Rm CH Research Articles

Detection of antifreeze molecule ethylene glycol in the hot molecular core G358.93–0.03 MM1

ABSTRACT The identification of complex pre-biotic molecules using millimetre and submillimetre telescopes allows us to understand how the basic building blocks of life are formed in the universe. In the interstellar medium, ethylene glycol ($({\rm CH}_2{\rm OH})_{2}$) is the simplest sugar alcohol molecule, and it is the reduced alcohol of the simplest sugar-like molecule, glycolaldehyde (${\rm CH}_{2}{\rm OHCHO}$). We present the detection of the rotational emission lines of $aGg^{\prime }$ conformer of ethylene glycol ($({\rm CH}_2{\rm OH})_{2}$) towards the hot molecular core G358.93–0.03 MM1 using the Atacama Large Millimeter/Submillimeter Array. The estimated column density of $aGg^{\prime }$-$({\rm CH}_2{\rm OH})_{2}$ towards the G358.93–0.03 MM1 is (4.5$\pm 0.1)\times 10^{16}$ cm$^{-2}$ with an excitation temperature of 155$\pm$35 K. The abundance of $aGg^{\prime }$-$({\rm CH}_2{\rm OH})_{2}$ with respect to ${\rm H}_{2}$ is (1.4$\pm 0.5)\times 10^{-8}$. Similarly, the abundances of $aGg^{\prime }$-$({\rm CH}_2{\rm OH})_{2}$ with respect to ${\rm CH}_{2}{\rm OHCHO}$ and ${\rm CH}_{3}{\rm OH}$ are 3.1$\pm$0.5 and (6.1$\pm 0.3)\times 10^{-3}$. We compare the estimated abundance of $aGg^{\prime }$-$({\rm CH}_2{\rm OH})_{2}$ with the existing three-phase warm-up chemical model abundance of $({\rm CH}_2{\rm OH})_{2}$, and we notice the observed abundance and modelled abundance are nearly similar. We discuss the possible formation pathways of $aGg^{\prime }$-$({\rm CH}_2{\rm OH})_{2}$ towards the hot molecular cores, and we find that $aGg^{\prime }$-$({\rm CH}_2{\rm OH})_{2}$ is probably created via the recombination of two ${\rm CH}_{2}{\rm OH}$ radicals on the grain surface of G358.93–0.03 MM1.

Investigating the impact of reactions of C and CH with molecular hydrogen on a glycine gas-grain network

ABSTRACT The impact of including the reactions of C and CH with molecular hydrogen in a gas-grain network is assessed via a sensitivity analysis. To this end, we vary three parameters, namely, the efficiency for the reaction ${\rm C} + {\rm H}_2 \longrightarrow {\rm CH}_{2}$, and the cosmic ray ionization rate, with the third parameter being the final density of the collapsing dark cloud. A grid of 12 models is run to investigate the effect of all parameters on the final molecular abundances of the chemical network. We find that including reactions with molecular hydrogen alters the hydrogen economy of the network; since some species are hydrogenated by molecular hydrogen, atomic hydrogen is freed up. The abundances of simple molecules produced from hydrogenation, such as CH4, CH3OH, and NH3, increase, and at the same time, more complex species such as glycine and its precursors see a significant decrease in their final abundances. We find that the precursors of glycine are being preferentially hydrogenated, and therefore glycine itself is produced less efficiently.

Energetics of buoyancy-generated turbulent flows with active scalar: pure buoyant plume

A framework for the budget of Reynolds stress, temperature and density variations, turbulent mass flux and turbulent heat flux is presented for buoyancy-generated turbulent flows with a focus on turbulent plumes. The dynamical interactions between the turbulence generated from the velocity and thermodynamic fluctuations in thermal and heated gas plumes is studied. A large-eddy simulation tool has been used to simulate heavier and lighter than air plumes released from a circular heated source for high Reynolds number (Re). The budget equations are developed using a Favre-averaging approach. Both heated air plumes and heated gas plumes, namely, heated ${\rm SO}_2$ and heated ${\rm CH}_4$ plumes, are included in the study. The study focuses on addressing key questions – does the turbulence kinetic energy (TKE) spectrum follow the classical inertial $-5/3$ spectrum or is there a $-3$ buoyancy regime with a different scaling law? Fundamental pathways for generation of turbulence through velocity fluctuations, and temperature and density fluctuations are discussed. Analysis of the TKE and scalar variance budget equations has demonstrated that multiple mechanisms dominate the transport of Reynolds stresses, and in particular that correlations between the density and the velocity dominates the turbulence production mechanisms. Entrainment is connected to the turbulent transport and pressure-dilation processes.

Particle Production as a Function of Underlying-event Activity and Search for Jet-like Modifications in \(pp\), \(p\)–Pb, and Pb–Pb Collisions at \(\sqrt {s_{NN}}=5.02\)\thinspace TeV with ALICE

The similarity between small- and large-collision systems is explored using the charged-particle multiplicity in the transverse region, $N^{\rm T}_{\rm ch}$, which is sensitive to the underlying event. Measurements of charged-particle production as a function of $N^{\rm T}_{\rm ch}$ in pp, p-Pb and Pb-Pb collisions at $\sqrt{s_{\rm NN}}=5.02$ TeV in the toward, away and transverse regions are discussed. These three regions are defined relative to the track with the largest transverse momentum in the event ($p_{\rm T}^{\rm trig}$). The activity in the transverse region is subtracted from the activity in the toward and the away regions to search for jet-like modifications in small-collision systems. The jet-like signals are studied both as a function of $N^{\rm T}_{\rm ch}$ and $p_{\rm T}^{\rm trig}$. Results are compared with two general purpose Monte Carlo event generators: PYTHIA~8 and EPOS~LHC.

Constraints on Neutron Skin Thickness and Nuclear Deformations Using Relativistic Heavy-ion Collisions from STAR

In these proceedings, we present the measurements of neutron skin thickness and nuclear deformation using isobar $^{96}_{44}$Ru+$^{96}_{44}$Ru and $^{96}_{40}$Zr+$^{96}_{40}$Zr collisions at $\sqrt{s_{_{\rm NN}}}=200$ GeV by the STAR detector. The significant deviations from unity of the isobar ratios of elliptic flow $v_{2}$, triangular flow $v_{3}$, mean $p_{\rm T}$ fluctuations $\langle\delta p_{\rm T}^{2}\rangle/\langle p_{\rm T}\rangle^{2}$, and asymmetric cumulant ${\rm ac}_{2}\{3\}$ indicate large differences in their quadrupole and octuple deformations. The significant deviations of the isobar ratios of produced hadron multiplicity $N_{\rm ch}$, mean transverse momentum $\langle p_{\rm T}\rangle$, and net charge number $\Delta Q$ indicate a halo-type neutron skin for the Zr nucleus, much thicker than for the Ru nucleus, consistent with nuclear structure calculations. We discuss how we extract the neutron skin thickness, the symmetry energy slope parameter, and deformation parameters from data.

FAUST VI. VLA1623−2417 B: a new laboratory for astrochemistry around protostars on 50 au scale

ABSTRACT The ALMA (Atacama Large Millimeter Array) interferometer, with its unprecedented combination of high sensitivity and high angular resolution, allows for (sub-)mm wavelength mapping of protostellar systems at Solar system scales. Astrochemistry has benefitted from imaging interstellar complex organic molecules in these jet–disc systems. Here, we report the first detection of methanol (CH3OH) and methyl formate (HCOOCH3) emission towards the triple protostellar system VLA1623−2417 A1+A2+B, obtained in the context of the ALMA Large Programme FAUST (Fifty AU STudy of the chemistry in the disc/envelope system of solar-like protostars). Compact methanol emission is detected in lines from Eu = 45 K up to 61 K and 537 K towards components A1 and B, respectively. Large velocity gradient analysis of the CH3OH lines towards VLA1623−2417 B indicates a size of 0.11–0.34 arcsec (14–45 au), a column density $N_{\rm CH_3OH}$ = 1016–1017 cm−2, kinetic temperature ≥ 170 K, and volume density ≥ 108 cm−3. A local thermodynamic equilibrium approach is used for VLA1623−2417 A1, given the limited Eu range, and yields Trot ≤ 135 K. The methanol emission around both VLA1623−2417 A1 and B shows velocity gradients along the main axis of each disc. Although the axial geometry of the two discs is similar, the observed velocity gradients are reversed. The CH3OH spectra from B show two broad (4–5 km s−1) peaks, which are red- and blueshifted by ∼ 6–7 km s−1 from the systemic velocity. Assuming a chemically enriched ring within the accretion disc, close to the centrifugal barrier, its radius is calculated to be 33 au. The methanol spectra towards A1 are somewhat narrower (∼ 4 km s−1), implying a radius of 12–24 au.

Possible formation of a perfect fluid in pp, p–Pb, Xe–Xe and Pb–Pb collisions at the Large Hadron Collider energies: a color string percolation approach

Isothermal compressibility ($\kappa_{\rm T}$) is an important thermodynamic observable which gives information about the deviation of a system from perfect fluid behavior. In this work, for the first time we have estimated the isothermal compressibility of QCD matter formed in high energy hadronic and nuclear collisions using color string percolation model (CSPM), where we investigate the change in $\kappa_{\rm T}$ as a function of final state charged particle multiplicity and initial percolation temperature across various collision species. The estimated initial percolation temperature for different collision systems at different collision energies helps us to have a better understanding of the system at the initial phase of evolution. The comparison of the CSPM results for isothermal compressibility with that for the well known fluids, indicates that the matter formed in heavy-ion collisions might be the {\it closest perfect fluid} found in nature. This estimation complements the well-known observation of minimum shear viscosity to entropy density ratio for a possible QGP medium created in heavy-ion collision experiments. A threshold of pseudorapidity density of charged particles, $\langle dN_{\rm ch}/d\eta \rangle \geq 20 $ in the final state event multiplicity is observed, after which one may look for a possible QGP formation at the LHC energies.

The Late-Time Light Curves of Type Ia Supernovae: Confronting Models with Observations

Type Ia supernovae (SNe Ia) play a crucial role as standardizable candles in measurements of the Hubble constant and dark energy. Increasing evidence points towards multiple possible explosion channels as the origin of normal SNe Ia, with possible systematic effects on the determination of cosmological parameters. We present, for the first time, a comprehensive comparison of publicly-available SN Ia model nucleosynthetic data with observations of late-time light curve observations of SN Ia events. These models span a wide range of white dwarf (WD) progenitor masses, metallicities, explosion channels, and numerical methodologies. We focus on the influence of $^{57}$Ni and its isobaric decay product $^{57}$Co in powering the late-time ($t > 1000$ d) light curves of SNe Ia. $^{57}$Ni and $^{57}$Co are neutron-rich relative to the more abundant radioisotope $^{56}$Ni, and are consequently a sensitive probe of neutronization at the higher densities of near-Chandrashekhar (near-$M_{\rm Ch}$) progenitor WDs. We demonstrate that observations of one SN Ia event, SN 2015F is only consistent with a sub-$M_{\rm Ch}$ WD progenitor. Observations of four other events (SN 2011fe, SN 2012cg, SN 2014J, SN2013aa) are consistent with both near-$M_{\rm Ch}$ and sub-$M_{\rm Ch}$ progenitors. Continued observations of late-time light curves of nearby SNe Ia will provide crucial information on the nature of the SN Ia progenitors.

English

In this paper we study sums and products in a field. Let $F$ be a field with ${\rm ch}(F)\not=2$, where ${\rm ch}(F)$ is the characteristic of $F$. For any integer $k\ge4$, we show that each $x\in F$ can be written as $a_1+\ldots+a_k$ with $a_1,\ldots,a_k\in F$ and $a_1\ldots a_k=1$ if ${\rm ch}(F)\not=3$, and that for any $\alpha\in F\setminus\{0\}$ we can write each $x\in F$ as $a_1\ldots a_k$ with $a_1,\ldots,a_k\in F$ and $a_1+\ldots+a_k=\alpha$. We also prove that for any $x\in F$ and $k\in\{2,3,\ldots\}$ there are $a_1,\ldots,a_{2k}\in F$ such that $a_1+\ldots+a_{2k}=x=a_1\ldots a_{2k}$.

Hunting for QCD instantons at the LHC in events with large rapidity gaps

We outline a strategy of how to search for QCD instantons of invariant mass 20 -- 60 GeV in diffractive events in low luminosity runs at the LHC. We show that by imposing appropriate selection criteria on the final states, one can select the kinematic regime where the instanton signal exceeds the background by a factor of at least 8. In spite of the relatively strong cuts that we impose on the total transverse energy and the number of charged tracks, $\sum_i E_{T,i}>15$ GeV, $N_{\rm ch}>20$ measured within the $0<\eta<2$ interval and excluding events with high $p_{T}$ particles, the expected cross-section is sufficiently large to study the instanton production in the events with Large Rapidity Gaps at low luminosities, thus avoiding problems with pile-up. The paper also includes an updated computation of instanton cross-sections and other parameters relevant for the ongoing studies.

Dark cloud-type chemistry in photodissociation regions with moderate ultraviolet field

ABSTRACT We present a study of emission lines of small hydrocarbons C2H and c-C3H2, and COMs precursors H2CO and CH3OH in order to better understand the possible chemical link between the molecular abundances and UV radiation field in photodissociation regions (PDRs). We study two PDRs around extended and compact H ii regions with G ≤ 50 Habings in the S235 star-forming complex. We find the highest abundances of both hydrocarbons on the edges of molecular clumps, while c-C3H2 is also abundant in the low-density expanding PDR around compact H ii region S235 A. We see the highest methanol column density towards the positions with the UV field G ≈ 20−30 Habings and explain them by reactive desorption from the dust grains. The $N_{\rm C_2H}/N_{\rm CH_3OH}$ ratio is lower by a factor of few or the order of magnitude in comparison with the Horsehead and Orion Bar PDRs. The ratio is similar to the value observed in hot corinos in the Perseus cloud. We conclude that ion-molecular and grain surface chemical routes rule the molecular abundances in the PDRs, and the PDRs inherit molecular abundances from the previous dark stage of molecular cloud evolution in spite of massive stars already emitting in optics.

Soft-Dielectron Excess in Proton-Proton Collisions at s=13 TeV

A measurement of dielectron production in proton-proton (pp) collisions at $\sqrt{s} = 13$ TeV, recorded with the ALICE detector at the CERN LHC, is presented in this Letter. The data set was recorded with a reduced magnetic solenoid field. This enables the investigation of a kinematic domain at low dielectron invariant mass $m_{\rm ee}$ and pair transverse momentum $p_{\rm T,ee}$ that was previously inaccessible at the LHC. The cross section for dielectron production is studied as a function of $m_{\rm ee}$, $p_{\rm T,ee}$, and event multiplicity ${\rm d} N_{\rm ch}/{\rm d} \eta$. The expected dielectron rate from hadron decays, called hadronic cocktail, utilizes a parametrization of the measured $\eta/\pi^0$ ratio in pp and proton-nucleus (p-A) collisions, assuming that this ratio shows no strong dependence on collision energy at low transverse momentum. Comparison of the measured dielectron yield to the hadronic cocktail at $0.15<m_{\rm ee}<0.6$ GeV/$c^2$ and for $p_{\rm T,ee} < 0.4$ GeV/$c$ indicates an enhancement of soft dielectrons, reminiscent of the 'anomalous' soft-photon and -dilepton excess in hadron-hadron collisions reported by several experiments under different experimental conditions. The enhancement factor over the hadronic cocktail amounts to $1.61\pm 0.13\,(\rm{stat.})\pm 0.17\,(\rm{syst., data}) \pm 0.34\,(\rm{syst., cocktail})$ in the ALICE acceptance. Acceptance-corrected excess spectra in $m_{\rm ee}$ and $p_{\rm T,ee}$ are extracted and compared with calculations of dielectron production from hadronic bremsstrahlung and thermal radiation within a hadronic many-body approach.

Where infall meets outflows: turbulent dissipation probed by CH+ and Lyα in the starburst/AGN galaxy group SMM J02399−0136 at z ∼ 2.8

ABSTRACT We present a comparative analysis of the $\rm CH^+$(1–0) and Lyα lines, observed with the Atacama Large Millimeter Array and Keck telescope, respectively, in the field of the submillimetre-selected galaxy SMM J02399−0136 at z ∼ 2.8, which comprises a heavily obscured starburst galaxy and a broad absorption line quasar, immersed in a large Lyα nebula. This comparison highlights the critical role played by turbulence in channelling the energy across gas phases and scales, splitting the energy trail between hot/thermal and cool/turbulent phases in the circumgalactic medium (CGM). The unique chemical and spectroscopic properties of $\rm CH^+$ are used to infer the existence of a massive (∼3.5 × 1010 M⊙), highly turbulent reservoir of diffuse molecular gas of radius ∼20 kpc coinciding with the core of the Lyα nebula. The whole cool and cold CGM is shown to be inflowing towards the galaxies at a velocity ∼ 400 km s−1. Several kpc-scale shocks are detected tentatively in $\rm CH^+$ emission. Their linewidth and specific location in space and velocity with respect to the high-velocity Lyα emission suggest that they lie at the interface of the inflowing CGM and the high-velocity outflowing gas. They signpost the feeding of CGM turbulence by active galactic nuclei- and stellar-driven outflows. The mass and energy budgets of the CGM require net mass accretion at a rate commensurate with the star formation rate. From this similarity, we infer that the merger-driven burst of star formation and black-hole growth are ultimately fuelled by large-scale gas accretion.

Topological Invariant for Bosonic Bogoliubov–de Gennes Systems with Disorder

Using the method of noncommutative geometry, we define a topological invariant in disordered bosonic Bogoliubov-de Gennes systems, which possess a unique mathematical property---non-Hermiticity. To demonstrate the validity of the definition, we investigate a disordered artificial spin ice model in two dimensions numerically. In the clean limit, we clarify that the topological index perfectly coincides with the Chern number. We also show that the topological index is robust against disorder. The formula provides the topological index $n_{\rm Ch}=1$ in the magnon Hall regime and $n_{\rm Ch}=0$ in a trivial localized one. We also show by example that our method can be extended to other symmetry classes. Our results pave the way for further studies on topological bosonic systems with disorder.

Strange hadron production in Au+Au collisions at sNN=7.7 , 11.5, 19.6, 27, and 39 GeV

We present STAR measurements of strange hadron ($\mathrm{K}^{0}_{\mathrm S}$, $\Lambda$, $\overline{\Lambda}$, $\Xi^-$, $\overline{\Xi}^+$, $\Omega^-$, $\overline{\Omega}^+$, and $\phi$) production at mid-rapidity ($|y| < 0.5$) in Au+Au collisions at $\sqrt{s_{_{\mathrm{NN}}}}$ = 7.7 - 39 GeV from the Beam Energy Scan Program at the Relativistic Heavy Ion Collider (RHIC). Transverse momentum spectra, averaged transverse mass, and the overall integrated yields of these strange hadrons are presented versus the centrality and collision energy. Antibaryon-to-baryon ratios ($\overline{\Lambda}$/$\Lambda$, $\overline{\Xi}^+$/$\Xi^-$, $\overline{\Omega}^+$/$\Omega^-$) are presented as well, and used to test a thermal statistical model and to extract the temperature normalized strangeness and baryon chemical potentials at hadronic freeze-out ($\mu_{B}/T_{\rm ch}$ and $\mu_{S}/T_{\rm ch}$) in central collisions. Strange baryon-to-pion ratios are compared to various model predictions in central collisions for all energies. The nuclear modification factors ($R_{\textrm{CP}}$) and antibaryon-to-meson ratios as a function of transverse momentum are presented for all collision energies. The $\mathrm{K}^{0}_{\mathrm S}$ $R_{\textrm{CP}}$ shows no suppression for $p_{\rm T}$ up to 3.5 $\mathrm{GeV} / c$ at energies of 7.7 and 11.5 GeV. The $\overline{\Lambda}$/$\mathrm{K}^{0}_{\mathrm S}$ ratio also shows baryon-to-meson enhancement at intermediate $p_{\rm T}$ ($\approx$2.5 $\mathrm{GeV} / c$) in central collisions at energies above 19.6 GeV. Both observations suggest that there is likely a change of the underlying strange quark dynamics at collision energies below 19.6 GeV.

Complications in the interpretation of the charge-asymmetry-dependent π flow for the chiral magnetic wave

The charge asymmetry ($A_{\rm ch}$) dependence of the $\pi^{-}$ and $\pi^{+}$ elliptic flow difference, $\Delta v_{2}(A_{\rm ch})$, has been regarded as a sensitive observable for the possible chiral magnetic wave (CMW) in relativistic heavy ion collisions. In this work, we first demonstrate that, due to non-flow backgrounds, the flow measurements by the Q-cumulant method using all charged particles as reference introduce a trivial linear term to $\Delta v_{2}(A_{\rm ch})$. The trivial slope can be negative in the triangle flow difference $\Delta v_{3}(A_{\rm ch})$ if the non-flow is dominated by back-to-back pairs. After eliminating the trivial term, we find that the non-flow between like-sign pairs gives rise to an additional positive slope to $\Delta v_{2}(A_{\rm ch})$ because of the larger dilution effect to $\pi^{+}$ ($\pi^{-}$) at positive (negative) $A_{\rm ch}$. We further find that the competition between different $\pi$ sources can introduce another non-trivial linear-$A_{\rm ch}$ term due to their different multiplicity fluctuations and anisotropic flows. We then study the effect of neutral cluster (resonance) decays as a mechanism for local charge conservation on the slope parameter of $\Delta v_{2}(A_{\rm ch})$. We find that the slope parameter is sensitive to the kinematics of those neutral clusters. Light resonances give positive slopes while heavy resonances give negative slopes. Local charge conservation from continuum cluster mass distribution can give a positive slope parameter comparable to experimental data. Our studies indicate that many non-CMW physics mechanisms can give rise to a $A_{\rm ch}$-dependent $\Delta v_{2}(A_{\rm ch})$ and the interpretation of $\Delta v_{2}(A_{\rm ch})$ in terms of the CMW is delicate.

Entropy production in pp and Pb-Pb collisions at energies available at the CERN Large Hadron Collider

We use experimentally measured identified particle spectra and Hanbury Brown-Twiss radii to determine the entropy per unit rapidity $dS/dy$ produced in $\sqrt{s} = 7$ TeV pp and $\sqrt{s_{\rm NN}} = 2.76$ TeV Pb-Pb collisions. We find that $dS/dy = 11335 \pm 1188$ in 0-10% Pb-Pb, $dS/dy = 135.7 \pm 17.9$ in high-multiplicity pp, and $dS/dy = 37.8 \pm 3.7$ in minimum bias pp collisions and compare the corresponding entropy per charged particle $(dS/dy)/(dN_{\rm ch}/dy)$ to predictions of statistical models. Finally, we use the QCD kinetic theory pre-equilibrium and viscous hydrodynamics to model entropy production in the collision and reconstruct the average temperature profile at $\tau_0 = 1$ fm/$c$ for high multiplicity pp and Pb-Pb collisions.

Canonical statistical model analysis of p−p , p -Pb, and Pb-Pb collisions at energies available at the CERN Large Hadron Collider

The system-size dependence of hadrochemistry at vanishing baryon density is considered within the canonical statistical model (CSM) with local exact conservation of three conserved charges, allowing for a possibility of strangeness undersaturation, i.e. $\gamma_S \leq 1$. Exact baryon number conservation is found to be even more important than that of strangeness in the canonical suppression picture at the LHC, in contrast to intermediate and low collision energies. The model is applied to p-p, p-Pb, and Pb-Pb data of the ALICE collaboration. A chemical equilibrium CSM with a fixed $T_{\rm ch} = 155$ MeV describes the trends seen in most yield ratios. However, this vanilla version of CSM predicts an enhancement of the $\phi/\pi$ ratio at smaller multiplicities, in stark contrast to the suppression seen in the data. The data are described with a 15% relative accuracy level whence a multiplicity dependence of both the temperature and the strangeness saturation parameter $\gamma_S \leq 1$ is accepted. Both the canonical suppression and the strangeness undersaturation effects are small at $d N_{\rm ch} / d\eta \gtrsim 100$, but they do improve substantially the description of hadron yields in p-p collisions, in particular the $\Omega$ yields. A possibility to constrain the rapidity correlation volume using net-proton fluctuation measurements is pointed out.

Dependence of static K DPAL performance on addition of methane to He buffer gas: 3D CFD modeling and comparison with experimental results

Recently it was observed that adding a small amount of methane to the He buffer gas of a static potassium diode pumped alkali laser (K DPAL) increases considerably the laser power. Further increase in the amount of methane leads to a moderate decrease in power. In the present work the effect of methane addition was investigated theoretically applying a 3D computational fluid dynamics (CFD) and potassium kinetics model, which was supplemented by the analysis of the electron temperature and K ion ambipolar diffusion. It was found that for a pure He buffer the K DPAL power is lower than for ${\rm He}/{{\rm CH}_4}$He/CH4 mixtures due to slow ion-electron recombination and high electron temperature exceeding 3000 K. The high electron temperature in pure He results in fast ambipolar diffusion of K ions to the wall and depletion of the neutral K atoms in the lasing region. These effects are mitigated when methane is added to the buffer gas. The calculated results for the normalized laser power are in satisfactory agreement with the experimental ones.

Two-component gas quartz-enhanced photoacoustic spectroscopy sensor based on time-division multiplexing of distributed-feedback laser driver current.

A two-component gas sensor in quartz-enhanced photoacoustic spectroscopy based on time-division multiplexing (TDM) technology of a distributed-feedback (DFB) laser driver current was proposed and experimentally demonstrated. The quartz tuning-fork-based photoacoustic spectroscopy (PAS) cell configuration with two optical collimators and two acoustic microresonators was designed to detect the second-harmonic (${2}f$2f) PAS signal. The two optical collimators guaranteed that the two laser beams would inject the PAS cell conveniently, providing higher power input than a 3 dB optical fiber coupler. Two-component gas sensing was achieved by the TDM of the DFB laser driver current. We used this two-component gas sensing technique to detect acetylene (${{\rm C}_2}{{\rm H}_2}$C2H2) at 1532.83 nm and methane (${{\rm CH}_4}$CH4) at 1653.722 nm. The ${{\rm C}_2}{{\rm H}_2}$C2H2 and ${{\rm CH}_4}$CH4 detection was achieved at a 2.4 s interval. The minimum detection limits of 1 ppmv for ${{\rm C}_2}{{\rm H}_2}$C2H2 and 13.14 ppmv for ${{\rm CH}_4}$CH4 were obtained, and the linear responses reached were 0.99968 and 0.99652 for ${{\rm C}_2}{{\rm H}_2}$C2H2 and ${{\rm CH}_4}$CH4, respectively. Moreover, the continuous monitoring of ${{\rm CH}_4}$CH4 and ${{\rm C}_2}{{\rm H}_2}$C2H2 for 40 min showed a good stability. The TDM technology of the DFB laser driver current would play an important role on the multi-component detection.