter. These larger MAD and RMSD are caused by the differential heating of the top of the gravel/rocks as observed by the satellite compared to their underside, where the loggers were installed, and are also impacted by the time step of the in situ logging (3 h) and the non–linear heating of the surface. In addition, for the different study sites different biases were observed as a result of the spatial resolution of the TIRS, depending on the composition, structure, geomorphology, and the surroundings of the logger position. Sites on a narrow rock outcrop (e.g. the Perlebandet and Utsteinen nunataks) show a negative bias due to the surrounding ice fields decreasing the satellite pixel average temperature compared to the in situ measured temperatures. For sites with a more extensive rock and gravel composition further away from the ice sheet (Dry and Yuboku Valleys), a positive bias was found as a result of the temperature differential between the exposed top and covered bottom of the rocks and gravel. The DSM derived from Pléiades (without bias correction) showed in general a bias of −6 m (MAD) and scatter of 9 m (RMSD) when compared to the Reference Elevation Model of Antarctica and IceSAT-1 LIDAR data. Lowest errors were also found here for the extensive Dry and Yuboku Valley sites (respectively −5 and 3 m MAD, 7 and 4 m RMSD). Correspondence with in situ logged GPS positions was slightly worse, with a positive bias of 12 m (MAD) and scatter of 15 m (RMSD) across the sites. An analysis on the basis of these LST and DSM datasets, show a clear separability of sites by their average temperature and solar exposition (in terms of slope and aspect) at the time of Landsat overpass. Due to the Landsat overpass times, the LST datasets are however strongly biased, and further work is needed for a better understanding of the light and temperature climate in the ice-free regions. This could for example be achieved by coupling the DSM to a solar irradiance and terrain shadowing model.

A large meteoritic event over Antarctica ca. 430 ka ago inferred from chondritic spherules from the Sør Rondane Mountains.

Large airbursts, the most frequent hazardous impact events, are estimated to occur orders of magnitude more frequently than crater-forming impacts. However, finding traces of these events is impeded by the difficulty of identifying them in the recent geological record. Here, we describe condensation spherules found on top of Walnumfjellet in the Sør Rondane Mountains, Antarctica. Affinities with similar spherules found in EPICA Dome C and Dome Fuji ice cores suggest that these particles were produced during a single-asteroid impact ca. 430 thousand years (ka) ago. The lack of a confirmed crater on the Antarctic ice sheet and geochemical and 18O-poor oxygen isotope signatures allow us to hypothesize that the impact particles result from a touchdown event, in which a projectile vapor jet interacts with the Antarctic ice sheet. Numerical models support a touchdown scenario. This study has implications for the identification and inventory of large cosmic events on Earth.

Evidence for the presence of chondrule‐ and CAI‐derived material in an isotopically anomalous Antarctic micrometeorite

AbstractWe report the discovery of a unique, refractory phase‐bearing micrometeorite (WF1202A‐001) from the Sør Rondane Mountains, East Antarctica. A silicate‐rich cosmic spherule (~400 µm) displays a microporphyritic texture containing Ca‐Al‐rich inclusion (CAI)‐derived material (~5–10 area%), including high‐Mg forsterite (Fo98‐99) and enstatite (En98‐99, Wo0‐1). The micrometeorite also hosts a spherical inclusion (~209 µm), reminiscent of chondrules, displaying a barred olivine texture. Oxygen isotopic compositions of the micrometeorite groundmass (δ17O = –3.46‰, δ18O = 10.43‰, ∆17O = –1.96‰) are consistent with a carbonaceous chondrite precursor body. Yet, a relict forsterite grain is characterized by δ17O = –45.8‰, δ18O = –43.7‰, ∆17O = –23.1‰, compatible with CAIs. In contrast, a relict low‐Ca pyroxene grain (δ17O = –4.96‰, δ18O = –4.32‰, ∆17O = –2.71‰) presumably represents a first‐generation silicate grain that accreted 18O‐rich gas or dust in a transient melting scenario. The spherical inclusion displays anomalous oxygen isotope ratios (δ17O = –0.98‰, δ18O = –2.16‰, ∆17O = 0.15‰), comparable to anhydrous interplanetary dust particles (IDPs) and fragments from Comet 81P/Wild2. Based on its major element geochemistry, the chondrule size, and oxygen isotope systematics, micrometeorite WF1202A‐001 likely sampled a carbonaceous chondrite parent body similar to, but distinct from CM, CO, or CV chondrites. This observation may suggest that some carbonaceous chondrite bodies can be linked to comets. The reconstructed atmospheric entry parameters of micrometeorite WF1202A‐001 suggest that the precursor particle originated from a low‐inclination, low‐eccentricity source region, most likely either the main belt asteroids or Jupiter family comets (JFCs).

Late Neoproterozoic–Cambrian magmatism in Dronning Maud Land (East Antarctica): U–Pb zircon geochronology, isotope geochemistry and implications for Gondwana assembly

Dronning Maud Land (DML) is a key area for the better understanding of the geotectonic history and amalgamation processes of the southern part of Gondwana. Here, we present comprehensive new zircon U–Pb–Hf–O, whole-rock Sm–Nd isotopic and geochemical data for late Neoproterozoic-Cambrian igneous rocks along a profile from central to eastern DML, which provides new insights into the crustal evolution and tectonics of the region. In central DML, magmatism dominantly occurred at 530–485 Ma, with 650–600 Ma charnockite and anorthosite locally distributed at its eastern periphery. In contrast, eastern DML experienced long-term and continuous granitic magmatism from ca. 650 Ma to 500 Ma. In central DML, the 650–600 Ma samples are characterized by highly elevated δ18O (7.5–9.5‰) associated with slightly negative to positive εHf(t) values (−1 to +3), indicating significant addition of high-δ18O crustal components, such as sedimentary material at the margin of the Kalahari Craton. Evolved Hf isotopic signatures (εHf(t) = −15 to −6) and moderately elevated O isotopic data (δ18O = 6–8‰) of the Cambrian granitic rocks from central DML indicate a significant incorporation of the pre-existing, old continental crust. In eastern DML, the suprachondritic Hf–Nd isotope signatures and moderate δ18O values of the late Neoproterozoic granites (650–550 Ma) from the Sør Rondane Mountains support the view that they mainly originated from crust of the Tonian Oceanic Arc Super Terrane (TOAST). The post-540 Ma granites, however, have more evolved Hf and Nd isotopic compositions, suggesting an increasing involvement of older continental components during Cambrian magmatism. Nd isotopes of the Cambrian granitic rocks in DML display an increasingly more radiogenic composition towards the east with model ages ranging from late Archean to Mesoproterozoic times, which is in line with the isotopic trend of the Precambrian basement in this region. The late Neoproterozoic (>600 Ma) igneous rocks in central and eastern DML were emplaced in two independent subduction systems, at the periphery of the eastern Kalahari Craton and somewhere within the Mozambique Ocean respectively. The accretion and assembly of the TOAST to the eastern margin of the Kalahari Craton and their collision with surrounding continental blocks was followed by extensive post-collisional magmatism due to delamination tectonics and orogenic collapse in the Cambrian. The late Neoproterozoic–Cambrian igneous rocks in DML thus record an orogenic cycle from subduction-accretion, continental collision to post-collisional process during and after the assembly of Gondwana.

Build-up and chronology of blue ice moraines in Queen Maud Land, Antarctica

Blue ice moraines are common supraglacial landforms in Antarctica and they are considered to record the ice volume fluctuations. In this study, we use photogrammetry and the analysis of multiple cosmogenic nuclides (10Be, 26Al, and in-situ 14C) in boulders on three blue ice moraines to explore the timing of ice volume fluctuations in the Sør Rondane Mountains, Queen Maud Land, and provide insights into the role of sediment sources in the reconstruction of their chronology. In the field, we observe that the blue ice moraines are composed of subglacially and supraglacially transported sediments. Cosmogenic 10Be and 26Al exposure ages of 14 surface samples, collected from boulders on three blue ice moraines, range from 15.4 ± 1.1 to 659.5 ± 33.9 ka. 26Al/10Be ratios vary between 3.53 ± 0.20 and 7.01 ± 0.32, and many of these ratios indicate complex exposure histories. In contrast, among nine in-situ 14C exposure ages, five vary between 4.2 ± 0.1 and 22.0 ± 1.3 ka, and four are saturated. We conclude that the accumulation of these blue ice moraines commenced before or during the global Last Glacial Maximum. Our results indicate that surficial sediment sources can yield exposure ages that are older than real exposure age, and exhibit a wider scatter. This can alter the reconstructed chronology of these landforms. The analysis of in-situ 14C has a high potential in tracking the pace of their evolution, especially since the Last Glacial Maximum.

Rapid fluid infiltration and permeability enhancement during middle–lower crustal fracturing: Evidence from amphibolite–granulite-facies fluid–rock reaction zones, Sør Rondane Mountains, East Antarctica

Permeability is a key control on fluid infiltration in the crust. However, quantitative geological constraints on crustal permeability are limited, particularly with regards to its temporal evolution. Here we constrain the permeability evolution in the middle–lower crust, based on metamorphic processes associated with fluid infiltration and crustal fracturing. We investigated mafic granulite and orthopyroxene–hornblende schist (opx–hbl schist) samples from Mefjell, Sør Rondane Mountains, East Antarctica. Millimetre-scale amphibolite-facies reaction zones occur along fractures in these rocks. In the mafic granulite, two zones were identified: (i) reaction zones (1–2 mm thick); and (ii) mafic granulite host rock. The opx–hbl schist sample can be divided into the following three zones: (i) actinolite–cummingtonite zones (1.4 mm thick); (ii) actinolite–orthopyroxene zones (1.6 mm thick); and (iii) host rock. These zones are evident from the modal mineralogy, reaction textures, and trace element profiles. The P–T conditions of fluid infiltration are estimated to be 0.55 GPa and 620 °C for the mafic granulite, and 0.3 GPa and 450 °C for the opx–hbl schist, respectively. Chlorine concentrations in apatite grains show a gradual decrease from the fractures towards the host rocks. Chlorine concentration profiles suggest that the dominant processes of chlorine transport were advection with minor diffusion for both samples. Based on these results, the timescales of fluid infiltration are constrained to be ~8 h for the mafic granulite and ~10 h for the opx–hbl schist. The pressure gradient across the reaction zones was estimated from the H2O activity in the reaction zones to be 2–15 MPa/mm. The permeability of the host rock and fractures were estimated to be 10−21–10−23 and 10−8–10−9 m2, respectively. Our results show that rapid infiltration of Cl-bearing fluids (~10 h) occurred due to a limited fluid flux from low-permeability (10−21–10−23 m2) host rocks. The low-permeability media led to fluid accumulation and further fracturing. The spatio-averaged permeability then increased by more than several orders of magnitude (10−10–10−16 m2) and the fluid pressure decreased. The contrasting permeability between the host rocks and fractures reveals permeability enhancements associated with crustal fracturing on timescales comparable to geophysical observations. Compared with average long-term (Myr) permeability estimates from previous studies (e.g., 10−18 m2), the permeability obtained from the fracture–reaction zone systems shows large fluctuations in the middle–lower crust (10−21–10−23 to 10−10–10−16 m2).

東南極セールロンダーネ山地，グラニュライト・角閃岩相反応帯における多元微量元素解析による含Cl流体の浸透の時間スケール

東南極セールロンダーネ山地，グラニュライト・角閃岩相反応帯における多元微量元素解析による含Cl流体の浸透の時間スケール