Rod-connected Diamond Structures Research Articles

Self-Assembly of Patchy Colloidal Rods into Photonic Crystals Robust to Stacking Faults.

Diamond-structured colloidal photonic crystals are much sought-after for their applications in visible light management because of their ability to support a complete photonic band gap (PBG). However, their realization via self-assembly pathways is a long-standing challenge. This challenge is rooted in three fundamental problems: the design of building blocks that assemble into diamond-like structures, the sensitivity of the PBG to stacking faults, and ensuring that the PBG opens at an experimentally attainable refractive index. Here we address these problems simultaneously using a multipronged computational approach. We use reverse engineering to establish the design principles for the rod-connected diamond structure (RCD), the so-called "champion" photonic crystal. We devise two distinct self-assembly routes for designer triblock patchy colloidal rods, both proceeding via tetrahedral clusters to yield a mixed phase of cubic and hexagonal polymorphs closely related to RCD. We use Monte Carlo simulations to show how these routes avoid a metastable amorphous phase. Finally, we show that both the polymorphs support spectrally overlapping PBGs. Importantly, randomly stacked hybrids of these polymorphs also display PBGs, thus circumventing the requirement of polymorph selection in a scalable fabrication method.

Observation of Complete Photonic Bandgap in Low Refractive Index Contrast Inverse Rod-Connected Diamond Structured Chalcogenides

Three-dimensional complete photonic bandgap materials or photonic crystals block light propagation in all directions. The rod-connected diamond structure exhibits the largest photonic bandgap known to date and supports a complete bandgap for the lowest refractive index contrast ratio down to $n_{high}/n_{low} \sim 1.9$. We confirm this threshold by measuring a complete photonic bandgap in the infrared region in Sn--S--O $(n\sim1.9)$ and Ge--Sb--S--O $(n\sim2)$ inverse rod-connected diamond structures. The structures were fabricated using a low-temperature chemical vapor deposition process via a single-inversion technique. This provides a reliable fabrication technique of complete photonic bandgap materials and expands the library of backfilling materials, leading to a wide range of future photonic applications.

Evidence of near-infrared partial photonic bandgap in polymeric rod-connected diamond structures.

We present the simulation, fabrication, and optical characterization of low-index polymeric rod-connected diamond (RCD) structures. Such complex three-dimensional photonic crystal structures are created via direct laser writing by two-photon polymerization. To our knowledge, this is the first measurement at near-infrared wavelengths, showing partial photonic bandgaps for this structure. We characterize structures in transmission and reflection using angular resolved Fourier image spectroscopy to visualize the band structure. Comparison of the numerical simulations of such structures with the experimentally measured data show good agreement for both P- and S-polarizations.