This paper proposes a systematic method for detecting surface defects (SDs) on specimens by performing a pilot hot (850°C–950°C) bar rolling test and suggests a processing map for billet-to-oval groove pass in bar rolling mills. Unlike previous studies, the specimens for the rolling test were prepared such that the billet surface became the surface of the specimens. A series of the rolling tests were performed at different temperature and area reduction ratios. Physical-chemical nondestructive testing was employed to detect SDs in the specimens before and after the rolling test. The depth of the SDs of the rolled specimens was measured using an optical microscope. The results revealed that the SDs depended both on the rolling parameters (temperature and reduction ratios) and the contact condition between the specimen and the roll groove during rolling, which is one of the characteristics of bar rolling that distinguishes it from flat rolling. The decrease in temperature caused an increase in the defect depth above the appropriate reduction ratio of 24.61% when the part of the specimen was in contact with the roll shoulder curve and the relief line of the oval roll groove. The proposed processing map presents a guiding path for operators in actual bar rolling mills to quickly determine a rolling condition (combination of temperature and reduction ratio), avoid SDs, and minimize defect depth within an acceptable range.